1 s2.0 S0960148117310431 Main
1 s2.0 S0960148117310431 Main
1 s2.0 S0960148117310431 Main
Renewable Energy
journal homepage: www.elsevier.com/locate/renene
a r t i c l e i n f o a b s t r a c t
Article history: Senergy building integrated solar thermal collectors aim to reduce costs of solar water heating systems
Received 15 July 2017 by utilizing polymer materials and offsetting costs of conventional roofing construction components.
Received in revised form Carbon nanotubes can be added to polymer materials to improve their thermal, optical and mechanical
6 October 2017
properties. Two working prototypes; one Polycarbonate Carbon Nano-Tube (PCNT) collector and one
Accepted 25 October 2017
Asphalt Carbon Nano-Tube (ACNT) collector; have been tested using the solar simulator facility at Ulster
Available online 28 October 2017
University and their performances compared. The PCNT collector is single glazed and uses a twinwall
sheet to act as both the solar absorptive surface and the heat transfer fluid channeling element. The ACNT
Keywords:
Carbon nanotubes (CNT)
collector is unglazed and has an asphalt based absorber with embedded serpentine copper tubing to
Solar water heater channel the heat transfer fluid. Tests were conducted with 800 W m2 illumination intensity and for
Polymeric solar collector water inlet temperatures between from 23 C and 47 C. The PCNT collector achieved 62% maximum
Polymer absorber collection efficiency compared to 45% for the ACNT collector. The heat loss coefficients were 6.0 and
Nanocomposite 8.1 W m2 K1 respectively. The performance of the PCNT collector was similar to benchmark values for
single glazed collectors with selective absorber surfaces. The ACNT collector responded very slowly and
performance was lower than a typical unglazed solar water heater with non-selective absorber due to
the high thermal resistance between the absorber surface and the serpentine tubing.
© 2017 Elsevier Ltd. All rights reserved.
https://doi.org/10.1016/j.renene.2017.10.082
0960-1481/© 2017 Elsevier Ltd. All rights reserved.
A. Pugsley et al. / Renewable Energy 137 (2019) 2e9 3
water temperature, especially when located in exposed sites sub- development is the selection of appropriate polymers which ach-
jected to wind. Whilst heat loss causes inefficiency, it also has the ieve sufficient robustness when subjected to stresses associated
benefit of protecting collectors from overheating and high pres- with fluctuating temperatures and pressures. Robustness must be
sures during tagnation. maintained throughout the whole service life, hence aging behav-
Most plastics have thermal conductivities of iour of polymers subjected to temperature fluctuations, prolonged
k z 0.1e0.5 W m1K1, radiative heat emissivities of ε z 0.9, and UV light exposure, and high humidity is a key issue [12,17e20]. This
solar absorptance of a z 0.9 when pigmented black. By compari- has significant bearing on the economics of polymeric collectors
son, copper and aluminium used in conventional solar collectors given that low cost commodity plastics generally have inferior
have much better thermal conductivities mechanical properties to more expensive engineering plastics.
(k z 200e300 W m1K1) and emissivities (ε < 0.1 when polished) Several authors have investigated fabricating absorbers from
but are reflective (a < 0.5). Metallic absorbers are therefore usually nanocomposites which can be engineered to improve optical,
treated with optically selective coatings which maximise absorp- thermal, and mechanical properties of base polymers. Kim et al.
tion whilst also minimising radiant heat emissions. Most [21] demonstrated that the solar thermal efficiency performance of
commercially available selective coatings use galvanic or high a transparent polycarbonate twinwall absorber could be signifi-
temperature application processes and are therefore unsuitable for cantly improved by adding 2%wt CNTs as a solar absorptive
polymer absorbers, although coatings with a ¼ 0.94 absorptivity pigment. Kurzbo €ck et al. [22] compared random copolymer poly-
and ε ¼ 0.09 emissivity have been successfully applied to extruded propylene samples pigmented with carbon black (1.5%wt) and
twinwall polycarbonate absorbers using sputtering techniques carbon nanotube (CNT) pigments (1.5%wt) and found that CNTs
[7,8]. achieved marginally higher solar absorption performances
A large body of work on glazed polymeric collectors has been (a ¼ 0.96) than carbon black samples (a ¼ 0.95). Abdelal and
undertaken in the last two decades, with considerable advances Taamneh [23] found that the performance of a solar distiller could
achieved under IEA-SHC Task 39 [9,10]. The most extensively be improved by adding CNTs or graphene platelets to epoxy resin
studied polymer absorber design concepts are extruded twinwall or based solar absorber plates, although the specific optical and/or
triplewall type arrangements [7,8,11e15] similar to Fig. 1. These thermal mechanisms underlying the performance increase are
designs utilize the upper surface of the twinwall as the absorber unclear. One possible mechanism is that CNT addition could be
and the internal channel structure as the working fluid contain- beneficial in reducing surface emissivity. Solar selective coatings
ment, which maximises heat transfer area. based on vertically aligned CNT forests on aerogel film substrates
Much of the work on single glazed polymeric collector design were developed and tested by Martinez et al. [24] who report solar
development has focused on preventing damagingly high stagna- absorptivity of a z 0.96 and emissivity of ε z 0.7 for their best
tion temperatures by employing methodologies such as absorber (densified) samples. Similar optical performance values are re-
venting, thermochromic glazing, and Integrated Collector-Storage ported by Mizuno et al. [25] for their roll-pressed sheet and filtrated
concepts which feature high thermal masses [6,15,16]. Several buckypaper CNT forest samples, although much higher emissivities
methods for reducing pressure related stresses in polymer collec- (around ε z 0.9) are reported for spray applied coatings.
