2 Jee Main 2021 Feb 24 Second Shift Paper

FIITJEE
Solutions to JEE(Main) -2021

Test Date: 24th February 2021 (Second Shift)
PHYSICS, CHEMISTRY & MATHEMATICS

Paper - 1
Time Allotted: 3 Hours Maximum Marks: 300
 Please read the instructions carefully. You are allotted 5 minutes specifically for this
purpose.
Important Instructions:
1. The test is of 3 hours duration.
2. This test paper consists of 90 questions. Each subject (PCM) has 30 questions. The
maximum marks are 300.
3. This question paper contains Three Parts. Part-A is Physics, Part-B is Chemistry and
Part-C is Mathematics. Each part has only two sections: Section-A and Section-B.
4. Section – A : Attempt all questions.
5. Section – B : Do any 5 questions out of 10 Questions.
6. Section-A (01 – 20) contains 20 multiple choice questions which have only one correct
answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
7. Section-B (01 – 10) contains 10 Numerical based questions with answer as numerical
value. Each question carries +4 marks for correct answer. There is no negative marking.
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JEE-MAIN-2021 (24th February-Second Shift)-PCM-2
PART – A (PHYSICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q1. On the basis of kinetic theory of gases, the gas exerts pressure because its molecules:
(A) Continuously lose their energy till it reaches wall.
(B) Suffer change in momentum when impinge on the walls of container.
(C) Are attracted by the walls of container.
(D) Continuously stick to the walls of container.
Q2. Figure shows a circuit that contains four identical S
resistors with resistance R = 2.0, two identical
inductors with inductance L = 2.0mH and an ideal L
battery with emf E = 9 V. The current ‘i’ just after A R
switch ‘S’ is closed will be: R
E=9V R
(A) 2.25 A (B) 3.0 A L
(C) 9 A (D) 3.37 A
R
L
Q3. The period of oscillation of a simple pendulum is T  2. Measured value of ‘L’ is 1.0 m from
g
meter scale having a minimum division of 1 mm and time of one- complete oscillation is 1.95s
measured from stopwatch of 0.01s resolution. The percentage error in the determination of ‘g’
will be:
(A) 1.33% (B) 1.13%
(C) 1.03% (D) 1.30%
Q4. Zener breakdown occurs in a P n junction having P and n both:

(A) Lightly doped and have wide depletion layer.
(B) Heavily doped and have wide depletion layer.
(C) Lightly doped and have narrow depletion layer.
(D) Heavily doped and have narrow depletion layer.
Q5. A body weighs 49 N on a spring balance at the north pole. What will be its weight recorded on the
same weighing machine, if it is shifted to the equator?
Gm
[ use g = 2 = 9.8 ms2 and radius of earth, R = 6400 km ].
R
(A) 49.83 N (B) 48.83 N
(C) 49 N (D) 49.17 N
Q6. A soft ferromagnetic material is placed in an external magnetic field. The magnetic domains:
(A) Decrease in size and change orientation.
(B) Increases in size but no change in orientation.
(C) May increase or decrease in size and change its orientation.
(D) Have no relation with external magnetic field.
Q7. Given below are two statements:

Statement I : PN junction diodes can be used to function as transistor simply by connecting
two diodes, back to back, which acts as the base terminal.
Statement II : In the study of transistor, the amplification factor  indicates ratio of the collector
current to the base current.
In the light of the above statements, choose the correct answer from the options given below.
(A) Statement I is false but Statement II is true
(B) Statement I is true Statement II is false
(C) Both Statement I and Statement II are false
(D) Both statement I and Statement II are true.
Q8. A particle is projected with velocity v0 along x-axis. A damping force is acting on the particle
which is proportional to the square of the distance from the origin i.e. ma = - x2. The distance at
which the particle stops:
1 1
 2v  3  3v 2  2
(A)  0  (B)  0 
 3   2 
1 1
 2v 2  2  3v 2  3
(C)  0  (D)  0 
 3   2 
Q9. Two electrons each are fixed at a distance ‘2d’. A third charge proton placed at the midpoint is
displaced slightly by a distance x ( x << d) perpendicular to the line joining the two fixed charges.
Proton will execute simple harmonic motion having angular frequency:
(m = mass of charged particle)
1 1
 2q2 2  20 md3 2
(A)  3  (B)  
 0md   q2 
1 1
 q2 2  20 md3 2
(C)  3  (D)  2 
 20 md   2q 
Q10. According to Bohr atom model, in which of the following transitions will the frequency be
maximum ?
(A) n = 3 to n= 2 (B) n = 4 to n = 3
(C) n = 2 to n = 1 (D) n = 5 to n = 4
Q11. In the given figure, a body of mass M is held

between two massless springs, on a smooth inclined
plane. The free ends of the springs are attached to k
firm supports. If each spring has spring constant k,
the frequency of oscillation of given body is: M
k
1 k 1 k
(A) (B)
2 2m 2 Mgsin 
1 2k 1 2k
(C) (D)
2 M 2 Mgsin 
Q12. An X- ray tube is operated at 1.24 million volt. The shortest wavelength of the produced photon
will be:
(A) 104 nm (B) 103 nm
1
(C) 10 nm (D) 102 nm
Q13. When a particle executes SHM, the nature of graphical representation of velocity as a function
of displacement is:
(A) Circular (B) Straight line
(C) Parabolic (D) Elliptical
Q14. If one mole of an ideal gas at (P1 V1) is P

allowed to expand reversibly and
isothermally ( A to B) its pressure is
reduced to one- half of the original P1 A
pressure (see figure). This is followed by
a constant volume cooling till its pressure
is reduced to one-fourth of the initial P1 B
value (B  C). Then it is restored to its 2
initial state by a reversible adiabatic P1
compression (C to A). The net work done
C
4
by the gas is equal to: V
V1 2V1
(A) 0 (B) RT ln2
 1  RT
(C) RT  ln 2   (D) 
 2    1  2    1

Q15. Match List – I with List –II

List – I List – II
(a) Source of microwave frequency (i) Radioactive decay of nucleus
(b) Source of infrared frequency (ii) Magnetron
(c) Source of Gamma Rays (iii) Inner shell electrons
(d) Source of X- rays (iv) Vibration of atoms and molecules
(v) LASER
(vi) RC circuit
Choose the correct answer from the option given below:
(A) (a) – (ii), (b) – (iv), (c) - (vi), (d) – (iii)
(B) (a) – (ii), (b) – (iv), (c) – (i), (d) – (iii)
(C) (a) – (vi),(b) – (iv), (c) – (i), (d) - (v)
(D) (a) – (vi), (b) - (v), (c) – (i), (d) – (iv)
Q16. If the source of light used in a Young’s double slit experiment is changed from red to violet:
(A) The fringes will become brighter.
(B) Consecutive fringe lines will come closer
(C) The central bright fringe will become a dark fringe
(D) The intensity of minima will increase
Q17.
A C
B
The logic circuit shown above is equivalent to:
(A) (B)
A C A C
B
B
(C) A (D)
C A C
B B
Q18. The de Broglie wavelength of a proton and  - particle are equal. The ratio of their velocities is:
(A) 4:2 (B) 4 :3
(C) 4 :1 (D) 1:4
Q19. Which of the following equations represents a traveling wave?

