1ST Term S1 Chemistry
1ST Term S1 Chemistry
1ST Term S1 Chemistry
SCHEME OF WORK
WEEK TOPIC
1. INTRODUCTION TO CHEMISTRY
2. LABORATORY FAMILIARIZATION
3. NATURE OF MATTER
4. ELEMENTS & SYMBOLS, VALENCY
5. COMPOUNDS AND MIXTURES
6. STANDARD SEPARATION TECHNIQUES FOR MIXTURES
7. PARTICULATE NATURE OF MATTER
8. IUPAC NOMENCLATURE OF CHEMICAL COMPOUNDS
9. ATOMIC NUMBER, MASS NUMBER, ISOTOPES AND CALCULATIONS
10 STRUCTURE OF THE ATOM: ORBITALS AND ELECTRONIC
STRUCTURE OF THE ATOM
11 REVISION
12 EXAMINATION
REFERENCE MATERIALS
New School Chemistry for Senior Secondary School by Osei Yaw A.
Practical Chemistry for Schools and Colleges by G. O. Ojokuku
Calculation in Chemistry by E.U. Akusoba and G.O Ewelukwa
WASSCE Past Questions and Answers on Chemistry
UTME Past Questions and Answers on Chemistry
WEEK ONE
TOPIC: INTRODUCTION TO CHEMISTRY
CONTENT
CHEMISTRY AS A SCIENCE SUBJECT
BRANCHES OF CHEMISTRY
SOME LABORATORY APPARATUSES AND THEIR USES
CHEMISTRY AS A SCIENCE SUBJECT
Science is an organized body of knowledge gathered through systematic experimentations and
philosophical observations. Chemistry can be defined as a branch of science which deals with the
study of the nature, structure, composition, properties and uses of all forms of matter and the
changes in structure and composition which matter undergoes.
BRANCHES OF CHEMISTRY
Chemistry is divided into three main branches, namely
Physical chemistry
Organic chemistry
Inorganic chemistry
Physical chemistry deals with the physical aspect of chemistry like quantum theory, heat and
electricity.
Organic chemistry deals with the study of carbon and its compounds.
Inorganic chemistry deals with the study of elements, their properties and uses
Hypothesis refers to a prediction or guesses which explains an observed problem. When the
hypothesis has been tested and found to be true within the limits of available evidence, it
becomes a theory. A theory which has been extensively tested and proven correct without any
exception becomes a scientific law.
EVALUATION
1. Define chemistry
2. State the stages or steps involved in scientific discoveries
3. When does a theory become a scientific law?
APPLICATIONS OF CHEMISTRY
Chemistry is applied in our everyday life as different activities take place in the environment. The
effect of chemistry is felt in different aspects of life such as cooking, washing with soaps or
detergent, digestion of food, drugs etc. Other applications of chemistry include health care,
transportation, food, houses and clothes.
EVALUATION
1. State five applications of chemistry in our daily life.
2. Mention five adverse effects of chemicals and how they can be controlled.
GENERAL EVALUATION
1. Mention ten (10) career opportunities in chemistry.
2. List the branches of chemistry.
READING ASSIGNMENT
New School Chemistry for SSS by O.Y Ababio. Pg 2 to 7
Practical Chemistry for School and Collegs by G. O. Ojokuku pg 2-15
WEEKEND ASSIGNMENT
1. The aspect of chemistry that deals with the study of carbon and its compound is called
(a) physical chemistry (b) Organic chemistry (c) Inorganic chemistry (d) Analytical
chemistry
2. Which of the following is not an adverse effect of chemistry? (a) pollution (b) poisoning
(c) emulsion (d) corrosion
Name_____________________________________________ Date_______________
3. A stage in scientific method of discoveries is (a) Evaporating (b) Hypothesis (c)
Dehydrating (d) dissolving
4. A theory which has been extensively tested and proven correct without any exception
becomes (a) scientific law (b) hypothesis (c) experiment (d) pattern
5. Career prospects in chemistry includes all the following EXCEPT (a) Biochemistry (b)
Quality control (c) Accounting (d) Metallurgy
THEORY
1. State five applications of chemistry in our daily life
2. Mention five laboratory apparatus and their uses
WEEK TWO
TOPIC: LABORATORY FAMILIARIZATION
CONTENT
DEFINTION OF LABORATORY
LABORATORY APPARATUS; MEANING, USES AND IDENTIFICATION
LABORATORY SAFETY RULES
Name_____________________________________________ Date_______________
DEFINITION OF LABORATORY
A laboratory is a room or building equipped for scientific experimentation or research. It is a
special facility where experiments are done and typically contains scientific equipment and
apparatus.
LABORATORY APPARATUS
Laboratory apparatus refers to the various tools or equipment used by scientists working in the
laboratory.
