CHEMISTRY - Marking Scheme Osman Jayasinghe Revision 2022

(c) (i) wi;Hh (ii) wi;H

q e we.hSï mÍCIKh - Impression Assessment Test
wkqyr
(iii) i;H (iv) i;H (05 x 4 = 20)
(IAT - 02)
^c fldgig ,l=Kq 20&
Marking Scheme

02' (a) (i) A - K E - H 2O 2

A - fldgi - jHQy.; rpkd
B - K2SO4 F-S
01' (a) (i) Mg (ii) Al3+
C - H2(g) G - H2S
(iii) Ar (iv) N
D - KO2 (03 x 7 = 21)
(v) Be2+ (vi) O
(05 x 6 = 30)
(ii) K + ;'H2SO4 K2SO4 + H2
^a fldgig ,l=Kq 30&
K + O2 KO2
(c) (i) O H 2KO2 + 2H2O 2KOH(aq)+H2O2(aq)+ O2(aq)

H−N−C=C−C−C−H (06) H2(g) + S

∆
H2S(aq)

H H H H 2H2S + SO2 3S + 2H2O(05 x 5 = 25)

(iii)
(ii) 2𝑀𝑛𝑂4− + 5H2O2+6H+ 2Mn2++8H2O+5O2 (04)
O H O H
+ + 𝐶𝑟2 𝑂72− + 8H+ + 3H2S 2Cr3+ + 3S + 7H2O (04)
H−N=C−C=C−C−H H−N=C−C−C−C−H
^a fldgig ,l=Kq 54&
H H H H H H H H
(b) (i) 3H2 + N2 2NH3 (06)
(05 x 2 = 10)
(ii)I.2Na(s) + 2NH3(g) H2(g) + 2NaNH2(s)(05)
(iii) fyda
1 2 4 5
N C C C 6Li(s) + 2NH3(g) 2Li3N + 3H2(g)
I 4 3 4 4 fyda
II p;=ia;,Sh ;,Sh p;=ia;,Sh p;=ia;,Sh 3Mg(s) + 2NH3(g) Mg3N2 + 3H2(g)
;%sfldaKdldr
II. NH3 + 3Cl2 3HCl + NCl3
III ;%sfldaKdldr ;,Sh p;=ia;,Sh p;=ia;,Sh fyda
msróvh ;%sfldaKdldr 4NH3 + 3O2 6H2O + 2N2
3 2 3 3
fyda
IV sp sp sp sp 2NH3 + 3CuO 3Cu + N2 + 3H2O (05)
(01 x 16 = 16)
(iii)I. 2NH3 + 2Na 2NaNH2 + H2
1 3 2 2
(iv) N - sp C - sp
II. NH3 + HCl NH4Cl (05 x 2 = 10)
C2 - sp2 C3 - sp2
C3 - sp2 C4 - sp3 ^b fldgig ,l=Kq 26&

C4 - sp3 C5 - sp3 (01 x 8 = 08) (c)

(v) mrudKql
n 𝑙 𝑚𝑙
2p kquqyqï mrudKql ldCIslh
2p
ldCIsl md¾Yaúl I 3 0 0 −
w;sÉPdokh 𝜋
II − 2 − 3d
nkaOkh
III − − − 2p
2
sp uqyqï IV − − 0 4s
ldCIsl 2 f¾Çh w;sÉPdokfhka 𝜎 nkaOkh
(02 x 8 = 16)
ldCIsl j, yevh (ii) 2p < 3s < 3d < 4s (04)
ldCIsl kï lsÍu fyda
w;sÉPdok fmkaùu (02 x 5 = 10)
w;sÉPdok j¾.h III < I < II < IV
^b fldgig ,l=Kq 50&
nkaOk j¾.h ^c fldgig ,l=Kq 20&
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CHEMISTRY - Marking Scheme Osman Jayasinghe Revision 2022

𝑃𝑉 2𝑚𝑜𝑙
03' (i) 𝑍 = (04) (iv) HCl m%udKh = × 125𝑐𝑚3
𝑛𝑅𝑇 1000 𝑐𝑚 3

(ii) wvx.= n`ÿfka mßudj yd iei`§fï§ jdhqfõ = 0.25𝑚𝑜𝑙 (02)