(A) y = A sinx cost (B) y = Asin(15x 2t)
2
x
(C) y=Ae cos(t  ) (D) y = Ae  x (vt + )
a Y- aixs
Q20. A circular hole of radius   is cut of a circular
 2
disc of radius ‘a’ as shown in figure. The
centroid of the remaining circular portion with a
respect to point ‘O’ will be: a/2
x- aixs
O
5 1
(A) a (B) a
6 6
10 2
(C) a (D) a
11 3
SECTION - B
(Numerical Answer Type)
This section contains 10 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place).
Q1. The root mean square speed of molecules of a given mass of a gas at 27oC and 1 atmosphere
pressure is 200 ms1. The root mean square speed of molecules of the gas at 127oC and 2
x
atmosphere pressure is ms1. The value of x will be…………….
3
Q2. A point charge of + 12C is at a distance +q
6 cm vertically above the centre of a
squared of side 12cm as shown in figure.
The magnitude of the electric flux
through the square will be………… 103 6cm
Nm2 / C.
12cm
12cm
Q3. A uniform thin bar of mass 6 kg and length 24 meter is bent to make an equilateral hexagon. The
moment of inertia about an axis passing through the centre of mass and perpendicular to the
plane of hexagon is………..101 kg m2.
Q4. A uniform metallic wire is elongated by 0.04 m when subjected to a linear force F. The elongation,
if its length and diameter is doubled and subjected to the same force will be …………..cm.
Q5. A series LCR circuit is designed to resonate at an angular frequency 0 = 105 rad/s. The circuit
draws 16 W power from 120 V source at resonance. The value of resistance ‘R’ in the circuit is
…………………..
Q6. A signal of 0.1 kW is transmitted in a cable. The attenuation of cable is -5dB per km and cable
length is 20 km. The power received at receiver is 10xW. The value of x is………………
P 
[ Given in dB = 10 log10  0  ]
 Pi 
Q7. An electromagnetic wave of frequency 3GHz enters a dielectric medium of relative electric
permittivity 2.25 from vacuum. The wavelength of this wave in that medium will
be………………102cm.
Q8. A cylindrical wire of radius 0.5 mm and conductivity 5  107 S / m is subjected to an electric field
of 10mV/m. The expected value of current in the wire will be x 3mA. The value of x is
……………...
Q9. Two cars are approaching each other at an equal speed of 7.2 km / hr. When they see each
other, both blow horns of 676 Hz. The beat frequency heard by each driver will be……………Hz.
[Velocity of sound in air is
340 m/s]
Q10. Two solids A and B of mass 1kg and 2kg respectively are moving with equal linear momentum.
A
The ratio of their kinetic energies (K.E)A : (K.E)B will be , so the value of A will
1
be…………………...
PART – B (CHEMISTRY)
SECTION - A
Q1. What is the correct order of the following elements with respect to their density?
(A) Zn < Cr < Fe < Co < Cu (B) Zn < Cu < Co < Fe < Cr
(C) Cr < Fe < Co < Cu < Zn (D) Cr < Zn < Co < Cu < Fe
Q2. Match List – I and list – II.

(a) Valium (i) Antifertility drug
(b) Morphine (ii) Pernicious anaemia
(c) Norethindrone (iii) Analgesic
(d) Vitamin B12 (iv) Tranquilizer
(A) (a) – (iv), (b) – (iii), (c) – (i), (d) – (ii) (B) (a) – (i), (b) – (iii), (c) – (iv) , (d) – (ii)
(C) (a) – (ii), (b) – (iv) (c) – (iii), (d) – (i) (D) (a) – (iv), (b) – (iii), (c) – (ii), (d) – (i)
Q3. Most suitable salt which can be used for efficient clotting of blood will be:
(A) Mg(HCO3)2 (B) FeSO4
(C) NaHCO3 (D) FeCl3
Q4. Match List – I with List – II
(Metal) (Ores)
(a) Aluminium (i) Siderite
(b) Iron (ii) Calamine
(c) Copper (iii) Kaolinite
(d) Zinc (iv) Malachite
Choose the correct answer from the options given below:
(A) (a) – (iii), (b) – (i) , (c) – (iv), (d) – (ii) (B) (a) – (iv), (b) – (iii), (c) – (ii), (d) – (i)
(C) (a) – (ii), (b) – (iv), (c) – (i), (d) – (iii) (D) (a) – (i), (b) – (ii), (c) – (iii), (d) – (iv)
Q5. Match List – I and List – II

O
(a) R C Cl R CHO (i) Br2 / NaOH

(b) R CH2 COOH R HC COOH (ii) H2 / Pd - BaSO 4
Cl
O
(c) R C NH2 R NH2
(iii) Zn(Hg) / Conc. HCl
O
(d) R C CH3 R CH2 CH3 (iv) Cl 2 / Red P, H2O
(A) (a) – (iii), (b) – (i), (c) – (iv), (d) –(ii) (B) (a) – (iii), (b) – (iv), (c) – (i), (d) – (ii)
(C) (a) – (ii), (b) – (i), (c) – (iv), (d) – (iii) (D) (a) – (ii), (b) – (iv) , (c) – (i), (d) – (iii)
Q6. The incorrect statement among the following is:

(A) VOSO4 is a reducing agent
(B) RuO4 is an oxidizing agent
(C) Cr2O3 is an amphoteric oxide
(D) Red colour of ruby is due to the presence of Co3+
Q7. Which one of the following compounds is non- aromatic?
(A) (B)
O
(D)
(C)
Q8. Given below are two statements : one is labelled as Assertion A and the other is labelled as
Reason R.
Assertion A : Hydrogen is the most abundant element in the Universe, but it is not the most
abundant gas in the troposphere.
Reason R : Hydrogen is the lightest element
In the light of the above statements, choose the correct answer from the options given below:
(A) Both A and R are true but R is NOT the correct explanation of A
(B) A is false but R is true
(C) Both A and R are true and R is the correct explanation of A
(D) A is true but R is false
Q9. The correct set from the following in which both pairs are in correct order of melting point is :
(A) LiF > LiCl ; MgO > NaCl (B) LiCl > LiF; NaCl > MgO
(C) LiF > LiCl; NaCl > MgO (D) LiCl > LiF; MgO > NaCl
Q10. The calculated magnetic moments (spin only value) for species [FeCl4]2 , [Co(C2O4)3]3 and
MnO24 respectively are:
(A) 4.90, 0 and 1.73 BM (B) 5.92, 4.90 and 0 BM
(C) 4.90, 0 and 2.83 BM (D) 5.82, 0 and 0 BM
Q11. Which one of the following carbonyl compound cannot be prepared by addition of water on an
alkyne in the presence of HgSO4 and H2SO4?
O O
(A) CH3 CH2 C H (B) CH3 C CH2CH3
O
O
(C) C CH3
(D) CH3 C H
Q12. In polymer Buna – S: ‘S’ stands for:

(A) Sulphonation (B) Strength
(C) Sulphur (D) Styrene
Q13. What is the correct sequence of reagents used for converting nitrobenzene into m-
dibromobenzene?
NO 2 Br
Br
(A) Sn / HCl Br2 NaNO2 NaBr
(B) Sn / HCl KBr Br2 H+
Br2 / Fe Sn / HCl NaNO2 / HCl CuBr / HBr

(C)
NaNO2 HCl KBr H+

(D)
Q14. The diazonium salt of which of the following compounds will form a coloured dye on reaction with
- Naphthol in NaOH?
CH3
N CH3 CH2NH2
(A) (B)
NH2 NH CH3
(C) (D)
Q15. Given below are two statements:

Statement I : The value of the parameter “ Biochemical Oxygen Demand (BOD)’ is important
for survival of aquatic life.
Statement II : The optimum value of BOD is 6.5 ppm.
In the light of the above statements, choose the most appropriate answer from the options given
below:
(A) Both statement I and Statement II are false
(B) Statement I is false but Statement II is true
(C) Statement I is true but Statement II is false
(D) Both Statement I and Statement II are true
Q16. The correct order of the following compounds showing increasing tendency towards nucleophilic
substitution reaction is:
Cl Cl CH3 Cl
NO2 O2 N NO2
NO2 NO2 NO2

(i) (ii) (iii) (iv)
(A) (iv) < (i) < (iii) < (ii) (B) (iv) < (iii) < (ii) < (i)
(C) (i) < (ii) < (iii) < (iv) (D) (iv) < (i) < (ii) < (iii)
Q17. According to Bohr’s atomic theory:

z2
(A) Kinetic energy of electron is 2
n
(B) The product of velocity (v) of electron and principal quantum number (n) ‘vn’  Z2
3
(C) Frequency of revolution of electron in an orbit is  Z
n3
(D) Coulombic force of attraction on the electron is  Z3
n4
Choose the most appropriate answer from the options given below:
(A) (A) and (D) only (B) A only
(C) (A), (C) and (D) only (D) (C) only
Q18. Match List – I with List – II

List – I (salt) List – II (Flame colour wavelength)
(a) LiCl (i) 455.5 nm
(b) NaCl (ii) 670.8 nm
(c) RbCl (iii) 780.0 nm
(d) CsCl (iv) 589.2 nm
(A) (a) – (ii), (b) – (iv) , (c) – (iii), (d) – (i)
(B) (a) – (ii), (b) – (i), (c) – (iv), (d) – (iii)
(C) (a) – (i), (b) – (iv), (c) – (ii), (d) – (iii)
(D) (a) – (iv) , (b) – (ii), (c) – (iii), (d) – (i)
Q19. The correct shape and I – I – I bond angles respectively in I3 ion are:
o
(A) Linear; 180
o o
(B) T- shaped ; 180 and 90
o
(C) Trigonal planar; 120
(D) Distorted trigonal planar; 135o and 90o
Q20.
Which of the following reagent is suitable for the preparation of the product in the above reaction?
(A) Red P + Cl2 (B) Ni / H2
 
(C) NH2  NH2 / C2H5 ONa (D) NaBH4
SECTION - B
decimal place).
Q1. The total number of amines among the following which can be synthesized by Gabriel synthesis
is…………….
H3C
(A) H C CH CH2 NH2
3 (B) CH3CH2NH2
CH2 NH2 NH2
(C) (D)
Q2. Sucrose hydrolyses in acid solution into glucose and fructose following first order rate law with a
 1
half- life of 3.33 h at 25oC. After 9h, the fraction of sucrose remaining is f. The value of log10  
f
2
is …………….10 . (Rounded off to the nearest integer)
[Assume: ln10=2.303, ln2 = 0.693]
Q3. The solubility product of Pbl2 is 8.0  109. The solubility of lead iodide in 0.1 molar solution of
lead nitrate is x 106 mol / L. The value of x is …………….. (Rounded off to the nearest integer)
[Given 2 = 1.41]
Q4. The formula of a gaseous hydrocarbon which requires 6 times of its own volume of O2 for
complete oxidation and produces 4 times its own volume of CO2 is CxHy. The value of y is
…………….
Q5. 1.86 g of aniline completely reacts to form acetanilide. 10% of the product is lost during
purification. Amount of acetanilide obtained after purification (in g) is …………….102.
Q6. The volume occupied by 4.75 g of acetylene gas at 50oC and 740 mmHg pressure is…………….L
(Rounded off to the nearest integer)
[Given R = 0.0826L atm K-1 mol-1]
+
Q7. The magnitude of the change in oxidising power of the MnO 4 / Mn2  couple is x 104 V, if the H
concentration is decreased from 1M to 104 M at 25oC (Assume concentration of MnO4 and
+
Mn2  to be same on change in H concentration). The value of x is ……………. (Rounded
off to the nearest integer)
[ Given : 2.303RT  0.059 ]
F
o
Q8. Assuming ideal behaviour, the magnitude of log K for the following reaction at 25 C is x 101 .
The value of x is …………….. (integer answer)
3HC  CH(g)  C6H6(l)
[Given : fGo(HCCH) =  2.04 105J mol-1 ; fGo(C6H6) = 1.24  105 J mol1:
R = 8.314 JK1mol1]
Q9. C6H6 freezes at 5.5oC. The temperature at which a solution of 10 g of C4H10 in 200g of C6H6
o o
freeze is ……………. C (The molal freezing point depression constant of C6H6 is 5.12 C / m)
Q10. Among the following allotropic forms of sulphur, the number of allotropic forms, which will show
paramagnetism is …………….
(A)  - sulphur (B) - sulphur (C) S2 - form
PART – C (MATHEMATICS)
SECTION - A
Q1. Let f(x) be a differentiable function defined on [0, 2] such that f '( x)  f '(2  x) for all x(0,2),
2
2
f(0) = 1 and f(2) = e . Then the value of  f(x) dx is
0
(A) 2(1+e2) (B) 1 – e2
(C) 1 + e2 (D) 2(1-e2)
3
2
Q2. The value of the integral  [x  2x  2] dx, where [x] denotes the greatest integer less than or
1
equal to x, is
(A)  2  3  1 (B)  2  3  1
(C) -5 (D)  4
Q3. For the system of linear equations:

x – 2y = 1, x-y + kz = 2, ky +4z = 6, kR,
Consider the following statements:
(A) The system has unique solution if k 2, k 2.
(B) The system has unique solution if k =  2.
(C) The system has unique solution if k= 2.
(D) The system has no solution if k = 2.
(E) The system has infinite number of solutions if k 2.
Which of the following statements are correct?
(A) (B) and (E) only (B) (A) and (E) only
(C) (C) and (D) only (D) (A) and (D) only
Q4. Let a, b R. If the mirror image of the point P ( a, 6, 9) with respect to the line
x  3 y  2 z 1
  is
7 5 9
(20, b, a 9), then |a +b | is equal to:
(A) 90 (B) 86
(C) 84 (D) 88
Q5. Let a, b, c be in arithmetic progression. Let the centroid of the triangle with vertices (a, c), (2,b)
 10 7 
and (a, b) be  ,  . If ,  are the roots of the equation ax 2 + bx + 1= 0, then the value of
 3 3
 2  2   is:
69 69
(A)  (B)
256 256
27 71
(C) (D) 
256 256
Q6. Let f: R  R be defined as

55x, if x  5

f(x) = 2x3  3x 2  120x, if  5  x  4
 3 2
2x  3x  36x  336, if x  4,
Let A = {xR: f is increasing}. Then A is equal to:
(A) (5, 4)  (4,) (B) (,5)  (4, )
(C) (,5)  (4, ) (D) (5, )
Q7. The probability that two randomly selected subsets of the set { 1, 2, 3, 4, 5} have exactly two
elements in their intersection is:
65 35
(A) 7 (B) 7
2 2
135 65
(C) 9 (D) 8
2 2
Q8. The area of the region : R = {(x, y) : 5x 2  y  2x2 + 9} is:

(A) 9 3 square units (B) 12 3 square units
(C) 6 3 square units (D) 11 3 square units
Q9. Let A and B are 33 real matrices such that A is symmetric matrix and B is skew- symmetric
matrix. Then the system of linear equations (A2B2  B2A2) X = O, where X is a 31 column matrix
of unknown variables and O is a 31 null matrix has:
(A) a unique solution (B) exactly two solutions
(C) infinitely many solutions (D) no solution
 3 3 1
Q10. For which of the following curves, the line x  3y  2 3 is the tangent at the point  , ?
 2 2 
 
1
(A) 2x2 18y2 = 9 (B) y 2  x
6 3
(C) x2 + y2 = 7 (D) x2 + 9y2 = 9
Q11. If n  2 is a positive integer, then the sum of the series n 1

C2  2  2

C2 3 C2  4 C2  .... n C2 is:
2
n  n  1  n  2  n  n  1 2n  1
(A) (B)
12 6
n  n  1 2n  1 n  2n  1 3n  1
(C) (D)
6 6

Q12. The vector equation of the plane passing through the intersection of the planes r. î  ˆj  kˆ = 1  

 
and r. î  2jˆ  2 , and the point (1,0,2) is:
 7 

(A) r. î  7ˆj  3kˆ  
3

(B) r. 3iˆ  7ˆj  3kˆ  7 
 7 

(C) r. î  7ˆj  3kˆ  
3

(D) r. î  7ˆj  3kˆ  7 
Q13. The negation of the statement p(pq) is:
(A) p q (B) pq
(C) pq (D) pq
Q14. Let f be a twice differentiable function defined on R such that f(0)=1, f '(0)  2 and f(x)0 for all
f(x) f '(x)
xR. If = 0, for all xR, then the value of f(1) lies in the interval.
f '(x) f "(x)
(A) (3,6) (B) (6,9)
(C) (0,3) (D) (9,12)
Q15. If P is a point on the parabola y = x2 + 4 which is closest to the straight line y = 4x – 1, then the
co-ordination of P are:
(A) (2,8) (B) (3,13)
(C) (1,5) (D) (-2,8)
1 63 
Q16. A possible value of tan  sin1  is:
4 8 

1
(A) (B) 2 2  1
7
1
(C) (D) 7 1
2 2
Q17. For the statements p and q, consider the following compound statements:
(a) (q  (p  q))  p
(b) ((p  q)  p)  q
Then which of the following statements is correct?
(A) (b) is a tautology but not (a) (B) (a) is a tautology but not (b)
(C) (a) and (b) both are tautologies (D) (a) and (b) both are not tautologies
Q18. If the curve y = ax 2 + bx+ c, xR passes through the point (1, 2) and the tangent line to this curve
at origin is y = x, then the possible values of a,b,c are:
1 1
(A) a  ,b  ,c  1 (B) a  1,b  1,c  1
2 2
(C) a  1,b  1,c  0 (D) a  1,b  0,c  1
Q19. The angle of elevation of a jet plane from a point A on the ground is 60o. After a flight of 20
seconds at the speed of 432 km / hour, the angle of elevation changes to 30o. If the jet plane is
flying at a constant height, then its height is:
(A) 3600 3 m (B) 2400 3 m
(C) 1200 3 m (D) 1800 3 m
dy
Q20. If a curve y = f(x) passes through the point (1,2) and satisfies x  y  bx 4 , then for what value
dx
2
62
of b,  f(x)dx  5
?
f
62
(A) 5 (B)
5
31
(C) 10 (D)
5
SECTION - B
decimal place).
Q1. Let  be an integer. If the shortest distance between the lines x= 2y 1 = 2z and
7
x = y + 2 = z   is , then the value of || is…………….
2 2
 n   n C , if n  r  0
Q2. For integers n and r, let     r
 r   0, otherwise
The maximum value of k for which the sum
k 10
  15  k 1  12  13 
  i  k  i     i   k  1  i  exists, is equal to…………….
i 0    i 0    
21 21
Q3. Let i  1 . If
 1  i 3  
1  i 3  = k, and n = [|k|] be the greatest integral part of |k|. Then
1  i24 1  i 24
n 5 n5
2
  j  5     j  5 is equal to…………….
j 0 j 0
2 27
Q4. The number of the real roots of the equation (x +1) + |x-5| = is …………….
4
Q5. Let a point P be such that its distance from the point (5,0) is thrice the distance of P from the
point (5,0). If the locus of the point P is a circle of radius r, then 4r2 is equal to…………….
65
Q6. The sum of first four terms of a geometric progression (G.P) is and the sum of their respective
12
65
reciprocals is . If the product of first three terms of the G.P is 1, and the third term is , then
18
2 is…………….
Q7. The students S1, S2,………S10 are to be divided into 3 groups A, B and C such that each group
has at least one student and the group C has at most 3 students. Then the total number of
possibilities of forming such groups is…………….
 1
f(x)  f  
 1  x
Q8. If a +  =1, b +=2 and af(x) + f    bx  ,x  0 , then the value of the equation
x
  x 1
x
x
is…………….
Q9. If the variance of 10 natural numbers 1,1,1……1, k less than 10, then the maximum possible
value of k is…………….
Q10. If the area of the triangle formed by the positive x-axis, the normal and the tangent to the circle
(x2)2 + (y3)2 = 25 at the point (5, 7) is A, then 24A is equal to…………….
FIITJEE
KEYS to JEE (Main)-2021
SECTION - A
1. B 2. A 3. B 4. D
5. B 6. C 7. A 8. D
9. C 10. C 11. C 12. B
13. D 14. C 15. B 16. B
17. D 18. C 19. B 20. A
SECTION - B
1. 400 2. 226 3. 8 4. 2
5. 900 6. 8 7. 667 8. 5
9. 8 10. 2
SECTION - A
1. A 2. A 3. D 4. A
5. D 6. D 7. B 8. C
9. A 10. A 11. A 12. D
13. C 14. C 15. C 16. C
17. A 18 A 19. A 20. C
SECTION - B
1. 3 2. 81 3. 141 4. 8
5. 243 6. 5 7. 3776 8. 855
9. 1 10. 1
SECTION - A
1. C 2. A 3. D 4. D
5. D 6. A 7. C 8. B
9. C 10. D 11. B 12. D
13. C 14. B 15. A 16. A
17. C 18. C 19. C 20. C
SECTION – B
1. 1 2. Question Dropped 3. 310
4. 2 5. 56 6. 3
7. 31650 8. 2 9. 11
10. Question Dropped
FIITJEE
Solutions to JEE (Main)-2021
SECTION - A
1. According to KTG, the gas exerts pressure because its molecule:
suffer change in momentum when impinge on the walls of container .
2. R = 2 S
L = 2 mH
E = 9V L
A R
 9v
i   2.25A R
2R 4
Just after the switch ‘S’ is closed, the E=9V R L
inductor acts as open circuit.
R
L L
3. T  2 or T 2  4 2  
g  g
 L 
 g  4 2  2 
T 
g  L 2T   1mm 2  0.01
 %  %     100%   0.001  0.0102   100 = 1.13%
g  L T   1m 1.95 
4. Zener break down occurs in p-n junction having p and n both: Heavily doped and have narrow
depletion layer.
5. As we go from pole to equator, acceleration due to gravity decreases. So, weight of the body will
also reduces. Thus, weight on equator will be slightly smaller than 49N.
ie, 48.83 N.
6. When a soft ferromagnetic substance is placed in external magnetic field, the size of domain lying
in the opposite direction of external magnetic field increases while size of domain lying in the
opposite direction of field decreases if field is weak. However, if field is strong then the domain
rotate in the direction of external magnetic field due to strong torque.
7. A tristor is formed by doping a semi conducting wafer from one side by N-type dopant (high
concentration) while comparatively lower concentration on other side thus forming NPN tristor &
vice- versa.
So, statement (I) is false & statement (II) is true.
mvdv
8. F = - x 2   x 2
dx
0 x 2
 2 02 v 0  3
  vdv   x dx    x
v0
m 0 2 2 3m
1/ 3
v 2  3  3v 2m 
 0  x  x   0 
2 3m  2 
 2ke2  p
2kee  
9. Fnet = 2 sin  

d  x2
 
 d2  2 
   
x

 e
[ for small displacement i.e, x is small so, sin  e
d d
  tan]
2ke2 x 1 2 x
 .  2. q 3 [ q = e]
d 2
x 2
 d 40 d
q2
 x = m2 x
20 d3
q2
 
