Baker 1987
Baker 1987
Baker 1987
Early work4 (using a novel test approach) identified Minimum adhesive cure temperature
the epoxy-nitrile structural film adhesive AFI26 Studies 5 were made to assess the minimum temperature
(supplied by 3M) as providing excellent fatigue and at which satisfactory cure of adhesives AFI26 and
stress relaxation resistance and adequate bond FM73M (by Cyanamid) could be achieved: both
durability, with alumina grit blasting as the only adhesives have a recommended cure temperature of
surface treatment. Despite this adhesive's drawback of about 120°C. Adhesive FM73M is a state-of-the-art
requiring an elevated temperature cure (120°C epoxy-nitrile adhesive with improved storage life and
recommended) it was chosen for most of our practical moisture resistance, compared with the older types
applications and has given excellent service. Efforts such as AF126.
have also been made to find suitable adhesives curing
To evaluate cure behaviour, various experimental
at, or close to, ambient temperature. Several epoxy
techniques were employed such as infra-red spectro-
paste adhesives and modified acrylic adhesives have
graphy, differential thermal analysis and scanning
been found suitable, however, these are limited to less
calorimetry. Table 2 lists the minimum effective cure
stringent repair applications than possible with the
times, based on observations of the disappearance of
film adhesives. Recent repair applications 3 were based
the epoxy band in the IR spectra for the adhesive. It is
on the Boeing PANTA (phosphoric acid non-tank
evident from these results that FM73M cures in a
anodizing) surface treatment process which provides
usefully short time at temperatures as low as 80°C. The
excellent bond durability for depot or field repairs.
results of tension tests performed on standard lap shear
specimens (Table 3) show that only a small penalty is
incurred by use of the low cure temperature. Tests 6
Table 2. Times for consumption of epoxide for to measure glass transition temperature (Tg) showed
adhesives A F 1 2 6 and F M 7 3 M "~ o - o •
that, for FM7_ M cured at 76 C, Tg is 103 C while for
the standard 120°C cure, Tg is 98°C. Adhesive AFI26
Temperature (°C) Time for consumption of epoxide behaves more normally where the 76°C cure gives a Tg
of 94°C and the standard 120°C cure gives a Tg of 128°C
AF126
Minimum surface treatments for high bond durability
Recent work 7 has been aimed at evaluating the use of a
80 >12h silane coupling agent to improve bond durability. The
90 5.5 h silane used to promote bonding of epoxy adhesives to
110 70 min aluminium is usually 7-glycidoxypropyltrimethoxy
120 35 min ,silane ('y-GPS). In our study Union Carbide silane
131 23 min A-187 ('y-GPS) was evaluated on clad 2024 T3, using
either alumina grit blasting or the PANTA process 8 as
FM73M the method of surface treatment. The treatment was as
follows:
• abrade to remove scratches:
81 6h • methyl ethyl ketone wipe
• grit blast (50 ttm alumina):
0.8 0.8
0.7 0.7
a b
Fig. 2 Histogram of wedge test data for (a) adhesive AF126, and (b) FM73M, following surface treatment by various techniques; An refers to the PANTA
process. GB to alumina grit-blast and S to the use of 7-GPS silane. The percent figures refer to the approximate degree of cohesive failure (failure within the
adhesive layer) for each treatment
O0~ oop
//I/, II lli,,, J
~,1~1 i ; , 1 1 ] x
/ "x.,'~z !! IJ ( \ \
~\
ii 1~ ii II ~1 \ \\ \ \ \ \ \
/ iI i/ / I ~ \~ \~
a b c
t ~.ff K~
I
A
d
Fig. 5 Schematic illustration of the analytical approach to crack-patching
where ¢ is a factor depending on the shape and elastic rrA = (tA/G A)Eptpfl
properties of the patch. Some relationships for q~ are
noted in the Appendix.
which, as can be seen, is independent of crack size a. A
The second stage of the analysis assumes that the relationship for an upper bound for the stress intensity
situation in the cracked region is as represented by factor, allowing for yield in the adhesive (K " ) can also
Fig. 5c where the reinforcement completely covers its be obtained) with/3 is as given in Equation (9).
surface and the applied force intensity (force per unit
Using the above approach, it is shown that conserva-
width) is F.