mßudj fkd.sKsh yelsh' NaOH ujq, .Kk
jdhq wKq w;r wka;¾ wKql wdl¾IK n, = 2𝑚𝑜𝑙𝑑𝑚−3 × 125 × 10−3 𝑑𝑚3 = 0.25𝑚𝑜𝑙 (02)
fkdue;'
NaOH yd HCl 1:1 ujq, wkqmd;fhka m%;sl%shd jk ksid
jdhq wKq úúO fõ.j,ska p,kh fjñka mj;S'
0.25𝑚𝑜𝑙 i`oyd msgjk ;dmh = 14.175𝑘𝐽 (02)
^ksjerÈ ms<s;=rlg& (02 x 3 = 06)
1𝑚𝑜𝑙 i`oyd msgjk ;dmh = 14.175 × 4 𝑘𝐽 (02)
(iii) mSvkh wvqjk úg jdhqka tlsfkl wE;a jk
tka;e,ams úm¾hdih = −56.7𝑘𝐽𝑚𝑜𝑙−1 (02)
neúka jdhQka w;r wka;¾wKql wdl¾IK n,
ÿ¾j, fõ' (v) n`ÿka fol w;r isÿjk ;dmh ydksùu wju
tneúka ;d;aúl jdhq mßmQ¾K ;;a;ajhg ,`.d lsÍug'(03)
jk ksid Z ys w.h 1 g ióm fõ' (vi)
(01) (01) ∅
^ksjerÈ meyeÈ,s lsÍug 06& (01) ∆𝐻𝑓 (𝐶𝑂,𝑔) (01) (01)
C(s) + O2(g) CO(g) + ½ O2(g)
(iv) A - CO B - CH4 C - He (02 x 3 = 06)
𝑎
(v) 𝑃+ 𝑣 − 𝑏 = 𝑅𝑇 (04) ∆𝐻𝑐∅ (𝐶, 𝑠) ∆𝐻𝑐∅ (𝐶𝑂, 𝑔)
𝑣2
(01) (01) (01)
^a fldgig ,l=Kq 26& CO2(g)
(b) (i) 1𝑚𝑜𝑙 →
15
𝑚𝑜𝑙 = 7.5𝑚𝑜𝑙 (04) ∆𝐻𝑓∅ (𝐶𝑂, 𝑔) → 𝐶𝑂 j, iïu; W;amdok tka;e,amsh
2
4.54𝑔 ∆𝐻𝑐∅ (𝐶𝑂, 𝑔) → 𝐶𝑂(𝑔) j, iïu; oyk tka;e,amsh
(ii) 𝑇𝑁𝑇 ujq, .Kk = (02)
227 𝑔𝑚𝑜𝑙 −1
∆𝐻𝑐∅ (𝐶, 𝑠) → 𝐶(𝑠) j, iïu; oyk tka;e,amsh
= 0.02𝑚𝑜𝑙 (02)
^c fldgig ,l=Kq 36&
0.02
𝐶𝑂 m%udKh = × 7 𝑚𝑜𝑙 (02)
2

= 0.07𝑚𝑜𝑙 (02) 04' (a) (i)1. 2MNO3 2MNO2 + O2 (05)

∆
0.02
𝐻2 𝑂 m%udKh = × 5 𝑚𝑜𝑙 (02) 2. 2M(NO3)2 2MO + 4NO2 + O2 (05)
2 ∆
= 0.05𝑚𝑜𝑙 (02) (ii)
0.02
𝑁2 m%udKh = × 3 𝑚𝑜𝑙 (02) Be(NO3)2 < Mg(NO3)2 < Ca(NO3)2 < Sr(NO3)2 < Ba(NO3)2
2
(05)
= 0.03𝑚𝑜𝑙 (02)
(iii) fuys ish¿u legdhk wdfrdamKh +2 jk w;r
uq¿ jdhq ujq, .Kk= 0.07 + 0.05 + 0.03 𝑚𝑜𝑙 (02)
wekdhk wdfrdamKh −1 fõ' (02) kuq;a ldKavfha
= 0.15𝑚𝑜𝑙
my<g hk úg legdhkfha úYd,;ajh jeäfõ'(02)
𝑃𝑉 = 𝑛𝑅𝑇 (03)
8.314x105Pa x V = 0.15mol x 8.314Jmol-1K-1 x 600K(02) O%eùldrl yelshdj Be isg Ba olajd wvqfõ' (02)
Be2+ > Mg2+ > Ca2+ > Sr2+ > Ba2+ fõ'
𝑉 = 0.9 × 10−3 𝑚3
𝑉 = 9 × 10−4 𝑚3 (03) ∴ 𝑁𝑂3− whfha O%eùlrKh ldKavfha my<g hk

(iii) ldnka wxY= (04) úg wvqjk neúka (02) nkaOkfha whksl ,CIK

(iv) jdhqf.da,hg CO uqla; ù jdhq ¥IKh isÿùu' (04) jeä ùu (02) ksid ;dm ia:dhs;dj jeäfõ' (02)
(iv)
^b fldgig ,l=Kq 38&
(I) 6H++2𝑀𝑛𝑂4− + 5𝑁𝑂2− 2𝑀𝑛2+ + 5𝑁𝑂3− +3H2O(05)
(c) (i) (41.5−28)0C = 13.50C (02)
Ba(NO3)2 + H2SO4 BaSO4(s) + 2HNO3 (05)
(ii) 𝑄 = 𝑣𝑑𝑐∆𝑡 (03)
0.1×10
𝑄 = 250𝑐𝑚3 × 1𝑔𝑐𝑚 −3 × 4.2𝐽𝑔−1 0𝐶 −1 × 13.5 0𝐶 (03) (II) jeh jQ KMnO4 ujq, .Kk = (02)
1000
0.1 5
𝑄 = 14.175𝑘𝐽 (03) m%;sl%shd l, NaNO2 ujq, .Kk = × 10 × (02)
1000 2
(iii)  ødjK ñY% lsÍfï§ mßud úm¾hdihla isÿfkdfõ'
idïm,fha wvx.= jQ uq¿ NaNO2 ujq, .Kk
 fhdod.kakd ødjKj, úYsIag ;dm Odß;dj c,hg 0.1 5 100
= × 10 × ×
iudkfõ' 1000 2 25