Some common laboratory apparatuses include: test tube, beaker, conical flask, flat bottomed
flask, round-bottomed flask, funnel (plastic or glass) thistle funnel, brush, Woulff’s bottle tripod
stand, retort stand, spatula, Bunsen burner, separating funnel, wire gauze, clamp, beehive shelf,
gas jar, desiccated, reflux-condenser, Liebig condenser, pipette, burette, delivery tube,
deflagrating spoon, u-tube, thermometer, aspirator bottle, wash bottle, chemical balance,
reagent bottle, fume cupboard etc.
EVALUATION
1. Mention ten (10) laboratory pieces of apparatus you know and their uses
2. Define (a) Laboratory (b) Laboratory apparatus
A B c
E F
D
G
H
READING ASSIGNMENT
Practical Chemistry for School and Collegs by G. O. Ojokuku pg 2-15
WEEKEND ASSIGNMENT
1. An apparatus in the laboratory in which the preparation of poisonous gases is done is
called (a) distillation tank (b) Aspirator bottle (c) fume cupboard (d) bell jar
2. In the laboratory _______ is used for the collection of a gas over water (a) gas jar (b)
Woulff’s bottle (c) reagent bottle (d)burette
3. Two liquids which are immiscible with each other can be separated using (a) bell jar (b)
gas jar (c) wash bottle (d) separating funnel
4. An apparatus used to hold drying agents during the preparation of dry gases is (a)
conical flask (b) gas jar (c) Woulff’s bottle (d) flat bottom flask
5. Coloured reagent bottles are used to store reagents which are capable of _____ easily by
sunlight (a) evaporating (b) decomposing (c) dehydrating (d) dissolving
THEORY
1. a. Define Laboratory
b. List five safety measures that must be taken when in the laboratory
2. State the use of the following apparatuses
a. Separating funnel
b. Condenser
WEEK THREE
TOPIC: NATURE OF MATTER
CONTENT
NATURE OF MATTER
COMPARISON BETWEEN SOLID, LIQUID AND GAS
TYPES OF CHANGE
NATURE OF MATTER
Matter is anything that has weight and occupies space. It exists in three states namely: solid,
liquid and gas.
The fundamental difference between the three states of matter depends on the degree of
movement of the particles they are made of.
SOLID STATE
The particles of a solid are tightly packed and held together by a strong electrostatic force.
The particles only vibrate to and fro about an equilibrium or a fixed position. They have a
definite shape and volume and very difficult to compress.
LIQUID STATE
The forces of attraction between molecules of liquids are weak compared to that of solids. Hence
they have slight movements. This is why liquids can flow. They have definite volume but not
definite shape.
GASEOUS STATE
As a result of the distance between the molecules of gases, the cohesive forces between them
are very negligible and so they move randomly. Gases have no definite shape and volume. They
assume the shape of the containing vessel.
EVALUATION
1. What is matter?
2. List and explain the three states of matter.
Name_____________________________________________ Date_______________
EVALUATION
1. Define matter
2. Compare the three states of matter in terms of (a) density (b) compressibility
TYPES OF CHANGES
Whenever a given substance is heated, its state changes. There are two types of changes:
physical and chemical.
PHYSICAL CHANGE:
A physical change is a change which is easily reversible and in which no new substances are
formed. Examples are:
1. Dissolution of common salt
2. Changes in states of matter such as melting of solids, freezing of liquids, evaporation of
liquids, liquefaction of gases to solids, sublimation of solids.
3. Magnetization and demagnetization of iron nails.
4. Separation of mixture by evaporation, distillation, fractional distillation etc.
EVALUATION
1. What is a physical change?
2. Give two examples of a physical change.
CHEMICAL CHANGE:
A chemical change is a change which is not easily reversible and in which new substances are
formed.
Examples of chemical change
1. Rusting of iron/metals.
2. Dissolution of metals and limestone in acids.
3. Fermentation and decay of substances.
4. Changes in electrochemical cells.
5. The addition of water to quick lime.
6. Burning of materials.
GENERAL EVALUATION/REVISION
1. What is a chemical change?
2. Give two examples of a chemical change.
3. State three differences between physical and chemical changes.
Name_____________________________________________ Date_______________
4. State the function of the following laboratory apparatuses: a) Fume cupboard b) Burette
(c) Bunsen burner
READING ASSIGNMENT
New School Chemistry for SSS by O.Y. Ababio.Pg 8 -9
WEEKEND ASSIGNMENT
1. Which of the following changes is a chemical change? (a) melting of ice (b) liquefaction
of air (c) slaking of lime (d) evaporation of a liquid
2. Which of the following substances will occupy a wider space? (a)carbon (iv) oxide (b)
liquid milk (c) pieces of chalk (d) water
3. When a solid changes to gas directly, this process is called (a) freezing (b) sublimation
(c) vaporization (d) evaporation
4. Which of the following changes produces a new substance ?(a) reaction of water with
sodium chloride (b) addition of acid to base (c) turning of margarine to oil (d)
evaporation of water
5. Which one of the following has a fixed shape and volume?
(a) a cube of sugar (b) liquid wax (c) smoke (d) kerosene
THEORY
1. Give two differences between physical and chemical changes.
2. Give three processes, which involve a physical change
WEEK FOUR
TOPIC: ELEMENTS, SYMBOLS & VALENCY
CONTENT
ELEMENTS AND SYMBOLS
CLASSIFICATION OF ELEMENTS
VALENCY
ELEMENTS AND SYMBOLS
An element is a substance which cannot be split into simpler units by ordinary chemical process.
