Air and The Atmosphere - AKHS Edition 2020
Air and The Atmosphere - AKHS Edition 2020
Air and The Atmosphere - AKHS Edition 2020
Composition of air
Approximate percentage composition of air by volume
Component Approximate percentage
composition by volume
1. Nitrogen, N2 78
2. Oxygen, O2 21
3. Rare/noble/inert gases 0.97
4. Carbon dioxide, CO2 0.03
5. Water vapour Variable
6. Impurities Variable
From the above table, it’s evident that the two major components of air are
Nitrogen and oxygen.
The components of air are separated by fractional distillation method.
Uses of nitrogen
1. Nitrogen gas is used in the manufacture of ammonia gas by the Haber
process. Ammonia is used to manufacture fertilizers e.g. ammonium
sulphate.
2. Liquid nitrogen is used as a refrigerant for freezing food stuffs.
3. Nitrogen in form of nitrates is a useful plant nutrient required for proper
plant growth and survival.
4. Gaseous nitrogen is used to fill petrol and oil storage tanks since it
doesn’t burn therefore reduces the risk of explosion.
5. Outside parts of flying aircrafts and spacecrafts are tested by putting
them in liquid nitrogen.
6. Nitrogen dilutes oxygen in the atmosphere, making processes such as
combustion, respiration and rusting slower.
Note:
Uses of oxygen
1. Oxygen gas is used for aerobic respiration of food substances (e.g.
glucose) so as to release energy in living cells.
2. Oxygen gas is essential for processes such as respiration, combustion,
rusting and germination to occur.
3. Oxygen combines with ethyne(acetylene) or hydrogen to form
oxyacetylene and oxyhydrogen flames respectively which are used for
welding and cutting steel.
4. Stored oxygen is used to aid breathing when the natural supply of
oxygen is insufficient e.g. intensive care/ anaesthetized patients,
astronauts, mountain climbers, sky divers, underwater divers and
miners.
5. Oxygen is used in the making of steel.
6. Oxygen is used to burn fuel in spacecrafts and rockets.
Note:
▪ Oxygen is added to the atmosphere naturally by photosynthesis
carried out by plants.
▪ Oxygen is removed from the atmosphere by processes such as;
respiration, combustion, rusting, germinations etc.
Water vapour
The percentage of water vapour varies from place to place.
Water vapour is added to the atmosphere by evaporation of water from
water bodies, transpiring plants and desiccation by other organisms.
(Refer to your Biology notes of the water cycle)
Impurities
They include; dust, smoke and other gases such as carbon monoxide,
Sulphur dioxide, Sulphur trioxide, hydrogen sulphide and nitrogen oxides.
The composition of impurities varies from place to place.
Most industrial areas and urban areas contain high levels of impurities
since they constitute gaseous industrial wastes and automobile exhaust
fumes.
Read about and make notes on
Pollution
▪ Definition of pollution
▪ Types of pollution
▪ Common pollutants and their sources
▪ Causes of pollution
▪ Effects of pollution
▪ Measures to avoid or control pollution.
Drying of gases
A drying agent is a compound used to absorb water or moisture from other
substances.
Examples of common drying agents include;
i) Concentrated sulphuric acid
Concentrated sulphuric acid is used to dry gases that do not react with it
e.g. Oxygen, Hydrogen, Carbon dioxide, Hydrogen chloride and Sulphur
dioxide.
When the tap is opened, hydrogen peroxide flow from the thistle funnel
drop-wise to manganese(IV) oxide in the flask.
Observation
Effervescence (rapid evolution of gas bubbles) occurs and a colourless gas
is given off which can be collected over water if NOT required dry.
Equation for the reaction
2H2O2 (g) → 2H2O (l) + O2 (g)
2. Calcium
Calcium metal burns in air (oxygen) with a bright red (characteristic
brick-red) flame forming a white solid of Calcium oxide.
2Ca(s) + O2 (g) → 2CaO(s) Calcium oxide – white solid
Calcium oxide slowly dissolves in water to form an alkaline solution of
calcium hydroxide.
CaO (s) + H2O (l) → Ca(OH)2 (aq) Calcium hydroxide
3. Magnesium
Magnesium burns in air (oxygen) with a very bright white (dazzling)
flame forming a white ash of magnesium oxide.
2Mg(s) + O2 (g) → 2MgO(s) magnesium oxide – white solid
Magnesium oxide does not readily dissolve in water.
4. Aluminium
When strongly heated, Aluminium burns in oxygen to form a white solid
of Aluminium oxide (Alumina)
4Al (s) + 3O2 (g) → 2Al2O3 (s) Aluminium oxide
5. Zinc
Zinc burns in oxygen with a bluish-green flame forming a yellow solid of
Zinc oxide that turns into a white powder on cooling.
2Zn(s) + O2 (g) → 2ZnO(s) zinc oxide – yellow when hot and white when cold.
2. Carbon
Wood charcoal (carbon) burns in plentiful supply of oxygen with an
orange flame and bright sparks forming a colourless gas (carbon
dioxide) that turns limewater milky.
C(s) + O2 (g) → CO2 (g)
Carbon dioxide slightly in water to form a weakly acidic solution.
In limited or insufficient oxygen supply, carbon monoxide is formed
instead of carbon dioxide.
2C(s) + O2 (g) → 2CO (g)
Carbon monoxide is insoluble in water and is neutral i.e. neither acidic
nor basic.
Classification of oxides
There are four main classes of oxides i.e.
▪ Basic oxides
▪ Acidic oxides
▪ Amphoteric oxides
▪ Neutral oxides
1. Basic oxides
These are oxides of metals which react with acids to form a salt and
water only.
Examples of basic oxides
▪ Sodium oxide Na2O ▪ Magnesium oxide MgO
▪ Potassium oxide K2O ▪ Copper(II) oxide CuO
▪ Calcium oxide CaO ▪
Mixed oxides
These are oxides that appear to be consisting of two or more simpler
oxides. They react like a mixture of two or more simpler oxides.
Mixed oxides are formed by metals having more than one valency.
Examples of mixed oxides
i) Tri-lead tetra-oxide or Di-lead(II) lead(IV) oxide (Pb3O4)
It appears to be consisting of 2PbO and PbO2
ii) Tri-iron tetra-oxide (Fe3O4)
Higher oxides
These are oxides which contain more oxygen per molecule than the
corresponding normal oxide.
Examples
Element Normal oxide Higher oxide
Iron FeO Fe2O3 and Fe3O4
Lead PbO PbO2 and Pb3O4
Sodium Na2O Na2O2
Hydrogen H 2O H2O2
Tin SnO SnO2
Potassium is the most reactive metal and gold is the least reactive metal is
gold.
More reactive metals displace less reactive metals from their compounds.
For example, Zinc being more reactive than copper, it displaces copper
from copper(II) sulphate solution forming a brown solid of copper and a
colourless solution of zinc sulphate.
Zn(s) + CuSO4 (aq) → Cu(s) + ZnSO4 (aq)
Less reactive metals CANNOT displace more reactive metals from their
compounds
For example;
ZnSO4(aq) + Cu(s) → No reaction