Safety Data Sheet according to Regulation (EC) No

1907/2006

Product

NALCO 77336

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1 Product identifier: NALCO 77336

Type of substance CLP Mixture

1.2 Relevant identified uses of the substance or mixture and uses advised against:

Use of the : CLOSED SYSTEM TREATMENT

Substance/Mixture

1.3 Details of the supplier of the safety data sheet:

COMPANY IDENTIFICATION LOCAL COMPANY IDENTIFICATION

NALCO EUROPE B.V. Nalco Ltd.
Postbus 627 P.O. BOX 11, WINNINGTON AVENUE
2300 AP Leiden, The Netherlands NORTHWICH, CHESHIRE, U.K. CW8 4DX
TEL: 0031 71 5241100 TEL: +44 (0)1606 74488

For additional copies of an MSDS visit www.nalco.com and request access.

For Product Safety information please contact: EUProductSafety@nalco.com

1.4 Emergency telephone number: +32-(0)3-575-5555 Trans-European

Date of Compilation/Revision:: 03.10.2012

Version Number: 1.0

SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture:

Classification according to Regulation (EC) No 1272/2008

This product is not classified according to (EC) Regulation (No) 1272/2008

Classification according to EU Directives 67/548/EEC or 1999/45/EC

This product is not classified as dangerous in accordance with Directives 67/548/EEC or 1999/45/EC.

2.2 Label elements:

Labelling according to Regulation (EC) No 1272/2008

This product is not classified, however, we recommend the following Precautionary Statements:

Precautionary Statements
P202 Do not handle until all safety precautions have been read and understood.
P262 Do not get in eyes, on skin, or on clothing.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

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P314 Get medical advice/ attention if you feel unwell.

Supplemental information:

EUH210 Safety data sheet available on request.

2.3 Other hazards:

None known

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixture:

This product is not classified according to (EC) Regulation (No) 1272/2008

SECTION 4. FIRST AID MEASURES

4.1 Description of necessary first-aid measures:

In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt,
contact emergency

INHALATION
Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice.

SKIN CONTACT
Immediately flush with plenty of water for at least 15 minutes. Get medical attention. For a large splash, flood
body under a shower.

EYE CONTACT
Immediately flush with plenty of water for at least 15 minutes. Get medical attention.

INGESTION
Seek medical advice immediately, showing the label and/or SDS. If conscious, washout mouth and give water to
drink. If unconsious, do not give anything by mouth, place in the recovery position, check breathing and pulse. If
necessary give artifical respiration.

PROTECTION FOR FIRST AID PERSONNEL

Wear adequate personal protective equipment.

4.2 Most important symptoms and effects, both acute and delayed:

A review of available data does not identify any symptoms from exposure not previously mentioned.

4.3 Indication of immediate medical attention and special treatment needed:

Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms
and clinical condition.

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 Safety Data Sheet according to Regulation (EC) No
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SECTION 5. FIRE-FIGHTING MEASURES

5.1 Extinguishing media:

SUITABLE EXTINGUISHING MEDIA

Water mist may be used to cool closed containers.
Alcohol foam, Carbon dioxide, Dry powder, Other extinguishing agent suitable for Class B fires, For large fires,
use water spray or fog, thoroughly drenching the burning material.

UNSUITABLE EXTINGUISHING MEDIA

Do not use water unless flooding amounts are available.

5.2 Special hazards arising from the substance or mixture:

May evolve oxides of carbon (COx) under fire conditions.

In the event of a spill, prevent material and fire water from entering sewers or waterways.

5.3 Advice for firefighters:

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures:

ADVICE FOR NON-EMERGENCY PERSONNEL

For small spills i.e. For <10 litres Ensure clean-up is conducted by trained personnel only. Use personal
protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Restrict access to
area as appropriate until clean-up operations are complete. Large spills should only be cleaned up by
emergency responders.

For >10 liters Notify emergency personnel immediately. Use personal protective equipment recommended in
Section 8 (Exposure Controls/Personal Protection). Restrict access to area as appropriate until clean-up
operations are complete.

Ventilate spill area if possible. Ensure clean-up is conducted by trained personnel only. Have emergency
equipment (for fires, spills, leaks, etc.) readily available. Notify appropriate government, occupational health and
safety and environmental authorities.

