JEE (Main + Advanced) 2023

REVISION ASSIGNMENT # 01 (SET-2) ENTHUSIAST COURSE

PHYSICAL CHEMISTRY MOLE CONCEPT, CONCENTRATION TERMS

SECTION–I : (i) Only One option correct Type

This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct. 3(–1)
1. Estimation of phosphorous : A known mass of compound is heated with fuming HNO3 or sodium
peroxide ( Na2O2) in Carius tube which converts phosphorous to H3PO4. Magnesia mixture (MgCl2 +
NH4Cl) is then added, which gives the precipitate of magnesium ammonium phosphate (MgNH4.PO4)
which on heating gives magnesium pyrophosphate (Mg2P2O7), which is weighed.
An organic compound has 6.2 % of phosphorus. On sequence of reaction, the phosphorous present in
the 10 gm of organic compound is converted to Mg2P2O7. Find the weight of Mg2P2O7 formed.
(A) 2.22 gm (B) 10.0 gm (C) 4.44 gm (D) 1.11 gm
2. Three substances A, B and C can react to form E and D as shown
2A + 3B + C ¾® 4D + 2E
If molar masses of A,B,C and D are 40, 30, 20 and 15 respectively and 570 gm of mixture
of A,B & C is reacted then maximum mass of E which can be obtained will be.
(A) 570 gm (B) 400 gm (C) 390 gm (D) 90 gm
3. If mole fraction of NaCl(aq) is same as that of water then molality of NaCl is
(A) 5.55 (B) 55.55 (C) 0.18 (D) 58.5
4. If a solution of stearic acid (C18H36O2 ; M = 284) in benzene contains 1.42 gm acid per L. When
this solution (100 L) is dropped on surface, C6H6 gets evaporated and acid forms a unimolecular layer
on the surface. If it covers an area 6020 cm2 with unimolecular film. Find the area covered by one
molecule of acid. [NA = 6.02 × 1023]
(A) 2 × 10–20 cm2 (B) 4 × 10–20 cm2 (C) 2 × 1020 cm2 (D) 4 × 1020 cm2
5. The ratio of mass percent of C and H of an organic compound (CXHYOZ) is 6 : 1. If one molecule of
the above compound (CXHYOZ) contains half as much oxygen as required to burn one molecule of
compound CXHY completely to CO2 and H2O. The empirical formula of compound CXHYOZ is
(A) C2 H4 O (B) C3H4O2 (C) C2H4O3 (D) C3H6O3
6. 12.5gm of fuming H2SO4 (labelled as 112%) is mixed with 100 lit water. Molar concentration of H+ in
resultant solution is :
[Note : Assume that H2SO4 dissociate completely and there is no change in volume on mixing]

2 2 3 3
(A) M (B) M (C) M (D) M
700 350 350 700

PC-RA # 01 (mole concept, concentration terms) E-1/7

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7. When a sample of Ne and SO3 gases is just collected in a platinum vessel, the vapour density
of mixture was 25. Platinum resulted dissociation of some or all SO3 gas into SO2 and O2
gases. After certain time, the vapour density of sample became 21. The degree of disso-
ciation of SO3 is (Ne = 21)

(A) 0.19 (B) 0.16 (C) 0.775 (D) 0.38

8. The results obtained by four students, each performing a set of four titrations with the same solution
under identical conditions, are given below. If the expected titre value is 20.0 mL, the set of data (mL)
with good accuracy and poor precision is :
(A) 19.9, 20.0, 20.1, 19.9 (B) 18.1, 18.2, 18.0, 18.1
(C) 17.9, 18.1, 21.5, 21.0 (D) 20.0, 19.8, 19.4, 20.2

(ii) One or more options correct Type

This section contains 1 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE are correct. 4(–1)
9. Sulphur molecule exists under various condition as S8, S6, S4, S2 and S. Which of the
following statement(s) is (are) INCORRECT :
(A) Mass of one mole of each of these is same
(B) One mole each of these contains equal number of species represented
(C) Number of atoms in one mole of each of these is same
(D) Molar mass of one mole each of these is same.