tors have been developed, including the use of vented open-loop Several authors [26e28] have shown that carbon nanotubes
hydraulic circuits and also the drainback system concept which (preferably functionalized species) and other engineered graphene
has the added advantage of offering freeze protection without the particles such as nanoplatelets can be added to base polymers to
need for antifreeze chemicals. improve their thermal conductivity. Significant benefits (10-fold
One of the most challenging issues for polymeric solar collector increase bringing conductivities to k z 2e5 W m1K1) appear
Transparent cover
Air gap
Inlet Outlet
manifold manifold
Extruded polymer twinwall absorber
Fig. 5. Schematic detail of test facility and instrumentation (two collectors, side by side).
6 A. Pugsley et al. / Renewable Energy 137 (2019) 2e9
70
Ambient (Tamb)
Inlet (Tin)
65
PCNT outlet (Tout)
PCNT absorber surface (Tabs)
60
ACNT outlet (Tout)
ACNT absorber surface (Tabs)
55 ACNT absorber core (Tabs)
Temperature (°C)
50
45
40
35
30
25
20
11:45 12:00 12:15 12:30 12:45 13:00 13:15 13:30 13:45 14:00
Time (hh:mm)
Fig. 7. Measured temperature time histories under lowest inlet temperature conditions.
A. Pugsley et al. / Renewable Energy 137 (2019) 2e9 7
Fig. 8. Measured temperature time histories under highest inlet temperature and stagnation conditions.
Fig. 9. Comparison of instantaneous efficiencies of Senergy prototypes against other solar collector benchmarks.
Table 1
Comparison of Senergy prototypes against performance benchmarks for other solar collector types.
Giovannetti et al. [35]. components. Given the early stage of development of the PCNT
The measured zero temperature rise efficiencies (the h0 ¼ FRta prototype it is not yet possible to offer reliable comments on the
values apparent from the y-axis intercepts on Fig. 9) of the PCNT anticipated cost of a finished product. The above analysis will
and ACNT collectors are broadly similar to the benchmark for however aid the establishment of a suitable price-point against
evacuated tube collectors but considerably lower than achieved by which design development options can be evaluated in future.
most other flat plate collectors. The ACNT collector appeared to
have reasonably good light absorption characteristics (black 5. Conclusions
bitumen absorber surface with a slight sheen) and is unlikely to
have suffered from significant reflection losses (as it was unglazed) The performance of the Senergy polycarbonate (PCNT) and
which suggests that the low measured efficiency (h0 ¼ 45% asphalt (ACNT) carbon nanotube solar water heating collectors was
compared to h0 ¼ 90% for the unglazed collector benchmark) is investigated experimentally under controlled solar simulated
primarily attributable to a low heat removal factor. The relatively conditions. The single glazed PCNT collector achieved higher
low measured efficiency for the PCNT collector (h0 ¼ 62% compared collection efficiencies than the unglazed ACNT collector under all
to h0 ¼ 83% for the single glazed matt black collector) may also be tested conditions. Test results have been compared to published
partially attributable to a low heat removal factor, although optical benchmark performances for flat plate and evacuated tube solar
losses (absorber and cover reflectivity and low optical trans- water heaters. Both collectors achieved measured zero temperature
missivity of the semi-translucent cover) seem likely to be the more rise efficiencies (h0 ¼ 45% for ACNT and h0 ¼ 62% for PCNT) of
significant causes. Absorbers made of polymeric materials often similar magnitude to the benchmark for evacuated tube collectors.
