Chemistry Vol.2 Figures Class 12

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Chapter Name

Haloalkanes and Haloarenes


Alcohol and Phenols
Aldehydes, Ketones and Carboxylic Acids
Amines
Biomolecules
Polymers
Chemistry in Everyday life
CHEMISTRY CLASS 12 VOLUME 2 LIST OF FIGURES
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EMISTRY CLASS 12 VOLUME 2 LIST OF FIGURES (316)
Name of the Figure

Mono haloalkane
Dihaloalkane
Trihaloalknae
Monohaloarene
Dihaloarene
Trihaloarene
Primanry Secondary and Tertiary Alkyl Halides
Alliylic Haides
Benzyllic Halides
Vinyl Halides
Aryl Halides
N Propyl Bromide
Isopropyl Chloride
Isobutylchloride
Bromobenzene
MDibrormobenzene
Sym Tribromobenzene
1Chloro2,2Dimethylpropane
2Bromopropane
1,1Dichloroethane
1,2 Dichloroethane
Addition of hydrogen halides:
Free Radical Halogenation
Addition of Halogens
Finkelstein Reaction
Swarts Reaction
Preaparatin of Haloarenes
Sandmeyers Reaction
Comparision of Boiling Point of Some Alkyl Halides
Nucleophilic substitution reactions
Subsitution Nucleophile Bimolecular
Red Ball represents the incoming hydroxide ion and green ball repres
Steric effects in SN2 reaction. The relative rate of SN2 reaction is giv
Substitution nucleophilic unimolecular (SN1)
Some common examples of chiral and achiral objects
B is mirror image of A; B is rotated by 180o and C is obtained; C is su
E is mirror image of D; E is rotated by 180o to get F and F is non sup
A chiral molecule and its mirror image
Retention:
Inversion, retention and racemisation:
Wurtz reaction
Resonance effect
Difference in hybridisation of carbon atom in C—X bond:
Replacement by hydroxyl group
Electrophilic substitution reactions
Halogenation
Nitration
Sulphonation
Friedel-Crafts reaction
Wurtz-Fittig reaction
Fittig reaction
DDT
Monohydric Alcohols
Dihydric Alcohols
Trihydric Alcohols
Allylic alcohols:
Benzylic alcohols:
Phenol Mono Di Tri Alcohol
Cyclohexanol
2-Methylcyclopentanol
Phenol
o-Cresol
m-Cresol
p-Cresol
Catehol
Resorcinol
Quinol
Methanol
Phenol
Methooxymethane
acid catalysed hydration
Mechanism of acid catalysed hydration
By hydroboration–oxidation
By reduction of aldehydes and ketones
By reduction of carboxylic acids and esters:
By Grirands Reagents
From haloarenes
From benzenesulphonic acid
From diazonium salts
From cumene
OH Bonding in Alcohols and Phenols
Ethanol
Methoxymethane
Propane
Diagram opposide to Solubility Topic
Alcohol as Nucleophiles
Pronated Alcohol as Electrophile
Reaction with metals
Acidity of alcohols
Acidity of phenols
Esterication
Acteylation of Saliyic Acid
Reaction with Hydrogen Halides
Reaction with Phosphorous Trihalides
Dehydration
Mechanism of dehydration
Oxidation
Electrophilic aromatic substitution nirtion
Picric Aicid Production
Halogenation
Kolbes Rwaction
Reimer Tiemann Reaction
Reaction of phenol with zinc dust
Prodcution of Benzoquione
Methanol ReCTION
Ethanol Reaction
Ethers Prepared by Dehydration of Alchol
Willamson Synthesis
Cleavage of CO Bond in Ethers
Halogenation
Fiedel Crafts Reaction
Nitration
Vanillin
Salicylaldehyde
Cinnamaldehyde
Acetaldehde
Benzaldehyde
B-Bromobutryraldehyde
Acetone
Acetopheone
Propiophenone
Benzophenone
Ethanol
4Bromo3Methylheptanal
3Methylcyclopentanone
Pent2enal
1phenylpropan1one
Cyclohexanecabaldehyde
3oxopental
24dimenthylpentan3one
4nitrobenzaldehyde
Propan123tricarbaldehyde
Orbital diagram for the formation of carbonyl group
Preparation of Aldehydes From acyl chloride (acid chloride)
From nitriles and esters
By oxidation of methylbenzene
Use of chromic oxide (CrO3 ):
By side chain chlorination followed by hydrolysis
By Gatterman – Koch reaction
From acyl chlorides Preparation of Ketones
From nitriles
From benzene or substituted benzenes
Physical Properties of Ketone
Nucleophilic attack on carbonyl carbon
Addition of hydrogen cyanide (HCN)
Addition of sodium hydrogensulphite
Addition of alcohols:
Addition of ammonia and its derivatives
Wolff-Kishner reduction)
Clemmensen reduction
Tollens’ test:
Fehling’s test: F
Oxidation of methyl ketones by haloform reaction
Acidity of α-hydrogens of aldehydes and ketones:
Aldol condensation:
Cross aldol condensation:
Cannizzaro reaction:
Electrophilic substitution reaction
Structure of Carboxyl Group
Methods of Preparation of Carboxylic Acids From primary alcohols a
From alkylbenzenes
From nitriles and amide
From Grignard reagents
From acyl halides and anhydrides
From esters
In vapour state or in aprotic solvent
Hydrogen bonding of RCOOH with H2O
Reactions Involving Cleavage of O–H Bond Acidity
Electron Withdrawing Group
Elctron Donating Group
4-Methoxy benzoic acid (pK = 4.46)
Benzoic acid (p = 4.19)
4-Nitrobenzoic acid (pK = 3.41)
Formation of anhydride
Esterification
Reactions with PCl5, PCl3 and SOCl2
Reaction with ammonia
Reduction Reactions Involving –COOH Group
Decarboxylation
Halogenation Substitution Reactions in the Hydrocarbon Part
Ring substitution