(iii) Paragraph Type

This section contains 1 paragraphs each describing theory, experiment, data etc. 3 questions relate
to two paragraphs with two questions on each paragraph. Each question of a paragraph has only one
correct answer among the four choices (A), (B), (C) and (D). 3(0)
Paragraph for Q.10 to Q.12
The following sequence of reaction occurs in commercial production of aqueous nitric acid.
NH3(g) + O2(g) ¾¾
® NO(g) + H2O(l) .....(1)

NO(g) + O2(g) ¾¾
® NO2(g) .....(2)

NO2(g) + H2O(l) ¾¾
® HNO3(aq)+ NO(g) .....(3)

In an industry 378 kg of HNO3 was required to be produced

E-2 / 7 PC-RA # 01 (mole concept, concentration terms)

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10. If % yield all reactions is 100% then mass (kg) of NH3 required is (NO produced in reaction-3 is not re-
used in reaction-2)

(A) 306 (B) 170 (C) 126 (D) 153

11. If % yield of reaction (1), (2) & (3) is 85%, 60% & 50% respectively. Then mass (kg) of NH3 required
(NO produced in reaction-3 is not re-used in reaction-2)

(A) 30 (B) 600 (C) 6000 (D) 300

12. If % yield all reactions is 100% then mass (kg) of NH3 required is (NO produced in reaction-3 is
re-used in reaction-2)

(A) 153 (B) 126 (C) 102 (D) can’t be determined.

SECTION-II (i): (Comprehension Integer Decimal) : 2(0)

˜ This section contains TWO (02) question stems.

˜ There are TWO (02) questions corresponding to each question stem.

˜ The answer to each question is a NUMERICAL VALUE.

˜ For each question, enter the correct numerical value corresponding to the answer in the
designated place.

˜ If the numerical value has more than two decimal places, truncate/round-off the value
to TWO decimal places.

˜ Answer to each question will be evaluated according to the following marking scheme:

Full Marks : +2   If ONLY the correct numerical value is entered at the designated place;

Zero Marks :  0  In all other cases.

Paragraph for Q.13 & Q.14

1292.5 gm of aquesous solution of ‘5m’ NaCl is kept in a large bucket. The bucket is placed under a
tap from which a ‘2m’ aqueous solution of NaCl is flowing. Rate of flow of solution from tap is
0.5 gm/sec.

13. The total amount of solution (in gm) finally present in bucket when soltuion present in bucket have
concentration of NaCl 4m.

14. The time (in seconds) after which the bucket will have ‘4m’ concentration of NaCl.

PC-RA # 01 (mole concept, concentration terms) E-3/7

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ENTHUSIAST COURSE

SECTION-II (ii): (Integer Second Decimal) : 4(0)

˜ This section contains 10 questions.

˜ The answer to each question is a NUMERICAL VALUE.

˜ For each question, enter the correct numerical value (If the numerical value has more
than two decimal places, truncate/round-off the value to TWO decimal places; e.g. 6.25,
7.00, –0.33, –.30, 30.27, –127.30, if answer is 11.36777..... then both 11.36 and 11.37 will
be correct) by darken the corresponding bubbles in the ORS.

For Example : If answer is –77.25, 5.2 then fill the bubbles as follows.
+ – + –
0 0 0 0 • 0 0 0 0 0 0 • 0 0
1 1 1 1 • 1 1 1 1 1 1 • 1 1
2 2 2 2 • 2 2 2 2 2 2 • 2 2
3 3 3 3 • 3 3 3 3 3 3 • 3 3
4 4 4 4 • 4 4 4 4 4 4 • 4 4
5 5 5 5 • 5 5 5 5 5 5 • 5 5
6 6 6 6 • 6 6 6 6 6 6 • 6 6
7 7 7 7 • 7 7 7 7 7 7 • 7 7
8 8 8 8 • 8 8 8 8 8 8 • 8 8
9 9 9 9 • 9 9 9 9 9 9 • 9 9

˜ Answer to each question will be evaluated according to the following marking scheme:

Full Marks : +4 If ONLY the correct numerical value is entered as answer.