have lower heat removal factors than conventional metal sheet- The measured heat loss coefficient for the ACNT collector
and-tube absorbers owing to inherently lower thermal conductiv- (8.1 W m2 K1) is significantly better than the benchmark for an
ities. The very low apparent heat removal factor for the ACNT is unglazed collector. The measured heat loss coefficient for the PCNT
likely to be caused by the heat exchanger pipework being buried collector (6.0 W m2 K1) is equivalent to that achieved by a con-
too deeply within the asphalt and perhaps also by the pipe length ventional one-cover liquid heater with moderately selective
being too short, which introduces very high thermal resistances absorber. The ACNT collector had a very slow thermal response rate
between the absorber and the working fluid. This is evidenced by due to its high thermal mass and a very low heat removal factor due
the significant difference (10e20 C) between the ACNT's absorber to high thermal resistances within the asphalt absorber.
surface and outlet temperatures and the 5e7 C temperature dif- The ACNT collector would be ineffective for domestic hot water
ference between the core and absorber surface temperatures. production and, even in low temperature applications, its low ef-
The thermal insulation performances (the FRUL values apparent ficiency would most likely render it uncompetitive relative to
from the trendline gradients on Fig. 9) of the prototype collectors existing unglazed polymeric collectors unless it could be produced
are considerably lower (better) than the corresponding bench- at a significantly lower cost.
marks. The ACNT achieved a heat loss coefficient of 8.1 W m2 K1 The PCNT collector can achieve 32% solar thermal efficiency
which is less than half the unglazed collector benchmark value when operating under conditions relevant to summertime do-
(18 W m2 K1). The PCNT achieved a heat loss coefficient of mestic hot water production (0.05 m2 K W1). Whilst this perfor-
6.0 W m2 K1 which is 28% lower than the benchmark value for mance is lower than that typically achieved by conventional metal-
single glazed collectors with matt black absorbers (8.3 W m2 K1) glass flat plate or evacuated tube collectors the PCNT concept could
and approaches the benchmark value of 5 W m2 K1 for single be economically attractive if the use of polymer materials enabled it
glazed collectors with selective absorbers (high absorptivity and to be produced at much lower cost, particularly if also designed to
low emissivity). The cause of the low heat loss coefficients cannot replace conventional roofing components.
be reliably determined from the test data but, particularly in the The study indicates that carbon nanotube addition in polymeric
case of the ACNT, this is thought to be primarily due to the low heat solar absorbers may be of benefit, but minimising the thickness of
removal factor. the absorber-to-fluid layer remains a crucial parameter affecting
It is clear from Table 1 that the ACNT collector would be inef- solar thermal collection efficiency. The degree to which the carbon
fective for domestic hot water applications since the efficiency is nanotubes increase the polymer thermal conductivity and benefi-
only ~5% under a solar thermal condition of 0.05 m2 K W1. This cially affect the optical properties of the absorber surfaces will be
solar thermal condition was chosen to be representative of a determined through further testing as part of the ongoing research.
“typical” summertime domestic hot water heating scenario where
the collector is used to heat water to >60 C when the ambient Acknowledgements
temperature is 20 C and the irradiance is at 800 W m2. Whilst the
ACNT collector could in principle be useful for applications The authors would like to thank Queens University Belfast and
requiring very low temperatures (eg swimming pool heating or low Lawell Asphalt Company Limited for designing and fabricating the
temperature source for heat pump systems at ~0.01 m2K$W1) its collector prototypes. This paper has been prepared as part of the
low efficiency would most likely render it uncompetitive relative to Senergy Demonstrator Project which is funded by Invest Northern
existing unglazed collectors unless it could be produced at a Ireland as part of the Centre for Advanced Sustainable Energy
significantly lower cost. (CASE) research initiative. Project partners include Ulster Univer-
By contrast, the PCNT collector would (assuming that leakage sity, Senergy Innovations Ltd, Lawell Asphalt Company Ltd, and
problems were resolved) achieve an efficiency of 32% under a solar Semple & McKillop Consulting engineers.
thermal condition of 0.05 m2 K W1. This performance is less than
two-thirds that of a conventional collector but the PCNT could Nomenclature
become an economically attractive option if it could be produced at
a cost which was half that of a conventional metal-glass collector
(eg evacuated tubes or flat plate types). Even if it was only possible Abbreviations
to produce the PCNT at two-thirds the cost of a conventional metal- ACNT Asphalt with Carbon Nano Tubes
glass collector, it could still be economically attractive if the design BISTS Building Integrated Solar Thermal System
enabled replacement of conventional roofing construction CNT Carbon Nano Tubes
A. Pugsley et al. / Renewable Energy 137 (2019) 2e9 9
IEA-SHC International Energy Agency Solar Heating and Cooling polymeric components for a new generation of solar thermal energy systems,
Energy Procedia 48 (2014) 130e136.
programme
[11] C. Cristofari, G. Notton, P. Poggi, A. Louche, Modelling and performance of a
PCNT Polycarbonate with Carbon Nano Tubes copolymer solar water heating collector, Sol. Energy 72 (2) (2000) 99e112.