^´kEu ksjerÈ lreKq 2la i`oyd& (02 x 2 = 04) = 0.01𝑚𝑜𝑙 (02)

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CHEMISTRY - Marking Scheme Osman Jayasinghe Revision 2022

idïm,fha wvx.= NaNO2 ialkaOh (ii)  ie,lsh hq;= wka;¾ wKql wdl¾IK n,
−1
= 0.01𝑚𝑜𝑙 × 69𝑔𝑚𝑜𝑙 (02) mej;Su' (03)
= 0.69𝑔 (02)  mßudj fkd.sksh yels ;rï ùu' (03)

(III) wjlafIam jQ BaSO4 ujq, .Kk (iii)  b;d wvq mSvk mej;Su' (03)
5.825 ×10 −2 𝑔
= (02)  b;d by< WIaK;ajh mj;ajd .ekSu' (03)
233 𝑔𝑚𝑜𝑙 −1

= 0.025 × 10−2 𝑚𝑜𝑙 (02) ^a fldgig ,l=Kq 22&

idïm,fha wvx.= Ba(NO3)2 ujq, .Kk (b) (i) tlsfkl m%;sl%shd fkdlrk jdhq ñY%Khl uq¿
mSvkh tla tla ix>Gl jdhqfõ wdxYsl mSvk j,
= 0.025 × 10−2 𝑚𝑜𝑙 (02)
tl;=jg iudk fõ' (10)
idïm,fha wvx.= uq¿ Ba(NO3)2 ujq, .Kk
100 (ii) 𝑃𝑉 = 𝑛𝑅𝑇 (02)
= 0.025 × 10−2 × (02)
25
𝐴 → 𝑃𝐴 𝑉 = 𝑛𝐴 𝑅𝑇 (02)
= 0.001𝑚𝑜𝑙
𝑃𝐵 𝑋 = 𝑛𝐵 𝑅𝑇 (02)
idïm,fha wvx.= uq¿ Ba(NO3)2 ialkaOh
𝑃𝑇 𝑉 = 𝑛 𝑇 𝑅𝑇 (02)
= 0.001𝑚𝑜𝑙 × 261𝑔𝑚𝑜𝑙−1 (02)
𝑛 𝑇 = 𝑛𝐴 + 𝑛𝐵 (02)
= 0.261𝑔 (02) 𝑃𝑇 𝑃𝐴 𝑉 𝑃𝐵 𝑉
= + (02)
𝑅𝑇 𝑅𝑇 𝑅𝑇
(IV) Ba(NO3)2 ujq, .Kk = 0.001
∴ 𝑃𝑇 = 𝑃𝐴 + 𝑃𝐵 (02)
NaNO2 ujq, .Kk = 0.01
^b fldgig ,l=Kq 24&
ujq, wkqmd;h = 1: 10 (03)
(c) (i) 𝑃𝑉 = 𝑛𝑅𝑇 (05)
^a fldgig ,l=Kq 60&
6𝑔 8.314 𝐽 𝐾 −1 𝑚𝑜𝑙 −1 ×300 𝐾
(b) i. Mn S H O 𝑃𝐻2 = × (05)
2𝑔𝑚𝑜𝑙 −1 831 .4×10 −6 𝑚 3
21.2 12.3 4.6 61.8
: : : (02) 𝑃𝐻2 = 9 × 106 𝑃𝑎 (05+01)
55 32 1 16

0.38 : 0.38 : 4.6 : 3.86 (02)

0.38
:
0.38
:
4.6
:
3.86
(02) (ii) 𝐻𝑒 i`oyd 𝑃𝑉 = 𝑛𝑅𝑇 fhdouq'
0.38 0.38 0.38 0.38
4𝑔
4.157 × 106 𝑃𝑎 × 𝑉 = × 8.314𝐽𝐾 −1 𝑚𝑜𝑙 −1 × 300𝐾(05)
1 : 1 : 12 : 10 (04) 4𝑔𝑚𝑜𝑙 −1

wdkqNúl iQ;%h = MnSH12O12 (04) 𝑉 = 6 × 10−4 𝑚3

𝑉 = 600𝑐𝑚3 (05+01)
ii. MnSO4.6H2O (05)
iii. +2 (05) (iii) 𝑃𝑉 = 𝑛𝑅𝑇
iv. 1s2 2s2 2p6 3s2 3p6 3d5 (03) uq¿ jdhq ujq, .Kk = 3𝑚𝑜𝑙 + 1𝑚𝑜𝑙
v. manganese(II) sulfate (03) = 4𝑚𝑜𝑙 (04)
vi. 𝑛𝑅𝑇 4𝑚𝑜𝑙 ×8.314𝐽 𝐾 −1 𝑚𝑜𝑙 −1 ×300 𝐾
O 𝑃= = (05)
𝑉 831 .4×10 −6 𝑚 3
− 𝑃𝑇 = 12 × 106 𝑃𝑎 (06+01)
O=S−O (05)
− (iv) 𝑃𝐻𝑒 𝑉 = 𝑛𝑅𝑇
O
1𝑚𝑜𝑙 ×8.314 𝐽 𝐾 −1 𝑚𝑜𝑙 −1 ×300 𝐾
𝑃𝐻𝑒 = (05)
vii. iqÿ mdg wjlafIamhla ,efí' (05) 831 .4×10 −6 𝑚 3