Zero Marks : 0 In all other cases.

15. NaClO3 is used, even in spacecrafts, to produce O2. The daily consumption of pure O2 by a person is
492L at 1 atm, 300K. How much amount of NaClO3, in grams, is required to produce O2 for the daily
consumption of a person at 1 atm, 300 K ?

NaClO3(s) + Fe(s) ® O2(g) + NaCl(s) + FeO(s) R = 0.082 L atm mol–1 K–1

16. Calculate molality (m) of each ion present in the aqueous solution of 2M NH4Cl assuming 100%
dissociation according to reaction.

NH4Cl (aq) ¾® NH +4 (aq) + Cl– (aq)

Given : Density of solution = 3.107 gm / ml.

17. 90 g of a silver coin was dissolved in strong nitric acid, and excess of sodium chloride solution was
added. The silver chloride precipitate was dried and weighed 71.75 g. Calculate the percentage of silver
in the coin (Atomic mass of Ag = 108)

Ag + 2HNO3 ¾® AgNO3 + NO2 + H2O

AgNO3 + NaCl ¾® AgCl + NaNO3

E-4 / 7 PC-RA # 01 (mole concept, concentration terms)

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18. For the given series of reaction

4NH3(g) + 5O2 (g) ® 4NO (g) + 6H2O (l)
2NO (g) + O2 (g) ® 2NO2 (g)
If 20 ml of NH3 is mixed with 100 ml of O2. Volume contraction at the completion of above reactions
is
19. Flourine reacts with uranium to produce uranium hexafluoride, UF6, as represented by this equation
U(s) + 3F2(g) ® UF6(g)
If no. of fluorine molecules are required to produce 7.04 mg of uranium hexafluoride, UF6, from an
excess of uranium is y × 1019 then value of y is ? The molar mass of UF6 is 352 gm/mol.
(NA = 6.022 × 1023)
20. What total volume, in litre at 627°C and 82.1 atm, could be formed by the decomposition of 16 gm of
NH4NO3 ? Reaction : 2 NH4NO3 ® 2N2 + O2 + 4H2O(g). (R : 0.0821 atm L/mole-K)
21. Determine the percentage composition (by mass) of a mixture of anhydrous sodium carbonate and
sodium bicarbonate from the following data:
wt. of the mixture taken = 2g
Loss in weight on heating = 0.124 gm.
22. If the yield of chloroform obtainable from acetone and bleaching powder is 58%. What is the weight of
acetone (in gm) required for producing 239 mg of chloroform ?
2CH3COCH3 + 6CaOCl2 ® Ca(CH3COO)2 + 2CHCl3 + 3CaCl2 + 2Ca(OH)2
23. 60 ml of a mixture of nitrous oxide and nitric oxide was exploded with excess of hydrogen. If 38 ml of
N2 was formed, calculate % volume of NO gas in the mixture.
24. Nitrogen (N), phosporus (P), and potassium (K) are the main nutrients in plant fertilizers. According to
an industry convention, the numbers on the label refer to the mass % of N, P2O5, and K2O, in that order.
If the N : P : K ratio of a 28: 11.75 : 11.75 fertilizer in terms of moles of each elements, and express it as
x : y : 1. Find value of y (P = 31, K = 39)

SECTION-III : (Integer Value Correct Type)

This section contains 6 questions. The answer to each question is a single digit Integer, ranging from
0 to 9 (both inclusive) 3(0)