tive values for the key design parameters can be
It is shown (in the absence of significant yielding in obtained by considering an overlap joint of geometry
the adhesive) that the stress inten~sity factor has an as depicted in Fig. 6a, which is subjected to a force
upper bound K= (Fig. 5d) where intensity 2F. The overlap joint is a much simpler
LR
j ~
62 tA
,=
t
/ / ~ G~an
1"y
l
Shear strain ")'A
a b
Fig. 6 (a) Schematic illustration of joint specimen indicating notation used for thickness and displacements, and (b) elastic/perfect plastic stress strain
behaviour assumed for the adhesive
YA = 8/2tA (7)
For elastic behaviour of the adhesive v < ry (Fig. 6b)
---I. I I I I
= 2F/(/~ ERtR) (8) ~ - ~ / C l i p gauge
/
S = E R I R / E p I P.
~Yl
- - as shown in Fig. 7b. Where damage was found it r ~/~C~/Patch L*
occurred as cohesive cracking within the adhesive ( E R , t R , O~a )
layer. Despite the doubt (in some cases) of the nature 7.:
of the cracking, the concept of effective crack size in
the adhesive appears to be most useful for design
purposes, using A),~ for acceptable levels of effective ~_j_~_j_ 2 WR
da/dN as the major design parameter. 7_7-~__ZZZ ~ fJ_TjZ-~Z~22
The experimental value for K= is given to a first
approximation by
+ , i
LX'~A(7) to (12)
taken are allowed, a warning of reduced durability is
Yes accordingly given.
In the design approach no attempt is made to design to
a specified stress intensity because of (i) the
KT 11} (3) or (4) insensitivity of K= to patch thickness, (ii) the difficulty
+ Warningof /
limited durability
of allowing for retardation effects (discussed later), (iii)
the uncertainties in the estimate of AK~, and (iv) the
large errors in prediction of crack growth due to
materials variablility and environmental influences.
Repair feasible l~
l---- I
I- Fig. 10 illustrates a simplified patching situation for the
r~ El"
t
/ '
edge-cracked configuration and lists the results
obtained from a computer program based on the flow
chart given in Fig. 9, using the input data listed in
Fig. 9 Flow diagram for patch analysis Table 4 for case 1. Table 4 also gives results for several
other similar cases.
I I ~ Input
parameters I
Example
Yl
o~,R I Inc I a ~ = 138, R = 0 . 1
thickness II ~
I 2024T3
Free edges
Cra&
JJY L * = 80 mm
e R = 5 x 10 _3
tA = 0.19
25 mm
~3 mm
I °utoutI
parameters @
First cycle for rain thickness
patch
Fig. 10 Schematic of patching situation, also showing simplified flow diagram for patch analysis and results for case 1, Table 4
Case
Input 1 2 3 4 5 6 7 8 9 10
~= (MPa) 138 138 138 216 138 138 138 138 138 138
R 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1
Ep (MPa) 72 72 72 72 72 72 72 110 110 110
te (mm) 3.14 3.14 3.14 3.14 7 3.14 3.14 3.14 3.14 3.14
ao(°(C-1 ) x 10-6 2.4 2.4 2.4 2.4 2.4 2.4 2.4 9 9 9
Lp (min) F-E oo 100 100 100 100 100 1O0 oo F-E
L* (mm) 80 80 80 80 80 80 40 80 80 80
a (mm) 25 25 25 25 25 25 25 25 25 25
ER (GPa) 200 200 200 200 200 200 200 200 200 200
TR (mm) 0.13 0.13 0.13 0.13 0.13 0.13 0.13 0.13 0.13 0.13
WR (mm) 80 80 80 80 80 80 40 80 80 80
GR (GPa) 10 10 10 10 10 10 10 10 10 10
e i~ x 10 -3 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0
Q'R (°C-1) X 10 -6 4 4 4 4 4 4 4 4 4 4
GA (GPa) 0.54 0.54 0.54 0.54 0.54 0.54 0.54 0.54 0.54 0.54
tA (mm) 0.19 0.19 0.19 0.19 0.19 0.19 0.19 0.19 0.19 0.19
Ay~ 0.18 0.18 0.18 0.18 0.18 0.18 0.18 0.18 0.18 0.18
ry (MPa) 30 30 30 30 30 30 30 30 30 30
TA (°C) 120 120 120 120 120 20 120 120 120 120
Output 1 2 3 4 5 6 7 8 9 10
n 7 5 5 9 9 5 3 4 4 5
L (mm) 57 48 48 65 76 48 37 44 44 49
A~A 0.16 0.16 0.13 0.17 0.28 0.14 0.22 0.16 0.17 0.16
ea X 10 -3 3 4.2 4.2 4.2 4.2 6.5 4.8 4.7 3.9
~r (MPa) 67 21 -4 -6 No repair 0 No repair -7 1.2 15
AK= (MPa m-y2) 12.5 14 14 18 14 19 19 18
AK" (MPa m-'A) 25 22 18 22 -- 18.7 -- 24 25 27
AKa (MPa m-'~) 38.7 38.7 38.7 60.5 -- 60.5 60.5 60.5 60.5 60.5
¢-
o
-3.8
-4.0- 0 •
/ factors could influence crack growth - - such as
environmental isolation of the crack by the patch) the
following conclusions are reached.