^b fldgig ,l=Kq 40& = 3 × 106 𝑃𝑎 (05+01)

(v) 𝐴 Ndckhg 𝑃𝑉 = 𝑛𝑅𝑇 fhdouq' ^oDV n`ÿkla ksid 𝑉
B - fldgi - rpkd ksh; fõ&
𝑃𝑉
05'(a) (i) 𝑃𝑉 = 𝑛𝑅𝑇 (05) 𝑛=
𝑅𝑇
𝑃 = mSvkh 𝑉 = mßudj 7.5 × 10 6 𝑃𝑎 × 831 .4 × 10 −6 𝑚 3
= (05)
8.314 𝐽 𝑚𝑜𝑙 −1 𝐾 −1 × 400 𝐾
𝑛 = ujq, .Kk 𝑅 = i¾j;% jdhq ksh;h
𝑛𝐻2 = 0.018𝑚𝑜𝑙 (06+01)
𝑇 = WIaK;ajh (05)
^c fldgig ,l=Kq 67&
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CHEMISTRY - Marking Scheme Osman Jayasinghe Revision 2022

(d) (ii)  N2O - fiñka r;a lsÍfuka NH4NO3 (02) /

wKql Nd.h (02) ∆
NH4NO3 N2O + 2H2O fyda (02)
T1 < T2
∆
T1 (05) NH4NO3 N2O
 NO - Cu, dill. HNO3 iu`. m%;sl%shd lrùu (02) $
T2 (05)
3Cu + dill. 8HNO3 3Cu(NO3)2 +2NO + 4H2O(02)
Cu + dill.HNO3 NO
−20 0 𝐶
 N2O3 - NO + NO2 N 2O 3
my<
(02)
WIaK;ajh
uOHkH fõ.h (02)
^d fldgig ,l=Kq 12&  NO2 - Cu, idkaø HNO3 iu`. m%;sl%shd lrùu (02) $
∆
(e) 𝑃𝑉 = 𝑛𝑅𝑇 — (1) (05) Cu. idkaø HNO3 NO2/Pb(NO3)2 NO2(02)
1 ∆
𝑃𝑉 = 𝑚𝑁𝐶 2 — (2) (05) 2Pb(NO3)2 2PbO + 4NO2 + O2
3
1 my< (02)
𝑛𝑅𝑇 = 𝑚𝑁𝐶 2 (05)  N2O4 - NO2 N2O4 (02)
3 WIaK;ajh
𝑀𝐶 2
(NO2 ixiaf,aIKh Èh hq;=h&
𝑛𝑅𝑇 = 𝑃4 𝑂10
3
3𝑅𝑇𝑛
 N2O5 - idkaø HNO3 N2O5 (02)
𝑀= fyda
𝐶2
3𝑅𝑇 P2O5(02)
𝐶2 = × 𝑛 (05)
𝑀 ´kEu ;=klg (02+02) x 3 = 12
3𝑅𝑇
jdhq ujq,hla i`oyd 𝐶2 = ×𝑛 (iii)
𝑀𝑛
3𝑅𝑇 ⊖ 2-
𝐶2 = (05) ⊕ ⊖ ⊕ ⊕ ⊕
𝑀
N≡N− O N=N= O N−N≡ O
^e fldgig ,l=Kq 25&
06' (a) (i) (04 x 3 = 12)

nyq,j wdï,sl$
Ndú;d (iv) NO, NO2 (04 x 2)
iQ;%h TlaislrK wxlh NdIañl$
jk
kï WodiSk isis,a lsÍu
iajNdjh NO N2O2

1 N2O +1 khsÜria Tlaihsâ $ WodiSk isis,a lsÍu

vhskhsg%cka fudfkdlaihsâ
NO2 N2O4

2 NO / +2 khsÜßla Tlaihsâ $ WodiSk isis,a lsÍu

NO + NO2 N2O3 / N2O4 / N2O2
N2O2 khsg%cka fudfkdlaihsâ
^´kEu M, folla ,l=Kq 08" M, tlla ,l=Kq 04&
3 N2O3 +3 v%hskhsÜrcka wdï,sl
^NO iy NO2 oaúhq.au ùug (dimerization) Ndckh fõ
g%fhdlaihsâ$ khsÜrcka
hhs ms<s.; yel' ,l=Kq 08 la m%odkh lrkak'&
g%fhdlaihsâ $khsÜrcka
^a fldgig ,l=Kq 60&
fiial=úTlaihsâ
vhskhsÜrcka wdï,sl (b) (i) Ca(OH)2, C2H2
4 N2O4/ +4
fgÜfg%dlaihsâ $ (ii) Mg(OH)2, NH3
NO2
khsÜrcka vfhdlaihsâ (iii) BiOCl , HCl
5 N2O5 +5 vhskhsÜrcka wdï,sl (iv) Al(OH)3, H2 (05 x 8 = 40)
fmkafgdlaihsâ $ ^b fldgig ,l=Kq 40&
khsÜrcka (c) (i) PV = nRT fhdouq'
fmkafgdlaihsâ 𝑃𝑉
n= (03)
𝑅𝑇
(01 x 20 = 20)
1.1×10 5 𝑃𝑎 ×1500 𝑚 3
= (05)
8.314 𝐽𝑚𝑜𝑙 −1 𝐾 −1 ×283 𝐾

