William&Airey (2004) Bringelly Shale
William&Airey (2004) Bringelly Shale
William&Airey (2004) Bringelly Shale
BRINGELLY SHALE
SUMMARY
This paper is concerned with the engineering behaviour of Bringelly Shale and how this can be assessed based on
laboratory index tests that are widely used for argillaceous rocks. Comparison will be made with data from Ashfield
shale to indicate the differences between these two members of the Wianamatta Group. It is shown that Bringelly shale
contains reactive clay minerals, absent in Ashfield Shale and, as a result, the shale is more sensitive to changes in
environmental conditions. Bringelly Shale is only weakly cemented and its strength and stiffness are lower than
Ashfield Shale. Both shales have similar unconfined compressive strengths, typically between 10 MPa and 50 MPa, but
in Bringelly Shale a large component of this strength appears to be derived from pore water suctions. When Bringelly
Shale is placed in water it disintegrates. The paper concludes with some implications of the data for construction in
Bringelly Shale.
1 INTRODUCTION
This paper is concerned with the shales of the Wianamatta group, known as Ashfield Shale and Bringelly Shale. These
shales outcrop over a large part of the Sydney metropolitan area as shown in Figure 1. Information on the geology of
these sediments has been reported in a number of studies and has been summarized in the Geology of the Penrith Sheet
(Jones and Clark, 1991). These studies have suggested that both these shales, and the Minchinbury Sandstone that lies
between them, were deposited in a single regressive episode during the Triassic age. The Ashfield Shale is comprised of
a sequence of dark-grey to black, sideritic claystone-siltstone which grades upwards into a fine sandstone-siltsone
laminite. The Bringelly Shale, which overlies the Ashfield Shale, is a more complex formation composed of different
lithologies, which in order of decreasing volumetric significance include: Claystone-Siltstone (70%), Laminite and
Sandstone (25%), Coal and highly carbonaceous claystone (3%) and Tuff (2%). The claystone units are composed of
several types of fine-grained sediments, namely light-grey leached claystone, dark-grey to black carbonaceous claystone
and non-carbonaceous mid to dark-grey claystone and siltstone. The different shale types are believed to reflect
different depositional environments, with the Ashfield shale deposited in a marine environment and the Bringelly Shale
deposited in an alluvial environment.
There is considerable debate about the post-depositional history of the shales in the Sydney Basin, with estimates for the
depth of over-lying sediments ranging from tens of metres to 4 km. Recently Bai et al. (2001) have suggested that the
Narrabeen group rocks were buried to a depth of about 3 km before rapid uplift and erosion of about 2 km of sediment
occurred with the Tasman Sea rifting in the mid-Cretaceous.
Ashfield Shale has been encountered in many engineering projects and consequently there is a range of data on basic
properties and engineering performance for this shale. However there is little information on the engineering geology of
the Bringelly Shale. Previous papers (Won, 1985; Chesnut, 1991) have suggested that the properties of the two shales
are similar. More recently it has been shown that there are significant differences in mineralogy and durability of the
two shales and differences in their engineering performance can be expected (William and Airey, 1999).
This paper will discuss basic laboratory characterization studies of the shales performed at Sydney University over the
last 10 years. Data will be provided on the mineralogy, micro-structure, durability, swelling, stiffness and strength of
the two shales. These studies have been limited to the claystone-siltstone materials which are the predominant lithology
in both shales. Large block samples and cores have been obtained from several locations, indicated on Figure 1, to give
a wide areal coverage and to investigate sample variability. Ashfield Shale samples have been obtained from sites at
Moorebank, Ryde, and Surry Hills. The Ashfield Shale samples all had a similar interbedded appearance with frequent
very thin light grey silty bands in dark grey siltstone. Samples of Bringelly Shale have been obtained from quarries used
to extract shale for brick manufacture at Kemps Creek, Badgerys Creek, Horsley Park and Mulgoa. The shale from all
these sites could be described as a non-carbonaceous mid to dark-grey claystone. For both shales the data base has been
widened by information supplied by several other organisations.
