Safety Data Sheet

Hempel's Curing Agent 9874D

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2020/878 - Europe

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name : Hempel's Curing Agent 9874D
Product identity : 9874D00000
Product type : Curing agent

1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application : used only as part of two- or multi component products.
Ready-for-use mixture : (see base component)
Identified uses : Industrial applications, Used by spraying.

1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number
Company details : HEMPEL A/S Emergency telephone number (with hours of operation)
Lundtoftegårdsvej 91
DK-2800 Kgs. Lyngby +45 45 93 38 00 (08.00 - 17.00)
Denmark See section 4 First aid measures.
Tel.: + 45 45 93 38 00
hempel@hempel.com
Date of issue : 21 November 2022
Date of previous issue : 3 August 2022.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS
Skin Corr. 1C, H314 SKIN CORROSION/IRRITATION
Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION
Skin Sens. 1, H317 SKIN SENSITIZATION
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : H226 - Flammable liquid and vapor.
H314 - Causes severe skin burns and eye damage.
H317 - May cause an allergic skin reaction.
Precautionary statements :
Prevention : Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking.
Response : IF INHALED: Immediately call a POISON CENTER or doctor. IF SWALLOWED: Immediately call a
POISON CENTER or doctor. IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water. Immediately call a POISON CENTER or doctor. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor.
Hazardous ingredients : butan-1-ol
2,4,6-tris(dimethylaminomethyl)phenol
3,6-diazaoctanethylenediamin
Supplemental label elements :
Special packaging requirements
Containers to be fitted with child- Not applicable.
resistant fastenings :
Tactile warning of danger : Not applicable.

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SECTION 2: Hazards identification

2.3 Other hazards

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
Other hazards which do not result None known.
in classification :

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Product/ingredient name Identifiers % Regulation (EC) No. 1272/2008 [CLP] Type

xylene REACH #: 01-2119488216-32 ≥10 - ≤25 Flam. Liq. 3, H226 ATE [Dermal] = 1100 mg/kg [1] [2]
EC: 215-535-7 Acute Tox. 4, H312 ATE [Inhalation (gases)] =
5000 ppm
CAS: 1330-20-7 Acute Tox. 4, H332
Index: 601-022-00-9 Skin Irrit. 2, H315
butan-1-ol REACH #: 01-2119484630-38 ≥10 - <20 Flam. Liq. 3, H226 ATE [Oral] = 790 mg/kg [1]
EC: 200-751-6 Acute Tox. 4, H302
CAS: 71-36-3 Skin Irrit. 2, H315
Index: 603-004-00-6 Eye Dam. 1, H318
STOT SE 3, H335
STOT SE 3, H336
2,4,6-tris(dimethylaminomethyl) REACH #: 01-2119560597-27 ≥5 - ≤10 Acute Tox. 4, H302 ATE [Oral] = 1200 mg/kg [1]
phenol EC: 202-013-9 Skin Corr. 1C, H314
CAS: 90-72-2 Eye Dam. 1, H318
ethylbenzene REACH #: 01-2119489370-35 ≥3 - ≤5 Flam. Liq. 2, H225 ATE [Inhalation (vapours)] = 11 [1] [2]
EC: 202-849-4 Acute Tox. 4, H332 mg/l
CAS: 100-41-4 STOT RE 2, H373
Index: 601-023-00-4 (hearing organs)
Asp. Tox. 1, H304
3,6-diazaoctanethylenediamin REACH #: 01-2119487919-13 ≥1 - ≤3 Acute Tox. 3, H311 ATE [Dermal] = 550 mg/kg [1]
EC: 203-950-6 Skin Corr. 1B, H314
CAS: 112-24-3 Eye Dam. 1, H318
Index: 612-059-00-5 Skin Sens. 1, H317
Aquatic Chronic 3, H412
bis[(dimethylamino)methyl] EC: 275-162-0 ≥1 - ≤3 Skin Corr. 1C, H314 - [1]
phenol CAS: 71074-89-0 Eye Dam. 1, H318
salicylic acid REACH #: 01-2119486984-17 <1 Acute Tox. 4, H302 ATE [Oral] = 891 mg/kg [1]
EC: 200-712-3 Eye Dam. 1, H318
CAS: 69-72-7 Repr. 2, H361d
Index: 607-732-00-5
toluene REACH #: 01-2119471310-51 ≤0.3 Flam. Liq. 2, H225 - [1] [2]
EC: 203-625-9 Skin Irrit. 2, H315
CAS: 108-88-3 Repr. 2, H361d
Index: 601-021-00-3 STOT SE 3, H336
STOT RE 2, H373
Asp. Tox. 1, H304
See Section 16 for the full text of the H statements declared
above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.