PMMA Poly(methyl methacrylate) polymer resin [12] A. Olivares, J. Rekstad, M. Meir, S. Kahlen, G. Wallner, A test procedure for
STS Solar Thermal System extruded polymeric solar thermal absorbers, Sol. Energy Mater. Sol. Cell. 92
(2008) 445e452.
UV Ultra Violet [13] G. Martinopoulos, D. Missirlis, G. Tsilingiridis, K. Yakinthos, N. Kyriakis, CFD
modeling of a polymer solar collector, Renew. Energy 35 (2010) 1499e1508.
Latin symbols and subscripts [14] D. Missirlis, G. Martinopoulos, G. Tsilingiridis, K. Yakinthos, N. Kyriakis,
Investigation of the heat transfer behaviour of a polymer solar collector for
Aap (m2) Collector aperture area different manifold configurations, Renew. Energy 68 (2014) 715e723.
cp (J$kg1K1) Specific heat capacity of the working fluid [15] A. Piekarczyk, M. Volk, M. Heck, S. Wiesmeier, K. Weiß, M. Ko €hl, Field test for
FR (dimensionless) Heat removal factor polymeric collector models in different climatic locations, Energy Procedia 91
(2016) 384e391.
I (W$m2) Solar radiation flux incident on collector [16] A. Weber, K. Resch, Thermotropic glazings for overheating protection, Energy
aperture Procedia 30 (2012) 471e477.
m (kg$s1) Working fluid mass flow rate [17] S. Kahlen, G. Wallner, R. Lang, Aging behavior of polymeric solar absorber
materials e Part 1: engineering plastics, Sol. Energy 84 (2010a) 1567e1576.
Q (J) Thermal energy, where subscripts denote energy [18] S. Kahlen, G. Wallner, R. Lang, Aging behavior of polymeric solar absorber
“incident” on aperture, and energy “collected” by working materials e Part 2: commodity plastics, Sol. Energy 84 (2010b) 1577e1586.
fluid [19] S. Kahlen, G. Wallner, R. Lang, M. Meir, J. Rekstad, Aging behavior of polymeric
solar absorber materials: aging on the component level, Sol. Energy 84
t (s) Time
(2010c) 459e465.
T ( C) Temperature, where subscripts denote water flowing [20] M. Povacz, G. Wallner, M. Grabmann, S. Beißmann, K. Grabmayer,
“in” and “out” of the collector, absorber surface (“abs”), W. Buchberger, R. Lang, Novel solar thermal collector systems in polymer
and ambient environment (“amb”) design e Part 3: aging behavior of PP absorber materials, Energy Procedia 91
(2016) 392e402.
UL (W m2 K1) Heat loss coefficient which quantifies [21] S. Kim, J. Kissick, S. Spence, C. Boyle, Design, analysis and performance of a
thermal conductance between the working fluid bulk and polymerecarbon nanotubes based economic solar collector, Sol. Energy 134
the ambient environment (2016) 251e263.
[22] M. Kurzbo € ck, G. Wallner, R. Lang, Black pigmented polypropylene materials
for solar absorbers (SHC 2012), Energy Procedia 30 (2012) 438e445, https://
Greek symbols and subscripts doi.org/10.1016/j.egypro.2012.11.052.
a (dimensionless) Solar absorption coefficient [23] N. Abdelal, Y. Taamneh, Enhancement of pyramid solar still productivity using
absorber plates made of carbon fiber/CNT-modified epoxy composites,
Dt (s) Duration of the test period Desalination 419 (2017) 117e124.
h (dimensionless) Solar thermal collection efficiency. [24] P. Martinez, V. Pozdin, A. Papadimitratos, W. Holmes, F. Hassanipour,
Subscript “0” denotes the zero temperature rise condition G. Dover, A. Zakhidov, Carbon nanotube dry spinnable sheets for solar se-
lective coatings by lamination, Eurasian Chem.-Technol. J. 18 (2016) 241e249.
t (dimensionless) Solar transmission coefficient [25] K. Mizuno, J. Ishii, H. Kishida, Y. Hayamizu, S. Yasuda, D. Futaba, M. Yumura,
K. Hata, A black body absorber from vertically aligned single-walled carbon
References nanotubes, Proc. Natl. Acad. Sci. 106 (15) (2009) 6044e6047.