H
M
B K 1 2
1 Moorebank
2 Surry Hills
3 Ryde
M Mulgoa
B Badgerys Creek
K Kemps Creek
H Horsley Park
2 CLAYSTONE-SILTSTONE PROPERTIES
2.1 MINERALOGY
The types and quantities of the various clay and other minerals comprising shale can have a significant influence on the
engineering behaviour. Herbert (1979) has reported clay mineral contents between 40% and 65% for the claystone-
siltstone materials in the Ashfield and Bringelly Shales, with a trend towards higher clay content in Bringelly Shale. For
the samples from the sites discussed above, Ashfield Shale was found to have an average clay mineral content of 43%
compared with 51.5% for Bringelly Shale. The other major constituents are shown in Table 1. The ranges for the
amounts of clay minerals, shown in Table 1, are relatively small and lie within the range previously reported by Herbert
(1979). In both shales quartz is the main non-clay mineral with significant amounts of siderite in Ashfield Shale and
feldspar in Bringelly Shale. Organic carbon content was measured for the Bringelly Shale, as organic matter appears to
contribute to cementation, but for Ashfield Shale this has not been determined as organic matter appears to be
negligible. One important difference between the two shales is the amount of siderite present.
Table 1: Mineral composition of fresh Wianamatta Group Shales.
Clay minerals Quartz (%) Siderite (%) Feldspar(%) Organic
(%) matter (%)
Ashfield Shale 43 (41-45) 47 10 0 ?
Bringelly Shale 51.5 (48-55) 38 3 6 1.5
Petrographic studies, comprising optical microscopy and scanning electron microscopy, have been used to investigate
the microstructure and nature of cementation in the Wianamatta Group shales. In Ashfield Shale siderite, which is
widely dispersed through the shale, acts as the primary cementing agent, while mica acts as a secondary cementing
agent. In Bringelly Shale siderite, organic matter and some recrystallisation of mica could contribute to cementation, but
none of these mechanisms is well developed and cementation is expected to be weak.
The distribution of the clay minerals within the shales was investigated by X-ray diffraction. Very similar distributions
were obtained from all samples and all sites and average values of our results are presented in Table 2.
Table 2: Percentages of the various clay minerals.
Ashfield Shale Bringelly Shale
Fresh Fresh Extremely Weathered
Kaolin 56 33 30
Illite-Smectite 40 55
Montmorillonite 2.5
Illite 44 21 12.5
Chlorite 6
Table 2 shows that there are very significant differences in the clay mineralogy of the two shales. The main difference is
the large amount of mixed layer, illite-smectite, in the Bringelly Shale. Mixed layer clays have properties intermediate
between illite and smectite and thus the shale can be expected to be reactive, susceptible to swelling and changes in pore
fluid chemistry. A previous study (Loughnan, 1960) also reported mixed layer clay minerals, but these only comprised
20% of the clay fraction. The greater amounts of mixed layer clay detected in this study could be the result of
improvements in analytical techniques or may reflect variability in the shale. For the Bringelly Shale additional tests
were performed on extremely weathered material from the four quarry sites and these indicated weathering is associated
with changes in mineralogy. It was found that chlorite and some illite had been broken down, with a corresponding
increase in mixed layer clay minerals and a small montmorillonite fraction forming. These changes will tend to increase
the reactivity of the residual soil compared to the parent shale. This trend is evident in the liquid limit of the crushed
shale which increases from 30 for fresh shale to over 50 for extremely weathered shale. In practice residual soils
developed over the Bringelly Shale are suspected to be relatively old as they are commonly leached and laterised so that
they are not as reactive as might be expected. Chesnut (1991) notes that soils derived from Bringelly Shale can show
significant effects from the presence of expansive clays and the problem is most acute on moderate slopes where the
soils are younger and show less evidence of laterisation. Tests were not performed on the extremely weathered Ashfield
Shale but it is suspected that even if the illite component breaks down, the amount of reactive clay minerals in the
residual soil will be considerably less than for soils derived from Bringelly Shale.
