GROUP 1

Bautista, Berin, Cabrera, Evangelista, Gomez

BS CHEM 3

Pset No. 3

1. The given reaction is:

2CO (g) + O2 (g) → 2CO2 (g)

According to second law of thermodynamics

∆U = ∆H - ngRT

Change in moles:

∆𝑛 = 2 − 3
∆𝑛 = − 1

Substituting values:

3
∆𝑈 = (− 566𝑥10 𝐽/𝑚𝑜𝑙 ) + (1)(8. 314 𝐽/𝐾𝑚𝑜𝑙)(298𝐾)

∆𝑈 = − 563. 52 𝑘𝐽/𝑚𝑜𝑙

2. Given reaction:

C2H6 (g) + O2 (g) → CO2 (g) +H2O (l)

Balanced equation:
7
C2H6 (g) + 2
O2 (g) →2CO2 (g) + 3H2O (l)
∆𝐻 = 𝐻𝑝𝑟𝑜𝑑𝑢𝑐𝑡𝑠 − 𝐻𝑟𝑒𝑎𝑐𝑡𝑎𝑛𝑡𝑠
𝐾𝐽 𝐾𝐽 𝐾𝐽 7 𝐾𝐽
∆𝐻 = [(2 𝑚𝑜𝑙)(− 393. 5 𝑚𝑜𝑙
) + (3 𝑚𝑜𝑙)(− 285. 8 𝑚𝑜𝑙
)] − [(1 𝑚𝑜𝑙)(− 84. 68 𝑚𝑜𝑙
) + ( 2 𝑚𝑜𝑙)(0 𝑚𝑜𝑙
)]

∆𝐻 = − 1558. 82 𝐾𝐽

3.
a) Calculating for the Initial Volume

P1V1=nRT1
𝑛𝑅𝑇1
V1= 𝑃1
𝐿•𝑎𝑡𝑚
(1 𝑚𝑜𝑙)(0.08206 𝐾•𝑚𝑜𝑙 )(298.15𝐾)
V1= 14.0 𝑎𝑡𝑚
V1= 1.748 L

Calculating for the Final Temperature

P2V2=nRT2
𝑃2𝑉2
T2= 𝑛𝑅
(1.00 𝑎𝑡𝑚)(23.5 𝐿)
T2= 𝐿•𝑎𝑡𝑚
(1 𝑚𝑜𝑙)(0.08206 𝐾•𝑚𝑜𝑙 )

T2= 286.376 K

b)
w = -Pext ∆V
w = -Pext (V2-V1)
w = -(1.00 atm)(23.5L-1.748L)
101.325 𝐽
w = -21.752 L•atm ( 1 𝐿•𝑎𝑡𝑚
)
w = -2204.02 J

∆U = nCvm(T2-T1)
𝐽
∆U = (1 mol) (27.35 𝐾•𝑚𝑜𝑙 )(286.376K-298.15K)
∆U = -322.019 J

q = ∆U - w
q = -322.019 J - (-2204.02J)
q= 1882.001 J
4. If a gas undergoes isothermal reversible equation from V1 to V2. Show the maximum work
done this gas that obeys the equation of the state:
GROUP 1
Bautista, Berin, Cabrera, Evangelista, Gomez
BS CHEM 3

Problem Set No.4

1.)

2.)
3.

