Safety data sheet

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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 18.02.2022 Version: 2.1
Product: Laromer® UA 9181
(ID no. 30794238/SDS_GEN_00/EN)
Date of print 21.09.2023

1. Identification
Product identifier

Laromer® UA 9181
Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: Raw material for coatings for industrial or professional use, polymers for
inks, varnishes or coatings, UV acrylic varnish
Uses advised against: All consumer uses are strongly advised against., The hazardous properties of
the substance require safety measures which can, in principle, not be sufficiently ensured in the
home worker sector.

Details of the supplier of the safety data sheet

Company:
BASF SE
67056 Ludwigshafen
GERMANY
Global Business Unit Resins and Additives

Telephone: +49 621 60-72509

E-mail address: ed-psr@basf.com

Emergency telephone number

International emergency number:

Telephone: +49 180 2273-112

2. Hazards Identification

Classification of the substance or mixture

According to UN GHS criteria

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Safety data sheet according to UN GHS 4th rev.
Date / Revised: 18.02.2022 Version: 2.1
Product: Laromer® UA 9181
(ID no. 30794238/SDS_GEN_00/EN)
Date of print 21.09.2023

Skin Corr./Irrit. 2
Eye Dam./Irrit. 1
Skin Sens. 1
Aquatic Acute 2

For the classifications not written out in full in this section the full text can be found in section 16.

Label elements

Globally Harmonized System (GHS)

Pictogram:

Signal Word:
Danger

Hazard Statement:
H318 Causes serious eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H401 Toxic to aquatic life.

Precautionary Statements (Prevention):

P280 Wear protective gloves and eye protection or face protection.
P261 Avoid breathing mist or vapour or spray.
P273 Avoid release to the environment.
P272 Contaminated work clothing should not be allowed out of the workplace.
P264 Wash contaminated body parts thoroughly after handling.

Precautionary Statements (Response):

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or physician.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P362 + P364 Take off contaminated clothing and wash it before reuse.

Precautionary Statements (Disposal):

P501 Dispose of contents and container to hazardous or special waste
collection point.

Other hazards

According to UN GHS criteria

No specific dangers known, if the regulations/notes for storage and handling are considered.
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Safety data sheet according to UN GHS 4th rev.
Date / Revised: 18.02.2022 Version: 2.1
Product: Laromer® UA 9181
(ID no. 30794238/SDS_GEN_00/EN)
Date of print 21.09.2023

3. Composition/Information on Ingredients
Substances

Not applicable

Mixtures

Chemical nature

acrylic ester, mixture

Hazardous ingredients (GHS)

According to UN GHS criteria

Oxybis(methyl-2,1-ethanediyl) diacrylate
Content (W/W): >= 25 % - < 50 % Acute Tox. 5 (oral)
CAS Number: 57472-68-1 Skin Corr./Irrit. 2
EC-Number: 260-754-3 Eye Dam./Irrit. 1
Skin Sens. 1
Aquatic Acute 2
H318, H315, H303, H317, H401

2-Propenoic acid, 2-hydroxyethyl ester, polymer with 1,3-diisocyanatomethylbenzene and alpha-

hydro-omega-hydroxypoly[oxy(methyl-1,2-ethanediyl)]

Content (W/W): >= 50 % - < 75 % Skin Corr./Irrit. 2

CAS Number: 37302-70-8 Eye Dam./Irrit. 2A
H319, H315

For the classifications not written out in full in this section the full text can be found in section 16.

4. First-Aid Measures
Description of first aid measures
Immediately remove contaminated clothing.

If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.

On skin contact:
Wash thoroughly with soap and water

On contact with eyes:

Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.

On ingestion:
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Safety data sheet according to UN GHS 4th rev.
Date / Revised: 18.02.2022 Version: 2.1
Product: Laromer® UA 9181
(ID no. 30794238/SDS_GEN_00/EN)
Date of print 21.09.2023
Rinse mouth and then drink 200-300 ml of water. Do not induce vomiting unless told to by a poison
control center or doctor.

Most important symptoms and effects, both acute and delayed

Symptoms: Information, i.e. additional information on symptoms and effects may be included in the
GHS labeling phrases available in Section 2 and in the Toxicological assessments available in
Section 11., (Further) symptoms and / or effects are not known so far

Indication of any immediate medical attention and special treatment needed

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.

