Design Considerations

103
Design Considerations
Activated
sludge
process
Sludge
Moving bed
dewatering
biofilm reactor
system
Wastewater
treatment
technologies
Evaporator
Membrane
with
bioreactor
crystallizer
Reverse
osmosis
CHAPTER MENU
4.1 Screening, 104
4.2 Equalization Unit, 105
4.3 Dissolved Air Flotation, 106
4.4 Clariflocculator, 108
4.5 Conventional Activated Sludge, 110
4.6 Moving Bed Biofilm Reactor, 120
4.7 Membrane Bioreactor, 124
4.8 Chlorination Unit, 130
4.9 Pressure Sand Filter, 131
4.10 Activated Carbon Filter, 133
4.11 Ultrafiltration, 135
4.12 Reverse Osmosis, 140
4.13 Evaporator with Crystallizer, 146
4.14 Filter Press, 149
4.15 Belt Press, 152
4.16 Centrifuge, 153
4.17 Gravity Thickener, 155
Wastewater Treatment Technologies: Design Considerations, First Edition. Mritunjay Chaubey.

© 2021 John Wiley & Sons Ltd. Published 2021 by John Wiley & Sons Ltd.
104 Wastewater Treatment Technologies: Design Considerations
This chapter provides brief descriptions of design considerations of various wastewater

treatment technologies.
4.1 Screening
A screening unit is used to trap large and small floating particles in wastewater (WW). Such
units are adopted as standard for wastewater treatment plants (WWTPs). In conjunction
with the screening unit, if needed, an oil and grease (O&G) separator may be installed. The
O&G separator is recommended for preliminary free O&G removal when no dissolved air
flotation (DAF) treatment is installed downstream. The specification reported in this chap-
ter should be considered indicative and not exhaustive since it is intended as typical and a
specific description of the supply should be developed for each single case.
The screening unit performs the following functions:
●● Screening by means of a coarse screen.
●● Removal of free O&G (if needed).
The unit should be provided in one single line but with a sparing philosophy considered
to have, for each of the most critical rotating equipment, a 1 + 1 philosophy, with an
installed spare that can be automatically switched into operation in case of failure of the
main one, in order to ensure the continuity of the operation of the WWTP. Each unit should
include a screening unit complete with a coarse screen and free O&G separator.
4.1.1 Process Parameters

Table 4.1 summarizes the main process parameters for the screening section.
Table 4.1 Main process parameters for screening unit.
Description Value/notes
Liquid depth of screen chamber 1.2 m

Length of channel at upstream of screen Minimum three times width of screen channel
mechanism
Free board 0.5 m
Angle of inclination of screen 45° to horizontal
Flow velocity through screen 1.0 m/s
Inlet and outlet gates or isolation valve Sluice gate or isolation valves to be considered to
control flow velocity
Bar screen openings (for coarse screening) 5 mm
4.1.2 Process Description

The raw WW is sent through a drain to the screening unit, which performs a coarse screen-
ing and free O&G removal if no DAF treatment is installed downstream. The screening
unit includes a first screening treatment performed by means of a fixed coarse mechanical
Design Considerations 105
bar screen (openings 5 mm). If the WW contains a high amount of free O&G (especially if
sticky and viscous), the fine screening section should not be installed as it can easily get
clogged. It is the responsibility of the screens vendor to ensure that the selected screens can
be applied to the raw WWs. The coarse material separated by the screening section is col-
lected in a dry box container that allows dewatering, and is then reused or disposed offsite.
Screens are cleaned automatically at fixed time intervals by mechanical scraper.
In the cases when no DAF unit is provided within the primary treatments, after the
screening phase WW flows by gravity into a chamber provided with baffles, installed in
conjunction with the screening unit, where the free O&G fraction is separated by gravity.
The free O&G stream is then removed with a skimmer and pumped to the oil/sludge stor-
age tank by means of external horizontal centrifugal pumps. The skimmer consists of a
horizontal slotted pipe located before the baffle. The pipe is periodically rotated by a lever
in order to submerge the slots under the water level and allow the floated material to be
carried into the pipe. A pH analyzer should be provided before the O&G removal section
for pH monitoring of the raw WW.
The required volume of the chamber should be calculated on the basis of the assumed
hydraulic retention time (HRT) and on the influent flow to be treated:
O&G separator volume m 3 required Influent flow m 3 /h HRT i.e.15 min / 60 min/h
The WW pretreated by the screening unit is collected in a pit and fed to the following
equalization unit by means of a centrifugal pump (one duty, one spare) provided with a
variable frequency driver (VFD) receiving inputs from a level indicating control (LIC)
located in the pit.
The unit will have integral level controls and instrumentation for the proper automation
through a programmable logic controller (PLC) system.
4.2 Equalization Unit
The equalization unit will have the following functions:

●● Reduction of possible peaks of hydraulics flow in the influent water.
●● Reduction of possible load variations in the influent water.
The unit will be provided in one single line but with a sparing philosophy considered to have,
for each of the most critical rotating equipment, a 1 + 1 philosophy, with an installed spare that
can be automatically switched into operation in case of failure of the main one, in order to
ensure the continuity of the operation of the WWTP. The equalization unit will include:
●● One equalization tank.
●● All the electromechanical and instrumentation and control (I&C) equipment (pumps,
compressor, mixers, piping, valves, instruments, etc.) necessary for proper operation.

Table 4.2 summarizes the main process parameters for the equalization tank.
Table 4.2 Main process parameters for equalization tank.
Description Value/notes
Equalization tank capacity Based on 12–24 h HRT

Construction of equalization tank Two compartments
Free board 0.5–1.0 m
Air mixing flow rate 0.9–1 Nm3 per m3 of tank capacity
Types of diffusers used Coarse or fine bubble
Recirculation pipelines provision From equalization pump discharge circulation line must be
considered
Off-spec tank provision An additional tank must be considered for off-spec effluent
with 12 h HRT

The equalization unit will be installed in order to:
●● Reduce possible peaks of hydraulics flow.
●● Reduce possible peaks in pollutants concentration in the water fed to downstream units.
The WW will come directly from the screening unit, and it will flow to the equalization
tank which will be provided with two submersible mixers (one duty, one stand by) to ensure
complete homogenization of the contents of the tank and to avoid total suspended solids
(TSS) sedimentation. The mixers should be designed to avoid excessive turbulence and to
prevent any volatile organic compounds (VOC) stripping if the WW contains any VOC.
The level of the equalization tank will change in order to compensate for the fluctuation
in incoming flow and to allow the downstream sections to be operated under flow indicator
control (FIC). A level indicating transmitter (LIT) with low and high alarm will be provided
for the equalization unit. The equalization tank will be operated with a variable level in the
range 30–80% of the total water level.
The equalized water will be transferred in normal operation under flow control mode
(FIC set at fixed flow rate acting on VFD of the pump) to the downstream physical/chemi-
cal treatment by means of external centrifugal pumps (one duty, one spare).
4.3 Dissolved Air Flotation
The DAF unit will be the preferred treatment to remove TSS and O&G (and eventually
phosphorus) to be installed downstream of the equalization unit when O&G concentration
in raw WW is higher than 100 mg/l. If surfactants are present in high concentration in the
WW to be treated, DAF treatment should be avoided in order to prevent foam formation
issues and a clariflocculation system should be preferred.
The DAF unit performs the following operations:
●● O&G, fats, and proteins removal (with de-emulsification of emulsified O&G).
●● TSS removal (with efficiency to be determined based on the upstream TSS content).
●● Chemical removal of phosphorus (when needed).
The unit will be provided in one single line but with a sparing philosophy considered to
have, for each of the most critical rotating equipment, a 1 + 1 philosophy, with an installed
spare that can be automatically switched into operation in case of failure of the main one, in
order to ensure the continuity of the operation of the WWTP. The DAF unit should include:
●● pH control system.
●● Coagulation-flocculation tanks.
●● Sedimentation and flotation basin.
●● Air saturation unit.
●● All the electromechanical and I&C equipment (pumps, compressor, mixers, piping,
valves, instruments, etc.) necessary for proper operation.