The differences in clay mineralogy are surprising as the accepted wisdom is that the two shales were deposited
contemporaneously with the same source material (e.g. Herbert, 1979). The differences in mineralogy cannot be easily
explained from differences in depositional environment or diagenesis as the estimated maximum sediment burial is
insufficient to lead to significant mineral alteration. Thus it is believed that the Bringelly Shale must have had some
different source material to the Ashfield Shale.
For Ashfield Shale the microscope studies show that silt-sized quartz particles are present in a clay matrix and that
siderite is widely distributed. The shale is highly compacted and this has led to a strong alignment of the clay particles.
A similar structure is observed for the Bringelly Shale, however in Bringelly Shale siderite is less significant and planar
micro-cracks are observed in the horizontal plane, associated with the clay particle alignment. These micro-cracks are
more prevalent in samples with higher porosity and in weathered samples. The extent to which these micro-cracks have
been influenced by stress-relief on coring is unclear, but they do support the idea that cementation is weak in Bringelly
Shale. In contrast no micro-cracks are evident in the Ashfield Shale.
Both shales have low porosities of between 5% and 12%. However, there is no evidence of any induration of the voids
with any cementing agent other than siderite mentioned above. It follows that the low porosities are primarily a
consequence of compaction. As noted previously there is some debate about the amount of sediment deposited on top of
the shale, and this has been estimated at between 2000 m and 4000 m in some recent studies (Stewart and Adler, 1995,
Bai et al., 2001). An estimate of the stress required to produce the observed porosity has been obtained by crushing the
Bringelly Shale, reconstituting the material to create a slurry, and then subjecting the slurry to high confining pressures
in a triaxial cell. The isotropic compression response, shown in Figure 2, indicates an effective confining stress of about
60 MPa is required to produce a porosity of 10%, similar to the natural material. The isotropic compression response of
natural shale is shown for comparison. An effective stress of 60 MPa would require burial depths of the order of 3km to
4km, which is consistent with previous estimates based on geological observations, e.g. Bai et al. (2001).
0.7
0.6
Reconstituted
0.5
Natural Shale
void ratio, e
0.4
0.3
0.2
0.1
0
10 100 1000 10000 100000
mean effective stress, p' (kPa)
100
Ashfield
80 Bringelly
Slake durability Index
60
40
20
0
1 2 3 4
Degree of weathering
Figure 3: 2-cycle slake durability index for different degrees of weathering (1=fresh, 4 = extremely weathered).
To investigate the mechanisms responsible for the slaking of the shales further tests were performed to assess the free
swell potential and the influence of pore fluid chemistry on the swelling of the shale. Figures 4 and 5 show some typical
results. Figure 4 shows strains for a period of 1 day in free swell tests on small cubes (3 cm×3 cm×3 cm) of the two
shales immersed in tap water. For Ashfield Shale the strains were isotropic and small and no further deformation was
observed for a further 5 days after which the test was terminated. For Bringelly Shale, much larger volumetric swelling
strains were measured. Deformation ceased after a few hours until after about 36 hours the sample lost its integrity with
some clay dispersing into the water. Figure 6 shows the effect of 48 hours immersion in water on a cylindrical sample.
Figure 4 shows that much greater swelling strains are measured for Bringelly Shale than Ashfield Shale and that for the
Bringelly Shale the strains are anisotropic, developing predominantly in the vertical direction. As noted previously
Bringelly Shale samples have horizontal micro-cracks and opening of these cracks could explain the greater vertical
strains. Other possible reasons for the difference in the behaviour include swelling due to a reduction in effective stress
associated with a reduction in pore water suctions and osmotic effects due to differences in chemistry of pore fluid and
swelling liquid. The results shown in Figure 4 are typical of swelling tests on Bringelly Shale, however the magnitude
of the swelling strain increased as sample dimensions decreased. The influence of sample size on the swelling of
Bringelly Shale is believed to result from the opening up of micro-cracks during specimen preparation. If this is the case
the amount of swelling in fresh shale exposed to water may be expected to depend on the excavation procedure.