5. Fire-Fighting Measures
Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam

Unsuitable extinguishing media for safety reasons:

water jet

Special hazards arising from the substance or mixture

harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of
fire.

Advice for fire-fighters

Special protective equipment:
Wear a self-contained breathing apparatus.

Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.

6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures
Use personal protective clothing. Breathing protection required.

Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.

Methods and material for containment and cleaning up

For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance
with regulations.
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Safety data sheet according to UN GHS 4th rev.
Date / Revised: 18.02.2022 Version: 2.1
Product: Laromer® UA 9181
(ID no. 30794238/SDS_GEN_00/EN)
Date of print 21.09.2023
7. Handling and Storage
Precautions for safe handling
No special measures necessary provided product is used correctly.

Protection against fire and explosion:

Heated containers should be cooled to prevent polymerization. Take precautionary measures
against static discharges.

Conditions for safe storage, including any incompatibilities

Further information on storage conditions: Protect against heat. Protect from the effects of light.
Avoid direct sunlight. Ensure adequate inhibitor and dissolved oxygen level. The stabilizer is only
effective in the presence of oxygen. Maintain contact with atmosphere containing 5 - 21% oxygen.

Protect from temperatures above: 40 °C

Slow non-hazardous polymerization possible when at or exceeding maximum temperatures.

Specific end use(s)

For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be
observed.

8. Exposure Controls/Personal Protection

Control parameters

Components with occupational exposure limits

No substance specific occupational exposure limits known.

Exposure controls
Personal protective equipment
Respiratory protection:
Suitable respiratory protection for higher concentrations or long-term effect: Gas filter for
gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)

Hand protection:
Chemical resistant protective gloves (EN ISO 374-1)
Suitable materials for short-term contact (recommended: At least protective index 2, corresponding >
30 minutes of permeation time according to EN ISO 374-1)
butyl rubber (butyl) - 0.7 mm coating thickness
nitrile rubber (NBR) - 0.4 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.

Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.

Body protection:
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Safety data sheet according to UN GHS 4th rev.
Date / Revised: 18.02.2022 Version: 2.1
Product: Laromer® UA 9181
(ID no. 30794238/SDS_GEN_00/EN)
Date of print 21.09.2023
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).

General safety and hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work
clothing is required additionally to the stated personal protection equipment.

9. Physical and Chemical Properties

Information on basic physical and chemical properties

Form: liquid
Colour: colourless
Odour: acrylic-like
Odour threshold:
Not determined due to potential
health hazard by inhalation.
pH value: 7-8 (ASTM E70)
(1 %(m))
Melting point: < -60 °C (DSC (DIN 51007))
Becomes very viscous at low
temperatures
boiling temperature: > 100 °C
(1.013 hPa)
The substance / product
decomposes.
Flash point: 138 °C (ISO 2719, closed cup)
Evaporation rate:
not determined
Flammability: not flammable (derived from flash point)
Lower explosion limit:
For liquids not relevant for
classification and labelling., The
lower explosion point may be 5 - 15
°C below the flash point.
Upper explosion limit:
For liquids not relevant for
classification and labelling.
Ignition temperature: 418 °C (DIN EN ISO/IEC 80079-20-1)
Vapour pressure: < 1 Pa
(20 °C)
The product has not been tested.
The statement has been derived from
the properties of the individual
components.
Density: 1,085 g/cm3 (ISO 2811-3)
(20 °C)
1,055 g/cm3 (ISO 2811-3)
(50 °C)
Relative density: 1,085 (calculated)
(20 °C)
Relative vapour density (air):
not determined
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Safety data sheet according to UN GHS 4th rev.
Date / Revised: 18.02.2022 Version: 2.1
Product: Laromer® UA 9181
(ID no. 30794238/SDS_GEN_00/EN)
Date of print 21.09.2023
Solubility in water: not determined
Solubility (qualitative) solvent(s): polar solvents
miscible
Partitioning coefficient n-octanol/water (log Kow):
not applicable for mixtures
Thermal decomposition: 160 °C, 252 J/g (DSC (DIN 51007))
Viscosity, dynamic: 1,8 - 2,0 Pa.s (DIN 53019)
(23 °C)
Viscosity, kinematic: approx. 1.500 - 2.000 mm2/s (calculated (from dynamic
(23 °C) viscosity))
Explosion hazard: not explosive
Fire promoting properties: not fire-propagating

Other information

Self heating ability: Study scientifically not justified.

