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Safety Data Sheet (SDS)

OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 08/06/2015 Reviewed on 08/06/2015

* 1 Identification

· Product identifier
· Trade name: Sigma MP 101
· CAS Number:
112-07-2
· EC number:
203-933-3
· Index number:
607-038-00-2
· Relevant identified uses of the substance or mixture and uses advised against:
No further relevant information available.
· Product description Retarder
· Details of the supplier of the safety data sheet:
· Manufacturer/Supplier:
Sigma Inks (US)
12113 Kirkham Road
Poway, CA 92064 USA
Phone: (888) 424-9300
Website: www.sigmainks.com or contact distributor: www.printexusa.com
· Emergency telephone number:
Chemtrec (US): (800) 424-9300
Chemtrec (Outside US): (703) 527-3887 (Collect calls accepted)
* 2 Hazard(s) identification

· Classification of the substance or mixture:

GHS07

Acute Tox. 4 H312 Harmful in contact with skin.

Acute Tox. 4 H332 Harmful if inhaled.
Flam. Liq. 4 H227 Combustible liquid.
· Label elements:
· GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms:

GHS07

· Signal word: Warning

· Hazard-determining components of labeling:
2-butoxyethyl acetate
· Hazard statements:
Combustible liquid.
Harmful in contact with skin or if inhaled.
· Precautionary statements:
Keep away from flames and hot surfaces. – No smoking.
Avoid breathing dust/fume/gas/mist/vapors/spray.
(Contd. on page 2)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 08/06/2015 Reviewed on 08/06/2015

Trade name: Sigma MP 101

Use only outdoors or in a well-ventilated area.

Wear protective gloves / eye protection / face protection.
Wear protective gloves / protective clothing.
Specific treatment (see supplementary first aid instructions on this Safety Data Sheet).
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Call a poison center/doctor if you feel unwell.
In case of fire: Use for extinction: CO2, powder or water spray.
If on skin: Wash with plenty of water.
Take off contaminated clothing and wash it before reuse.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
· Unknown acute toxicity:
0 percent of the mixture consists of ingredient(s) of unknown toxicity.
· Classification system:
· NFPA ratings (scale 0 - 4)
Health = 1
2 Fire = 2
1 0 Reactivity = 0
· HMIS-ratings (scale 0 - 4)
HEALTH 1 Health = 1
FIRE 2 Fire = 2
REACTIVITY 0 Reactivity = 0
· Hazard(s) not otherwise classified (HNOC): None known
* 3 Composition/information on ingredients

· Chemical characterization: Substance

· CAS No. Description
112-07-2 2-butoxyethyl acetate
· Identification number(s)
· EC number: 203-933-3
· Index number: 607-038-00-2
* 4 First-aid measures

· Description of first aid measures:

· General information:
Symptoms of poisoning may occur after several hours; therefore medical observation is advised for at least 48
hours after the accident.
· After inhalation:
Supply fresh air. If required, provide artificial respiration. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for at least 15 minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If swallowed and symptoms occur, consult a doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed: No further relevant information available.
· Indication of any immediate medical attention and special treatment needed:
No further relevant information available.
(Contd. on page 3)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 08/06/2015 Reviewed on 08/06/2015

Trade name: Sigma MP 101

* 5 Fire-fighting measures

· Extinguishing media:
· Suitable extinguishing agents:
CO₂, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture:
Combustible liquid. Vapors can travel to a source of ignition and flash back.
Explosive mixtures may occur at temperatures at or above flashpoint.
· Advice for firefighters:
· Protective equipment:
Mouth respiratory protective device.
As in any fire, wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent)
and full protective gear to prevent contact with skin and eyes.
* 6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures:

Wear protective equipment. Keep unprotected persons away.
· Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Ensure adequate ventilation.
Absorb with liquid-binding material (i.e. sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to section 13.
· Reference to other sections:
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
* 7 Handling and storage

· Handling
· Precautions for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about protection against explosions and fires:
Protect from heat.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· Conditions for safe storage, including any incompatibilities:
· Storage
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Protect from heat and direct sunlight.
· Specific end use(s): No further relevant information available.
* 8 Exposure controls/personal protection

· Additional information about design of technical systems: No further data; see section 7.
(Contd. on page 4)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 08/06/2015 Reviewed on 08/06/2015

Trade name: Sigma MP 101

· Control parameters:
· Components with occupational exposure limits:
112-07-2 2-butoxyethyl acetate
REL Long-term value: 33 mg/m³, 5 ppm
TLV Long-term value: 130 mg/m³, 20 ppm
· Additional information: The lists that were valid during the creation of this SDS were used as basis.
· Exposure controls:
· Personal protective equipment:
· General protective and hygienic measures:
Use adequate exhaust ventilation to prevent inhallation of product vapors.
Do not eat or drink while handling product.
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure,
use respiratory protective device that is independent of circulating air.
· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Select glove material based on penetration times, rates of diffusion and degradation.
· Material of gloves:
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
· Penetration time of glove material:
The exact break-through time has to be determined and observed by the manufacturer of the protective
gloves.
· Eye protection:

Tightly sealed goggles

* 9 Physical and chemical properties

· Information on basic physical and chemical properties

· General Information
· Appearance:
Form: Liquid
Color: Clear
· Odor: Not determined
· Odor threshold: Not determined.
· pH-value @ 20 °C (68 °F): 4
(Contd. on page 5)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 08/06/2015 Reviewed on 08/06/2015

