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FINAL JEE–MAIN EXAMINATION – JANUARY, 2023

Held On Sunday 29th January, 2023
TIME : 09:00 AM to 12:00 PM

SECTION-A 33. Which of the following salt solutions would

31. For 1 mol of gas, the plot of pV vs p is shown coagulate the colloid soloution formed when FeCl3
below. p is the pressure and V is the volume of the is added to NaOH solution, at the fastest rate?
gas. (1) 10 mL of 0.2 mol dm-3 AlCl3
(2) 10 mL of 0.1 mol dm-3 Na2SO4
(3) 10 mL of 0.1 mol dm-3 Ca3(PO4)2
(4) 10 mL of 0.15 mol dm-3 CaCl2
Official Ans. by NTA (1)
Allen Ans. (1)
What is the value of compressibility factor at Sol. Sol. Formed is negatively charged solution,
point A? therefore Al3+ has highest coagulating power
a b 34. The bond dissociation energy is highest for
(1) 1  (2) 1 
RTV V (1) Cl2
b a (2) I2
(3) 1  (4) 1 
V RTV (3) Br2
Official Ans. by NTA (1) (4) F2
Allen Ans. (1) Official Ans. by NTA (1)
Sol. For 1 mole of real gas Allen Ans. (1)
PV = ZRT Sol. Bond energy of F2 less than Cl2 due to lone pair –
from graph PV for real gas is less than PV for ideal lone pair repulsions.
gas at point A Bond energy order Cl2 > Br2 > F2 > I2
Z<1
35. The reaction representing the Mond process for
a metal refining is ______
Z=1–
Vm RT 
(1) Ni + 4CO  Ni(CO)4
32. The shortest wavelength of hydrogen atom in
Lyman series is . The longest wavelength in 
(2) 2K [Au(CN)2] + Zn  K2 [Zn(CN)4] + 2 Au
Balmer series of He+ is 
(3) Zr + 2I2  Zr I4
5 9
(1) (2) 
9 5 (4) ZnO + C  Zn + CO
36 5 Official Ans. by NTA (1)
(3) (4)
5 9 Allen Ans. (1)
Official Ans. by NTA (2) Sol. Mond‟s process uses:
Allen Ans. (2) Ni + 4CO  [Ni(CO)4]
1 1 1  36. Which of the given compounds can enhance the
Sol. For H:  R H 12  2  2  …(1)
 1   efficiency of hydrogen storage tank?
1 1 1 (1) Li/P4
 R H  22     …. (2)
 He 4 9 (2) SiH4
 He 9 (3) NaNi5
From (1) & (2) 
 5 (4) Di-isobutylaluminium hydride
9
 He   Official Ans. by NTA (3)
5
9
Allen Ans. (3)
 He 
5 Sol. Refer NCERT