Hygroscopy: Non-hygroscopic
Surface tension:
No data available.
Grain size distribution: The substance / product is marketed or used in a non solid or
granular form.

10. Stability and Reactivity

Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.

Chemical stability
The product is stable if stored and handled as prescribed/indicated.

Possibility of hazardous reactions

The product can polymerize if the shelf life or storage temperature are greatly exceeded. Heat
develops during polymerization. Reacts with peroxides and other radical components.
The product is stabilized against spontaneous polymerization prior to despatch.

Conditions to avoid
Avoid direct sunlight. Avoid extreme temperatures. Avoid inhibitor loss. To maintain inhibitor activity,
oxygen must not be eliminated from the atmosphere above the product. Avoid oxygen content above
the product of less than 5 %.

Incompatible materials

Substances to avoid:
strong acids, strong bases, radical formers, peroxides, Inert gas

Hazardous decomposition products

Hazardous decomposition products:

No hazardous decomposition products if stored and handled as prescribed/indicated.
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Safety data sheet according to UN GHS 4th rev.
Date / Revised: 18.02.2022 Version: 2.1
Product: Laromer® UA 9181
(ID no. 30794238/SDS_GEN_00/EN)
Date of print 21.09.2023
11. Toxicological Information
Information on toxicological effects

Acute toxicity

Assessment of acute toxicity:

Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact. The product
has not been fully tested. The statements have been derived in parts from products of a similar
structure or composition.

Experimental/calculated data:
LD50 rat (oral): > 5.000 mg/kg (OECD Guideline 401)
The product has not been fully tested. The statements have been derived in parts from products of a
similar structure or composition.

LC50 rat (by inhalation): 4 h

not determined

LD50 rabbit (dermal): > 2.000 mg/kg (OECD Guideline 402)

The product has not been fully tested. The statements have been derived in parts from products of a
similar structure or composition.

Irritation

Assessment of irritating effects:

Skin contact causes irritation. May cause severe damage to the eyes.

Experimental/calculated data:
Skin corrosion/irritation rabbit: Irritant. (OECD Guideline 404)
The product has not been fully tested. The statements have been derived in parts from products of a
similar structure or composition.

Serious eye damage/irritation rabbit: irreversible damage (OECD Guideline 405)

The product has not been fully tested. The statements have been derived in parts from products of a
similar structure or composition.

Respiratory/Skin sensitization

Assessment of sensitization:
Sensitization after skin contact possible.

Experimental/calculated data:
Mouse Local Lymph Node Assay (LLNA) mouse: skin sensitizing (OECD Guideline 429)
The product has not been fully tested. The statements have been derived in parts from products of a
similar structure or composition.

Germ cell mutagenicity

Assessment of mutagenicity:
Based on the ingredients, there is no suspicion of a mutagenic effect.

Carcinogenicity
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Safety data sheet according to UN GHS 4th rev.
Date / Revised: 18.02.2022 Version: 2.1
Product: Laromer® UA 9181
(ID no. 30794238/SDS_GEN_00/EN)
Date of print 21.09.2023
Assessment of carcinogenicity:
The whole of the information assessable provides no indication of a carcinogenic effect.

Reproductive toxicity

Assessment of reproduction toxicity:

Based on the ingredients, there is no suspicion of a toxic effect on reproduction.

Developmental toxicity

Assessment of teratogenicity:
Based on the ingredients, there is no suspicion of a teratogenic effect.

Specific target organ toxicity (single exposure)

Assessment of STOT single:

Based on the available information there is no specific target organ toxicity to be expected after a
single exposure.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure)

Assessment of repeated dose toxicity:

The information available on the product provides no indication of toxicity on target organs after
repeated exposure.

Aspiration hazard

not applicable

12. Ecological Information

Toxicity

Assessment of aquatic toxicity:

Acutely toxic for aquatic organisms. The inhibition of the degradation activity of activated sludge is
not anticipated when introduced to biological treatment plants in appropriate low concentrations.

Toxicity to fish:
LC50 (96 h) 1 - 10 mg/l, Fish (DIN 38412 Part 15, static)
The product has not been fully tested. The statements have been derived in parts from products of a
similar structure or composition.

Aquatic invertebrates:
EC50 (48 h) 10 - 100 mg/l, Daphnia magna (Directive 84/449/EEC, C.2, static)
The product has not been fully tested. The statements have been derived in parts from products of a
similar structure or composition.