SECTION 4: First aid measures

4.1 Description of first aid measures

General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by
mouth. If unconscious, place in recovery position and get medical attention immediately.

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SECTION 4: First aid measures

Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners. In case of burns flush with water until the
pain ceases. While flushing remove clothing from the affected area unless it is burnt into the skin. If
hospital treatment is necessary flushing must continue during transfer and until the hospital staff takes
over the treatment.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes severe burns. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : If gasses have been inhaled, from the decomposition of the product, symptoms may be delayed. Treat
symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested
or inhaled.
Specific treatments : No specific treatment.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray.
Not to be used: waterjet.

5.2 Special hazards arising from the substance or mixture

Hazards from the substance or Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated,
mixture : a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
Hazardous combustion products : Decomposition products may include the following materials: carbon oxides nitrogen oxides

5.3 Advice for firefighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters should
wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.

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SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Avoid all direct contact with the spilled material. Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid
breathing vapor or mist. Refer to protective measures listed in sections 7 and 8. No action shall be taken involving any personal risk or
without suitable training. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local
regulations.

6.2 Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air).

6.3 Methods and materials for containment and cleaning up

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same
hazard as the spilled product.

6.4 Reference to other sections

See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or
explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the
product should be used only in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment
should be protected to the appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receiving
container with bonding strap. No sparking tools should be used.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area
where this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers
made from the same material as the original one.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a cool, well-ventilated area away from incompatible materials and ignition sources.
Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking. Prevent unauthorized
access. Containers that are opened must be carefully resealed and kept upright to prevent leakage.

7.3 Specific end use(s)

See separate Product Data Sheet for recommendations or industrial sector specific solutions.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Product/ingredient name Exposure limit values

xylene EU OEL (Europe, 1/2022). [xylene, mixed isomers] Absorbed through skin.
TWA: 50 ppm 8 hours.
TWA: 221 mg/m³ 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 442 mg/m³ 15 minutes.
ethylbenzene EU OEL (Europe, 1/2022). Absorbed through skin.
STEL: 884 mg/m³ 15 minutes.
STEL: 200 ppm 15 minutes.
TWA: 442 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
toluene EU OEL (Europe, 1/2022). Absorbed through skin.
TWA: 192 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
STEL: 384 mg/m³ 15 minutes.
STEL: 100 ppm 15 minutes.

Recommended monitoring procedures

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SECTION 8: Exposure controls/personal protection

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres -
Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy)
European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure
to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of
procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Derived effect levels
Product/ingredient name Type Exposure Value Population Effects
xylene DNEL Long term Inhalation 77 mg/m³ Workers Systemic
DNEL Long term Dermal 180 mg/kg bw/day Workers Systemic
2,4,6-tris(dimethylaminomethyl)phenol DNEL Long term Inhalation 0.53 mg/m³ Workers Systemic
DNEL Long term Dermal 0.15 mg/kg bw/day Workers Systemic
ethylbenzene DNEL Long term Dermal 180 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 77 mg/m³ Workers Systemic
3,6-diazaoctanethylenediamin DNEL Long term Dermal 0.57 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 1 mg/m³ Workers Systemic
salicylic acid DNEL Long term Dermal 2 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 5 mg/m³ Workers Systemic
toluene DNEL Long term Dermal 384 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 192 mg/m³ Workers Systemic