There are over one hundred known elements.
SYMBOLS OF ELEMENTS
There are three ways in which symbols of elements are derived.
1. From the first letter of the name of the element
Element Symbols
Hydrogen H
Oxygen O
Iodine I
Fluorine F
Nitrogen N
Sulphur S
Carbon C
Phosphorus P
2. The first letter written in capital letter and one other letter from its name written in small
letter.
Element Symbol
Chlorine Cl
Bramine Br
Calcium Ca
Aluminium Al
Magnesium Mg
Berylium Be
Helium He
Neon Ne
Lithium L
Name_____________________________________________ Date_______________
3. The symbols of some elements were derived from their Latin names.
Elements Latin name Symbols
Mercury Hydragyrium Hg
Sodium Natrium Na
Iron Ferrum Fe
Copper Cuprum Cu
Silver Argentum Ag
Tin Stannum Sn
Gold Aurum Au
Potassium Kalium K
Lead Plumbum Pb
EVALUATION
1. How many elements are discovered now?
2. Write the symbols for the following elements: silicon, iodine, fluorine, sulphur, silver,
Iron, copper, potassium and sodium.
CLASSIFICATION OF ELEMENTS
Elements can be classified into metals and non-metals.
Examples of metals include iron, zinc, tin, aluminium, copper etc.
Examples of non-metals are: Chlorine, oxygen, sulphur, fluorine, hydrogen etc.
Some elements however possess the properties of metals as well as non-metals. They are called
metalloids, examples are silicon and germanium.
EVALUATION
1. What are metalloids?
2. State two differences between metals and non-metals.
VALENCY
Valency is the combining power of an element. It can also be defined as the number of hydrogen
atoms that can combine with or replace one atom of that element.
Valency of an element depends on the structure of that element. At times it corresponds to the
number of electrons in the outermost shells called valence electrons.
Below are the valencies of some elements:
Valencies have either positive or negative values showing whether electrons are gained or lost. If
an element gains electrons, its value is negative but positive when it loses electrons.
Generally, metals exhibit positive valencies while non – metal tend to have negative valencies.
Some element exhibit more than one valency. Valency can also be called oxidation number or
state.
RADICALS
A radical is a group of atoms having an electric charge either positive or negative which keeps its
identity and react as a single unit. Any small group of atoms carrying a negative charge is called
an acid radical. Examples of acid radicals include S042-, C032-, N03-
The valency of a radical corresponds to the charge it carries.
GENERAL EVALUATION/REVISION
1. Define (i) valency (ii) Radical
2. Write the valency of: a) Oxygen (b) Potassium c) Sulphur d) S0 42- e) NH4+
3. Classify the following into physical or chemical changes: a) Rusting of iron b)
Fermentation of palm wine c) Evaporation of a salt solution d) Melting of ice
READING ASSIGNMENT
New School Chemistry for SSS by O.Y Ababio. Pg 26, 32-33
WEEKEND ASSIGNMENT
1. The combining power of oxygen is (a)+2 (b)-2 (c)-1 (d)+1
2. Which of the following is a metalloid? (a) sulphur (b) iron (c) silicon (d) carbon
3. The symbol Au represents (a) silver (b) lead (c) copper (d) gold
4. Which of the following elements is used as a standard in defining valency?
(a) oxygen (b) copper (c) carbon (d) hydrogen
5. Which of the following metals is a liquid at room temperature?
(a) iron (b) gold (c) tin (d) mercury
THEORY
1. a. Define an element.
b. Write the symbols of the following elements
(i) Manganese (ii) Caesium (iii) Cobalt
2. a. What are metalloids?
b. Give two differences between metals and non-metal
WEEK FIVE
TOPIC: COMPOUNDS AND MIXTURES
CONTENT
COMPOUND
FORMULAE OF COMPOUNDS
MIXTURES
DIFFERENCES BETWEEN COMPOUNDS AND MIXTURES
COMPOUND
Name_____________________________________________ Date_______________
A Compound is a substance which contains two or more elements chemically combined together.
A compound is formed as a result of chemical change.