Aquatic plants:
EC50 (72 h) 1 - 10 mg/l (growth rate), Scenedesmus subspicatus (DIN 38412 Part 9, static)
The product has not been fully tested. The statements have been derived in parts from products of a
similar structure or composition.

Microorganisms/Effect on activated sludge:

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Safety data sheet according to UN GHS 4th rev.
Date / Revised: 18.02.2022 Version: 2.1
Product: Laromer® UA 9181
(ID no. 30794238/SDS_GEN_00/EN)
Date of print 21.09.2023
EC20 (0,5 h) > 1.000 mg/l, activated sludge, domestic (OECD Guideline 209, aerobic)
The inhibition of the degradation activity of activated sludge is not anticipated when introduced to
biological treatment plants in appropriate low concentrations. The product has not been fully tested.
The statements have been derived in parts from products of a similar structure or composition.

Chronic toxicity to fish:

No data available.

Chronic toxicity to aquatic invertebrates:

No data available.

Assessment of terrestrial toxicity:

No data available concerning terrestrial toxicity.

Persistence and degradability

Assessment biodegradation and elimination (H2O):

The ecotoxic component(s) is/are readily biodegradable. The polymer component of the product is
poorly biodegradable.
The product has not been fully tested. The statements have been derived in parts from products of a
similar structure or composition.

Assessment of stability in water:

According to structural properties, hydrolysis is not expected/probable.
Bioaccumulative potential

Assessment bioaccumulation potential:

The product has not been tested.

Mobility in soil

Assessment transport between environmental compartments:

Volatility: The substance will not evaporate into the atmosphere from the water surface.

Other adverse effects

The product does not contain substances that are listed in Regulation (EC) 1005/2009 on
substances that deplete the ozone layer.

Additional information

Add. remarks environm. fate & pathway:

Treatment in biological waste water treatment plants has to be performed according to local and
administrative regulations.

Other ecotoxicological advice:

Do not release untreated into natural waters.

13. Disposal Considerations

Waste treatment methods

Must be disposed of or incinerated in accordance with local regulations.

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Safety data sheet according to UN GHS 4th rev.
Date / Revised: 18.02.2022 Version: 2.1
Product: Laromer® UA 9181
(ID no. 30794238/SDS_GEN_00/EN)
Date of print 21.09.2023

Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.

14. Transport Information

Land transport

ADR
Not classified as a dangerous good under transport regulations
UN number or ID number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

RID
Not classified as a dangerous good under transport regulations
UN number or ID number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

Inland waterway transport

ADN
Not classified as a dangerous good under transport regulations
UN number or ID number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user:

Transport in inland waterway vessel

Not evaluated

Sea transport

IMDG
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Safety data sheet according to UN GHS 4th rev.
Date / Revised: 18.02.2022 Version: 2.1
Product: Laromer® UA 9181
(ID no. 30794238/SDS_GEN_00/EN)
Date of print 21.09.2023
Not classified as a dangerous good under transport regulations
UN number or ID number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

Air transport

IATA/ICAO
Not classified as a dangerous good under transport regulations
UN number or ID number Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

Maritime transport in bulk according to IMO instruments

Maritime transport in bulk is not intended.

15. Regulatory Information

Safety, health and environmental regulations/legislation specific for the substance or
mixture

Not applicable

16. Other Information

Full text of classifications, hazard symbols and hazard statements, if mentioned in section 2 or 3:
Skin Corr./Irrit. Skin corrosion/irritation
Eye Dam./Irrit. Serious eye damage/eye irritation
Skin Sens. Skin sensitization
Aquatic Acute Hazardous to the aquatic environment - acute
Acute Tox. Acute toxicity
H318 Causes serious eye damage.
H315 Causes skin irritation.
H303 May be harmful if swallowed.
H317 May cause an allergic skin reaction.
H401 Toxic to aquatic life.
H319 Causes serious eye irritation.

The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. This safety data sheet is neither a
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification
agreement. Identified uses in this safety data sheet do neither represent an agreement on the
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Safety data sheet according to UN GHS 4th rev.
Date / Revised: 18.02.2022 Version: 2.1
Product: Laromer® UA 9181
(ID no. 30794238/SDS_GEN_00/EN)
Date of print 21.09.2023
corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.

Vertical lines in the left hand margin indicate an amendment from the previous version.