Predicted effect concentrations

Product/ingredient name Compartment Detail Value Method Detail
xylene Fresh water 0.327 mg/l -
Marine water 0.327 mg/l -
Fresh water sediment 12.46 mg/kg -
Marine water sediment 12.46 mg/kg -
Soil 2.31 mg/kg -
Sewage Treatment Plant 6.68 mg/l -
2,4,6-tris(dimethylaminomethyl)phenol Fresh water 0.084 mg/l -
Marine water 0.0084 mg/l -
Sewage Treatment Plant 0.2 mg/l -
ethylbenzene Fresh water 0.1 mg/l -
Marine water 0.01 mg/l -
Sewage Treatment Plant 9.6 mg/l -
Fresh water sediment 13.7 mg/kg -
Soil 2.68 mg/kg -
3,6-diazaoctanethylenediamin Fresh water 190 µg/l -
Fresh water sediment 95.9 mg/kg -
Marine water 38 µg/l -
Marine water sediment 19.2 mg/kg -
Soil 19.1 mg/kg -
Sewage Treatment Plant 4.25 mg/l -
salicylic acid Fresh water sediment 1.42 mg/kg -
Soil 0.166 mg/kg -
Fresh water 0.2 mg/l -
Marine water 0.02 mg/l -
Marine water sediment 0.142 mg/kg -
Sewage Treatment Plant 162 mg/l -
toluene Fresh water 0.68 mg/l -
Marine water 0.68 mg/l -
Sewage Treatment Plant 13.61 mg/l -
Fresh water sediment 16.39 mg/kg -
Marine water sediment 16.39 mg/kg -
Soil 2.89 mg/kg -
phenol Fresh water 0.0077 mg/l -
Marine water 0.00077 mg/l -
Sewage Treatment Plant 2.1 mg/l -
Fresh water sediment 0.0915 mg/kg -
Marine water sediment 0.00915 mg/kg -
Soil 0.36 mg/kg -

8.2 Exposure controls

Appropriate engineering controls
Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust
lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-
station location.

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SECTION 8: Exposure controls/personal protection

Individual protection measures
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.

Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face
respirator may be required instead.
Hand protection : Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:

Short term exposure: natural rubber (latex)

Recommended: polyvinyl alcohol (PVA), Silver Shield / Barrier / 4H gloves, Viton®
May be used: neoprene rubber, polyvinyl chloride (PVC), butyl rubber, nitrile rubber

Body protection : Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Chemical-resistant apron.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator. If
working areas have insufficient ventilation: When the product is applied by means that will not generate
an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter of type A,
when grinding use particle filter of type P. When the product is applied by spraying and for continuous
or prolonged work always wear an air-fed respirator e.g. hood with supply of fresh or compressed air or
a full face, powered air purifying filter. Be sure to use an approved/certified respirator or equivalent.
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state : Liquid.
Color : Transparent
Odor : Solvent-like
pH : Testing not relevant or not possible due to nature of the product.
Melting point/freezing point : Testing not relevant or not possible due to nature of the product.
Boiling point/boiling range : Testing not relevant or not possible due to nature of the product.
Flash point : Closed cup: 33°C (91.4°F)
Evaporation rate : Testing not relevant or not possible due to nature of the product.
Flammability : Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Lower and upper explosive 0.8 - 11.3 vol %
(flammable) limits :
Vapor pressure : Testing not relevant or not possible due to nature of the product.
Vapor density : Testing not relevant or not possible due to nature of the product.
Specific gravity : 0.938 g/cm³
Partition coefficient (LogKow) : Testing not relevant or not possible due to nature of the product.
Auto-ignition temperature : Lowest known value: 337.78°C (640°F) (3,6-diazaoctanethylenediamin).
Decomposition temperature : Testing not relevant or not possible due to nature of the product.
Viscosity : Aspiration hazard (H304) Not classified. Testing not relevant due to nature of the product.

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SECTION 9: Physical and chemical properties

Explosive properties : Explosive in the presence of the following materials or conditions: open flames, sparks and static
discharge and heat.
Oxidizing properties : Testing not relevant or not possible due to nature of the product.

9.2 Other information

Solvent(s) % by weight : Weighted average: 35 %
Water % by weight : Weighted average: 0 %
VOC content : 331 g/l
TOC Content : Weighted average: 263 g/l
Solvent Gas : Weighted average: 0.089 m³/l

SECTION 10: Stability and reactivity

10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability

The product is stable.

10.3 Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat
or sources of ignition.

10.5 Incompatible materials

Extremely reactive or incompatible with the following materials: acids.
Highly reactive or incompatible with the following materials: oxidizing materials.
Reactive or incompatible with the following materials: reducing materials and organic materials.