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37. The correct order of hydration enthalpies is 40. The standard electrode potential (M3+/M2+) for V,
(A) K+ Cr, Mn & Co are -0.26 V, - 0.41 V, + 1.57 V and
(B) Rb+ +1.97 V, respectively. The metal ions which can
(C) Mg2+ liberate H2 from a dilute acid are
(D) Cs+ (1) V2+ and Mn2+
(E) Ca2+ (2) Cr2+ and CO2+
Choose the correct answer from the options given (3) V2+ and Cr2+
below: (4) Mn2+ and Co2+
(1) C > A > E > B > D Official Ans. by NTA (3)
(2) E > C > A > B > D Allen Ans. (3)
(3) C > E > A > D > B Sol. Metal cation with (–) value of reduction potential
(M+3/M+2)or with (+) value of oxidation potential
(4) C > E > A > B > D
(M+2/M+3) will liberate H2
Official Ans. by NTA (4) Therefore they will reduce H+
Allen Ans. (4)
i.eV+2 and Cr+2
Sol. Hydration enthalpies:
41. Correct statement about smog is
(i) K+ > Rb+ > Cs+ : (A) > (B) > (D)
(1) NO2 is present in classical smog
(ii) Mg+2 > Ca+2 : (C) > (E) (2) Both NO2 and SO2 are present in classical smog
Option (D) (3) Photochemical smog has high concentration of
(C) > (E) > (A) > (B) > (D) oxidizing agents
38. The magnetic behaviour of Li2O, Na2O2 and KO2, (4) Classical smog also has high concentration of
respectively, are oxidizing agents
(1) diamagnetic, paramagnetic and diamagnetic Official Ans. by NTA (3)
(2) paramagnetic, paramagnetic and diamagnetic Allen Ans. (3)
(3) paramagnetic, diamagnetic and paramagnetic Sol. Photochemical smog has high concentration of
(4) diamagnetic, diamagnetic and paramagnetic oxidising agents
Official Ans. by NTA (4) NO2 is produced from NO and O3 in the presence
Allen Ans. (4) of sunlight
Sol. Li2O  O2-  diamagnetic Classical smog contain smoke, fog and SO2 and it
Na2O2 O22- diamagnetic is known as reducing smog, as chemically it is
KO2 O2- paramagnetic reducing mixture
39. “A” obtained by Ostwald‟s method involving air 42. Chiral complex from the following is :
oxidation of NH3, upon further air oxidation Here en = ethylene diamine
produces “B”. “B” on hydration forms an oxoacid (1) cis – [PtCl2 (en)2]2+
of Nitrogen along with evolution of “A”. The (2) trans – [PtCl2(en)2]2+
oxoacid also produces “A” and gives positive (3) cis – [PtCl2(NH3)2]
brown ring test (4) trans – [Co(NH3)4 Cl2]+
(1) NO2, N2O5 Official Ans. by NTA (1)
(2) NO2, N2O4 Allen Ans. (1)
Sol.
(3) NO, NO2
(4) N2O3, NO2
Official Ans. by NTA (3)
Allen Ans. (3)

Sol. 4NH3 + 5O2 
 4NO + 6H2O
(A)
2NO + O2  
 2NO2
(B)

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43. Identify the correct order for the given property for List-I List-II
following compounds Reaction Reagents
(A) Boiling Point: Cl < Cl < Cl (A) Hoffmann (I) Conc.KOH, 
(B) Density: Br < Cl < I Degradation
Br Br
Br (B) Clemenson (II) CHCl3, NaOH/H3O+
(C) Boiling Point: Br < Br < Br
< Cl reduction
(D) Density: I< Br
Br (C) Cannizaro reaction (III) Br2, NaOH
Br
(D) Reimer-Tiemann (IV) Zn-Hg/HCl
(E)
reaction
Choose the correct answer from the option given (1) (A) – III, (B) – IV, (C) – II, (D) - I
below :- (2) (A) – II, (B) – IV, (C) – I, (D) - III
(1) (B), (C) and (D) only (3) (A) – III, (B) – IV, (C) – I, (D) - II
(2) (A), (C) and (E) only (4) (A) – II, (B) – I, (C) – III, (D) - IV
(3) (A), (C) and (D) only Official Ans. by NTA (3)
(4) (A), (B) and (E) only Allen Ans. (3)
Official Ans. by NTA (2) Sol. Reactions Reagent used
Allen Ans. (2) (A) Hoffmann degradation Br2/NaOH
Sol. Boiling point of alkyl halide increases with (B) Clemenson reduction Zn– Hg/HCl

increase in size, mass of halogen atom and size of (C) Cannizaro reaction conc.KOH/

alkyl group  (D) Reimer-Tiemann reaction CHCl3,

Boiling point of isomeric alkyl halide decreases NaOH/H3O+

46. The major product „P‟ for the following sequence
with increase in branching
of reactions is:
Density increases with increase in atomic mass of
halogen atom
44. The increasing order of pKa for the following
phenols is
OH
(1) 2, 4-Dinitrophenol (1) Ph OH
(2) 4 - Nitrophenol OH
(2) Ph NH2
(3) 2, 4, 5- Trimethylphenol
(3) Ph NH2
(4) Phenol
OH OH
(5) 3-Chlorophenol
(4) Ph NH2
Official Ans. by NTA (2)
Official Ans. by NTA (3)
Allen Ans. (2)
Allen Ans. (3)
Sol. Order of acidity for following phenol is
Sol.
OH OH OH OH OH
N O2 Me
> > > >
Me
N O2 N O2 Cl Me

- M and – I increases acidity

+ M and + I decreases acidity
45. Match List I with List II.