20 d3 m
 1 1
10. E  hv   2  2 
n 
 2 n1 
(1) n1 = 3 , n2 = 2
 1 1  94 5
 2  2   36  36
2 3 
(2) n1 =4 , n2 = 3
 1 1  16  9 7
 2  2   144  144
3 4 
(3) n1 = 2, n2 = 1
 1 1  4 1 3
 2  2 4 4
1 2 
(4) n1 = 5, n2 = 4
 1 1  25  16 9
 2  2   400  400
4 5 
11. Here, Keq = 2k

m
T  2 k
2k
1 2k
f  k M
2 m
6
12. V = 1.24 10 volt
min = ?
hc 1242nm 1000  109
min = = =  min = 103 nm

eV e 1.24  106  106
13. Let x = A sint & v = A cost v

ellipse
v =  A 2  x 2
v 2  2 x 2  2 A 2 x
v2 x2
 1
2 A 2 A 2
14. n=1mole P
v 2v
W AB = nRT ln 2  1 RT ln 1  RT ln2
v1 v1 A(P1,V1,T)
P1 isothermal
W BC = 0
P1
 2V1  P1  V1 P 
P1V1  P2 V2 B  1 ,2V1,T 
WCA   4 P1
2 
 1  2
P1 P T
P1V1 C  1 ,2V1, 
 P1V1 4 4 2
p1v1 1RT
 WCA  2 = = V
 1 2    1 2    1 V1 2V1
RT
 WCA 
2    1
 1 
 W total = RT  n2  
 2    1 
15. (A) Source of microwave frequency  Magnetron

(B) Source of infrared frequency  Vibration of atoms and molecules
(C) Source of Gamma rays  Radioactive decay of nucleus
(D) Source of x- rays  inner shell electrons.
16. Red > violet

D
  Fringe width
d
If the source of light used in a Young’s double slit experiment is changed from red to
violet:consecutive fringe lines will come closer.
17. Truth Table

A C A C
B B A B C
0 0 0
0 1 1
1 0 0
1 1 0
h h
18.  or  
p mv
p    [ Given]
h h v p m
  
mp v p m v  v  mp
vp 4m 4
   or 4:1
v m 1
 x
19. Traveling wave is represented by f  t  
 v
Thus, y = A sin (15x – 2t) represents a travelling wave
20.
y-axis
M1  a 2 a 2
M2 
removed 4

a/2 x  C1 C2
a
 a 
 3 2 ,0 
 
m1x1  m2 x2
x cm =
m1  m2
a2 3a 5
a2  a   a3
4 2 =8 5 4 5
=  a2  a2  a
 a 2 3 2 8 3 6
a 2  a
4 4
SECTION - B
1. T= 27oC, P= 1atm = 105N/m2, Vrms = 200m/s
As we know
3RT
3RT v rms M
v rms   
M v 'rms 3RT '
M
200 T 300
 
V 'rms T' 400
2 x
V 'rms  200  
3 3
x= 400
2. Flux through the 6 sides of square (i.e cube)

q 12  10 6 C +q
T  in =
0 0
 Flux through a square
 12  106 2  10 6 6cm
 T = =
6 0  6 0
2  106 C
 Nm2 / C2
8.85  1012
   0.22598  106 12cm
   225.98  103 Nm2 / C  226Nm2 / C 12cm
3.
B
A 0.2m M B
A C
6kg
2.4m O 0.4
F D O
E
Let mAB = m = 1kg
AB = 0.4m = 
d = OM = 0.16  0.04  0.12
d = 2 3  101
2
IAB about O = m  md2
12
 m 2  m 2
Ihexagon, about O =6  md2    6md2
 12  2
2
1  0.4  0.16 2
=
2

 6  1 2 3  10 1
2
  6  4  3  10 2
=
= 0.08  0.72 = 0.8kgm2 = 8  101 kgm2
4. As we know that
FL
Y
AL
FL
L = 0.04m = ……………………….(i)
AY
If length and diameter both are doubled
F.2L FL
L '   = 0.02m = 2cm
4A.Y 2Y
5
5. 0 = 10 rad / sec
P = 16w , 120v at resonance
2
v2 120  14400
P  16  R  900
R R 16
P  I
6. Sound level is given in dB = 10log  0  or 10 log  
 Pi   I0 
As sound level decreases 5dB every km,
So, in 20 km sound level will decrease by 20  5 = 100dB.
I 
 = 2 - 1 = 10 log  2 
 I1 
I 
-100 = 10log  2 
 I1 
I 
-10 = log  2 
 I1 
I
10 10  2  I2  1010 I1
I1
P2  1010 P1
 
P2  1010  0.1 103  P2  108 W  10 x W
x=8
7. f = 3GHz = 3109 Hz
v 3  108 m / s
vacuum =   10 1m  0.1m
f 3  109 / s
 0.1
 vacuum  vacuum 
medium medium
medium  r r  1 2.25  1.5
0.1m
 medium   0.0667m = 6.67cm= 667  10 2 cm
1.5
8. radius r = 0.5 mm
  5  107 s / m

E  10  103 V / m  102 V / m
As we know
J  E
i
J =  E
A
2

 i  EA = 5  107  102    0.5  103  = 1.25  10 1 A = 125 mA = x3  mA
x=5
5
9. 7.2   2m / s [ VA= VB = 2m/s]
18
VB
VA
A B
 v  vB 
f 'B  fA  
 v  vA 

App freq heard by car B
 340  2  342
f 'B  676    676  = 684 Hz
 340  2  338
 v  vB 
Similarly , f 'A  fB    684 Hz
 v  vB 
 Beat frequency heard by both = 684 – 676= 8Hz
10. A  mA = 1kg , PA = P
B  mB = 2kg , PB = P
P2
 kE 
2m
 P2 
 
kE A  2mA  mB 2
   
kEB  P 2  mA 1
 
 2mB 
SECTION - A
mass
1. Density =
Volume
Cu > Co > Fe > Cr > Zn
2. Valium – Tranquilizer
Morphine – Analgesic
Norethindrone – Antifertility drug
Vitamin B12 – Pernicious anaemia
3. Blood – Negatively charged colloid.

