Methyl Mesulfuront - SDS Metaprima 20 WDG

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CBA

Centa Brasindo Abadi

Material safety data sheet


1. PRODUCT AND COMPANY IDENTIFICATION

Trade name META PRIMA 20 WDG


Product code P-8.730
MSDS Number SDS/CBA/8.730
Chemical description/Application Herbicide
Manufacturer/ Supplier PT Centa Brasindo Abadi
Intercon Plaza Jln. Raya Meruya Ilir 14 blok A IV No. 27 Jakarta
Barat Indonesia 11620 Telp. +62 21 5868402
Email: info-pesticide@cbachemical.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

Common name Metsulfuron-Methyl


Chemical name Methyl 2[[[[ (4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]
carbonyl]amino]sulfonyl]benzoate)
CAS number 74223-64-6 (Metsulfuron-methyl)

3. HAZARDS IDENTIFICATION

Route of entry Skin absorption, skin contact, eye contact, inhalation, ingestion.
Hazard category Acute
Hazardous identification information -

4. FIRST AID MEASURES

Route(s) of entry: Skin and eye absorption.


Health Hazards (Acute and Chronic): Causes eye irritation and may cause skin irritation.
Sign and Symptoms: Tearing of eyes, pain or blurred vision. May causes skin itching,
burning, redness, and swelling.
Medical Conditions Generally Aggravated by exposure: No information
Emergency First Aid Procedure
Eyes Immediately flush eyes with water for at least 15 minutes and get
medical attention.
Skin Flush with soap and water. Get medical attention if irritation
persists. Remove and launder all contaminated clothing.
Inhalation remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen, and call a physician.
Ingestion Call a physician or Poison Control Center.

5. FIRE FIGHTING MEASURES

Flash point >200oF


Extinguishing media Water spray, foam, dry chemical, carbon dioxide.
Special fighting procedure Runoff from fire fighting may be a pollution hazard. Control
runoff.
Unusual fire and explosion hazards Like most powders, under severe dusting conditions, this material
may form explosive mixtures in air.
CBA
Centa Brasindo Abadi

6. ACCIDENTAL RELEASE MEASURES

Personal precautions For personal protection see Section 8.


Environmental precautions Do not discharge into the drains or water courses.
Methods for cleaning up Contain spill, sweep up and store material in a closed container
for future use or disposal. Wear appropriate protective equipment.

7. HANDLING AND STORAGE

Handling Avoid breathing vapors. Avoid contact with eyes, skin, or


clothing. Washing thoroughly after handling this product. Do not
store on consume food, drink or tobacco in areas where they may
become contaminated with this material.
Users should Wash hands before eating, drinking, chewing gum, using tobacco
or using toilet. Remove clothing immediately if pesticide get
inside. Then wash thoroughly and put on clean clothing. Remove
personal protective equipment immediately after handling this
product. Wash the outside of gloves before removing. As soon as
possible, wash thoroughly and change into clean clothing.
Storage Store below 284o F.

8. EXPOSURE CONTROL/PERSONAL PROTECTION

Ventilation requirements Use local exhaust ventilation for indoor operations.


Personal protective equipment
Protective clothing Long sleeved shirt, long pants, shoes and shocks, and chemical
resistant gloves.
Eye protective Safety glasses with side shield or safety goggles.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance @ 28º C Odorless off-white granules.


Melting point Not indicated Boiling point Not indicated
Evaporation rate (Butyl Acetate =1) <1
Vapour pressure Not indicated
Specific gravity (H2O =1) 1.47000
Explosion limit Not explosive
Solubility Dispersible
Other information Bulk density: 33.9 pounds per cubic foot.

10. STABILITY AND REACTIVITY

Chemical stability Stable under normal conditions.


Incompatibility None known
Hazardous Polymerization Will not occur.
Decomposition/by product None known

11. TOXICOLOGICAL INFORMATION

Metsulfuron-methyl
LD50 oral >5000 mg/kg in rats.
LD50 dermal >2000 mg/kg in rabbits.
Inhalation LC50 4 hours >5.3 mg/L in rats
CBA
Centa Brasindo Abadi

12. ECOLOGICAL INFORMATION

Metsulfuron-methyl
Aquatic toxicity 96 hours LC50 – Rainbow trout >150 ppm
96 hours LC50 – Bluegill sunfish > 150 ppm
Avian toxicity LC50 – Mallard Duck >2510 mg/kg
LC50 – Bobwhite Qual >5620 mg/kg

13. DISPOSAL CONSIDERATIONS

Dispose of material in an approved waste disposal facility in accordance with local, state and federal
regulations.
For containers, triple rinse and dispose in a sanitary landfill.

14. TRANSPORT INFORMATION

The following guidelines apply for domestic ground transport. If shipping by air or ocean, please contact our
transportation dept.
Freight class: Herbicides, NOI – NMFC #50320
In our current available sizes, this product does not qualify as a Hazardous Material.

15. REGULATORY INFORMATION

OSHA status This product is hazardous under criteria of the Federal OSHA Hazard Communication
Standard 29 CFR 1910.1200
TSCA status This product is exempt from TSCA Regulation under FIFRA Section 3(2)(B)(ii) when used
as a pesticide.
CERCLA REPORTABLE QUANTITY None
SARA TITLE III:
Section 302 extremely hazardous substance None
Section 311/312 hazard category Immediate Health
Hazard
Section 313 toxic chemicals None
RCRA status If discarded in its purchased form, this product would not be a hazardous waste either by
listing or by characteristic. However, under RCRA it is the responsibility of the product user
to determine at the time of disposal, whether a material containing the product or derived
from the product should be classified as a hazardous waste.(40 CFR 261.20-24)

16. OTHER INFORMATION

Disclaimer
Disclaimer: Nothing contained herein grants or extends a license, expressed or implied, in connection with
patents, issued or pending, of the manufacturer or others. The information herein is based on the
manufacturer’s own study and the works of others. The manufacturer makes no warranties, expressed or
implied, as to the accuracy, completeness, or adequacy of the information contained herein. The manufacturer
shall not be held liable (regardless of fault) to the vendee’s employees, or anyone for any direct, special or
consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing
of such information.

Date of printing 03/08/2006

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