𝑛 = 7.01 × 104 𝑚𝑜𝑙 (05+01)

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CHEMISTRY - Marking Scheme Osman Jayasinghe Revision 2022

𝑚
(ii) 𝑛 = = 0.1𝑚𝑜𝑙𝑑𝑚−3 (04)
𝑀

𝑀 =𝑛×𝑀 𝑆𝑂42− m%udKh = 0.004 − 0.001 𝑚𝑜𝑙 = 0.003𝑚𝑜𝑙 (04)

0.003
= 7.01 × 104 𝑚𝑜𝑙 × 29𝑔𝑚𝑜𝑙 −1 (04) 2−
𝑆𝑂4(𝑎𝑞 × 1000 𝑚𝑜𝑙𝑑𝑚−3
) =
10
𝑚 = 2.03 × 106 g (05)
= 0.3𝑚𝑜𝑙𝑑𝑚−3 (04)
(iii)50 K lska by< kexùug wjYH ;dmh
^b fldgig ,l=Kq 50&
= 50 x 2.03 x 106 J (05)
(c) (i)
= 1.015 x 108 J
6𝐻 + + 5𝑁𝑂2− + 2𝑀𝑛𝑂4− 5𝑁𝑂3− + 2𝑀𝑛2+ + 3𝐻2 𝑂 (02)
= 1.015 x 105 KJ (05)
𝐻2 𝑂 + 𝑂𝐻 + 𝑁𝑂2− + 2𝐴𝑙 2𝐴𝑙𝑂2− + 𝑁𝐻3 (02)
1.015 ×10 5 𝑘𝐽
wjYH C3H8 ujq, .Kk = (05)
2220 𝑘𝐽𝑚𝑜𝑙 −1 2𝐻2 𝑂 + 5𝑂𝐻 + 3𝑁𝑂3− + 8𝐴𝑙 8𝐴𝑙𝑂2− + 3𝑁𝐻3 (02)
= 45.7 mol (05)
wjYH C3H8 ialkaOh = 45.7 mol x 44 gmol-1 (05) 2𝑁𝐻3 + 𝐻2 𝑆𝑂4 𝑁𝐻4 2 𝑆𝑂4 (02)
= 2010.8 g (07) 𝐻2 𝑆𝑂4 +2𝑁𝑎𝑂𝐻 𝑁𝑎2 𝑆𝑂4 + 2𝐻2 𝑂 (02)
^c fldgig ,l=Kq 50&
3.16 25
(iii) jehjQ KMnO4 m%udKh= × 𝑚𝑜𝑙 (02)
155 1000
07'(a)(i) A - Na B - Na2CO3
0.02
C - BaCO3 D - CO2 = 𝑚𝑜𝑙
40
0.02 5
E - NaNO2 F - NH4NO2 𝑁𝑂2− m%udKh = × 𝑚𝑜𝑙 (02)
40 2
G - N2 H - Mg3N2 0.01
ødjK 31.25cm3 l 𝑁𝑂2− m%udKh = × 5 𝑚𝑜𝑙
I - NH3 40
0.01 250
(05 x 9 = 45) ødjK 250cm3 l 𝑁𝑂2− m%udKh = × 𝑚𝑜𝑙 (02)
8 31.25
(ii) D - yqKq Èhr mÍCIdj (02) 0.01 250
NaNO2 ialkaOh = × 𝑚𝑜𝑙 × 69𝑔𝑚𝑜𝑙−1
8 31.25
I - fkia,¾ m%;sldrlh u`.ska (03) 2.5×69
= 𝑔 = 0.6898𝑔 = 0.7𝑔 (03)
^a fldgig ,l=Kq 50& 8×31.25
0.2𝑚𝑜𝑙
jeh jQ NaOH m%udKh = × 32.5𝑐𝑚3
1000 𝑐𝑚 3
(b) H2O + 𝑆𝑂32− + I2 2𝐼 − + 𝑆𝑂42− + 2𝐻 + (05) = 6.5 × 10−3 𝑚𝑜𝑙 (03)
+4 0 -1 +6 6.5×10 −3
H2SO4 m%udKh = 𝑚𝑜𝑙
2
I2 + 2𝑆2 𝑂32− 𝑆4 𝑂62− + 2𝐼 −
(03)
= 3.25 × 10−3 𝑚𝑜𝑙 (03)
𝐵𝑎𝐶𝑙2 + 𝑆𝑂42− 𝐵𝑎𝑆𝑂4 + 2𝐶𝑙 − (02)
01
0.932𝑔 .;a uq¿ H2SO4 m%udKh = × 50 𝑚𝑜𝑙
𝐵𝑎𝑆𝑂4 m%udKh = 1000
233 𝑔𝑚𝑜𝑙 −1
= 5 × 10−3 𝑚𝑜𝑙 (03)
= 0.004𝑚𝑜𝑙 (04)
NH3 iu`. m%;sl%shd l< H2SO4 m%udKh
jeh jQ I2 m%udKh = 0.004𝑚𝑜𝑙 (04)
= 5 − 3.25 10−3 𝑚𝑜𝑙 (02)
m<uq wjia:dfõ§"
0.1𝑚𝑜𝑙 = 1.75 × 10−3 𝑚𝑜𝑙 (02)
jeh jQ 𝑆2 𝑂32− m%udKh = 3 × 30𝑐𝑚
3
1000 𝑐𝑚
NH3 m%udKh = 1.75 × 10−3 𝑚𝑜𝑙
= 0.003𝑚𝑜𝑙 (04)
= 3.5 × 10−3 𝑚𝑜𝑙 (02)
0.003
m%;sl%shd jQ I2 m%udKh = 𝑚𝑜𝑙(04) 0.01 25
2 𝑁𝑂2− u`.ska ,efnk NH3 m%udKh = × 𝑚𝑜𝑙
8 31.25
0.1𝑚𝑜𝑙
,nd.;a uq¿ I2 m%udKh = × 25𝑐𝑚3 0.25
1000 𝑐𝑚 3 = 𝑚𝑜𝑙
31.25×8
= 0.0025𝑚𝑜𝑙 (04)
= 1 × 10−3 𝑚𝑜𝑙 (02)
𝑆𝑂32− iu`. m%;sl%shd ù we;s I2 m%udKh
𝑁𝑂3− u`.ska ,efnk NH3 m%udKh
= 0.0025 − 0.0015 𝑚𝑜𝑙
= 3.5 − 1 10−3 𝑚𝑜𝑙 (02)
= 0.001𝑚𝑜𝑙 (04)
= 2.5 × 10−3 𝑚𝑜𝑙 (02)
𝑆𝑂32− m%udKh = 0.001𝑚𝑜𝑙 (04)
𝑁𝑂3− m%udKh = 2.5 × 10−3 𝑚𝑜𝑙 (02)
0.001
𝑆𝑂32− idkaøKh = × 1000 𝑚𝑜𝑙𝑑𝑚−3
10
5
CHEMISTRY - Marking Scheme Osman Jayasinghe Revision 2022

