Scribd Logo
Upload

Welcome to Scribd!

  • 139 views

    DPP - 06 - Substitution Reaction

    Uploaded by

    White Pubg Brothers
    1. The document discusses various organic chemistry reaction mechanisms including SN1, SN2, Wurtz reactions, and others. It provides multiple choice questions to test understanding of reaction rates, product stereochemistry, solvent effects, and determining the correct mechanisms. 2. For the SN1 reaction, the correct rate is S > R > P > Q and perfect racemization is observed. For SN2, the rate is S > Q > P > R. 3. Wurtz reactions are not suitable for preparing RR from RX where R is a tertiary alkyl group due to preferential formation of alkene products from the tertiary carbocation intermediate.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    DPP - 06 - Substitution Reaction

    Uploaded by

    White Pubg Brothers
    139 views4 pages
    1. The document discusses various organic chemistry reaction mechanisms including SN1, SN2, Wurtz reactions, and others. It provides multiple choice questions to test understanding of reaction rates, product stereochemistry, solvent effects, and determining the correct mechanisms. 2. For the SN1 reaction, the correct rate is S > R > P > Q and perfect racemization is observed. For SN2, the rate is S > Q > P > R. 3. Wurtz reactions are not suitable for preparing RR from RX where R is a tertiary alkyl group due to preferential formation of alkene products from the tertiary carbocation intermediate.

    Original Title

    DPP - 06 _ Substitution Reaction

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    1. The document discusses various organic chemistry reaction mechanisms including SN1, SN2, Wurtz reactions, and others. It provides multiple choice questions to test understanding of reaction rates, product stereochemistry, solvent effects, and determining the correct mechanisms. 2. For the SN1 reaction, the correct rate is S > R > P > Q and perfect racemization is observed. For SN2, the rate is S > Q > P > R. 3. Wurtz reactions are not suitable for preparing RR from RX where R is a tertiary alkyl group due to preferential formation of alkene products from the tertiary carbocation intermediate.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    139 views4 pages

    DPP - 06 - Substitution Reaction

    Uploaded by

    White Pubg Brothers
    1. The document discusses various organic chemistry reaction mechanisms including SN1, SN2, Wurtz reactions, and others. It provides multiple choice questions to test understanding of reaction rates, product stereochemistry, solvent effects, and determining the correct mechanisms. 2. For the SN1 reaction, the correct rate is S > R > P > Q and perfect racemization is observed. For SN2, the rate is S > Q > P > R. 3. Wurtz reactions are not suitable for preparing RR from RX where R is a tertiary alkyl group due to preferential formation of alkene products from the tertiary carbocation intermediate.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    You are on page 1of 4

    (Organic Chemistry) REACTION MECHANISM

    DPP-06
    1. Rate of SN1 reaction is:

    (A) 𝑆 > 𝑄 > 𝑅 > 𝑃 (B) S > R > P > Q (C) P > Q > R > S (D) S > R > Q > P
    2. Which one of the following statement is correct about SN1 reaction
    (A) Perfect racemization is observed
    (B) Only Walden inversion is observed
    (C) Total retention of configuration is observed
    (D) Polar protic solvent is preferred
    3. Correct order of SN2 reaction is:

    (A) S > P > Q > R (B) R > Q > P > S (C) Q > R > P > S (D) S > Q > P > R
    4. Which of the following is correct order towards of SN2 reaction
    Cl
    |
    (A) CH3Cl  CH3CH2Cl  CH3CH2CH2Cl  CH3 —CH —CH3

    (B)

    (C)

    (D)

    APNI KAKSHA 1
    (Organic Chemistry) REACTION MECHANISM

    5. Whichof the following is correct order towards of SN1 reaction:

    (A)

    (B)

    (C)

    (D)

    6. Possible products formed during the reaction is/are:

    (A) (B)

    (C) (D)

    APNI KAKSHA 2
    (Organic Chemistry) REACTION MECHANISM

    7. The correct statement for the given reaction is:

    (A) Product is trans-but-2- ene (B) Product is cis-but-2-ene


    (C) Product is erythro-2,3-diidobutane (D) Product is threo-2,3- diidobutane
    8. Statement-1: Wurtz reaction is not a good method to prepare R-R from R-X in which R is a 3
    alkyl group. (X −F)
    Statement-2: 3 carbocation is formed during the reaction which preferably give alkene.
    (A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for
    statement-1.
    (B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
    statement-1.
    (C) Statement-1 is true, statement-2 is false.
    (D) Statement-1 is false, statement-2 is true.

    9. Column I Column II
    (Reaction) (Statements)
    ( ) 2
    Hg OAc ,H O
    (A) ⎯⎯⎯⎯→
    NaBH4 ,OH (P) Electrophilic addition reaction.
    BH3 ,THF
    (B) ⎯⎯⎯⎯
    OH− ,H O
    → (Q) Markovnikoff's orientation is observed.
    2 2

    (C) ⎯⎯
    HBr
    → (R) Anti-markovnikoff's orientation is observed
    (D) ⎯⎯⎯⎯
    HBr/ROOR
    → (S) Cyclic intermediate is formed as intermediate
    (T) Carbocation is formed as intermediate

    10. Column I Column II

    (A) (P) Carbocation formation intermediate

    (B) (Q) Racemic mixture is formed

    (C) CH3 − CH2 − CH2 − Cl ⎯⎯→


    Na
    Et 2O
    (R) Aromatic product is formed

    (D) (S) Free radical found as intermediate

    (T) Carbanion found as intermediate/product

    APNI KAKSHA 3
    (Organic Chemistry) REACTION MECHANISM

    ANSWER KEY
    1. (A) 2. (D) 3. (A) 4. (ABD)
    5. (CD) 6. (B) 7. (A) 8. (A)
    9. (A)-P, S, Q; (B)-P, S, R; (C)-T, P, Q; (D)-R, 10. (A)-P; (B)-P, Q, R; (C)-S, T; (D)-R, T

    APNI KAKSHA 4

    You might also like