According to Hardy – Schulze Rule
FeCl3 is more efficient for blood clotting
4. Aluminium – Kaolinite
Iron – Siderite
Copper – Malachite
Zinc – Calamine
5.
O O
H2 / Pd - BaSO4
R C Cl R C H (Rosenmund Reduction)
O O
Cl2 / Red P, H2O
R CH2 C OH R CH C OH (HVZ)
Cl
O
Br2, NaOH
R C NH2 R NH2 (Hoffmann Bromamide)
O
Zn(Hg)
R C CH3 R CH2 CH3 (Clemmenson Reduction)
Conc. HCl
4+
6. VOSO4  V Reducing agent
Cr2O3  Amphoteric oxide
Red colour of ruby due to Cr3+ present in Al2O3
Ru8+  oxidizing agent
7.
Cyclic Conjugation Cycllic Cycllic

Planar Is not present Planar Planar
Follow Huckle Rule in whole ring Huckle Rule Follow Huckle Rule
Conjugation Conjugation
Conjugation
8. Hydrogen is most abundant element in earth crust and lightest element. But in troposphere
nitrogen gas is most abundant element
9.
LiF LiCl
+ - + -
Li F Li Cl
LiF has more lattice enthalpy than LiCl
MgO NaCl
2+ 2- + -
Mg O Na Cl
MgO has more lattice enthalpy than NaCl
10.
[ FeCl4 ]2-
0 6
[Fe] [Ar] 4s2 3d6 Fe2+ = 4s 3d
Cl Weak field ligand [Ar]
n=4
  4  4  2
= 4.90 BM
3 3+
[Co(C2O4)3]  Co
2 7
Co  [Ar]4s 3d
Co = [Ar] 4s 3d6
+3 o
+3
C2 O42  strong field ligand with Co
n=0
 = 0 BM
MnO24
Mn6  
Mn  [Ar] 4s2 3d5
o 1
Mn6   [Ar] 4s 3d
n=1
 = n  n  2  = 1 3  =1.73BM
11.
HgSO4
CH3 C C H CH3 C CH2
H2SO4
OH
O
CH3 C CH3
Hence
CH3CH2CHO can’t be formed.
In case of unsymmetrical alkynes, more positive charge stabilizing carbon attacked by H2O and
finally converted into carbonyl.
12. S styrene
Polymerisation
+ Ph-CH=CH2 Buna-S (Butadiene Styrene)
Buta-1,3- diene Styrene
13.
NO 2 NO 2 NH2
Br2 / Fe Sn
 HCl
Br Br
NaNO 2 / HCl
Br N 2Cl
Cu Br
HBr
Br Br
14.
+
N2 Cl
OH
NH2
NaNO2 +
HCl
b-naphthol
1o Amine
N N
OH
orange red dye
15. Clean water would have BOD Value less than 5ppm, highly polluted water could have BOD value
of 17ppm or more.
16. If we add –NO2 group on ortho and para position, then electron deficiency increases in benzene
ring so, order of nucleophilic attack is
Cl Cl Cl Cl
NO 2 NO 2 NO 2
> > >
NO 2 NO 2 NO 2
17. According to Bohr’s theory,

z2 z2
K.E  13.6 2 frequency () of revolution of electron 
n n3
z
v  2.18  106
n
kq q Kze2  n2 
F  12 2 = 2  r  
r r  z 
z3
F
n4
18. Li  Crimson Red

Na  Yellow
Rb  Red violet
Cs  Blue
VIBGYOR
Wavelength
Red violet > Crimson Red > Yellow > Blue
   
780nm 670.8nm 589.2nm 455.5nm
19.
I I I
Linear (180o)
20.
H2N NH2
C2H5ONa
O (Wolff - Kishner Reduction)
SECTION - B
1. Gabriel phthalimide synthesis is used for 1o Aliphatic / alicyclic amine
H3C
CH CH2 NH2
H3C
o
1 Amine
CH3 CH2 NH2

o
1 Amine
CH2 NH2
o
1 Amine
2. C12H22O11 + H2O  C6H12O6 + C6H12O6

Glucose Fructose
2.303 a
K log
t ax
kt a
 log
2.303 ax
ln 2  9  1
 log  
10 f
 2.303
3
 1
log    81.24  102 = 81 10 2
f
3. PbI2  Pb2   2I K sp  8.0  109

Pb  NO3 2  Pb2  2NO3
0.1M - -
- 0.1M 0.1M
PbI2 Pb2  2I

S 2S
(S+0.1)
2
Ksp = 8109; Using K sp  Pb2   I 
2
8109 = 0.1  (2S)
S= 141 106M
 y y
4. Cx Hy (g) +  x   O2 (g)  xCO2 (g) + H2 O()
 4  2
V 6V - -
- - 4V
Volume of CO 2  4  VCx Hy
Vx  4V
x4
Volume of O 2  6  VCxHy
 y
V  x    6V
 4 
y
4  6
4
y
2
4
y 8
O
||
90% efficiency
5. C6H5NH2   C6H5  NH  C CH3
Aniline (Acetanilide)
O
||
1 mole C6H5NH2  1 mole C6H5  NH  C CH3

1.86 w

93 135
W = 2.70g
90
Mass produced actual = 2.70  = 2.43= 243 102g
100
6. W = 4.75g
4.75
n T = 323K , R = 0.0826
26
740
P atm
760
nRT 4.75  0.0826  323
V  = 5litre
P  740 
26  
 760 
7. MnO 4  8H  5e  Mn2   4H2 O
0.059 Mn2    1  8
E1  Eo  log  
5 MnO4   H 
 
[H+] = 1M
0.059 Mn2  
E1  E  o
log  
5 MnO 4 
 
[H+] = 10-4
0.059 Mn2   1 8
E 2  Eo  log   
 
5 MnO4   10 4 
 
0.059 Mn2   0.059
 Eo  log    log10 32
5 MnO4  5
 
So, difference in E1 & E2 is
=0.3776 V
= 3776  104 V
8. 3CH  CH(g)  C6H6 ( )

Go  RTnK ……….(i)
Go = GoP - GoR ……….(ii)
Equating (i) & (ii)
2.303 RTlogk = 4.88  105
4.88  105 488000
logK   = 85.52= 855 101
2.303  R  T 5705.848
So; magnitude of logK = 855 x 101.
9. Tf = kf. m
 10 
 
Tfo – Tf = 5.12   58 
 200 
 1000 
 
5.5 – Tf = 5.12  5  10
58
Tf = 1.086oC=(1.086)oC 1oC
10.  - sulphar & - sulphur – Diamagnetic, S2-form is paramagnetic due to presence of unpaired
electron in * orbital like O2.
SECTION - A
2 2 2
2
1. I   f(x)dx   xf(x)0   xf '(x)dx = 2e2   xf '(x)dx ………………….(A)
0 0 0
2
Put I1   xf '(x)dx …………………( i)
0
b b
Using properties  f(x)dx   f(a  b  x)dx
a a
2 2
I1    2  x  f '  2  x  dx =   2  x  f '  x  dx ……………………..(ii)
0 0
Adding (i) and (ii) we get
2
2I1  2 f '(x)dx  I1  [f(x)]02
0
f(2)  f(0)  e2  1
From (A) I  2e2  e2  1  e2  1
3 3 3 3
2 2
2. I    x 2  2x  1  3 dx =   x  1  3  dx    x  1 dx  3 dx …………………..(A)
   
1 1 1 1
3
2 2
I1    x  1 dx Put  x  1  t
 
1
4
1 dt
I1 
20  t 2  x  1 dx  dt
t
dt
dx 
2 t
 1 2 3 4

1 
1 1
1 1
1  dt dt
1
dt
2 
dt  1  t 2 3
t 2 4
t 2  
I1  0   2  3  =  2 3  5 2 3
2  0 t 1 t t t  2   1  1 1 1
2 3  1   1 
 2 1 2 2 2 3 
Hence from (A)
 5  2  3  6  1  2  3
2nd method
3 3 3 y

