JAMES RUSE AGRICULTURAL HIGH SCHOOL

2019
YEAR 11 EXAMINATION

Chemistry
General Instructions

• Reading time – 5 minutes

• Working time – 2 hours

• Write using black pen

• Draw diagrams using pencil

• NESA approved calculators may be used

• A data sheet, formulae sheet and Periodic Table are provided at the back of this
paper

• For questions in Section II, show all relevant working in questions involving
calculations

Section I – 20 marks (pages 3–10) • Attempt Questions 1–20

• Allow about 35 minutes for this section

Section II – 60 marks (pages 12–22) • Attempt Questions 21–32

• Allow about 1 hour and 25 minutes for this section

JRAHS 2019 Year 11 Chemistry Yearly Exam Page 1

Section I

Multiple Choice: 20 marks

Attempt Questions 1-20

Mark your answers for Questions 1 – 20 in the Answer Box on page 11

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1. Which scientist hypothesized that the energy absorbed or emitted by an electron as it
changed energy levels would correspond to a particular wavelength of light?

(A) Dalton

(B) Rutherford

(C) Bohr

(D) Schrödinger

2. Which is the most electronegative element?

(A) Francium

(B) Lithium

(C) Fluorine

(D) Astatine

3. The graph shows the trend in a particular property across the third period of elements.

Property A

Property A is most likely:

(A) chemical reactivity.

(B) electronegativity.

(C) atomic radius.

(D) atomic mass.

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Use the equation to answer the next two questions, 4 and 5

N2 (g) + 2O2(g) → 2NO2(g)

4. What volume of nitrogen dioxide would be produced by the combustion of 1.2 L of

nitrogen gas in excess oxygen?

(A) 1.2 L

(B) 2.4 L

(C) 0.048 L

(D) 0.097 L

5. Whose Law of Combining Volumes is demonstrated in the reaction in question 4?

(A) Avogadro

(B) Boyle

(C) Gay-Lussac

(D) Charles

6. What are the products of photosynthesis?

(A) carbon dioxide

(B) carbon dioxide, water and oxygen

(C) oxygen and glucose

(D) oxygen and water

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7. What volume of water needs to be added to dilute 10.0 mL of a 0.100 mol L-1 solution to
a 0.0250 mol L-1 solution?

(A) 10.0 mL

(B) 20.0 mL

(C) 30.0 mL

(D) 40.0 mL

8. Which of the following compounds have H-bonding between the molecules?

(i) (ii)

(iii) (iv)

(A) (i), (ii), (iii) and (iv)

(B) (ii) and (iii)

(C) (i) and (iv)

(D) (ii) and (iv)

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9. Uranium -238 undergoes a sequence of both alpha and beta decays to finally become a
stable isotope of lead.

In the first part of this sequence, what is the isotope produced when Uranium -238
undergoes first an alpha decay then 2 beta decays?
234
(A) 92𝑈𝑈

238
(B) 92𝑈𝑈

234
(C) 90Th

234
(D) 91Pa

10. Which chromium oxide contains 68.45% chromium and 31.55% oxygen?

(A) chromium (II) oxide

(B) chromium (III) oxide

(C) chromium (IV) oxide

(D) chromium (VI) oxide

11. What are the products of complete combustion of ethane, C2H6?

(A) Carbon dioxide and water

(B) Carbon monoxide and water

(C) Carbon monoxide, soot, and water

(D) Carbon dioxide, carbon monoxide, soot, and water

12. What volume will 2.0 moles of hydrogen occupy at 150 oC and 100 kPa?

(A) 24.9 L

(B) 49.6 L

(C) 68.9 L

(D) 70.3 L

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13. The image below displays the fruits of the cycad Macrozamia, an important food
source for the Aboriginal and Torres Strait Islander Peoples. The fruits of this plant
are known to be highly toxic and carcinogenic.

Which of the following procedures is most effective in the removal of toxins from
this cycad?

(A) Allowing the seeds to age sufficiently before consumption.

(B) Removing the individual seeds from the husk before cooking them with fire.

(C) Cooking the seeds with fire before leaching them out in running water
overnight.

(D) Removing the individual seeds from the husk and allowing them to dry out
in sunlight.

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14. Which combination of oxidation and reduction reactions would be spontaneous?