10
Bringelly, vertical strain
Bringelly, lateral strain 1
8
Bringelly, lateral strain 2
Bringelly, volume strain
6 Ashfield, volume strain
strain (%)
0
1 10 100 1000 10000
time (mins)
Figure 4: Strains during free swell tests on cuboidal samples immersed in tap water.
10
water
CaCl2 solution
8 NaCl solution
volume strain (%)
KCl solution
6
0
1 10 100 1000 10000
time (mins)
Samples of both shales were obtained from locations above the groundwater table. It was found that Ashfield Shale
samples were close to being fully saturated, whereas Bringelly Shale samples had variable degrees of saturation from 50
to 80%. Tests on Bringelly shale from two sites indicated very high total suctions of 150 MPa (6.2 pF). Differences
between the shales are related to the presence of micro-cracks which are assumed to facilitate drainage from, and allow
air entry to, the Bringelly Shale. The very low porosity and clay fabric ensure relatively high degrees of saturation in
both shales. The large suction in Bringelly shale will contribute to the swelling when samples are immersed in water
and, as discussed further below, enhance the strength and stiffness of the in-situ shale.
Previous studies of groundwater in Bringelly Shale have indicated that the water is generally saline and unsuitable for
water extraction (PPK, 1999). Salinities between 5000 and 26000 ppm were reported by PPK. The pore fluid extracted
from one sample indicated a salinity of 1760 ppm, much less than the values in the groundwater.
Because of the presence of reactive mixed layer clays in the Bringelly Shale it can be expected that changes in pore
fluid will contribute to volume changes. Figure 5 shows the results of free swell tests with Bringelly Shale in a range of
pore fluids with 1 molar concentrations. Tap water and CaCl2 cause the most swelling and significant deterioration
occurs as shown in Figure 6. The least swelling occurs with the potassium chloride solution, and no deterioration
occurred when the shale was left in this solution for several days. This is expected as potassium muds are widely used
to ensure hole stability in reactive clay shales. The trends in Figure 5 are consistent with double layer interactions, and
demonstrate the importance of pore fluid chemistry in controlling the magnitude of any swelling strains. However, the
relative contributions of suction and osmosis to the swelling cannot easily be determined from these tests as the NaCl
concentration used was 58000 ppm, which was much higher than the pore water concentration.
3 STRENGTH
samples compared to Ashfield Shale, for which all samples were close to full saturation. As discussed further below the
apparent similarity of the two shales obscures some important differences in the mechanisms leading to their strengths.
One of the difficulties with obtaining UCS data for Bringelly Shale is that core recovery is low, and thus the number of
samples suitable for UCS testing is limited. This may have the result that only the more cemented material is tested and
the strength is over-predicted.
Because of the difficulty of performing UCS tests there is a widespread practice of relying on point load index tests and
relating these to a UCS value on the basis of an empirical correlation. Comparisons between the UCS strength and the
axial point load index are shown in Figure 8. Ghafoori (1995) has shown that the relation for Ashfield Shale is given by
UCS = 24 Isa(50). For Bringelly Shale the relation shown in Figure 8 can be described by UCS = 21 Isa(50). It should be
noted that the data is very limited and as mentioned above may be being biased towards more cemented material.
60
Uncofined compressive strength (MPa)
50
40
Ashfield
30
Bringelly
20
10
0
0 2 4 6 8 10
Moisture content (%)
Figure 7: Comparison of UCS versus moisture content for Ashfield and Bringelly Shales.
80
Unconfined Compressive Strength (MPa)
70 Bringelly
Ashfield
60
50
40
30
20
10
0
0 0.5 1 1.5 2 2.5 3
Axial point load strength, Isa(50) (MPa)
For Ashfield shale a number of direct shear tests have been reported by Ghafoori et al. (1993b). These indicated shear
strengths on the horizontal plane, aligned with the silty bands of about 2 MPa, whereas the strength perpendicular to the
laminations was about 4 MPa. This is consistent with the strength anisotropy index determined in the point load index
tests.