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47. During the borax bead test with CuSO4, a blue 50. Compound that will give positive Lassaigne‟s test
green colour of the bead was observed in oxidising for both nitrogen and halogen is
flame due to the formation of (1) N2H4.HCl
(1) Cu3B2 (2) Cu (2) CH3NH2. HCl
(3) Cu(BO2)2 (4) CuO (3) NH4Cl
Official Ans. by NTA (3) (4) NH2OH.HCl
Allen Ans. (3) Official Ans. by NTA (2)
Sol. Blue green colour is due to formation of Cu(BO2)2 Allen Ans. (2)

CuSO4 
 CuO + SO3 Sol. CH3NH2 . HCl 
Na
 NaCN and NaCl
fusion
CuO + B2O3  Cu (BO2)2
NaCN gives +ve test for nitrogen and
48. Match List I with List II
NaCl gives +ve test for halogen
List I List II
Antimicrobials Names
SECTION-B
(A) Narrow Spectrum (I) Furacin
51. Millimoles of calcium hydroxyide required to
Antibiotic produce 100 mL of the aqueous solution of pH 12 is
(B) Antiseptic (II) Sulphur dioxide x × 10–1. The value of x is _______ (Nearest integer).
(C) Disinfectants (III) Penicillin-G Assume complete dissociation.
(D) Broad spectrum (IV) Chloramphenicol Official Ans. by NTA (5)
antibiotic Allen Ans. (5)
(1) (A) – III, (B) – I, (C) – II, (D) - IV Sol. pH = 12
+ -12
 [H ] = 10 M
(2) (A) – I, (B) – II, (C) – IV, (D) - III - -2
 [OH ] = 10 M
(3) (A) – II, (B) – I, (C) – IV, (D) - III -3
 [Ca(OH)2] = 5 × 10 M
(4) (A) – III, (B) – I, (C) – IV, (D) - II milli moles of Ca  OH 2
Official Ans. by NTA (1) 5 × 10–3 =
100mL
Allen Ans. (1) milli moles of Ca(OH)2 = 5 × 10–1
Sol. (A) Narrow spectrum antibiotic – penicillin-G Ans. = 5
(B) Antiseptic – Furacine
(C) Disinfectants – sulphur dioxide 52. The number of molecules or ions from the
(D) Broad spectrum antisiotics – chloramphenicol following, which do not have odd number of
electrons are ________ .
49. Number of cyclic tripeptides formed with 2 amino
acids A and B is: (A) NO2

(1) 2 (2) 3 (B) ICl 4–

(3) 5 (4) 4 (C) BrF3
Official Ans. by NTA (4) (D) ClO2
Allen Ans. (4)
(E) NO 2
Sol. Two amino acid are
(F) NO
H2N - CH - COOH H2N - CH - COOH
,
(A) (B) Official Ans. by NTA (3)
R1 R2
Tripeptide are formed from three amino acids Allen Ans. (3)
A B A B Sol. ICl4-, BrF3 and NO2+ do not have odd number of e-
A A B B A B B A
, , ,

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53. Consider the following reaction approaching 55. Water decomposes at 2300 K
equilibrium at 27ºC and 1 atm pressure
1
K f 103 H 2 O(g)  H 2  g   O 2 (g)
AB CD 2
K r 102
The percent of water decomposing at 2300 K and
The standard Gibb‟s energy change  G 
r
o
at
1 bar is ________ (Nearest integer).
–1
27ºC is (–) _______ kJ mol
Equilibrium constant for the reaction is 2×10–3 at
(Nearest integer).
2300 K
(Given : R = 8.3 J K–1 mol–1 and ln 10=2.3)
Official Ans. by NTA (6) Official Ans. by NTA (2)
Allen Ans. (6) Allen Ans. (2)
Sol. G  RT ln K eq
o
1
Sol. H 2O(g) H 2  g   O 2 (g)
Kf 2
and Keq =
Kb P0
3 P0[1–] P0 partial pr. at eq.
10 2
 K eq  2  10
10
G  RT ln 10  
P0 1    1 ...(i)
 – (8.3 × 300 × 2.3) = – 5.7 kJ mole –1
 6 kJ  2
mole–1(nearest integer)
 P  P 
1/2