25. The number of significant figures in 0.00340 is __________ .

26. Silver (atomic weight = 108 g mol–1) has a density of 10.5 g cm–3. The number of silver atoms on
a surface of area 10–12 m2 can be expressed in scientific notation as y ´ 10x. The value of x is
27. The mole fraction of a solute in a solution is 0.1. At 298 K, molarity of this solution is the same as
its molality. Density of this solution at 298 K is 2.0 g cm–3. The ratio of the molecular weights of

æ MWsolute ö
the solute and solvent, ç ÷ , is
è MWsolvent ø

PC-RA # 01 (mole concept, concentration terms) E-5/7

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28. An organic compound contains carbon, hydrogen and nitrogen. If weight ratio of C, H, N
(in same order) is 9 : 1 : 3.5 and molar mass of compound is 216 gm/mole and number of

x
atoms present in 1 molecule of compound are x then calculate value of .
4

29. Acid sample is prepared using HCl, H2SO4,H2SO3 & H3PO4 separately or as mixture of
any two or more. Calculate the minimum volume of 4% w/v NaOH added (in litre) to 294
gm sample, in order to ensure complete neutralisation in every possible case.
1
30. A mixture of NaI and CaBr2 having mole fraction of CaBr2 equal to . To this mixture water is added
3
10
and solution is made upto 1 litre where molality of NaI is found to be . If density of solution is
9
1.15 g/ml. Calculate mol of NaI in original mixture. [Atomic mass of I = 127, Br = 80]

SECTION–IV : Matrix-Match Type

This Section contains 1 question. Question has four statements (A, B, C and D) given in Column
I and five statements (P, Q, R, S and T) in Column II. Any given statement in Column I can have correct
matching with ONE or MORE statement(s) given in Column II. For example, if for a given question,
statement B matches with the statements given in Q and R, then for the particular question, against
statement B, darken the bubbles corresponding to Q and R in the ORS. 8(0)
31. Match the column-
Column-I Column-II
(Concentration of aqueous solution) (Density of given solutions is 1.2 g/ml)
(A) 2M NaOH solution (P) 16gm solute in 240gm solution

æwö
(B) 8% ç ÷ KOH solution (Q) 60gm solute in 240 gm solution
èVø

æwö
(C) 25% ç ÷ CaCO solution (R) 8gm solute in 100 ml solution
èWø 3

1
(D) X C3H7OH = (S) 30 gm solute in 100 ml solution
11

(T) 1 mole solute in 400 gm solution

E-6 / 7 PC-RA # 01 (mole concept, concentration terms)

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ANSWER-KEY
SECTION–I : (i) Only One option correct Type
1. Ans. (A) 2. Ans. (C) 3. Ans. (B) 4. Ans. (A)
5. Ans. (C) 6. Ans. (A) 7. Ans. (C) 8. Ans. (D)

(ii) One or more options correct Type

9. Ans. (A,C,D)
(iii) Paragraph Type
10. Ans. (D) 11. Ans. (B) 12. Ans. (C)

SECTION-II (i): (Comprehension Integer Decimal) : 2(0)

13. Ans. (1851.00) 14. Ans. (1117.00)

SECTION-II (ii): (Integer Second Decimal) : 4(0)

15. Ans. (2120 to 2140) 16. Ans. (0.66 or 0.67)
17. Ans. (60.00) 18. Ans. (35.00)
19. Ans. (3.61) 20. Ans. (0.63)
21. Ans. (%NaHCO3 = 16.80 ; %Na2CO3 = 83.20) 22. Ans. (0.20)
23. Ans. (73.33) 24. Ans. (0.66)

SECTION-III : (Integer Value Correct Type)

25. Ans. (3) 26. Ans. (7) 27. Ans. (9) 28. Ans. (8)
29. Ans. (9) 30. Ans. (1)

SECTION–IV : Matrix-Match Type

31. Ans. (A) - P,R ; (B) - P,R ; (C) - Q,S,T ; (D) - S, Q

PC-RA # 01 (mole concept, concentration terms) E-7/7