10.6 Hazardous decomposition products

When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: carbon oxides nitrogen oxides

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratory
system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by
absorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in extreme
cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting
in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible
damage. Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the lungs via
vomiting.
Inhalation of a corrosive substance may result in health effects such as stinging, coughing and in extreme cases, dyspnoea or loss of
consciousness with a risk of lung damage, possibly lung oedema. Cauterization of skin and mucous membrane. If splashed in the eyes, the
liquid may cause ireversible damage. Accidental swallowing may cause stinging and cauterization to mouth, oesophagus and stomach.
Symptoms and signs include bloody vomiting, chock and loss of consciousness.
Acute toxicity

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SECTION 11: Toxicological information

Product/ingredient name Result Species Dose Exposure

xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LC50 Inhalation Vapor Rat 6350 ppm 4 hours
LD50 Dermal Rabbit >4200 mg/kg -
LD50 Oral Rat 3523 mg/kg -
butan-1-ol LC50 Inhalation Vapor Rat 24000 mg/m³ 4 hours
LD50 Dermal Rabbit 3400 mg/kg -
LD50 Oral Rat 790 mg/kg -
2,4,6-tris(dimethylaminomethyl) LD50 Dermal Rabbit 1465 mg/kg -
phenol
LD50 Oral Rat 1200 mg/kg -
LD50 Oral Rat 2169 mg/kg -
ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
3,6-diazaoctanethylenediamin LD50 Dermal Rabbit 550 mg/kg -
LD50 Oral Rat 1716 mg/kg -
salicylic acid LC50 Inhalation Dusts and mists Rat >0.9 mg/l 1 hours
LD50 Dermal Rat >2000 mg/kg -
LD50 Oral Rat 891 mg/kg -
toluene LC50 Inhalation Vapor Rat >20 mg/l 4 hours
LD50 Oral Rat 636 mg/kg -
Acute toxicity estimates
Product/ingredient name Oral Dermal Inhalation Inhalation Inhalation
mg/kg mg/kg (gases) (vapors) (dusts and
ppm mg/l mists)
mg/l
Hempel's Curing Agent 9874D 3995.6 6008.1 33291.7 329.6
xylene 3523 1100 5000
butan-1-ol 790 3400 24
2,4,6-tris(dimethylaminomethyl)phenol 1200
ethylbenzene 3500 11
3,6-diazaoctanethylenediamin 550
salicylic acid 891
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure
xylene Eyes - Severe irritant Rabbit - 24 hours 5 milligrams
Skin - Irritant Rabbit - -
Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
butan-1-ol Eyes - Severe irritant Rabbit - 24 hours 2 milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 milligrams
2,4,6-tris(dimethylaminomethyl) Eyes - Severe irritant Rabbit - 24 hours 50 Micrograms
phenol
Skin - Severe irritant Rabbit - 24 hours 2 milligrams
ethylbenzene Eyes - Mild irritant Rabbit - -
Respiratory - Mild irritant Rabbit - -
Skin - Mild irritant Rabbit - 24 hours 15 milligrams
3,6-diazaoctanethylenediamin Eyes - Moderate irritant Rabbit - 24 hours 20 milligrams
Skin - Severe irritant Rabbit - 24 hours 5 milligrams
salicylic acid Eyes - Severe irritant Rabbit - -
toluene Eyes - Mild irritant Rabbit - 0.5 minutes 100 milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 milligrams
Sensitizer
Product/ingredient name Route of exposure Species Result
3,6-diazaoctanethylenediamin skin Guinea pig Sensitizing

Mutagenic effects
No known significant effects or critical hazards.

Carcinogenicity
No known significant effects or critical hazards.

Reproductive toxicity
No known significant effects or critical hazards.

Teratogenic effects
No known significant effects or critical hazards.

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SECTION 11: Toxicological information

Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of exposure Target organs
butan-1-ol Category 3 Respiratory tract irritation
Category 3 Narcotic effects
toluene Category 3 Narcotic effects
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of exposure Target organs
ethylbenzene Category 2 - hearing organs
toluene Category 2 - -
Aspiration hazard
Product/ingredient name Result
ethylbenzene ASPIRATION HAZARD - Category 1
toluene ASPIRATION HAZARD - Category 1
Information on the likely routes of exposure
Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential chronic health effects
Sensitization : Contains 3,6-diazaoctanethylenediamin. May produce an allergic reaction.
11.2 Information on other hazards
Endocrine disrupting properties : See Section 15 for details.
Other information : No additional known significant effects or critical hazards.