ADVICE FOR EMERGENCY RESPONDERS

Restrict access to area as appropriate until clean-up operations are complete. Use personal protective
equipment recommended in Section 8 (Exposure Controls/Personal Protection). Ventilate spill area if possible.
Ensure clean-up is conducted by trained personnel only. Have emergency equipment (for fires, spills, leaks, etc.)
readily available. Notify appropriate government, occupational health and safety and environmental authorities.

6.2 Environmental precautions:

In the event of a spill, prevent material from entering sewers or waterways. Do not allow material to contaminate
ground water system. Prevent product from entering drains. If drains, streams, soil or sewers become
contaminated, notify local authority.

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6.3 Methods and materials for containment and cleaning up:

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled
container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or
by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated
surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated
recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal
Considerations).

6.4 Reference to other sections:

Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).

Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).

SECTION 7. HANDLING AND STORAGE

7.1 Precautions for safe handling:

HANDLING
Prevent contact with skin, eyes and clothing. Use with adequate ventilation. Do not breathe vapors/gases/dust.
Keep the containers closed when not in use. Ensure all containers are labeled. Have emergency equipment (for
fires, spills, leaks, etc.) readily available. Use personal protective equipment recommended in Section 8
(Exposure Controls/Personal Protection).

Refer to section 6.2 for Environmental Precautions

HYGIENE RECOMMENDATIONS
Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a
safety shower available. Always wash thoroughly after handling chemicals. When handling this product never
eat, drink or smoke. Eye wash station and safety shower are necessary. If clothing is contaminated, remove
clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Always wash
thoroughly after handling chemicals. When handling this product never eat, drink or smoke.

7.2 Conditions for safe storage, including any incompatibilities:

STORAGE CONDITIONS
Store in suitable labeled containers. Store the containers tightly closed. Store separately from oxidizers.

SUITABLE CONSTRUCTION MATERIAL

Polyethylene, Polypropylene, Stainless steel, Glass, Compatibility with Plastic Materials can vary; we therefore
recommend that compatibility is tested prior to use.

7.3 Specific end uses:

Specific use(s) :
CLOSED SYSTEM TREATMENT

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters:

OCCUPATIONAL EXPOSURE LIMITS

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 Safety Data Sheet according to Regulation (EC) No
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Exposure guidelines have not been established for this product. Available exposure limits for the substance(s)
are shown below.
Source Substance(s) Category: ppm mg/m3

United Kingdom Propylene Glycol (Particulate.) TWA 10

Propylene Glycol (Total vapour and particulates.) TWA 150 474

* A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route, including mucous membranes and
the eyes.

DNEL
Components:

End Use: Exposure routes: Potential health Value:

effects:
Propylene Glycol
Workers Inhalation long term - systemic 10 mg/m3
Workers Inhalation long term - systemic 10 mg/m3

PNEC
Components:

Value:
Propylene Glycol
Fresh water 260 mg/l
Marine water 26 mg/l
Intermittent release 183 mg/l
STP 20000 mg/l
Sediment 572 mg/kg
Soil 50 mg/kg

8.2 Exposure controls:

ENGINEERING MEASURES:
General ventilation is recommended. The use of local exhaust ventilation is recommended to control emissions
near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of
confined spaces.

PERSONAL PROTECTIVE EQUIPMENT

GENERAL ADVICE
The use and choice of personal protection equipment is related to the hazard of the product, the workplace and
the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with
side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area
where this product is handled should at least wear safety glasses with side-shields.

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 Safety Data Sheet according to Regulation (EC) No
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Product

NALCO 77336

EYE/FACE PROTECTION
When handling this product, the use of safety glasses with side shields is recommended. The applicable
European standard can be found in EN 166.

SKIN PROTECTION
When handling this product, the use of chemical gloves is recommended. The choice of work glove depends on
work conditions and what chemicals are handled, but we have positive experience under light handling
conditions using gloves made from Nitrile . Gloves should be replaced immediately if signs of degradation are
observed. Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable
European standard can be found in EN 374.
When handling this product, the use of overalls is recommended. The applicable European standard can be
found in EN ISO 20345.