H2 O2
Ans = 6 Kp
PH2O
54. Solid Lead nitrate is dissolved in 1 litre of water.
P
1/2
The solution was found to boil at 100.15ºC. When
(P0 )  0 
0.2 mol of NaCl is added to the resulting solution, it  2   2  103
was observed that the solution froze at –0.8º C. The P0 [1  ]
solutbility product of PbCl2 formed is ______ × 10–6
at 298 K. (Nearest integer) since  is negligible w.r.t 1 so P0 = 1 and 1 –   1
Given : Kb = 0.5 K kg mol–1 and Kf = 1.8 kg mol–1.  
Assume molality to be equal to molarity in all cases.  103
2
Official Ans. by NTA (13)
3/2 = 23/2 × 10–3
Allen Ans. (13)
Sol. Let a mole Pb(NO3)2 be added  = 23/2 × 2/3 × 10–3 × 2/3
Pb(NO3)2  Pb2+ + 2NO 3  = 2 × 10–2 %  = 2%
a a 2a 56. Following figure shows dependence of molar
Tb = 0.15 = 0.5 [3a]  a = 0.1 conductance of two electrolytes on concentration.
2 
Pb(aq)  2Cl(aq) PbCl2(s) 0

t=0 0.1 0.2  m is the limiting molar conductivity.

t= (0.1 – x) (0.2 – 2x)
In final solution
 0.3  3x  0.2  0.2 
Tf = 0.8 = 1.8  
 1
2.3
 x
27
2
 2.3  4.6  6 The number of Incorrect statement(s) from the
 Ksp   0.1   0.2    13 10
 27  27  following is ________

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0 59. Following chromatogram was developed by

(A)  m for electrolyte A is obtained by adsorption of compound „A‟ on a 6 cm TLC glass
extrapolation plate. Retardation factor of the compound „A‟ is
(B) For electrolyte B, vx m vs c graph is a ______ × 10–1.
0
straight line with intercept equal to  m
(C) At infinite dilution, the value of degree of
dissociation approach zero for electrolyte B.
0
(D)  m for any electrolyte A or B can be
calculated using  º for individual ions.
Official Ans. by NTA (2) Official Ans. by NTA (6)
Allen Ans. (2) Allen Ans. (6)
Sol. Statement (A) and Statement (C) are incorrect Sol. Rf 
Distance moved by thesubstancefrombaseline
57. For certain chemical reaction X  Y, the rate of Distance moved by thesolvent frombaseline
formation of product is plotted against the time as 3.0 cm
  0.6 or 6 × 10-1
shown in the figure. The number of Correct 5.0 cm
statement/s from the following is _______ 60. 17 mg of a hydrocarbon (M.F. C10H16) takes up
8.40 mL of the H2 gas measured at 0ºC and 760
mm of Hg. Ozonolysis of the same hydrocarbon
yields
CH3 – C – CH 3 –, H–C–H, H–C–CH 2 – CH 2 – C – C – H

O O O O O
The number of double bond/s present in the
(A) Over all order of this reaction is one hydrocarbon is ________ .
(B) Order of this reaction can‟t be determined Official Ans. by NTA (3)
(C) In region-I and III, the reaction is of first and Allen Ans. (3)
zero order respectively
17  10 3
(D) In region-II, the reaction is of first order Sol. Moles of hydrocarbon  = 1.25 × 10-4
136
(E) In region-II, the order of reaction is in the Mole of H2 gas
range of 0.1 to 0.9. 8.40
 1 = n × 0.0821 × 273
Official Ans. by NTA (2) 1000
Allen Ans. (1)  n = 3.75 × 10-4
Sol. Only option (B) is correct as order cannot be Hydrogen molecule used for 1 molecule of
determined hydrocarbon is 3
58. The sum of bridging carbonyls in W(CO)6 and Mn2 3.75  10 –4
(CO)10 is ________ . = 3
1.25  10 –4
Official Ans. by NTA (0)
Allen Ans. (0)
Sol.

(CO)5 Mn  Mn(CO)5 

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