Examples of compounds are
Compound Constituent Elements
Water Hydrogen, oxygen
Sand silicon, oxygen
Limestone calcium, carbon, oxygen
Common salt sodium, chlorine
Ethanol carbon, hydrogen, oxygen
PROPERTIES OF A COMPOUND
1. It has properties different from those of its component elements.
2. Its formation often requires large amount of heat.
3. It cannot be separated by physical means.
4. The components of a compound have a fixed ratio by mass.
5. Compounds are homogenous.
EVALUATION
1. Define a compound.
2. Give three examples of a compound.
FORMULAE OF COMPOUNDS
When an element exists as a molecule, a number is written as a subscript after the symbol of
that element. For example, hydrogen is written as H2 and oxygen as 02.
A compound contains whole numbers of atoms of the component elements. Its molecular
formula is written as follows.
1. The symbols of all the component elements are written close together as a group.
2. The number of atoms of each component element is written as a subscript after the
symbol of that element.
Examples
Compound Formula
Hydrochloric acid HCl
Water H20
Ammonia NH3
Carbon(IV)oxide C02
Lead II chloride PbCl2
Calcium trioxonitrate(V) Ca(NO3)2
Examples
1. Write the formula of sodium tetraoxosulphate(VI)
Rule 1 Na S04
Rule 2 & 3 1 2
Rule 4 Na2S04
MIXTURES
A mixture contains two or more constituents which can easily be separated by physical methods.
Examples of mixtures with their constituents are outlined below:
Mixture Constituents
Air Oxygen, Carbon (iv)oxide, nitrogen, rare gases,
dust, moisture
Soil Sand, clay, humus, water, air, mineral salts
Urine urea, water, mineral salt
Palm wine water, sugar, alkanol, mineral salts, vitamins,
yeast, protein, fat
Coca-cola water, sugar, cola, CO2
Milk water, sugar, fat, protein, mineral salts, vitamin
Sea water water, mineral salts, bacteria, remains of organic
matter
Brass copper and zinc
EVALUATION
1. List five (5) compounds and their formulae
2. What is a mixture?
3. State four differences between compound and mixture
READING ASSIGNMENT
New School Chemistry for SSS by O.Y Ababio. Pg 11, 36 to 37
GENERAL EVALUATION/REVISION
1. State the valency of the following elements and radicals: Na, K, S, O, SO 42-, NO3-, CO32-
2. Write the formula of: a) Lead (ii) tetraoxosulphate (vi) b) Hydrochloric acid c) Sodium
trioxocarbonate (iv) d) Calcium hydroxide
WEEKEND ASSIGNMENT
1. Which of the following is a mixture? (a) water(b) sugar(c) milk (d) starch
2. Which of the following is a compound? (a) water (b) soil (c) diamond (d) graphite
3. Which of these formulae represents ammonia? (a) NH3 (b) NH4+ (c) NH2 (d) CH4
4. The formula for sand is (a) C02 (b) SO2 (c) NO2 (d) SiO2
5. Compounds are always (a) heterogeneous (b) homogeneous (c) homogeneous or
heterogeneous (d) chemogeneous
Name_____________________________________________ Date_______________
THEORY
1. a. Define (i) Compound (ii) Mixture
b. Give two examples each of compound and Mixtures
2. a. State four differences between compound and mixture
b. What is the formula of
i) tetraoxosulphate (vi) acid
ii) Ammonium sulphide
iii) Sodium tetraoxophosphate
WEEK SIX
TOPIC: STANDARD SEPARATION TECHNIQUES
CONTENT
STANDARD SEPARATION TECHNIQUES
FILTRATION
Filtration is a separation technique that involves separating an insoluble solid from liquid using a
filter. For example, a mixture of chalk particles in water can be separated using filtration
technique. Filtration is used in industries such as water purification plants and breweries.
CENTRIFUGATION
A CENTRIFUGE MACHINE
DECANTATION
Decantation is a separation technique used to separate a mixture containing insoluble solid from
a liquid. This is done when the mixture is allowed to settle down with the upper clear liquid
carefully poured or decanted into a clean container thereby leaving the lower solid in the
container originally containing the mixture. This is a quick but inaccurate method of separating
the components of a mixture.
EVAPORATION
Name_____________________________________________ Date_______________
Evaporation is a separation technique used to recover soluble solute from its solvent. For
example salt can be separated from salt solution by evaporation.
A Salt Evaporation Pond
Salt is produced in the San Francisco area mainly by solar evaporation, where seawater is fed
into large ponds that are gradually evaporated by the sun and the wind. After the water is
evaporated, the salt is collected.
Evaporation is used in salt –making industries.
CRYSTALLIZATION
Crystallization is used to obtain pure crystals of salts which decompose easily on heating from its
solution. The solution is concentrated by heating. It is allowed to cool down and crystals start to
form. To induce crystal formation:
(a) add crystals of the salt (seedling)
(b) scratch the inside of the container with a glass rod
Crystallization is used in industries where purity of the product is important, such as in drug
industries and sugar industries.