1
 2
 
2

I    x  1   3 dx    x  1  dx  3  dx

1 1
4
3
2 3
  x  1 dx  6 …………………………(A)

1
2
3
2
Let I1    x  1  dx
 
1 1
3 x
O 1 2 1 2 1 3
2 1 2 1 3 3
 0  dx  1  dx  2  3  dx
1 2 1 2 1 3
  
= 1 2  2  2 1 3  1 2  3 3  1 3   
= 1  2  2 3  2 2  6  3 3 = 5  2  3
From (A) , I  5  2  3  6  1  2  3
3. x  2y  1 , x  y  kz  2 , ky  4z  6
x  2y  0.z  1  0
x  y  kz  2  0
0x  ky  4z  6  0
1 2 0
  1 1 k  
= 1 4  k 2  2  4  0  = 4  k 2  8 = k 2  4
0 k 4
2
 k  4  k  2
For unique solution   0  k  2
1 2 0
1  2 1 k    k  10  k  2 
6 k 4
For no solution
  0, 1  0
k=2
a  20
4.  3  7r
2
P (a,6,9)
a  20  6  14r …………………(i)
b6
 2  5r
2
b  6  4  10r
b  2  10r …………………….(ii) (3+7r, 2+5r,19r) x  3 y  2 z 1
  r
7 5 9
9a9
 1  9r
2
a  2  18r P(20, b, a9)
a  18r  2 ……………………(iii)
Solving (i) and (iii) we get
20  18r  2  6  14r
4r  8  20  12
r  3
 a = 14 +14(-3) = -56 and b=-2 30 = 32
| a  b | | 56  32 | 88
A (a,c)
a  2  a 10
5. 
3 3
2a  2  0
2a  8  a  4 ………………(i) G
and c bb 7

3 3 B (2,b) C (a,b)
2b  c  7 ----------------(ii)
Since a, b,c are in A.P
2b = a + c
From (i)  2b = 4+c………………..(iii)
Solving (ii) and (iii)
4+c+c=7
2c = 3
3
c
2
3 11
 2b  4  
2 2
11
b 
4
As per question
b 1
   and  
a a
11
11 1
 4   ,  
4 16 4
2
 2   2          3
121 3
 
256 4
121  192 71
 
256 256
y
6. let f:RR
 55, x  5
 2
f '(x)   6x  6x  120,  5  x  4 1 2 3 4
 2 -5 -4 -3 -2 -1
 6x  6x  36, x  4
55, x  5
 x
 6  x  5  x  4  , 5  x  4

6  x  3  x  2  , x4
f’(x) increasing in x   5, 4    4,  
7. Total possibilities = 25 25

5 3 3
Farounable case = C2 3 = 103
10  33 5  27 135
 required probability = 5   9
2  25 29 2
8. Area of shaded region (0,9)

3  3,15 

2  2x  9  5x 2 2
 dx
0
x
3 O
 2  9  3x dx  2

0
3 3
 x3  9 3  3 3 
 3  x 
2
 dx  6 3x    6    12 3
0  3 0  3 
T T
9. A = A and B = B
2 2 2 2
C=A B B A
T 2 2 T 2 2 T 2 2 2 2
C = (A B )  (B A ) =B A  A B
T
C = C. Hence C is skew symmetric matrix
 det (C) = 0
Hence system have infinite solutions
1
10. x  3y  2 3 , and m   ,C  2
3
x2 y 2 9 1 1
(1)  =1  c  a2m2  b2 =    1 , not possible
9 1 2 3 2
2 2
1 a 1  1  1
(2) y 2  x, c     , not possible
6 3 m 24 3  3  72
(3) c  a 1  m2  7  2  2 7 , not possible
x2 y 2 1
(4)   1 , C  9m2  1  9   1  2
9 1 3
11. n 1
C2  2  2
C2  3 C2  4 C2     n C2 
n1
n 1
C2  2 r 1C2
r 1
n 1
C2  2
r  1! n1 C  n1 (r  1)r
n 1
= 2 
r 1  r  1 !2! r 1
n  1! n  1 n  2(n  1)  1 n  1 n n n  1 n n  1 2n  1 n n  1

= + + = + +
2!(n  1)! 6 2 2 6 2
n n  1 2n  1  n 2n  2n  3n  1 2
= n  1  n  1  =  
2 3  2 3 
=

n 6n  2n2  3n  1  =  2n
2
 3n  1 = n  2n  1n  1
6 6 6
 ˆ ˆ ˆ 
12.    
r. i  j  k  1   r. î  2ˆj  2  0  

 
r. 1    î  1  2   ˆj  1  2  0
 point (1,0,2)  î  2kˆ
2
 1    2  1  2  0    
3
  î 7ˆj  7
 r    kˆ    0
3 3  3
 
 ˆ
 ˆ ˆ
r. i  7 j  3k  7 
13. (p(pq)) = pV(pq)
= (pvp)  (pv q)
=pv  q
f(X) f '(x)
14. 0
f '(x) f "(x)
f(x)f "(x)  f '(x)f '(x)
f "(x) f '(x)
 , Integrating on both sides
f '(x) f(x)
ln | f '(x) | ln | f(x) |  ln | c |
f '(x)  cf(x),f '(0)  cf(0)  c  2
f '(x)
 2 , again integrating on both side
f(x)
ln f(x)  2x  k
f(x)  e2x k
f(0)  ek  ek  1  k  0
 f(x)  e2x  e  2.718
2
 e   6,9 
15.
y= x2+4
x2 = y4
y = 4x 1
1 1
( t, t 2  4)
2 4
(0,4) P
1 1
| 4  t  t 2  4  1|
PQ  2 4
17
2
| t  8t  20 |
p
4 17
dp 1 dp
  2t  8  for maximum / minimum , 0 t4
dt 4 17 dt
d2p
also  0at t  4
dt 2
hence closest point becomes at t = 4 is (2,8)
1 63  63
16. tan  sin1  8
4 8
  4
1 1 63 1
Put sin 
4 8
63 1
sin 4   cos 4 
8 8
1 3
2cos2 2   1  cos 2 
8 4
1  tan2  3
  
1  tan2  4
(adding 1 both side)
2 7
2

sec  4
7 8
cos2    sec 2  
8 7
8 1
tan2    1 
7 7
1
tan  
7
17. (A)
P q p q pq q(pq) (q(pq)) p

T T F F T F T
T F F T F F T
F T T F T F T
F F T T T T T
tautology
(B)
pq (pq)p ((pq)p)q

T F T
T F T
T T T
F F T
tautology
18. y=ax2 + bx + c
a+b+c=2
dy dy
  2ax  b  b 1
dx dx  0,0 
It passes through (0,0),
0= 0+0+c  c=0
a =1
 a=1, b=1, c= 0
19. S= 432km/hr 20sec
h
tan60o 
y
h h
h  3y
h 30o
tan30o  A 60o
xy y x
x  y  3h
x  y  3. 3y
x  y  3y
x  2y
1000
 x = 432   20
3600
x  2400m
y  1200m
 h  1200 3 m
dy
20. x  y  bx 4
dx
dy y
  bx 3
dx x
1
 x dx
I.F.  e  eln x  x
bx 5
xy = b x 4 dx  c
5
b b
at(1,2), 1.2   c  c  2 
5 5
2 2 2
 bx 4 10  b   bx 5  10  b  
  f(x)dx      dx     ln x 
1 1
5 5x   25  5  1
As per question
32b b 62
 10  b  ln2  
25 32 5
31 62
b  10  b  ln 2 
25 5
62 31 31 b
10  b  ln2   b   2  
5 25 5 5
 b = 10
SECTION - B
1
y
x 2  z
1. L1  
1 1 1