Examples of Amines
Pyramidal shape of trimethylamine
primary (1o ), secondary (2o ) and tertiary (3o ) Amines
Reduction of nitro compounds
Ammolysis of Alkyl halides
Reduction of Nitriles
Reduction of Amides
Gabriel Phthalimide Synthesies
Hollfmaan Bromadide Degradation
Intermolecular hydrogen Bonding in Primary Amines
Basic character of amines
Alkanamines versus ammonia
Decreasing order of extent of H-bonding in water and order of stabilit
Arylamines versus ammonia
Acylation
Carbylamine reaction
Reaction with nitrous acid
Reaction with arylsulphonyl chloride
Electrophilic substitution
Nitration:
Sulphonation:
DIAZONIUM SALTS
Replacement by halide or cyanide ion:
Gatterman reaction.
Replacement by iodide ion:
Replacement by fluoride ion
Replacement by H:
Replacement by hydroxyl group:
Replacement by –NO2 group
Reactions involving retention of diazo group coupling reactions

Preparation of Glucose From sucrose (Cane sugar)


From starch:
Glucose
Prolonged Heating of Glucose with HI
Reaction of Hydroxylamine with Glucose
Oxidiation to Gluconic Acid
Acetylation of Glucose
Spatial Arrangements
Oxidation with Nitric Acid of Glucose
Glyceraldehyde +
Glyceraldehyde-
D Glyceraldehyde +
D Glucose
Alpha D Glucose
Beta D Glucose
Pyran
Glucopyranose Alpha
Glucopyranose Beta
D Frutose
Furan
D Alpha FructoFuranose
D Beta FructoFuranose
Haworth structures D Alpha FructoFuranose
Haworth structures D Beta FructoFuranose
Sucrose and its Reaction
Maltose
Lactose
Amylose
Amylopectin
Cellusoe
Amino Acid
Zwitter ion
Gly- Ala
Alpha Helix
: β-Pleated sheet structure of proteins
Diagrammatic representation of protein structure (two sub-units of tw
Primary, secondary, tertiary and quaternary structures of haemoglob
Hydrolysis of Maltose
Beta D Ribose
Beta d 2 deoxyribose
Adenine
Guanine
Custonine
Thymine
Uracil
Structure of (a) a nucleoside and (b) a nucleotide
Formation of a dinucleotide
Double strand helix structure for DNA
Chain initiation steps
Chain propagating step
Chain terminating step
Low Density polymers
High Density polymers
Teflon
Polyacrylonitrile
Condensation Polymerisation
Nylon 6,6
Nylon 6
Phenol
Bakelite
Melamine
Copolymerisation
Rubber
Isoprene
Vulcanized Rubber
Neoprene
Buna N
PHBV

Structural features of sulphonamides


Active site of an enzyme (b) Substrate (c) Substrate held in active sit
Drug and substrate competing for active site
Non-competitive inhibitor changes the active site of enzyme after bind
Receptor protein embedded in the cell membrane, the active site of t
Receptor receiving chemical messenger (b) Shape of the receptor ch
Histamine
Cimetime
Raniditime
Bromophiramine
Seldane
Nardil
Iphenozid
Chlorodiazephole
Equanil
Meprobamate
Veronal
Vallium
Serotonnin
Morphine
Heroin
Codeine
Salvarsam
Protonsil
Sulphanilamide
Sulphapyridinie
Azodye
Peniciliin
Chloramphenicol
Chloroxylenol
Terpineol
Bithionol
Norethindrone
Novestrol
Soap Reaction
Cetyltrimethyl ammonium bromide
Aninoic Detegents
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