FRACTIONAL CRYSTALLIZATION
It is used to separate two or more solutes (solids) which are present in the same solution. The
solutes to be separated must have different solubilities at different temperatures. Starting from a
particular temperature, as cooling of the solution of those solutes takes place, the crystals of the
relevant solutes appear leaving the other solutes in the solution.
EVALUATION
1. Explain briefly the following methods of separation of mixtures: (a) Filtration (b)
Decantation (c) Centrifugation
2. Explain how a pure sample of copper (II) tetraoxosulphate (VI) crystals can be obtained
from its solution in the laboratory.
3. How would you separate a mixture of PbCl2 and NaCl
PRECIPITATION
In precipitation, a difference in the solubility of a solid in two different miscible liquids is used.
For example, FeS04 is soluble in water but not on ethanol. If ethanol is added to a solution of
FeS04 in water, the FeS04 will be precipitated out of the solution and filtered out.
SUBLIMATION
Sublimation is the change of state from solid to gas directly on application of heat. Examples of
substances that sublime are iodine and ammonium chloride. Sublimation can be used to separate
these substances. The pure crystal recovered is the sublimate.
Name_____________________________________________ Date_______________
DISTILLATION
This is used to recover a solvent from a solution. It involves vapourising a liquid and then
condensing the vapour into a liquid called distillate. The solute and other impurities remain in the
distillation flask. It is used in gin and water distilleries to manufacture gin and distilled water.
FRACTIONAL DISTILLATION
This is used to separate a mixture of two or more miscible liquids based on their boiling points.
When two liquids have boiling points that are very close (less than 100 oC the use of simple
distillation becomes difficult. A fractionating column is inserted into the distillation flask. It is
used to separate crude oil into fractions, separation of liquid air into oxygen and nitrogen,
manufacture of spirits and to separate benzene and methyl benzene mixture.
EVALUATION
1. State the major difference between distillation and fractional distillation in terms of (a)
Features of the apparatus (b) Mixtures to be separated
2. Explain the following separation techniques
(a) Precipitation
(b) Sublimation
SEPARATING FUNNEL
This is used to separate immiscible liquids. It depends on the densities of the two liquids. The
less dense will be on top and the denser below. It is used to separate water and kerosene
SIEVING
This is used to separate solid particles of different sizes. Particles smaller than the size of the
sieve (mesh) pass through leaving behind particles of larger sizes. It is used in gold and diamond
mines and in garri industries.
MAGNETIC SEPARATION
Name_____________________________________________ Date_______________
This is used to separate magnetic substances from non-magnetic particles. It is used in mining
and steel industries. It can be used to remove magnetic impurities from tin ores. It can be used
to separate iron filings from sulphur powder.
CHROMATOGRAPHY
This method uses a solvent moving over an adsorbent medium (paper) which is porous to
separate mixtures of solutes.
Types
1. Paper chromatography
2. Thin layer chromatography
3. Gas chromatography
4. Column chromatography
In paper chromatography, a solution, such as ink, is spotted into the paper near one end. The
paper is dipped into an appropriate solvent such as water or ethanol in a closed air-tight jar. The
solvent moves up the paper. The paper is removed and dried. The different spots on the paper
show the different substances the solution (ink or dye) contains.
GENERAL EVALUATION
1. Explain the following separation techniques. Magnetic separation, paper chromatography
and sieving
2. Describe how you would separate a mixture of NaCl, PbCl2 and NH4Cl
3. What method can be applied to separate a mixture of iron filings and sulphur
4. Mention two criteria for purity of a substance.
READING ASSIGNMENT
New School Chemistry for SSS by O.Y Ababio.Pg 16 to 20
WEEKEND ASSIGNMENT
Name_____________________________________________ Date_______________
1. A mixture of oil and water can be separated by (a) sublimation (b) evaporation to
dryness
(c) using a separating funnel (d) fractional distillation
2. Fractional distillation is used to separate (a) an insoluble substance from a soluble
volatile substance (b) liquids with differing boiling points (c) gas, liquid or solid impurities
from a mixture (d) liquid with close boiling points
3. Which of the following separating techniques can be used to separate a mixture of iodine
and sodium chloride? (a) distillation (b) evaporation (c) sublimation (d) decantation
4. Which of the following is not a type of chromatography ?(a) thin layer (b) gas (c) paper
(d) glass
5. Which of the following is a quick but inaccurate way of separating mixture? (a)
decantation (b) evaporation (c) filtration (d) distillation
THEORY
1. Explain briefly the following separation techniques (a) evaporation (b) filtration (c)
fractional distillation
2. Mention two criteria for purity of a substance.
WEEK SEVEN
TOPIC: PARTICULATE NATURE OF MATTER
CONTENT
ATOMS AND MOLECULES
IONS
DALTON’S ATOMIC THEORY
MODIFICATIONS OF DALTONS ATOMIC THEORY
ATOMS AND MOLECULES
Matter is made up of discrete particles. The main ones are atoms, molecules, and ions.
