KENDRI

YAVI
DYALAYASANGATHAN,SILCHARREGI
ON
QUESTI
ONPAPER TERM-2
SUBJECT-CHEMISTRY(
043)
SET-
1
MM-
35 CLASS-XI TI
ME–2HOURS

GENERALI
NSTRUCTI
ONS:
Readt
hef
oll
owi
ngi
nst
ruct
ionscar
eful
l
y.

1.Thereare12questionsinthi
squestionpaperwithinternalchoice.
2.SECTIONA-Q.No.1t o3ar everyshortanswerquest i
onscar r
y i
ng2markseach.
3.SECTIONB-Q.No.4t o11ar eshortanswerquestionscar r
ying3mar kseach.
4.SECTIONC-Q.No.12i scasestudy-
basedquestioncar ryi
ng5mar ks.
5.All
questionsarecompulsory.
6.Useoflogt abl
eandcalculat
oriscompletel
yprohibit
ed.
SECTI
ON-A
Q1 i
) Wr
it
etheconj
ugat dofNH2-.
eaci 1

i
i
) Thesol
ubili
tyofFe(OH)3i
sxmol /L.WhatwouldbeKsp (sol
ubil
i
typr
oduct
). 1
Q2 Theconcentrat
ionofhydrogeni
oninasampl eofsoftdri
nkis 2
8X10-3M.Whati
3. sitspH?(Giv
enl og3.
8=0.58)
Q3 Whatdoy ouunderstandby(a)i
nertpai
reff
ect(b)al
l
otropy 2

SECTI
ON–B
Q4 Whati sani dealgas.Der i
vetheideal gasequat i
onPV=nRTusi ng 3
diff
erentgasl aws.
OR
Stateandexpl ainBoyle’slaw.Repr esentt helawgr aphi
call
y . 3
Q5 a) Whyar epot assium andcaesi um, r
athert hanlithi
um usedi nphotoel
ect
ri
c 1
cell
s?
b) Beryll
ium andmagnesi um donotgi v
ecol ourt ofl
amewher easother 1
al
kalineear thmet alsdoso.Why ?
c) Whyi sLi 2CO3 decomposedatal owert emper atur
ewher easNa2CO3 at 1
highertemper atur
e?
OR
Whathappenswhen
(i
)Sodi um met ali
sdroppedi nwat er? 1
(i
i)Sodium met alisheatedinf r
eesuppl yofai r
? 1
(i
ii
)Sodi um per oxidedissolvesinwat er? 1
Q6. Compar etheal kalimetalsandal kali
neear t
hmet alswit
hr espectto
(i
)ionizat i
onent halpy 1
 (ii
)basicityofoxides 1
(ii
i
)solubi l
ityofhydr
oxi
des. 1
Q7. (
a) StateLe- Chatli
erPri
nci
ple. 1
(
b) Whati stheef fectof
: ½
(i
) additi
onofH2 ½
(i
i) additi
onofCH3OH ½
½
(i
ii
) remov alofCO
(i
v) removal of CH3OH
ontheequi libr
ium

Q8. Howwi llyouconv ertbenzeneinto 

(
i) p- bromobenzene 1
(
ii
) t oluene 1
(
ii
i) acetophenone? 1
Q9. Giver easons:
(
i) Conc.HNO3  canbet ransport
edi nal uminum contai
ner. 1
(
ii
) Ami xtureofdi l
uteNaOHandal umi num piecesisusedtoopendr ai
n. 1
(
ii
i) Graphi teisusedasl ubri
cant. 1
OR
(
i) Di amondi susedasanabr asi
ve. 1
(
ii
) Al umi num al loy sareusedt omakeai r
craf
tbody . 1
(
ii
i) Alumi num ut ensil
sshoul dnotbekepti nwat erover
night. 1
Q10. Drawt heci s-andt r
ans-str
ucturesf orhex-2-
ene.Whichi somerwil
lhave 3
higherboi l
ingpoi ntandwhy ?
Q11. Whatar et hecondi t
ionsforacompoundt obear omat i
c,Giveoneexample 3
ofanar omat iccompound
OR
Q11 Explaint hef ollowingwi thexampl es:
(
i) Wur tzr eaction 1
(
ii
) Hy drogenat i
on. 1
(
ii
i) Mar koni kov ’
sr ule 1
SECTI ON–C( Casebasedquest i
on)
Q.
12 Readt
hef
oll
owi
ngpassageandanswert
hequest
ionst
hatf
oll
ow:
Wecanmeasur ethet ransferofheatf r
om onesy st
em t oanot herwhich
causesachangei ntemper ature.Themagni tudeofchangei n
temperaturedependsupont heheatcapaci tyoft hesubst ance.The
enthal
pychangeofr eactionr emai nsthesamei rrespect i
veoft henumber
ofstepsisHess’ slaw.Ithel pst ocalculatet heent halpyoff ormation,
combust i
on,andot herent hal pychanges.Ent halpychangecanal sobe
cal
culatedbyusi ngbondent halpi
es.Thef ir
stlawgi vest hel awof
conservati
onofener gybutdoesnotgi vet hedi r
ect i
onoft her eacti
on.The
secondlawst ates,theent ropyoft heuni ver seiscont inuouslyincreasi
ng
duetospont aneouspr ocessest akingpl acei nit
.ΔHandΔS( entr
opy
change)cannotdeci det hespont aneit
yoft heprocess.WeneedΔG( free
 energychange)whi chi s–v eforspont aneous, +vefornon- spontaneous.
ΔG=0f ort hepr ocessi nequi li
bri
um.ΔGi sr el
atedt otheequi l
ibri
um
constant.IfΔG=–v e,‘
K’ i
s+v eandv icev ersa.Thet hir
dl awof
ther
mody nami csst atestheent ropyofaper fectl
ycry st
allinesubst ancei
s
zeroatzer okel vi
n.
a) Hess'slawi sacor ollaryofthef i
rstl
awoft hermody nami cs.Comment . 1
b) Whichf actordeci dest hespont aneit
yofar eact i
on?Andwhatshoul dbe 1
i
tssignf oraspont aneouspr ocess
c) Explainwhyt heent ropyofapur ecrystall
inesubst anceiszer oat0K? 1
d) Predictinwhi choft hef ollowing,entropyincr eases/decr eases
i
)Al iqui
dcr y st
all
izesi ntoasol id 1
i
i)Temper atureofacr ystall
i
nesol i
di sraisedf rom 0Kt o115K 1
OR
d Forther eactionat298K, 2
2A+B→ C
–1
2kJK–1mol –1
ΔH=400kJmol and ΔS=0.
Atwhatt emper aturewi ll
ther eacti
onbecomespont aneousconsi deri
ng
ΔHandΔSt obeconst antov erthetemper aturer ange.

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