RESPIRATORY PROTECTION
Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air
supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of
chemicals being handled. Consider the use of filter type: A-P The applicable European standard can be found in
EN 140, EN 137, EN 143 and EN 14387. In event of emergency or planned entry into unknown concentrations a
positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete
respiratory protection program including selection, fit testing, training, maintenance and inspection.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Note: These physical properties are typical values for this product and are subject to change.
9.1 Information on basic physical and chemical properties:
9.1 Information on basic physical and chemical properties:

PHYSICAL STATE Liquid

APPEARANCE Red
Odour None
Odour Threshold No data available.
pH 7
MELTING POINT -60.0 °C
BOILING POINT > 100 °C
FLASH POINT 107 °C ASTM D-93
EVAPORATION RATE No data available.
FLAMMABILITY (solid, gas) No data available.
LOWER EXPLOSION LIMIT No data available.
UPPER EXPLOSION LIMIT No data available.
VAPOR PRESSURE 0.03 kPa (20.0 °C)
VAPOR DENSITY No data available.
Relative density 1.04
DENSITY No data available.
SOLUBILITY IN WATER Complete
OCTANOL/WATER COEFFICIENT No data available.
(log Kow)
AUTOIGNITION TEMPERATURE No data available.
DECOMPOSITION TEMPERATURE No data available.
VISCOSITY 45 cps (20 °C)
EXPLOSIVE PROPERTIES Not applicable
OXIDIZING PROPERTIES Not applicable

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9.2 Other information:

Not applicable

SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity:

Stable under normal conditions.

10.2 Chemical stability:

Stable under normal conditions.

10.3 Possibility of hazardous reactions:

Hazardous polymerization will not occur.

10.4 Conditions to avoid:

Avoid extremes of temperature.

10.5 Incompatible materials:

Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen,
permanganate) may generate heat, fires, explosions and/or toxic vapors.

10.6 Hazardous decomposition products:

Under fire conditions: Oxides of carbon

SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects:

Product:
Acute oral toxicity : LD50: > 20,000 mg/kg, Rat, Test substance: Product
Acute inhalation toxicity : Based on available data, the classification criteria are not met.
Acute dermal toxicity : LD50: > 10,000 mg/kg, Rabbit, Test substance:
Product
Skin corrosion/irritation : Based on available data, the classification criteria are not met.
Serious eye damage/eye : Based on available data, the classification criteria are not met.
irritation
Respiratory or skin : Based on available data, the classification criteria are not met.
sensitization
Genotoxicity

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 Safety Data Sheet according to Regulation (EC) No
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Assessment : Contains no ingredient listed as a mutagen

Carcinogenicity : Based on available data, the classification criteria are not met.
None of the substances in this product are listed as
carcinogens by the International Agency for Research on
Cancer (IARC), the National Toxicology Program (NTP) or the
American Conference of Governmental Industrial Hygienists
(ACGIH).
Reproductive toxicity : Based on available data, the classification criteria are not met.
Assessment: No toxicity to reproduction
STOT - single exposure : Remarks: Based on available data, the classification criteria
are not met.
STOT - repeated exposure : Based on available data, the classification criteria are not met.
Aspiration toxicity : No aspiration toxicity classification

Components:

Propylene Glycol
Acute oral toxicity : LD50: 22,000 mg/kg, Rat, Other guidelines, GLP: No
Acute dermal toxicity : LD50: > 2,000 mg/kg, Rabbit, Other guidelines, GLP: No
Skin corrosion/irritation : Rabbit, Result: Not irritating, OECD 404, 4 h
Serious eye damage/eye : Rabbit, Result: Not irritating, OECD 405
irritation
Respiratory or skin : Guinea pig, Result: Negative, OECD 406
sensitization
Genotoxicity
Genotoxicity in vitro : Ames test, Result: negative, Other guidelines
: Chromosome aberration test in vitro, Result: negative, OECD
473
Genotoxicity in vivo : In vivo micronucleus test, Mouse, Other guidelines, Result:
negative
Assessment : In vitro tests did not show mutagenic effects, In vivo tests did
not show mutagenic effects
Carcinogenicity : Rat, Oral, Other guidelines, GLP: No, Result, negative
Animal testing did not show any carcinogenic effects.
Reproductive toxicity : Mouse, Oral, NOAEL: 10,100 mg/kg, F1: 10,100 mg/kg, F2:
10,100 mg/kg, Other guidelines
Assessment: No toxicity to reproduction
Teratogenicity : Mouse, Oral, NOAEL: 10,400 mg/kg, 52 mg/kg, OECD 414
Assessment: Did not show teratogenic effects in animal
experiments.
STOT - repeated exposure : Rat, Oral, 730 d, NOAEL: 1,700 - 2,100 mg/kg, Other