An atom is the smallest part of an element which can take part in a chemical reaction.
A molecule is the smallest particle of a substance that can exist alone and still retains the
chemical properties of that substance. Molecules are made up of atoms.
Atomicity of an element is the number of atoms in one molecule of the element.
We have monatomic, diatomic and triatomic for those elements that contain one atom, two
atoms and three atoms respectively in their molecules.
Examples:
Element Atomicity
Hydrogen Diatomic
Oxygen Diatomic
Nitrogen Diatomic
Neon Monoatomic
Helium Monoatomic
Argon Monoatomic
EVALUATION
1. Define an atom.
2. Give two examples of diatomic molecules.
IONS
An ion is an atom or group of atoms which carries an electric charge. Such groups of atoms that
carry either a positive or negative charge are called RADICALS.
An acid radical is thus a small group of atoms carrying a negative charge that keeps its identity.
Examples include S042-, N03- e.t.c.
Generally ions are grouped as cations and anions. Cations are positively charged ions e.g Ca 2+,
Na+, NH4+ e.t.c.
Anions are negatively charged ions e.g.. C032-, S042-, Cl-, OH-, etc.
Name_____________________________________________ Date_______________
EVALUATION
1. What are ions?
2. State the cation and anion present in (I) H2S04 (ii) NaCl (iii) FeS04
GENERAL EVALUATION/REVISION
1. State the modifications of the Dalton’s atomic theory.
2. A mixture contains propanone, ethanol and water with boiling point of 56 0C, 780C and
1000C respectively.
a) What method will be used to separate the liquids
b) Name the first liquid that will distil over. Explain your answer
c) Name an industrial process that uses fractional distillation
READING ASSIGNMENT
New School Chemistry for SSS by O.Y Ababio. Pg 25-26
WEEKEND ASSIGNMENT
1. Which of the following is not a constituent of the atom (a) proton (b) electron (c)
neutron
(d) isotope
2. Which of the following statement about an atom is not correct? (a) it is indivisible (b) it is
destructible in some cases (c) it is the smallest part of a substance that takes part in a
reaction (d) it is made up of protons, neutrons and electrons
3. Which of the following is a liquid at room temperature? (a) copper (b) gold (c) mercury
(d) silver
4. How can you separate a mixture of iron filings and sulphur powder? (a) distillation
(b) chromatography (c) magnetization (d) evaporation
5. What is the atomicity of neon? (a) monoatomic (b) diatomic (c) triatomic (d) polyatomic
THEORY
1. Give any two postulates of the Dalton’s atomic theory.
2. (a) Differentiate an atom from a molecule.
Name_____________________________________________ Date_______________
(b) How will an atom become an ion?
WEEK EIGHT
IUPAC NOMENCLATURE OF CHEMICAL COMPOUNDS
CONTENT
Naming of:
---- binary compounds
---- radials and compounds having elements with variable oxidation numbers.
---- tertiary and quartenary compounds.
---- compounds with cations replaced with hydrogen.
EVALUATION
Name the following compounds: (a) NaCl (b) CaO (c) H2O2.
Name_____________________________________________ Date_______________
NAMING OF RADICALS AND COMPOUNDS HAVING ELEMENTS WITH VARIABLE
OXIDATION NUMERS
Radicals (group of atoms of element carrying electrical charge) are treated as a single element
when naming their compounds.
Examples of radicals with their names are as follows:
Radical IUPAC NAME
NH4+ Ammonium ion
OH- Hydroxyl ion
But in naming acid radicals, the oxidation number of elements is indicated by Roman numbers in
bracket.
Example:
Formula IUPAC
NO2- Dioxonitratei(iii) ion
NO3- Trioxonitrate(v) ion
CO32- Trioxocarbonate(iv) ion.
Also the compounds having elements with Roman numbers in bracket indicating their oxidation
numbers in that compound
Examples
Formula IUPAC
FeO Iron (ii) oxide
Cu2O Copper (i) oxide
MgCO3 Magnesium trioxocarbonate (iv)
EVALUATION
1. Name the following compounds (a) Fe2O3 (b) CuO
2. What are the oxidation numbers of Fe and Cu in (1) above?
EVALUATION
1. Determine the oxidation number of: a) C in H2CO3 b) Mn in KMnO4 c) Cu in CuSO4
2. Name the compounds in 1 above
Name_____________________________________________ Date_______________
NAMING OF COMPOUNDS WHOSE CATIONS HAS BEEN PARTIALLY REPLACED WITH
HYDROGEN IONS.
In naming compounds whose cations have been partially replaced with hydrogen ion, the cations
is named first followed by hydrogen, then the radicals present indicating the roman number
standing for the oxidation number of the element that is combined with oxygen to form the
radical.