SECTION 12: Ecological information

12.1 Toxicity
Do not allow to enter drains or watercourses.
Product/ingredient name Result Species Exposure
butan-1-ol Acute EC50 1328 mg/l Daphnia 96 hours
Acute LC50 1.376 mg/l Fish 96 hours
2,4,6-tris(dimethylaminomethyl) Acute EC50 84 mg/l Algae 72 hours
phenol
Acute LC50 175 mg/l Fish 96 hours
ethylbenzene Chronic NOEC <1000 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours
3,6-diazaoctanethylenediamin Acute EC50 20 mg/l Algae 72 hours
Acute EC50 31.1 mg/l Daphnia 48 hours
Acute LC50 330 mg/l Fish 96 hours
toluene Chronic NOEC <500000 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours
Chronic NOEC 1000 µg/l Fresh water Daphnia - Daphnia magna 21 days

12.2 Persistence and degradability

Product/ingredient name Test Result Dose Inoculum
xylene OECD 301F Ready 90 - 98 % - Readily - 28 days - -
Biodegradability - Manometric
Respirometry Test
- >60 % - Readily - 28 days - -
butan-1-ol OECD 301D Ready 92 % - 20 days - -
Biodegradability - Closed Bottle Test
2,4,6-tris(dimethylaminomethyl) OECD 301D 301D Ready 4 % - Not readily - 28 days - -
phenol Biodegradability - Closed Bottle Test
ethylbenzene - >70 % - Readily - 28 days - -
salicylic acid - 100 % - Readily - 14 days - -
toluene - 100 % - Readily - 14 days - -

Product/ingredient name Aquatic half-life Photolysis Biodegradability

xylene - - Readily
butan-1-ol - - Readily
2,4,6-tris(dimethylaminomethyl) - - Not readily
phenol
ethylbenzene - - Readily
salicylic acid - - Readily
toluene - - Readily

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Safety Data Sheet
Hempel's Curing Agent 9874D

SECTION 12: Ecological information

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
xylene 3.12 8.1 - 25.9 low
butan-1-ol 1 3.16 low
2,4,6-tris(dimethylaminomethyl)phenol 0.219 - low
ethylbenzene 3.6 - low
3,6-diazaoctanethylenediamin -1.66 - -1.4 - low
salicylic acid 2.21 - 2.26 - low
toluene 2.73 90 low

12.4 Mobility in soil

Soil/water partition coefficient No known data avaliable in our database.
(KOC) :
Mobility : No known data avaliable in our database.

12.5 Results of PBT and vPvB assessment

Product/ingredient name PBT P B T vPvB vP vB
This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Endocrine disrupting properties

See Section 15 for details.
12.7 Other adverse effects
No known significant effects or critical hazards.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

The generation of waste should be avoided or minimized wherever possible. Residues of the product is listed as hazardous waste. Dispose
of according to all state and local applicable regulations. Waste should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Spillage, remains, discarded clothes and similar should be discarded in a fireproof
container.
European waste catalogue no. (EWC) is given below.
European waste catalogue (EWC) : 08 01 11*
Packaging
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible.

SECTION 14: Transport information

Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by
sea, IATA for transport by air.
14.1 14.2 14.3 14.4 14.5
UN / ID no. Proper shipping name Transport hazard class(es) PG* Env* Additional information

ADR/RID UN3469 PAINT, FLAMMABLE, CORROSIVE 3 III No. Tunnel code (D/E)
Class 8

IMDG UN3469 PAINT, FLAMMABLE, CORROSIVE 3 III No. Emergency schedules

Class 8 F-E, S-C

IATA UN3469 PAINT, FLAMMABLE, CORROSIVE 3 III No. -

Class 8

PG* : Packing group

Env.* : Environmental hazards

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Safety Data Sheet
Hempel's Curing Agent 9874D

SECTION 14: Transport information

14.6 Special precautions for user
Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
14.7 Maritime transport in bulk according to IMO instruments
Not applicable.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization - Substances of very high concern
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
Not applicable.
Other EU regulations
Seveso category This product is controlled under the Seveso III Directive.
Seveso category
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b

15.2 Chemical Safety Assessment

Yes.