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 Safety Data Sheet according to Regulation (EC) No
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guidelines, GLP: No
STOT - repeated exposure : Rat, Inhalation, 90 d, NOAEC, 1000 - 2200 mg/m3, Other
guidelines
: Target Organs: no data available

SECTION 12. ECOLOGICAL INFORMATION

12.1 Toxicity:

The following results are for the product.

Product:
Toxicity to fish : LC50: 4,600 mg/l, 96 hrs, Fathead Minnow, Test substance:
Product
Toxicity to daphnia and other : LC50: 4,580 mg/l, 48 hrs, Daphnia magna, Test substance:
aquatic invertebrates. Product
Ecotoxicology Assessment
Acute aquatic toxicity : Not expected to be harmful to aquatic organisms.
Chronic aquatic toxicity : Not expected to demonstrate chronic toxicity to aquatic
organisms

Components:
Propylene Glycol
Toxicity to fish : LC50: 40,613 mg/l, 96 h, Rainbow Trout, Other guidelines,
GLP: No
Toxicity to daphnia and other : LC50: 18,800 mg/l, 96 h, Mysid Shrimp (Mysidopsis bahia),
aquatic invertebrates. EPA FIFRA 72-3
Toxicity to algae : EC50: 19,300 mg/l, 72 h, Marine Algae (Skeletonema
costatum), OECD 201
Toxicity to bacteria : NOEC: > 20,000 mg/l, 18 h, Pseudomonas putida, Other
guidelines, GLP: No
Toxicity to fish (Chronic : ChV: 2,500 mg/l, 30 d, Fish, Calculated
toxicity)
Toxicity to daphnia and other : EC25 / IC25: 13,470 mg/l, 7 d, Ceriodaphnia (water flea), EPA
aquatic invertebrates. 600/4-89/001
(Chronic toxicity)

12.2 Persistence and degradability:

Product:
Biodegradability : The organic portion of this preparation is expected to be
readily biodegradable.

Components:
Propylene Glycol
Biodegradability : 100 %, Result: Readily biodegradable., Exposure time: 28 d,
OECD 301 F (Manometric RespirometryI)

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 Safety Data Sheet according to Regulation (EC) No
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12.3 Bioaccumulative potential:

Product:
Bioaccumulation : This preparation or material is not expected to bioaccumulate.

Components:
Propylene Glycol
Bioaccumulation : Bioconcentration factor (BCF): 0.09, Calculated,
Bioaccumulation is unlikely.

12.4 Mobility in soil:

Product:
Environmental fate and : This substance is water soluble and is expected to remain
pathways primarily in water.

Components:
Propylene Glycol
Distribution among : Koc: 2.9, log Koc: 0.46, Calculated
environmental compartments

12.5 Results of PBT and vPvB assessment:

Product:
Assessment : This mixture contains no substance considered to be
persistent, bioaccumulating nor toxic (PBT)., This mixture
contains no substance considered to be very persistent nor
very bioaccumulating (vPvB).

12.6 Other adverse effects:

Product:
Biochemical Oxygen : Biological degradation: Approx, >80%
Demand (BOD)
Additional ecological : No adverse effects expected.
information

SECTION 13. DISPOSAL CONSIDERATIONS

If this preparation becomes a waste, the final user must define and assign the appropriate European Waste
Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations.

13.1 Waste treatment methods:

Contact an approved waste hauler for disposal of contaminated recovered material. Any chemical waste is a
potential environmental pollutant and is NOT suitable for disposal via ground, municipal sewers, drains, natural
streams or rivers. Dispose of wastes in an approved incinerator or waste treatment/disposal site, in accordance
with all applicable regulations. Do not dispose of wastes in local sewer or with normal garbage.

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Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed
contractor.

EUROPE WASTE CODE:

16 03 05*- OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Organic wastes containing
dangerous substances. If this product is used in any further processes, the final user must redefine and assign
the most appropriate European Waste Catalogue Code.