E.g Formula IUPAC
NaHSO4 Sodium hydrogen tetraoxosulphate (vi)
KHSO3 Potassium hydrogen trioxosulphate (iv)
GENERAL EVALUATION/REVISION:
1. Determine the following oxidation number of a) C in LiHCO 3 b) S in KHSO4 and name the
compounds
2. Write the chemical formula of the following compounds a) Oxochlorate (I) acid b) Iron
(ii) tetraoxosulphate (VI) pentahydrate
3. State the uses of the following laboratory apparatuses a) Condenser b) Kipp’s apparatus
c)Tripod stand
READING ASSIGNMENT
Practical Chemistry for Senior Secondary Schools By Godwin O. Ojokuku pg 20-28.
WEEKEND ASSIGNMENT
1. The compound Na2S is called ____ (a) Sodium (ii) sulphate (b) Sodium sulphur (c)
Sodium sulphide (d) Sodium sulphite.
2. The formula of sulphur (iv) oxide is (a) SO4 (b) SO2 (c) S2O4 (d) S4O2
3. Ammonium chloride can be written as (a) NH4Cl (b) NH3Cl2 (c) NH4HCl
(d) NH4OH
4. The IUPAC name of NaHSO4 is (a) Sodium bicarbonate (b) Sodium tetraoxosulphate (vi)
acid (c) Sodium sulphate (c) Sodium hydrogen tetraoxosulphate (vi)
5. Which of the following compounds have cation with variable oxidation state.
(a) FeO3 (b) ZnCO3 (c) CuO (d) KU
THEORY
1. Name the following compounds (a) Fe2O3 (b) KMnO4 (c) KClO3
2. Calculate the oxidation number of (a) Sulphur in H 2SO4 (b) Carbon in CuCO3
WEEK NINE
ATOMIC NUMBER, RELATIVE ATOMIC MASSES, ISOTOPES AND CALCULATIONS
CONTENT
ATOMIC NUMBER AND MASS NUMBER
ISOTOPES
CALCULATIONS OF RELATIVE ATOMIC MASS
Name_____________________________________________ Date_______________
CONSTITUENTS OF AN ATOM
Atoms are made up of sub-particles. Protons, electrons and neutrons. Proton has a positive
charge, electron has a negative charge and neutron has no charge.
EVALUATION
1. State the constituents of an atom.
2. What is the number of proton in the following elements?
(a) 11B (b) 12C
5 6
ISOTOPES
Isotopy is the occurrence of atoms of elements having the same atomic number but different
mass numbers. This is due to the difference in the number of neutrons present in the atoms.
The atoms that exhibit isotopy are called ISOTOPES.
Examples of atoms that exhibit isotopy are chlorine 35Cl and 37 Cl
Carbon- 12 C, 13 C and 14 C
Potassium – 39K19 and 41K19
Oxygen- 16O16 and 18O16
EVALUATION
1. Define isotopy.
2. Write the isotopes of chlorine.
= 41-19 = 22
b. R.A.M = 90 x 39 + 10 x 41
100 100
= 90 x 39 + 41 x 10
100
= 3920 = 39.20
100
EVALUATION
1. How many neutrons are present in the isotope 37Cl17 ?
2. A given quantity of chlorine contains 75% 35Cl17, and 25% 37
Cl17, determine the relative
atomic mass of chlorine.
CALCULATIONS
1. The following are more examples of calculations of relative atomic masses of elements.
2. An element Y exist in two isotopic forms 39Y18 and 40Y18 in the ratio 3:2 respectively. What
is the relative atomic mass of the element?
SOLUTION
R.A.M of Y = 3 x 39 + 2 x 40
5 1 5 1
= 0.6 x 39 + 0.4 x 40
= 23.4 + 16
= 39.4
3. An element with relative atomic mass 16.2 contains two isotopes 16P8 with relative
abundance 90% and mP8 with relative abundance 10%. What is the value of m?
SOLUTION
16.2 = 90 x 16 + 10 x m
100
16.2 = 9 x 16 + m
10 10
16.2 = 144 + m
10 10
16.2 = 144 + m
10
16.2 x 10 = 144 + m
162 = 144 + m
162 – 144 = m
18 = m
The value of m is 18
GENERAL EVALUATION/REVISION
1. Consider the atoms represented below:
q r
X X
p p
a. State the relationship between the two atoms.
b. What is the difference between them?
c. Give two examples of other elements which exhibit the phenomenon illustrated.
2. State the number of electrons, protons and neutrons present in the following atoms/ions
a) Ca b) S2- c) Al3+ d) P
3. If an element R has isotopes 60% 12R6 and 40% xR6 and the relative atomic mass of R is
12.4, find x.
