DPP - 03 - Coordination Compound
DPP - 03 - Coordination Compound
DPP - 03 - Coordination Compound
APNI KAKSHA 1
(INORGANIC CHEMISTRY) Rankers Group
8. What is the hybridisation of [Ni(H2 O)6 ]2+
(A) sp3 d2 (B) d2 sp3
(C) sp3 d (D) dsp3
9. What is the geometry of [Co(NH3 )6 ]2+
(A) Octahedral (B) tetrahedral
(C) square planar (D) square pyramidal
10. Which of the following complex is paramagnetic in nature -
(A) K 4 [Fe(CN)6 ] (B) K 3 [Fe(CN)6 ]
(C) [Pt(NH3 )4 ]2+ (D) None of these
Paragraph for 𝐐. 𝟏𝟏 & 𝟏𝟐.
According to the Valence Bond Theory (VBT), the metal atom or ion under the influence of the
ligands can use its (n-1)d, ns, np and nd orbitals for hybridization. These hybrid orbitals overlap
with ligand orbitals that can donate electron pairs for bonding. The symbol "१L" indicates
electrons in metal and the symbol "xx" indicates electrons from the ligand. (Write approprite
alphabets in the boxes)
11. Using VBT match the complexes (1-3) with appropriate hybridization schemes (a-c).
APNI KAKSHA 2
(INORGANIC CHEMISTRY) Rankers Group
14. Column-I Column-II
(Complex compound) (Characteristics)
(A) [Co(CN)(NH3 )5 ]SO4 (P) Diamagnetic
(B) K[Co(CO)4 ] (Q) O.N. of metal ≤ 0
(C) K 4 [Co(C2 O4 )3 ] (R) Metal-Metal bond
(D) Co2 (CO)8 (S) Paramagnetic
(T) Optically active
Integer :
15. Find the number of unpaired electron in [Fe(CO)3 (CN)3 ]−
16. Find the number of unpaired electron in energy orbital of K 4 [Fe(CN)6 ]
17. Find the Co-ordination number of the central atom of the complex. [M(NH3 )4 (SO4 )]Br, which is
having one ring.
18. Find the co-ordination number of central atom in [Pt (trien)]2+
19. Find the number of difference in number of nodal planes when two dxy orbitals are forming δ-
bonding molecular orbitals and two dx2−y2 orbitals are forming δ-antibonding molecular
orbitals.
20. Find the E.A.N. value of Fe in Na2 [Fe(CO)4 ].
Fill your answer as sum of digits till you get the single digit answer.
APNI KAKSHA 3
(INORGANIC CHEMISTRY) Rankers Group
ANSWER KEY
1. (A) 2. (D) 3. (C) 4. (A, B, D) 5. (C, D) 6. (B, C, D)
7. (B) 8. (A) 9. (A) 10. (B) 11. (1) b, (2) c, (3) a
12. (D)
13. (A)-S,T;(B)-Q,R;(C)-Q,S,T;(D) −𝐏, 𝐐, 𝐓 14. (A)-P ;(B)-P,Q ;(C)-S,T ;(D)-P,Q,R
15. (0) 16. (0) 17. (6) 18. (4) 19. (1) 20. (9)
APNI KAKSHA 4