NaNO3 ialkaOh = 2.5 × 10−3 𝑚𝑜𝑙 × 85𝑔𝑚𝑜𝑙−1 (02) = 13.6 x 105Pa = 1.36 x 106 Pa (04)
= 0.2125𝑔 (03) ^a fldgig ,l=Kq 75&
^c fldgig ,l=Kq 50& (b) (i) 𝐶(𝑠) + 𝐻2 𝑂(𝑔) 𝐶𝑂(𝑔) + 𝐻2(𝑔)
∆𝐻𝑟𝜃 = Σ𝐻𝜃 M, − Σ𝐻𝜃 m%;sl%shl (03)
08' (a) ksh; WIaK;ajfha ksh; mßudjla ;=< mj;sk 𝜃
+131kJmol-1 = ∆𝐻𝐶𝑂(𝑔) + 𝑂(𝑔) (𝑂 + (−242) kJmol-1 (05)
mßmQ¾K jdhq ñY%Khla u.ska we;s lrkq ,nk 𝜃
∆𝐻𝐶𝑂(𝑔) = 131𝑘𝐽𝑚𝑜𝑙−1 − 242𝑘𝐽𝑚𝑜𝑙−1
iuia: msvkh ñY%Khg wh;a tla tla ixrpl jdhq
𝜃
;ks ;ksj ta ta mßudj, mj;sk úg we;s jk mSvk ∆𝐻𝐶𝑂(𝑔) = −111 kJmol-1 (05)
j, tl;=jg iudk fõ' (10)
fyda 3 −520 𝑘𝐽𝑚𝑜𝑙 −1
𝐶𝐻4(𝑔) + 𝑂2(𝑔) 𝐶𝑂(𝑔) + 2𝐻2 𝑂(𝑔)
mßmq¾K jdhq ñY%Khl ^tlsfkl iu`. m%;sl%shd 2

fkdlrk jdhq ñY%Khl& uq¿ mSvkh tla tla ∆𝐻𝑟𝜃 = Σ𝐻𝜃 M, − Σ𝐻𝜃 m%;sl%shl (03)
𝜃
jdhqfõ wdxYsl mSvkj, tl;=jg iudk fõ' (t.g) -520kJmol-1=-111kJmol-1+(2x-242kJmol-1)- ∆𝐻𝐶𝐻 4(𝑔)
+O(05)
𝜃
−520 = −111 − 484 − ∆𝐻𝐶𝐻 4(𝑔)
(ii) I. He mßudj = 9 - 0.686 dm3 = 8.314 dm3 (03) 𝜃
∆𝐻𝐶𝐻 4(𝑔)
= −75𝑘𝐽𝑚𝑜𝑙−1 (05)
𝑃𝑉 1×10 5 𝑁𝑚 −2 ×8.314 ×10 −3 𝑚 3
𝑛𝐻𝑒 = = (03+01)
𝑅𝑇 8.314 𝑁𝑚𝐾 −1 𝑚𝑜𝑙 −1 ×400 𝐾

= 0.25 mol (04+01) 𝐶𝐻4(𝑔) + 𝐻2 𝑂(𝑔) 𝐶𝑂(𝑔) + 3𝐻2(𝑔)