READING ASSIGNMENT
New School Chemistry for SSS by O.Y Ababio. Pg 48-49
Name_____________________________________________ Date_______________
WEEKEND ASSIGNMENT
1. The atomic number of an element is precisely
(a) the number of protons in the atom (b) the number of electrons in the atom (c) the
number of neutrons in the atom
2. An atom can be defined more accurately as (a) the smallest indivisible parts of an
element that can take part in a chemical reaction (b) the smallest part of an element that
can take part in a chemical reaction (c) a combination of protons, neutrons
3. The mass number is (a) proton number + neutron number (b) electron number + proton
number (c) neutron number + electron number
4. Calculate the relative atomic mass of an element having two isotopes 107 Ag and 109Ag in
the ratio 1:1 (a)106 (b)107 (c)108
5. An element X has two isotopes 18.8X and 15.8X in the proportion of 1:9 respectively. Find
the relative atomic mass of X (a)16.1 (b)13.6 (c)16.8
THEORY
1. (a) Define the term isotopy.
(b) Determine the number of electrons, protons and neutrons in each of the
following: 39K19, 63.5Cu29
2. If an element R has isotopes 60% of 12R6 and 40% xR6 and the relative atomic mass is
12.4, find x.
WEEK TEN
TOPIC: STRUCTURE OF THE ATOM
CONTENT
Orbitals of The Atom
Electronic Structure Of the Atom
Filling Of Electrons in to Orbitals
Quantum Numbers
ORBITALS OF THE ATOM
The region in space within which there is maximum possibility of finding an electron in an atom
is called an ATOMIC ORBITAL. We have s, p, d, and f orbitals.
Shapes of s and p orbitals are as follows:
s-orbital
px orbital
py orbital
pz orbital
EVALUATION
1. Define atomic orbital
2. State the shape of (i) S-orbital (ii) P-orbital.
a) that within a given principal quantum number or energy level, there are sub energy levels, i.e.
energy levels otherwise called K,L,M,N,O,P AND Q shells have sub-energy levels otherwise called
s,p,d and f orbitals
(c) In a given orbital there could be a maximum of only two electrons and electron in all orbitals
of the same type within a principal quantum number possess equal energies.
(d) The electrons in the different sub- shells or orbitals within a principal quantum number do
not all have equal energies.
The gradation of energies of orbitals is as follows:
1s< 2s<2p<3s<3p<3d<4s<4p<4d---
EVALUATION
1. State the first five energy levels.
2. Calculate the total no of electrons when n is equal to (i) 2 (ii) 4.
AUFBAU PRINCIPLE states that electrons go in to fill orbitals of lower energy first before filling
orbitals of higher energy and each orbital may hold up to two electrons.
PAULI EXCLUSION PRINCIPLE states that no two electrons have identical sets of the four
quantum numbers {n, l, m and s in an atom}.
HUND’S RULE OF MAXIMUM MULTIPLICITY state that in filling degenerate orbitals with
electrons, electrons go in singly first before pairing up occurs.
EVALUATION
State the following principle
{a} Aufbau Principle {b} Hund’s rule.
QUANTUM NUMBERS
Studies show that the energy of an electron may be characterized by four quantum numbers.
These are
{1}The principal quantum number represented by n with integral values of 1,2,3,4 e.t.c.
{2}The subsidiary or Azimuthal quantum number represented by l with integral values
ranging from O to (n-1).
(3) The magnetic quantum number represented by m with integral values ranging
from –l to +l.
4. The spin quantum number represented by s with integral values – 1/2 and = 1/2.
Element Atomic Number Electronic configuration.
H 1 1S 1
He 2 1S 2
Li 3 1S 2 2S1
Be 4 1S 2 2S2
B 5 1S 2 2S2 2P1
C 6 1S 2 2S2 2P2
N 7 1S 2 2S2 2P3
O 8 1S 2 2S2 2P4
F 9 1S 2 2S2 2P5
Ne 10 1S 2 2S2 2P6
Name_____________________________________________ Date_______________
Na 11 1S 2S 2P 3S
2 2 6 1
GENERAL EVALUATION
1. State the four quantum numbers.
2. Write the electronic configuration of the following a) Mg b) S 2- c) Ca2+ d) Si
READING ASSIGNMENT
New School Chemistry By O.Y. Ababio pg 49-54.
WEEKEND ASSIGNMENT
1. Which of the following orbitals is spherical in shape?
(a) s (b) p (c) d (d) f
2. Which of the following shells have a maximum of eight electrons ?
(a) k (b) l (c) m (d) n
3. 1s2 2s2 2p6 3p1 is the electronic configuration of
(a) potassium (b) calcium (c) sodium (d) aluminum.
4. “No two electrons have identical sets of four quantum numbers”. This statement is
(a) Aufbau principle (b) Pauli exclusion (c) Hund’s rule (d) Rutherford’s model.
5. Which of the quantum number is represented by L?
(a) principal quantum no (b) subsidiary quantum no (c) magnetic quantum
(d) spin quantum.
THEORY
1. State the following principle (a) Pauli exclusion principle. (b) Aufbau principle.
2. Write the electronic configuration of
(a) Oxygen
(b) Calcium (c) Chloride ion (Cl-) (d) Aluminum ion (Al3+)