2 2
x y  2 z  
L2   
1 1 1
   
SD 
 a1  a2  b1  b2
 
 
b1  b2
î ˆj kˆ
 
b1  b2  2 1 1  2iˆ  3ˆj  kˆ
1 1 1
 
b1  b2 2iˆ  3ˆj  kˆ
  
b1  b2 14
   1
b2  b1   0    î   2   ˆj     0  kˆ
 2 
 1  3
2  3  2     5 
 2 2
 SD  
14 14
3
5 
2 7 3 7
   5  
14 2 2 2 2
3 7 2
 5    5   2   
2 2 5
3 7
or 5     5  5    1
2 2
|  | 1
k
 10  15  k 1  12  13 
2.        
i 0  i  k  i  i 0  i  k  1  i 
k 10 15
k 1 12
 Ci Ck i   Ci13 Ck 1i
i 0 i 0
10
C015 Ck  10
C115 Ck 1 10 C215 Ck  2     10 Ck .15 C0
10 15
Equating the coefficient of x k in 1  x   x  1
25
= Equating the coefficient of x in 1  x   25 Ck ……………….(i)
k
k 1 13
12
 Ci Ck 1i
i 0
12
= C013 Ck 1 12 C113 Ck 12 Ck 1      12 Ck 113 C0
12 13
= Equating the coefficient of xk+1 in 1  x   x  1
25
= Equating the coefficient of xk+1 in 1  x  = 25
Ck 1 …………………..( ii)
25 25 26
From (i) and (ii) Ck  Ck 1  Ck 1
Hence 26  k  1  k  25
But maximum value of k is not defined bonus
21 21
 1  i 3 
21
 1  3i 
21
2   2  
 2   2 
3. 24
 24
k
24  1 i  24  1  i 
  2 
 2
  
2 
 2

e14 i 9 e
i7 
29  2 k
ei6  ei6 
1 1
29     k
1 1 
0k
 n  | k |  0
5 5
2
  j  5    j  5
j 0 j 0
5 5
   j  5  j  5  1    j  5  j  4 
j 0 j 0
5
5  6  11 9  5  6
j 0

  j2  9ˆj  20 
6
 2
 20  6
55  135  120  310
27
4.  x  12  | x  5 |
4
Case I x<5
27
x 2  2x  1  x  5 
4
27
x2  x  6   4x2  4x  3  0
4
3 1
 2x  3  2x  1  0  x   ,
2 2
Case II x  5
27
x 2  2x  1  x  5 
4
2 27
x  3x  4 
4
2
4x  12x  43  0
12  144  43  16 12  832
x  (rejected)
2 4 8
Because x > 5
5. Let P(h,k)
 h  5 2  k 2 3  h  5 2  k 2
h2  10h  25  k 2  9h2  90h  225  9k 2
8h2  8k 2  100h  200  0
25
x2  y2  x  25  0
2
625 625  400 225
r2   25  
16 16 16
225
4r 2   56.25
4
6. Let a,ar,ar2,ar3 are in G.P

2 3 65
a+ar+ar +ar =
12
1 1 1 1 65
  2 3 
a ar ar ar 18

a 1 r4 
1 r 65 18
 
1 1  12 65
 1  
a  r4 
1
1
r
2 3 2 3
 ar  r   a  ,r 
2 3 2
2 9 3
 third term = ar 2   
3 4 2
3
    2  3
2
7. A B C
  1
  2
  3
Number of groups = 10
 
C1 29  2  5100
C 2
2
8
 2   11430
C 2
3
7
 2   15120
Total number of groups = 31650
 1 
8. af(x)  f    bx  ………………….(i)
x x
1
Replace x by
x
1
  b
af    f(x)   x …………………..(ii)
x x
 1  1  1  1
a  f(x)  f( )   (f(x)  f( ))  b  x      x  
 x  x  x  x
 1  1
 a     f(x)  f     b     x  
  x   x
 1
f(x)  f  
  x  b  2  2
1 a 1
x
x
2 2
9. 2  x2    x  9  k2  9  k 
 
 n 
    10
n   10  10 
10 10
k  1  k  11
3
 maximum value of k is 11
10. Equation of normal is 4x 3y + 1=0 y

Equation of tangent is 3x+4y43 =0
1  43 1  (5,7)
Area of triangle =   7
2 3 4
(2,3)
1  172  3  1225
  7 
2  12  24
 24A = 1225 O
x
 43 
(-1/4,0)  3 ,0 
 

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FIITJEE

Solutions to JEE(Main) -2021

PHYSICS, CHEMISTRY & MATHEMATICS

Time Allotted: 3 Hours Maximum Marks: 300

5. Section – B : Do any 5 questions out of 10 Questions.

Q4. Zener breakdown occurs in a P n junction having P and n both:

Q7. Given below are two statements:

Q11. In the given figure, a body of mass M is held

Q14. If one mole of an ideal gas at (P1 V1) is P

Q15. Match List – I with List –II

Q19. Which of the following equations represents a traveling wave?

Q2. Match List – I and list – II.

Q5. Match List – I and List – II

(a) R C Cl R CHO (i) Br2 / NaOH

Q6. The incorrect statement among the following is:

Q7. Which one of the following compounds is non- aromatic?

Q12. In polymer Buna – S: ‘S’ stands for:

(A) Sn / HCl Br2 NaNO2 NaBr

(B) Sn / HCl KBr Br2 H+

Br2 / Fe Sn / HCl NaNO2 / HCl CuBr / HBr

NaNO2 HCl KBr H+

Q15. Given below are two statements:

NO2 NO2 NO2

Q17. According to Bohr’s atomic theory:

Q18. Match List – I with List – II

Q3. For the system of linear equations:

Q6. Let f: R  R be defined as

Q8. The area of the region : R = {(x, y) : 5x 2  y  2x2 + 9} is:

Q11. If n  2 is a positive integer, then the sum of the series n 1

11. Here, Keq = 2k

13. Let x = A sint & v = A cost v

15. (A) Source of microwave frequency  Magnetron

16. Red > violet

17. Truth Table

2. Flux through the 6 sides of square (i.e cube)

= 0.08  0.72 = 0.8kgm2 = 8  101 kgm2

3. Blood – Negatively charged colloid.

Cyclic Conjugation Cycllic Cycllic

Cl Weak field ligand [Ar]

orange red dye

17. According to Bohr’s theory,

18. Li  Crimson Red

CH3 CH2 NH2

2. C12H22O11 + H2O  C6H12O6 + C6H12O6

3. PbI2  Pb2   2I K sp  8.0  109

PbI2 Pb2  2I

1 mole C6H5NH2  1 mole C6H5  NH  C CH3

7. MnO 4  8H  5e  Mn2   4H2 O

8. 3CH  CH(g)  C6H6 ( )

7. Total possibilities = 25 25

8. Area of shaded region (0,9)

n  1! n  1 n  2(n  1)  1 n  1 n n n  1 n n  1 2n  1 n n  1

P q p q pq q(pq) (q(pq)) p

pq (pq)p ((pq)p)q

19. S= 432km/hr 20sec

55  135  120  310

6. Let a,ar,ar2,ar3 are in G.P

10. Equation of normal is 4x 3y + 1=0 y

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