II. ∆𝐻𝜃 = Σ𝐻𝜃 M, − Σ𝐻𝜃 m%;sl%shl (03)
𝑃𝑉 1.56×10 6 𝑁𝑚 −2 ×8.314 ×10 −3 𝑚 3
1. uq¿ jdhq ujq, nT = = 𝜃
∆𝐻 𝜃 = ∆𝐻𝐶𝑂(𝑔) + ∆𝐻𝐻𝜃 2(𝑔) × 3 − ∆𝐻𝐶𝐻
𝜃
+ ∆𝐻𝐻𝜃2 𝑂(𝑔) (05)
𝑅𝑇 8.314 𝑁𝑚𝐾 −1 𝑚𝑜𝑙 −1 ×800 𝐾 4(𝑔)

(03+01) = −111 + 0 𝑘𝐽𝑚𝑜𝑙−1 − (−75 + (−242))𝑘𝐽𝑚𝑜𝑙−1

uq¿ jdhq ujq, ixLHdj = 1.95 mol (03+01) = +206𝑘𝐽𝑚𝑜𝑙−1 (05)
2. C(s) + H2O(g) CO(g) + H2(g)
wdrïNl 1.0 0 0 (01) ∆𝑆 𝜃
0
(ii) (I) 𝐶𝐻4(𝑔) + 𝐻2 𝑂(𝑔) 𝐶𝑂(𝑔) + 3𝐻2(𝑔)
527 C 1-x x x (01)
∆𝑆𝑟𝜃 = Σ𝑆 𝜃 M, − Σ𝑆 𝜃 m%;sl%shl (03)
uq¿ ujq, 1 - x + x + x = 1 + x
𝜃
1+x = 1.95 - 0.25 𝑆𝐶𝑂 + 𝑆𝐻𝜃2 × 3 − 𝑆𝐶𝐻
𝜃
4
+ 𝑆𝐻𝜃2 𝑂

1+x = 1.70 = (198 + (131 x 3)Jmol-1K-1 − (186+189) Jmol-1K-1(03)

x = 0.7 (04) = 591 − 375 Jmol-1K-1

H2O ujq, = 1 - 0.7 = 0.3mol (02) = +216 Jmol-1K-1

CO ujq, = H2 ujq, = 0.7 mol (02+02) = 0.216 kJ mol-1K-1 (05)

0.3
3. 𝑃𝐻2 𝑂 = × 1.56 × 106 𝑃𝑎 (03)
1.95
(II) ∆𝐺 𝜃 = ∆𝐻𝜃 − 𝑇∆𝑆 𝜃 (03)
= 2.4 x 105 Pa (02+01)
=206kJmol-1 − [298K × (+216 x 10-3)]kJmol-1 K-1 (05)
0.7 6
PCO = PH2 = × 1.56 × 10 𝑃𝑎 (03)
1.95 = 206 − (298 × (+216 × 10−3 )
5
= 5.6 x 10 Pa (02+01) = 206 − 64.368
0.25 6
𝑃𝐻𝑒 = × 1.56 × 10 𝑃𝑎 (03) =141.64 kJmol-1 (05)
1.95

= 2.0 x 105 Pa (04+01)

(III) (1) He m%;sl%shd fkdlrk neúka wdxYsl mSvkh fjkia (III) ∆𝐺 = Ok w.hla neúka m%;sl%shdj 298K § iajhxisoaO
fkdfõ' fkdjk nj (05)
5
(1) 𝑃𝐻2 𝑂 = 2.4 x 10 Pa (03) (iii) NH3 ksIamdokh $ fyan¾ l%uh jeks wjia:djla (05)
6
(2) PCO = 5.6 x 10 Pa (03) ^b fldgig ,l=Kq 75&
5
(3) 𝑃𝐻2 (𝑔) = 5.6 x 10 Pa (03)
(4) PT = 𝑃𝐻2 𝑂 + 𝑃𝐻2 + PCO
= 2.4 x 105 + 5.6 x 105 + 5.6 x 105 Pa
6
CHEMISTRY - Marking Scheme Osman Jayasinghe Revision 2022

09'(a) (i) wmf.a weig fmfkk" oDYH wdf,dalh yd wdkqNúl iQ;%h NaCO2 (04)
fkdfmfkk x lsrK" 𝛾 lsrK" UV, IR ;rx. yd
13.4𝑔
f¾äfhda ;rx.j, tl;=j fuf,i y`ÿkajhs' (05) (ii) ixfhda.fha ujq,sl ialkaOh = (04)
0.1𝑚𝑜𝑙
(ii) (1) C = 𝑣𝜆 (03) = 134𝑔𝑚𝑜𝑙 −1 (03)
3.0 ×10 8 𝑚𝑠 −1
∴𝑣= (05) wKql iQ;%h = ^wdkqNúl iQ;%h&n
325 ×10 −9 𝑚

iq¾hdf,dalfha ixLHd;h = 9.2 x 10 s (03+01) 14 -1 67 = 134 × 𝑛

134
𝑐 6.632 ×10 −14 𝐽𝑠 ×3.0×10 8 𝑚𝑠 −1 𝑛= = 2 (05)
(2) E = h𝜐 = h = (05) 67
𝜆 325 ×10 −9 𝑚

f*dafgdakhl Yla;sh = 6.1 x 10-19 J (03+01) wKql iQ;%h Na2C2O4 (04)