SECTION 14. TRANSPORT INFORMATION

The information in this section is for reference only and should not take the place of a shipping paper (bill of
lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging,
properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.

LAND TRANSPORT
14.1 UN number: not applicable
14.2 UN proper shipping name: PRODUCT IS NOT REGULATED DURING
TRANSPORTATION
14.3 Transport hazard class(es): not applicable
14.4 Packing group: not applicable
14.5 Environmental hazards: No
14.6 Special precautions for user: not applicable

AIR TRANSPORT (ICAO/IATA)

14.1 UN number: not applicable
14.2 UN proper shipping name: PRODUCT IS NOT REGULATED DURING
TRANSPORTATION
14.3 Transport hazard class(es): not applicable
14.4 Packing group: not applicable
14.5 Environmental hazards: No
14.6 Special precautions for user: not applicable

MARINE TRANSPORT (IMDG/IMO)

14.1 UN number: not applicable
14.2 UN proper shipping name: PRODUCT IS NOT REGULATED DURING
TRANSPORTATION
14.3 Transport hazard class(es): not applicable
14.4 Packing group: not applicable
14.5 Environmental hazards: No
14.6 Special precautions for user: not applicable
14.7 Transport in bulk according to not applicable
Annex II of MARPOL 73/78 and the IBC
Code:

SECTION 15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:

INTERNATIONAL CHEMICAL CONTROL LAWS

EUROPE
Safety Data Sheet according to Regulation (EC) No 1907/2006.

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 Safety Data Sheet according to Regulation (EC) No
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Nalco is committed to and fully supports the Registration, Evaluation, Authorization and restriction of CHemicals
(REACH) regulation. It is our intention to pre-register all chemical substances that we manufacture or import into
European Union and to work with our suppliers to ensure a smooth transition to this new regulatory environment.
Should you require any further information on Nalco's REACH programme please contact us at
reach@nalco.com or visit our website.

CANADA
The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been
reported in accordance with the New Substances Notification Regulations.

UNITED STATES
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)

NATIONAL REGULATIONS GERMANY

WGK: 1 (Annex 4)

15.2 Chemical Safety Assessment:

A Chemical Safety Assessment has been carried out for the substance(s) that makes/make up this material or
for the material itself.

SECTION 16. OTHER INFORMATION

LIST OF RELEVANT R-PHRASES, NOTAS AND HAZARD STATEMENTS IN SECTION 2.1 AND 3
Not applicable

REVISED INFORMATION: section(s): 2, 3, 15, 16

This product Safety Data Sheet provides health, safety, and regulatory information. The information contained in
this Safety Data Sheet is based on data available to us at the date of issue , and is provided in good faith, and
believed to be accurate and reliable at the date of issue, however, no warranty, express or implied is provided,
and Nalco disclaims all liability for reliance on such information. The product is to be used in applications
consistent with Nalco’s product literature. For any other uses, exposures should be evaluated so that the
appropriate handling practices and training programs can be established to ensure safe working conditions and
operations. It is the buyer’s/user’s responsibility to satisfy itself that the product is suitable for the intended use,
and to ensure that its activities comply with all federal, state, provincial, or local laws and regulations.
Regulatory requirements are subject to change and may differ between European Member States and Nations.
Individuals handling this product should be informed of the recommended safety precautions and should have
access to this information. Please consult your local sales representative for any further information.

REFERENCES

IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health
Organization, International Agency for Research on Cancer.

Ariel Insight™ (An integrated guide to industrial chemicals covered under major regulatory and advisory
programs), North American Module, Western European Module, Chemical Inventories Module and the Generics
Module (Ariel Insight™ CD-ROM Version), Ariel Research Corp., Bethesda, MD.

The possible key literature references and data sources which may have been used in conjunction with the
consideration of expert judgment to compile this Safety Data Sheet: European regulations/directives (including

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(EC) No. 1907/2006, (EC) No. 1272/2008, 67/548/EEC, 1999/45/EC), supplier data, inter-net, ESIS, IUCLID,
ERIcards, Non European official regulatory data and other data sources.

Date issued : 03.10.2012

Version Number : 1.0
Prepared By: SHE Department

Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1
tenth and 0.001 = 1 thousandth

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