20000
Deviator stress (kPa)
15000
10000
Saturated
5000
Natural moisture content
0
0 2 4 6 8
Confining stress (MPa)
Natural moisture
20000 20000 Natural moisture content
content
Saturated shale Reconstituted shale
Saturated shale
15000 15000
Deviator stress (kPa)
5000 5000
0 0
0 0.01 0.02 0.03 0.04 0.05 0 0.02 0.04 0.06 0.08
Axial strain Axial strain
Figure 10 Stress, strain responses from triaxial tests, (a) confining stress = 1 MPa, (b) confining stress = 6 MPa
Because the cementation appears to be weak and because of the difficulty of obtaining large enough samples for triaxial
testing, specimens of Bringelly Shale were reconstituted by breaking down the shale and reconstituting it with water. A
series of standard drained and undrained triaxial tests were performed on saturated specimens with over-consolidation
ratios up to 10 with a maximum effective confining stress of 1 MPa. These gave results consistent with many other
reconstituted materials and a normalized response as shown in Figure 11. The ultimate or critical state friction angle
estimated from these tests is 28.5o. Tests were performed in shear box and ring shear apparatus and these also indicated
a residual friction angle of about 28o. This was much greater than the friction angle of 16.5o determined from tests on
the saturated shale. In order to investigate whether this behaviour was a consequence of a low void ratio, the
reconstituted material was isotropically compressed to an effective pressure of 60 MPa at which the void ratio was 0.1,
similar to the natural shale. Tests were performed on normally and over-consolidated specimens with this pre-
consolidation stress.
that for the natural shale. Figure 10b also shows that the differences between the intact shale and the reconstituted
material are relatively minor when the confining stress reaches 6 MPa. This is another indication that the cementation is
relatively weak in this material and that strength is controlled mostly by frictional effects.
A related study, concerned with the behaviour of highly plastic intensely fissured clay shales from Italy, has been
presented by Picarelli et al. (1998, 2003). Picarelli et al. show that the normalized failure surface of their intact shale
lies below the surface for the reconstituted material tested at higher density and lower pre-consolidation stresses.
Picarelli et al. interpreted the difference in behaviour as evidence of the effects of fissuring in the natural soil, and
suggested a mechanism where deformation and strength are controlled by movements along joints and fissures. They
also noted that OCR did not seem to significantly affect the strength. The results presented in Figures 9 to 11 show the
same pattern of behaviour as reported by Picarelli et al. The observation that the reconstituted shale also has a low
frictional resistance suggests that in addition to fissures, the fabric associated with the low porosity, created by the high
stress, is also contributing to reduced strength and different deformation mechanisms. At low porosity there must be
locally a high degree of alignment of the plate-like clay particles. It is possible that failure surfaces could develop that
pass through regions where the particles are highly aligned.
The mechanism suggested is illustrated in Figure 12 and is identical to that proposed by Picarelli et al. (1998) for their
fissured shale. The effective friction angle is controlled by the interparticle friction angle between the particles, φµ, and
the effective dilation angle, which will depend on the roughness of the failure surfaces. It is postulated here that this
mechanism is controlling the behaviour of the low porosity reconstituted material even though fissures are not present.
The natural Bringelly shale has a very low porosity, similar to that produced by the high stresses in this study. In
addition it has significant micro-cracking in the plane of the laminations. At confining stresses of 6 MPa and above
there is no difference in the ultimate friction angles of the reconstituted and natural material. It is possible that tests on
natural shale cores oriented at other angles to the vertical may show even lower frictional strengths when failure
surfaces are aligned with the micro-cracks.
Figure 12: Mechanism of shear deformation and rupture (after Picarelli et al., 1998).
4 STIFFNESS
For Ashfield Shale estimates of modulus were obtained from strain gauges stuck to the shale specimens. For Bringelly
Shale the lack of suitably sized samples has meant that only external measurements of deformation have been obtained,
and the values are expected to under-estimate the true stiffness of the shale. Consequently, they cannot be directly
compared with values reported for Ashfield Shale.