(3) f*dafgdak ujq,hl Yla;sh

(iii) O O
= 6.02214 x 1023 mol-1 x 6.1 x 10-19 J (03)
= 367.4 x 101 kJ mol-1 (03+01) O—C—C—O (07)
1.0 × 10 −3 𝐽
(4) f*dafgdak .Kk = (03)
6.1×10 −19 𝐽 26.8𝑔
(iv) Èh l< Na2C2O4 ujq, =
15 134 𝑔𝑚𝑜𝑙 −1
= 1.6 × 10 (02)
= 0.2𝑚𝑜𝑙 (04)
(iv) UV (02)
3
ødjKfha 25cm l we;s Na2C2O4 ujq,
^a fldgig ,l=Kq 40&
25
(b)(i) fojk uÜgu i`oyd 𝐸 = 𝑕𝜐 fhdouq' (03) = 0.2 × 𝑚𝑜𝑙
1000

𝐶 = 𝜐𝜆 (03) = 0.005𝑚𝑜𝑙 (04)

𝜐=
𝐶 𝐶2 𝑂42− 2𝐶𝑂2 + 2𝑒 — (1) (02)
𝜆
𝐶 𝑀𝑛𝑂4− +
+ 8𝐻 + 5𝑒 𝑀𝑛 2+
+ 4𝐻2 𝑂— (2) (02)
𝐸2 = 𝑕 × (03)
𝜆
(1) x 5 + (2) x 2,
−34 3×10 8 𝑚𝑠 −1
𝐸2 = 6.626 × 10 𝐽𝑠 × (03) 2𝑀𝑛𝑂4− + 16𝐻+ + 5𝐶2 𝑂42− 10𝐶𝑂2 + 2𝑀𝑛2+ + 8𝐻2 𝑂(03)
656 ×10 −9 𝑚

𝐸2 = 3.03 × 10−19 𝐽 (03) 𝑀𝑛𝑂4− : 𝐶2 𝑂42−

y;rjk uÜgu i`oyd 𝐸 = 𝑕𝜐 fhdouq' 2 : 5 (02)
3×10 8 𝑚𝑠 −1 ie'hq' ;=,s; whksl iólrKh muKla we;s úg o ,l=Kq 07
𝐸𝐴 = 6.626 × 10−34 𝐽𝑠 × (03)
434 ×10 −9 𝑚 fokak'
= 4.58 × 10−19 𝐽 (03) 2
∴ wjYH 𝐾𝑀𝑛𝑂4 ujq, = × 0.005𝑚𝑜𝑙
5
Yla;s uÜgï w;r fjki
= 0.002𝑚𝑜𝑙 (04)
= 4.58 − 3.03 × 10−19 𝐽 (03)
1000 𝑐𝑚 3
= 1.55 × 10−19 𝐽 (03+02) wjYH 𝐾𝑀𝑛𝑂4 mßudj = × 0.002𝑚𝑜𝑙 (04)
0.12𝑚𝑜𝑙

(ii) 𝐸 = 𝑕𝜐 = 16.66𝑐𝑚3 (04+01)

600𝑘𝐽𝑚𝑜𝑙−1 = 6.626 × 10−34 𝐽𝑠 × 𝜐 (03) ^c fldgig ,l=Kq 70&
600 𝑘𝐽𝑚𝑜𝑙 −1 /6.02214 ×10 23 𝑚𝑜𝑙 −1
𝜐= (03)
6.626 ×10 −34 ×10 −3 𝑘𝐽𝑠 MCQ IAT - 02
99.634 ×10 −23 𝑘𝐽 (1) 4 (11) 1 (21) 3 (31) 2 (41) 5
𝜐=
6.626 ×10 −34 ×10 −3 𝑘𝐽𝑠
(2) 2 (12) 2 (22) 1 (32) 3 (42) 4
𝜐 = 15.036 × 1014 𝑠 −1 (03+02)
(3) 4 (13) 2 (23) 4 (33) 1 (43) 5
^b fldgig ,l=Kq 40&
(4) 2 (14) 1 (24) 4 (34) 3 (44) 3
(c) (i) Na : C : O
(5) 4 (15) 3 (25) 3 (35) 1 (45) 1
ialkaO wkqmd; 34.32 : 17.92 : 47.76
(6) 3 (16) 5 (26) 1 (36) 5 (46) 2
34.32 17.92 47.76
ujq, wkqmd; : : (03)
23 12 16 (7) 3 (17) 4 (27) 1 (37) 2 (47) 3
1.492 : 1.493 : 2.985 (03) (8) 3 (18) 2 (28) 1 (38) 5 (48) 1
1.492 1.493 2.985
ir,u ujq, : : (03) (9) 4 (19) 5 (29) 2 (39) 4 (49) 4
1.492 1.492 1.492

wkqmd;h (10) 1 (20) 3 (30) 2 (40) 4 (50) 3

1 : 1 : 2 (04)
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CHEMISTRY - Marking Scheme Osman Jayasinghe Revision 2022