Oxidation Reduction
(A) Ni (s) → Ni2+ (aq) + 2e– Cu2+ (aq) + 2e– → Cu (s)
(B) Ag (s) → Ag+ (aq) + e– Fe3+ (aq) + e– → Fe2+ (s)
(C) Pb2+ (aq) + 2e– → Pb (s) Cu (s) → Cu2+ (aq) + 2e–
(D) Cu2+ (aq) + 2e– → Cu (s) Fe (s) → Fe2+ (aq) + 2e–

15. Which statement is correct for the following reaction?

Mg (s) + Fe2+ (aq) → Mg2+ (aq) + Fe(s)

(A) Mg is the reducing agent because it undergoes reduction.

(B) Mg is the reducing agent because it undergoes oxidation.

(C) Fe2+ is the oxidising agent because it undergoes oxidation.

(D) Fe2+ is the reducing agent because it undergoes oxidation.

16. Which of the following species decreases in oxidation number?

5Sn2+ (aq) + 2MnO4– (aq) + 16H+ (aq) ⇋ 5Sn4+ (aq) + 2Mn2+ (aq) + 8H2O (l)

(A) Sn2+

(B) MnO4-

(C) H2O

(D) H+

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17. Which statement best describes the energy profile diagram shown below?

(A) The products have more energy than the reactants and the surroundings get
colder.

(B) The products have more energy then the reactants and the surroundings get hotter.

(C) The products have less energy than the reactants and the surroundings get colder.

(D) The products have less energy than the reactants and the surroundings get hotter.

18. A 10.0 L sample of water (density = 1.0 kg L-1) is contaminated with 10 ppm of lead
ions.

What is the mass of lead in this sample?

(A) 100 mg

(B) 10 g

(C) 20 mg

(D) 1000 mg

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19. For each mole of oxygen consumed in complete combustion, which fuel produces the
most number of moles of carbon dioxide ?

(A) Methane, CH4

(B) Ethyne, C2H2

(C) Ethene, C2H4

(D) Propane, C3H8

20. Which of the following changes will cause a decrease in entropy?

(A) Ice changing into water

(B) Ethanol mixing with water

(C) Precipitation of barium sulfate in a solution containing barium ions

and sulfate ions.

(D) Water boiling

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 Student No. ....................................................

Total Mark ………………………………..

Multiple Choice Answer Sheet
Section I : Allow 30 minutes for this part

1. A B C D

2. A B C D

3. A B C D

4. A B C D

5. A B C D

6. A B C D

7. A B C D

8. A B C D

9. A B C D

10. A B C D

11. A B C D

12. A B C D

13 A B C D

14. A B C D

15. A B C D

16. A B C D

17. A B C D

18. A B C D

19. A B C D

20. A B C D

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Section II - 60 marks
Attempt questions 21 - 32
Allow about 90 minutes for this part
Answer the questions in the spaces provided. These spaces provide guidance for the expected
length of response
Show all relevant working in questions involving calculations
Question 21 (4 marks)

Below is the orbital diagram for phosphorus.

(a) Complete the orbital diagram for sulfur. 1

1s 2s 2p 3s 3p

(b) The first ionisation energies of the elements in the third period are shown in the graph.

Question 21 continued on the next page

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Explain the difference in first ionisation energy between phosphorus and sulfur. 3

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Question 22 (4 marks)

Explain the characteristics of the two chlorides given below. 4

Compound Melting Point oC Conductivity when molten

XCl2 714 good
YCl2 -121 poor

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Question 23 (4 marks)

Carbon has both allotropes and isotopes.

Compare and contrast:

(a) TWO allotropes of carbon. 2

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(b) TWO isotopes of carbon 2

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Question24 (7 marks)

Copper (II) hydroxide can be precipitated from the reaction of copper (II) chloride solution with
sodium hydroxide solution.

(a) Write the net ionic equation for the precipitation reaction. 2

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(b) Calculate the mass of precipitate formed when 20.0 mL of 0.100 mol L-1 of
copper (II) chloride solution is added to 30.0 mL of 0.200 mol L-1 sodium hydroxide
solution. 3

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(c) Calculate the concentration of the chloride ions in the final solution. 2

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Question 25 (3 marks)

A student performed a series of experiments to investigate the solubility of silver salts. He

tested the reactions of a 0.1 mol L-1 silver nitrate solution with 0.1 mol L-1 solutions of
magnesium hydroxide, magnesium chloride, and magnesium sulfate and obtained the
following table of results:

Observation
Magnesium
No reaction
hydroxide
Magnesium chloride White precipitate
Magnesium sulfate No reaction

(a) Write a balanced chemical equation for the reaction with magnesium chloride. 2

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(b) Name the white precipitate. 1

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Question 26 (1 marks)

A series of experiments were conducted to demonstrate the reactivity of different metals.