Trade name: Sigma MP 101

· Change in condition
Melting point/Melting range: -64 °C (-83 °F)
Boiling point/Boiling range: 184-195 °C (363-383 °F)
· Flash point: 78 °C (172 °F)
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: 280 °C (536 °F)
· Decomposition temperature: Not determined.
· Auto igniting: Not determined.
· Danger of explosion: Not determined.
· Explosion limits:
Lower: 1.7 Vol %
Upper: 8.4 Vol %
· Vapor pressure @ 20 °C (68 °F): 0.4 hPa
· Density @ 20 °C (68 °F): 0.94 g/cm³ (7.844 lbs/gal)
· Relative density: Not determined.
· Vapor density: Not determined.
· Evaporation rate: Not determined.
· Solubility in / Miscibility with:
Water @ 20 °C (68 °F): 15 g/l
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic @ 20 °C (68 °F): 1.8 mPas
Kinematic: Not determined.
Organic solvents: 100.0 %
VOC content: 100.0 %
· Other information: No further relevant information available.
10 Stability and reactivity
· Reactivity: No further relevant information available.
· Chemical stability: Stable under normal conditions.
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions: No dangerous reactions known.
· Conditions to avoid: No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.
* 11 Toxicological information

· Information on toxicological effects:

· Acute toxicity:
· LD/LC50 values that are relevant for classification:
112-07-2 2-butoxyethyl acetate
Oral LD50 2400 mg/kg (rat)
Dermal LD50 1580 mg/kg (rabbit)
(Contd. on page 6)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 08/06/2015 Reviewed on 08/06/2015

Trade name: Sigma MP 101

· Primary irritant effect:

· On the skin: No irritating effect.
· On the eye: No irritating effect.
· Additional toxicological information:
· Carcinogenic categories:
· IARC (International Agency for Research on Cancer):
· NTP (National Toxicology Program):
Substance is not listed.
· OSHA-Ca (Occupational Safety & Health Administration):
Substance is not listed.
* 12 Ecological information

· Toxicity:
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability: No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential: No further relevant information available.
· Mobility in soil: No further relevant information available.
· Additional ecological information:
· General notes: Not known to be hazardous to water.
· Results of PBT and vPvB assessment:
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects: No further relevant information available.
* 13 Disposal considerations

· Waste treatment methods:

· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Observe all federal, state and local environmental regulations when disposing of this material.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
* 14 Transport information

· UN-Number:
· DOT UN1263
· ADR, ADN, IMDG, IATA Non-Regulated Material
· UN proper shipping name:
· DOT Paint
· ADR, ADN, IMDG, IATA Non-Regulated Material
· Transport hazard class(es):
· DOT

· Class: 3 Flammable liquids

(Contd. on page 7)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 08/06/2015 Reviewed on 08/06/2015

Trade name: Sigma MP 101

· Label: 3
· ADR
· Class: Non-Regulated Material
· Label: -
· ADN/R Class: Non-Regulated Material
· Packing group:
· DOT III
· ADR, IMDG, IATA Non-Regulated Material
· Environmental hazards: Not applicable.
· Special precautions for user: Not applicable.
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code: Not applicable.
· Transport/Additional information:
· DOT
· Quantity limitations: On passenger aircraft/rail: 60 L
On cargo aircraft only: 220 L
· UN "Model Regulation": Non-Regulated Material
* 15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture:
· SARA (Superfund Amendments and Reauthorization):
· Section 355 (extremely hazardous substances):
Substance is not listed.
· Section 313 (Specific toxic chemical listings):
Substance is listed.
· TSCA (Toxic Substances Control Act):
Substance is listed.
· California Proposition 65:
· Chemicals known to cause cancer:
Substance is not listed.
· Chemicals known to cause reproductive toxicity for females:
Substance is not listed.
· Chemicals known to cause reproductive toxicity for males:
Substance is not listed.
· Chemicals known to cause developmental toxicity:
Substance is not listed.
· Carcinogenic categories:
· EPA (Environmental Protection Agency):
Substance is not listed.
· TLV (Threshold Limit Value established by ACGIH):
112-07-2 2-butoxyethyl acetate A3
· NIOSH-Ca (National Institute for Occupational Safety and Health):
Substance is not listed.
(Contd. on page 8)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 08/06/2015 Reviewed on 08/06/2015

Trade name: Sigma MP 101

· GHS label elements

The substance is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms:

GHS07

· Signal word: Warning

· Hazard-determining components of labeling:
2-butoxyethyl acetate
· Hazard statements:
Combustible liquid.
Harmful in contact with skin or if inhaled.
· Precautionary statements:
Keep away from flames and hot surfaces. – No smoking.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves / eye protection / face protection.
Wear protective gloves / protective clothing.
Specific treatment (see supplementary first aid instructions on this Safety Data Sheet).
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Call a poison center/doctor if you feel unwell.
In case of fire: Use for extinction: CO2, powder or water spray.
If on skin: Wash with plenty of water.
Take off contaminated clothing and wash it before reuse.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
· National regulations:
Non-Regulated Material
· State Right to Know:
None of the ingredients are listed
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate as
of the date of issue. Nothing herein shall be deemed to create warranty, expressed or implied, and shall not
establish a legally valid contractual relationship. It is the responsibility of the user to determine applicability of
this information and the suitability of the material or product for any particular purpose.
· Date of preparation / last revision: 08/06/2015 / 5
· Abbreviations and acronyms:
ADR: The European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN: The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
(Contd. on page 9)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 08/06/2015 Reviewed on 08/06/2015

Trade name: Sigma MP 101

LC50: Lethal concentration, 50 percent

LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 4: Flammable liquids, Hazard Category 4
Acute Tox. 4: Acute toxicity, Hazard Category 4
· * Data compared to the previous version altered.
SDS created by MSDS Authoring Services www.msdsauthoring.com +1-877-204-9106

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