SECTION 16: Other information

Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
EUH statement = CLP-specific Hazard statement
RRN = REACH Registration Number
DNEL = Derived No Effect Level
PNEC = Predicted No Effect Concentration
Full text of abbreviated H statements : H225 Highly flammable liquid and vapor.
H226 Flammable liquid and vapor.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
Full text of classifications [CLP/GHS] : Acute Tox. 3 ACUTE TOXICITY - Category 3
Acute Tox. 4 ACUTE TOXICITY - Category 4
Aquatic Chronic 3 AQUATIC HAZARD (LONG-TERM) - Category 3
Asp. Tox. 1 ASPIRATION HAZARD - Category 1
Eye Dam. 1 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Flam. Liq. 2 FLAMMABLE LIQUIDS - Category 2
Flam. Liq. 3 FLAMMABLE LIQUIDS - Category 3
Repr. 2 TOXIC TO REPRODUCTION - Category 2
Skin Corr. 1B SKIN CORROSION/IRRITATION - Category 1B
Skin Corr. 1C SKIN CORROSION/IRRITATION - Category 1C
Skin Irrit. 2 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1 SKIN SENSITIZATION - Category 1
STOT RE 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
STOT SE 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 3
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

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Safety Data Sheet
Hempel's Curing Agent 9874D

SECTION 16: Other information

Classification Justification
FLAMMABLE LIQUIDS On basis of test data
SKIN CORROSION/IRRITATION Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION Calculation method
SKIN SENSITIZATION Calculation method

Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.

Version: 0.06 Page: 12/14

Safe Use of Mixture Information
Hempel's Curing Agent 9874D

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Indoor or outdoor spray painting by professionals or with brush, roller, putty knife, dipping etc. with good general room ventilation
This safe use information is : Professional spray painting and/or low-energy painting, Substance-specific
linked to TETA
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Indoor or outdoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions

Risk management measures (RMM)

Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 1 to 4 hours Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
application ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with
factor of at least 10. specific activity training.

Loading of application PROC08a 1 to 4 hours Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
equipment and handling ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
of coated parts before an assigned protection in combination with
curing factor of at least 10. specific activity training.

Professional application of PROC10 More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
coatings by brush or roller hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with
factor of at least 10. specific activity training.

Professional application of PROC11 3 hours Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
coatings by spraying ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with
factor of at least 10. specific activity training.

Industrial application of PROC07 More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
coatings by spraying hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with
factor of at least 10. specific activity training.

Film formation - force PROC04 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
drying, stoving and other hours ventilation - Outdoors according to EN 166. tested to EN374.
technologies

Cleaning PROC05 1 to 4 hours Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with
factor of at least 10. specific activity training.

Waste management PROC08a 1 to 4 hours Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with
factor of at least 10. specific activity training.
See chapter 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 13/14
Safe Use of Mixture Information
Hempel's Curing Agent 9874D

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Indoor or outdoor spray painting by professionals or with brush, roller, putty knife, dipping etc. with good general room ventilation
This safe use information is : Professional spray painting and/or low-energy painting, local effect - Level III
linked to Skin Corr. 1, Eye Dam. 1, Resp. Sens. 1 or EUH071
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Indoor or outdoor use

Risk management measures (RMM)

Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
application hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with 'basic'
factor of at least 10. employee training.

Loading of application PROC08a More than 4 Good general room 3-5 None Use eye protection Wear chemical-resistant
equipment and handling hours ventilation - Outdoors according to EN 166. gloves (tested to EN374)
of coated parts before in combination with 'basic'
curing employee training.

Professional application of PROC10 More than 4 Good general room 3-5 None Use eye protection Wear chemical-resistant
coatings by brush or roller hours ventilation - Outdoors according to EN 166. gloves (tested to EN374)
in combination with 'basic'
employee training.

Professional application of PROC11 More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
coatings by spraying hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with 'basic'
factor of at least 10. employee training.

Film formation - force PROC04 More than 4 Good general room 3-5 None None Wear suitable gloves
drying, stoving and other hours ventilation - Outdoors tested to EN374.
technologies

Cleaning PROC05 More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with 'basic'
factor of at least 10. employee training.

Waste management PROC08a More than 4 Good general room 3-5 None Use eye protection Wear chemical-resistant
hours ventilation - Outdoors according to EN 166. gloves (tested to EN374)
in combination with 'basic'
employee training.
See chapter 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
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