[26] Z. Han, A. Fina, Thermal conductivity of carbon nanotubes and their polymer
nanocomposites: a review, Prog. Polym. Sci. 36 (2011) 914e944, https://
[1] S. Kalogirou, Chapter 1.1 description of the action TU1205: building integrated
doi.org/10.1016/j.progpolymsci.2010.11.004.
solar thermal systems (BISTS), in: S. Kalogirou (Ed.), COST Action TU1205
[27] W. Hong, N. Tai, Investigations on the thermal conductivity of composites
BISTS e Design and Applications Handbook, COST office, Brussels, Belgium,
reinforced with carbon nanotubes, Diam. Relat. Mater. 17 (2008) 1577e1581.
2017, ISBN 978-9963-697-22-9.
[28] Y. Jia, H. He, Y. Geng, B. Huang, X. Peng, High through-plane thermal con-
[2] Maurer, Smyth, Chapter 2.11 economics, in: S. Kalogirou (Ed.), COST Action
ductivity of polymer based product with vertical alignment of graphite flakes
TU1205 BISTS e Design and Applications Handbook, COST office, Brussels,
achieved via 3D printing, Compos. Sci. Technol. 145 (2017) 55e61.
Belgium, 2017, ISBN 978-9963-697-22-9.
[29] F. Du, J. Fischer, K. Winey, Coagulation method for preparing single-walled
[3] C. Lamnatou, D. Chemisana, R. Mateus, M. Almeida, S. Silva, Review and per-
carbon nanotube/poly(methyl methacrylate) composites and their modulus,
spectives on life cycle analysis of solar technologies with emphasis on
electrical conductivity, and thermal stability, J. Polym. Sci. Part B Polym. Phys.
building-integrated solar thermal systems, Renew. Energy 75 (2015)
41 (2003) 3333e3338.
833e846.
[30] A. Ormsby, T. McNally, C. Mitchell, A. Dunne, Incorporation of multiwalled
[4] M. Buker, S. Riffat, Building integrated solar thermal collectors e a review,
carbon nanotubes to acrylic based bone cements: effects on mechanical and
Renew. Sustain. Energy Rev. 51 (2015) 327e346.
thermal properties, J. Mech. Behav. Biomed. Mater. 2 (2010) 136e145.
[5] C. Cappel, T. Kuhn, C. Maurer, Research and Development Roadmap for
[31] S. Kalogirou, Solar Energy Engineering, Academic Press (Elsevier), London,
Façade-integrated Solar Thermal Systems, Available at:, Fraunhofer ISE, Frei-
2009, ISBN 978-0-12-374501-9.
burg, Germany, 2015 http://publica.fraunhofer.de/documents/N-349494.html.
[32] J. Twidell, T. Weir, Renewable Energy Resources, second ed., Taylor Francis,
[6] T. Ramschak, R. Hausner, C. Fink, Polymeric materials in solar-thermal systems
London, 2006, ISBN 978-0-419-25330-3.
- performance requirements and loads, Energy Procedia 91 (2016) 105e112.
[33] A. Zacharopoulos, J. Mondol, M. Smyth, T. Hyde, V. O'Brien, State of the art
[7] A. Kudish, E. Evseev, G. Walter, T. Leukefeld, Simulation study of a solar col-
solar simulator with flexible mounting, in: Proceedings ISES Solar World
lector with a selectively coated polymeric double walled absorber plate, En-
Congress, 11-14 October 2009, Johannesburg, South Africa, 2009,
ergy Convers. Manag. 43 (2002) 651e671.
pp. 854e863.
[8] M. Rommel, M. Koehl, W. Graf, C. Wellens, F. Brucker, K. Lustig, P. Bahr,
[34] R. Liang, M. Ma, J. Zhang, D. Zhao, Theoretical and experimental investigation
Corrosion-free collectors with selectively coated plastic absorbers, Desalina-
of the filled-type evacuated tube solar collector with U tube, Sol. Energy 85
tion 109 (1997) 149e155.
(2011) 1735e1744.
[9] M. Koehl, M. Meir, P. Papillon, G. Wallner, S. Saile (Eds.), Polymeric Materials
[35] F. Giovannetti, S. Foste, N. Ehrmann, G. Rockendorf, High transmittance, low
for Solar Thermal Applications, Wiley-VCH, Weinheim, Germany, 2012, ISBN
emissivity glass covers for flat plate collectors: applications and performance,
978-3-527-33246-5.
Sol. Energy 104 (2014) 52e59.
[10] M. Koehl, S. Saile, A. Piekarczyk, S. Fischer, Task 39 exhibition e assembly of