Ghafoori (1995) showed that the stress, strain response of the Ashfield Shale was consistent with a cross anisotropic
material with a ratio between modulus in the plane of the laminations and in the plane perpendicular to the laminations
of 3. Young’s modulus for specimens tested perpendicular to the laminations varied from 3 GPa to 7 GPa in uniaxial
compression and these values increased with increasing confining stress according to a power law of the form
n
E σ
= A 1 + 3 (3)
pa pa
where A and n are constants. It is believed A depends on moisture content in a similar way to UCS but insufficient data
are available to provide a useful relation: n = 0.035 from available data.
Table 3 shows values of E50 determined from tests on intact and reconstituted Bringelly Shale. These values are about
an order of magnitude lower than those recorded for the Ashfield Shale. It may be noted that at a confining stress of 6
MPa, where direct comparison is possible, the stiffness of the reconstituted and natural shales are similar. These
observations are consistent with the weaker cementation in the Bringelly Shale. The highest stiffness is indicated for the
shale at the natural moisture content at low confining stress where pore water suctions are most significant.
Table 3: Values of E50 determined from tests on natural and reconstituted Bringelly Shale.
Effective confining Shale at natural moisture Shale saturated Reconstituted,
stress content void ratio = 0.1
(MPa) (MPa) (MPa) (MPa)
0 2300 - -
1 1500 738 -
6 751 823 627
60 - 2800 1500
5 DISCUSSION
Both Ashfield and Bringelly Shale have very low porosity and similar unconfined strengths, but in almost all other
aspects there are significant differences between the two materials. Bringelly Shale is comprised of mixed layer clay
minerals which have greater potential for swelling and physico-chemical changes than the clay minerals in Ashfield
Shale. Bringelly Shale contains less siderite than Ashfield Shale in which siderite acts as an effective cementing agent.
Weak cementation may be present in Bringelly Shale but this is difficult to detect with certainty in the laboratory. This
leads to poor core recovery, particularly when water is used as drilling fluid, as the shale can swell and disintegrate
when the confining stress is removed by coring. When exposed to the atmosphere Bringelly Shale degrades more
rapidly than Ashfield Shale.
An important factor controlling the strength and stiffness of Bringelly Shale appears to be pore water suction. Despite
reasonably high degrees of saturation the shale has a very high total suction. When the shale is saturated some of this
strength and stiffness is lost. As the ground-water table is located at depths of 20 to 40 m over much of Western
Sydney, when Bringelly Shale is encountered in construction it is likely to be unsaturated. Some caution is
recommended, therefore, if it is proposed to use high UCS values and stiffnesses in foundation design.
This study has been limited to the claystone-siltstone materials that comprise the majority of the Wianamatta group
shales, and has only considered the intact rock properties. The influence of joints and fissures has not been considered.
Within these limitations some general observations can be made concerning the implications of these results for
construction on and with these shales.
1. There are significant differences in the engineering behaviour of Ashfield Shale and Bringelly Shale, and
identification of the shale type should be required before construction.
2. Bringelly Shale, and residual soils derived from it, contain reactive swelling clay minerals. Construction on
residual soil will require special attention, particularly where the soils have not been affected by laterisation.
3. Removal of residual soil to found structures on the underlying shale will not eliminate ground movements
because Bringelly Shale has the potential to swell if water is provided to it and stress levels are low.
4. High strength and stiffness derive in part from pore water suction. These values cannot be relied upon if
environmental conditions change.
5. Use of Bringelly Shale as a fill material is not recommended as it deteriorates rapidly in the presence of water
and is prone to swelling.
6 ACKNOWLEDGEMENT
This work has been funded in part by an ARC project investigating the behaviour of structured soils. The authors are
grateful for the supply of samples, data and equipment from the following organizations: NSW RTA, Coffey
Geosciences, Douglas Partners, Jeffery & Katauskas, UNSW, CSIRO.
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