T (K) P (atm) 1/T In P

226.18 3874.35 4.42x10-3 8.26

231.64 5707.53 4.32x10-3 8.65

237.56 8477.97 4.21x10-3 9.05

240.01 9907.19 4.17x10-3 9.20

242.40 11523.05 4.13x10-3 9.35

245.98 14353.49 4.07x10-3 9.57

y = -3732x + 24.762
∆𝐻𝑣𝑎𝑝
-3732 = 𝑛𝑅
∆𝐻𝑣𝑎𝑝 = 31029. 71 𝐽
4) ∆𝐻 :
𝑠𝑢𝑏𝑙𝑖𝑚𝑎𝑡𝑖𝑜𝑛

𝑃2 ∆𝐻𝑠𝑢𝑏𝑙𝑖𝑚𝑎𝑡𝑖𝑜𝑛 1 1
𝑙𝑛 𝑃1
= 𝑅
(𝑇 − 𝑇1
)
2
𝑃
𝑅𝑙𝑛( 𝑃2 )
∆𝐻𝑠𝑢𝑏𝑙𝑖𝑚𝑎𝑡𝑖𝑜𝑛 = 1 1
1

(𝑇 −𝑇 )
1 2

∆𝐻𝑠𝑢𝑏𝑙𝑖𝑚𝑎𝑡𝑖𝑜𝑛 =
(8.3145 𝐽
𝐾·𝑚𝑜𝑙 )𝑙𝑛( 100
40
)
1 1
( (1048 ℃+273.15 𝐾) − (1108 ℃+273.15 𝐾)
)
𝐽 1 𝑘𝐽
∆𝐻𝑠𝑢𝑏𝑙𝑖𝑚𝑎𝑡𝑖𝑜𝑛 = 231692. 0637 𝑚𝑜𝑙
× 1000 𝐽
𝑘𝐽
∆𝐻𝑠𝑢𝑏𝑙𝑖𝑚𝑎𝑡𝑖𝑜𝑛 = 231. 6920637 𝑚𝑜𝑙

𝑘𝐽
∆𝐻𝑠𝑢𝑏𝑙𝑖𝑚𝑎𝑡𝑖𝑜𝑛 = 231. 69 𝑚𝑜𝑙

∆𝐻𝑣𝑎𝑝𝑜𝑟𝑖𝑧𝑎𝑡𝑖𝑜𝑛:
𝑃
𝑅𝑙𝑛( 𝑃2 )
∆𝐻𝑣𝑎𝑝𝑜𝑟𝑖𝑧𝑎𝑡𝑖𝑜𝑛 = 1
1
1
(𝑇 −𝑇 )
1 2

∆𝐻𝑣𝑎𝑝𝑜𝑟𝑖𝑧𝑎𝑡𝑖𝑜𝑛 =
(8.3145 𝐽
𝐾·𝑚𝑜𝑙 )𝑙𝑛( 760
400
)
1 1
( (1221 ℃+273.15 𝐾) − (1281 ℃+273.15 𝐾)
)
𝐽 1 𝑘𝐽
∆𝐻𝑣𝑎𝑝𝑜𝑟𝑖𝑧𝑎𝑡𝑖𝑜𝑛 = 206541. 9125 𝑚𝑜𝑙
× 1000 𝐽
𝑘𝐽
∆𝐻𝑣𝑎𝑝𝑜𝑟𝑖𝑧𝑎𝑡𝑖𝑜𝑛 = 206541. 9125 𝑚𝑜𝑙

𝑘𝐽
∆𝐻𝑣𝑎𝑝𝑜𝑟𝑖𝑧𝑎𝑡𝑖𝑜𝑛 = 206. 54 𝑚𝑜𝑙

∆𝐻𝑓𝑢𝑠𝑖𝑜𝑛:
∆𝐻𝑓𝑢𝑠𝑖𝑜𝑛 = ∆𝐻𝑠𝑢𝑏𝑙𝑖𝑚𝑎𝑡𝑖𝑜𝑛 − ∆𝐻𝑣𝑎𝑝𝑜𝑟𝑖𝑧𝑎𝑡𝑖𝑜𝑛
𝑘𝐽 𝑘𝐽
∆𝐻𝑓𝑢𝑠𝑖𝑜𝑛 = 231. 69 𝑚𝑜𝑙
− 206. 54 𝑚𝑜𝑙

𝑘𝐽
∆𝐻𝑓𝑢𝑠𝑖𝑜𝑛 = 25. 15 𝑚𝑜𝑙

Temperature at the triple point:

At the triple point, the solid and liquid have the same vapor pressure:

∆𝐻𝑠𝑢𝑏𝑙𝑖𝑚𝑎𝑡𝑖𝑜𝑛 1 1 𝑃𝑠𝑜𝑙𝑖𝑑 ∆𝐻𝑣𝑎𝑝𝑜𝑟𝑖𝑧𝑎𝑡𝑖𝑜𝑛 1 1 𝑃𝑙𝑖𝑞𝑢𝑖𝑑

𝑅
(𝑇 − 𝑇
) + 𝑙𝑛 𝑃𝑠𝑜𝑙𝑖𝑑, 𝑟𝑒𝑓
= 𝑅
(𝑇 − 𝑇
) + 𝑙𝑛 𝑃𝑙𝑖𝑞𝑢𝑖𝑑, 𝑟𝑒𝑓
𝑠𝑜𝑙𝑖𝑑, 𝑟𝑒𝑓 𝑙𝑖𝑞𝑢𝑖𝑑, 𝑟𝑒𝑓

1 1 ∆𝐻𝑠𝑢𝑏𝑙𝑖𝑚𝑎𝑡𝑖𝑜𝑛 ∆𝐻𝑣𝑎𝑝𝑜𝑟𝑖𝑧𝑎𝑡𝑖𝑜𝑛
𝑇
= ∆𝐻𝑠𝑢𝑏𝑙𝑖𝑚𝑎𝑡𝑖𝑜𝑛 − ∆𝐻𝑣𝑎𝑝𝑜𝑟𝑖𝑧𝑎𝑡𝑖𝑜𝑛
( 𝑇𝑠𝑜𝑙𝑖𝑑, 𝑟𝑒𝑓
− 𝑇𝑙𝑖𝑞𝑢𝑖𝑑, 𝑟𝑒𝑓
) + 𝑅𝑙𝑛 (𝑃𝑠𝑜𝑙𝑖𝑑, 𝑟𝑒𝑓 − 𝑃𝑙𝑖𝑞𝑢𝑖𝑑, 𝑟𝑒𝑓)
 𝐽 𝐽
231690 𝑚𝑜𝑙 206540 𝑚𝑜𝑙
1
𝑇
=
231690
𝐽
𝑚𝑜𝑙
1
− 206540
𝐽
𝑚𝑜𝑙
⎡(
⎢ (1108 ℃+273.15 𝐾) −
⎣
(1221 ℃+273.15 𝐾) (
) + 8. 3145
𝐽
𝐾·𝑚𝑜𝑙 )(𝑙𝑛 100 𝑇𝑜𝑟𝑟
400 𝑇𝑜𝑟𝑟
)⎤⎥
⎦
1 −4 −1
𝑇
= 7. 154165848 × 10 𝐾

𝑇 = 1397. 786997 𝐾

𝑇𝑡𝑟𝑖𝑝𝑙𝑒 𝑝𝑜𝑖𝑛𝑡 = 1398 𝐾

Pressure at the triple point:

∆𝐻
𝑃𝑠𝑜𝑙𝑖𝑑 (𝑇) = 𝑃𝑠𝑜𝑙𝑖𝑑, 𝑟𝑒𝑓𝑒𝑥𝑝⎡⎢ 𝑠𝑢𝑏𝑙𝑖𝑚𝑎𝑡𝑖𝑜𝑛 − 𝑇 )⎤⎥
1 1
𝑅
(𝑇
⎣ 𝑠𝑜𝑙𝑖𝑑, 𝑟𝑒𝑓 ⎦
𝐽
⎡ 231690 𝑚𝑜𝑙 1 1 ⎤
𝑃𝑡𝑟𝑖𝑝𝑙𝑒 𝑝𝑜𝑖𝑛𝑡 = (100 𝑇𝑜𝑟𝑟) 𝑒𝑥𝑝⎢ ( (1108 ℃+273.15 𝐾) − )⎥
⎣( 𝐾·𝑚𝑜𝑙 )
𝐽 (1398 𝐾
8.3145
⎦

𝑃𝑡𝑟𝑖𝑝𝑙𝑒 𝑝𝑜𝑖𝑛𝑡 = 127. 8092503 𝑇𝑜𝑟𝑟

𝑃𝑡𝑟𝑖𝑝𝑙𝑒 𝑝𝑜𝑖𝑛𝑡 = 128 𝑇𝑜𝑟𝑟