(i) Agreement between AK= and Z~R is sufficiently
-4.2 MPa good for ~ = to be usefully used for preliminary
7.9-79 R=0.1 design estimation.
= 7.9-79 R=0.1 (ii) The value of z~d£" which allows for plasticity in
-4.4 " 4.0-40 R=0.1
._1 0
• 20 - 60 R = 0.3
the adhesive clearly over-estimates Z~R.
• 40 -120 R=0.3 (iii) The influence of a T on Z ~ R is not great, about
-4.6
o 6 0 - 100 R = 0.6 10%, and may not be a major concern in most
patching applications.
-4.8 (iv) Z ~ R varies (to a small extent) with crack size a in
contrast to theoretical prediction; this variation
-5.0 may result from the development of some
0.7 0.8 0.9 1.0 1.1 1.2 1.3 1.4 1.5 delamination damage in the patch.
Log A K a (MPa m 1/2)
Finally, a similar approach to the above was used to
Fig. 13 Plots of log crack growth rate (da/dN) versus log A K a for R provide a preliminary estimate of patching efficiency
values as indicated for a range of candidate repair adhesives. These are (i)
Flexon 241 (from Permabond), a modified acrylic
adhesive suitable for near-ambient temperature repair
(v) Use of an adhesive (FM300 from Cyanamid) applications, (ii) AFI63 (from 3M) and FM73M,
curing at the highest temperature (175°C) leads to a alternatives to AFI26 for intermediate temperature
moderately increased rate of crack growth. This is applications up to about 80°C, and (iii) FM300, for
probably due to the higher level of aT when the application to temperatures up to about 110°C.
patch is applied at 175°C. Thus further reference
to Fig. 12 shows that when the patch is applied The results of the experiments, plotted in Fig. 15
(taking R = 0.1), show that AK R for the above
at 120°C followed by heat treatment at 175°C no
adhesives falls within a fairly narrow band; for
increase in growth rate is evident - - even though
example, at a crack length of 20 m m AK R ranges from
the degree of retardation is similar. The theore-
above 11 M P a m '/2 to under 13 MPa m '/2. Adhesive
tical value of aT following patching with adhesive
AF126 is about 67 MPa (case 1, Table 4) whereas FM300 is the least efficient, as expected from the high
with adhesive FM300 aT is about 102 MPa. level of a T resulting from its high cure temperature.
Acrylic adhesive Flexon 241 shows excellent
performance, considering its ambient temperature cure.
Estimation of stress intensity, K R
In an effort to provide an approximate quantitative
assessment of ZXKR for comparison with zXK=, the A
the two extreme R values 0.1 and 0.6; these results are ,~ 30
plotted in Fig. 14. As shown in the following, these R
AK"
values bracket the effective R value in the patched ~e- 20
specimen RR. / R = 0.1 ]-AKR
N ~AK®~ R = 0.6 J
For the unpatched panel, tested under the same
nominal stress conditions as the patched panel, we N End o f patch
CASE STUDY
APPENDIX
I -~- 2(1 -]- S ) / ~ 1 / v p S - - (l + S)/~ 2
Inclusion factor q5 (see References 11, 22) -}i + / 1 + (l + + 2(1 + S)X-lR
The reduced stress in the prospective location of the
patch is given by P 1
- - S ( I - - 1,'p]~";~) ~ (A2b)
q -vp
~ 0 = q~°'~
In the simplest case where the patch totally covers the where X = G R / E R x , ER~ is the transverse modulus lor
panel the situation is similar to a lap joint, then the patch and R = L R / W R.