Samples of four different metals (W, X, Y, and Z) were placed into separate beakers
containing water, boiling water (to represent steam) and dilute hydrochloric acid. The results
are recorded in the table below:

Reactant
Metal Water Steam Dilute Acid
Mild reaction producing Mild reaction producing
W No reaction
H2 gas H2 gas
Mild reaction producing Rapid reaction producing Violent reaction
X
H2 gas H2 gas producing H2 gas
Y No reaction No reaction No reaction

Mild reaction producing

Z No reaction No reaction
H2 gas

Rank the metals from MOST to LEAST reactive. 1

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Question 27 (4 marks)

Explain the relationship between atomic radius and ionization energy with metal reactivity
down Group 2 of the Periodic Table. 4

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Question 28 (3 marks)

A galvanic cell was assembled as shown below.

Tin electrode Silver electrode

Salt bridge
Tin sulfate (potassium nitrate)
Silver nitrate
solution
solution

(a) Indicate the direction of electron flow with a labelled arrow on the diagram. 1

(b) Label the anode and the cathode. 1

(c) Indicate the direction of anion flow with a labelled arrow. 1

Question 29 (2 marks)

Catalysts are chemicals which are often used in chemical reactions. 2

Explain how the use of a catalyst affects the rate of a reaction.

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Question 30 (8 marks)

A student conducted an experiment to measure the enthalpy change when 1.00 g of solid
ammonium nitrate was dissolved in 50.0 mL of deionised water. The student measured the
initial and final temperature of the water and recorded their results in the table below:

Mass of water 50.0 g

Mass of ammonium nitrate 1.00 g
Initial temperature of water 21.6 o C
Final Temperature of water 20.2 o C
Temperature Change 1.40 o C

(a) Draw a labelled diagram of the set up for this experiment. 3

(b) Calculate the molar heat of solution of ammonium nitrate. 4

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(c) Outline ONE possible source of error in this experiment. 1

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Question 31 ( 12 marks)

A student carried out a set of first-hand investigations in which 5.00g of calcium carbonate was
reacted with excess hydrochloric acid at 250 C and 100 kPa. The volume of carbon dioxide gas
produced was measured at regular time intervals in each experiment.

In one experiment calcium carbonate was supplied as marble chips and in another experiment, as
a powder.

The results of the two experiments are tabulated below :

Time (s) Experiment A Experiment B

Volume of CO2(g) produced (mL) Volume of CO2(g) produced (mL)
0 0.00 0.00
10 60.0 15.0
20 78.0 30.0
30 85.0 42.0
40 90.0 56.0
50 90.0 68.0
60 90.0 80.0
70 90.0 90.0
80 90.0 90.0
90 90.0 90.0

(a) Construct a graph of volume of CO2(g) against time for each investigation and draw TWO
lines of best fit on the grid. 5

Question 31 continued on next page

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(b) Label the lines as Experiment A for the use of marble chips and Experiment B for the use
of powdered calcium carbonate. 1

(c) (i) Which experiment had the faster reaction? ………………………………………….. 1

(ii) Explain why one reaction was faster than the other? 1

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(d) Calculate the maximum mass of carbon dioxide produced for the reactions. 3

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(e) Why did both experiments produce the same volume of carbon dioxide? 1

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Question 32 (8 marks)

The enthalpy changes for many thermochemical reactions cannot be accurately determined in the
school laboratory. However the heats of formation for individual chemical species are known
and so enthalpies for complex reactions can be calculated, using Hess’ Law.

(a) State Hess’s Law. 2

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(b) Given these heats of formation, ∆Hf : 4

Chemical ∆Hf (kJ mol-1)

C2H2(g +226
CO2(g) -393
CO(g) -115
H2O(l) -286

Calculate the enthalpy change for the combustion of :

(i) 1 mole of ethyne, C2H2 to produce carbon dioxide and water.

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(ii) 1 mole of ethyne, C2H2 to produce carbon monoxide and water.

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(c) Explain the difference in values determined in (b). 2

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End of Theory Exam

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Part B extra writing space.

If you use this space, clearly indicate which question you are answering.

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