Table 4.3 summarizes the main process parameters for the DAF unit.
Table 4.3 Main process parameters for DAF units.
Parameter Units Value
HRT in DAF unit min 50

Hydraulic load in DAF unit m/h 3–4
COD total removal efficiency % 30–60
Saturation vessel pressure bar 3.5–5.5
Percentage of influent flow to be recycled % 50
Air to solids ratio (A/S) kg/kg of solids 0.02

The WW coming out from the equalization unit is transferred to the DAF unit which
performs the following operations:
●● De-emulsification of emulsified O&G and removal of free O&G by means of air bubble
flotation.
●● TSS removal for gravity settling.
●● Chemical removal of phosphorus (if needed).
The DAF unit will consist of the following main components:
●● pH adjustment tank with rapid mixer for the dosage of lime solution (Ca(OH)2) or
ydrochloric acid solution (HCll).
h
●● Coagulation tank with rapid mixer for dosage of ferric chloride (FeCl3) (used both as a
coagulant and for phosphorus removal, if phosphorus chemical precipitation is needed).
●● Flocculation tank with slow mixer for flocs formation and dosage of:
–– de-emulsifier to transform emulsified O&G into free O&G;
–– polymer to allow proper flocculation.
●● Air flotation unit with oil/sludge removal systems.
●● Saturation unit (pressure tanks and related compressor) to dissolve air into water.
●● Saturation pumps for the recycled water.
Table 4.4 Chemicals application with pH range.
Chemical Dosage range (mg/l) pH
Lime (Ca(OH)2) 150–500 9–11

Ferric chloride (FeCl3) 35–150 4–7
Cationic polymers 2–5 Not affected
Anionic polymers 0.25–1 Not affected
To allow for the air to dissolve in water, a quote of the effluent is recycled and held under
pressure in a pressure retention tank where air is injected. Air flow is controlled by a pres-
sure control which regulates a valve on the air line. When water leaves the pressure tank
and is mixed with the unpressurized untreated stream that enters the DAF tanks, air is
released from solution in the form of fine bubbles and rises to the top of the tank, capturing
the floating materials.
In the coagulation-flocculation chamber the pH will be adjusted to the optimal operating
value to destabilize the emulsions. The choice between the dosage of Ca(OH)2 and HCl solutions
will be based on the pH of the incoming stream. The operating pH value and the chemical dos-
age should be adjusted on the basis of specific jar tests. A pH set-point control is implemented in
the DAF tanks to provide the inputs to the relative dosing pumps. As an alternative, the coagula-
tion-flocculation chamber can be replaced with a pipe flocculation configuration with an in-line
static mixer installed. A de-emulsifier solution is dosed by means of a dosing pump in order to
improve the emulsion destabilization and the phase separation between oil and water.
If phosphorus removal is needed, it will be achieved by chemical precipitation by dosing
iron salts (FeCl3). Phosphate is incorporated in TSS and removed with the sludge. FeCl3
will be dosed by means of metering pumps controlled with a loop on the incoming flow rate
(the dosage rate will be adjusted on the basis of specific jar tests).
In order to promote the aggregation of larger flocks to be separated in a much more
easy way, a polymer solution will be dosed by means of metering pumps controlled
based on the incoming flow (the dosage rate will be proportional to the incoming flow
and determined with jar-tests). Generally, Table 4.4 can be followed for chemicals
application with pH range.
The collected oil will be pumped to the oil/sludge storage tank by means of external hori-
zontal centrifugal pumps (one duty, one spare). The solids will be scraped into the central
hopper of the tank and pumped by means of screw pumps (one duty, one spare) to the oil/
sludge storage tank. The DAF effluent will flow by gravity to a pit and will be fed to the down-
stream biological unit by means of a set of external centrifugal pumps (one duty, one spare).
The pump will be provided with VFD receiving inputs from a LIC located in the pumping pit.
4.4 Clariflocculator
Clariflocculator reduces suspended solids from effluent with the help of chemicals. The
clariflocculator, installed downstream of the equalization unit, is an alternative treatment
to the DAF process to remove TSS and O&G (and eventually phosphorus) when O&G
concentration in raw WW is lower than 100 mg/l. Moreover, it is considered a reliable
alternative when high surfactant concentrations could create foaming issues for the DAF
due to the presence of micro air bubbles.
The clariflocculator performs the following operations:
●● TSS removal (with efficiency to be determined based on the upstream TSS content).
●● O&G removal (obtained by de-emulsification of emulsified O&G).
●● Chemical removal of phosphorus (when needed).
spare that can be automatically switched into operation in case of failure of the main one,
in order to ensure the continuity of the operation of the WWTP.
The clariflocculator should include:
●● Upstream coagulation.
●● Coagulation chamber.
●● Flocculation-sedimentation chambers.
●● pH control system.

Table 4.5 summarizes the main process parameters for the clariflocculator.
Table 4.5 Main process parameters for clariflocculators.
HRT in coagulation chamber (minimum–maximum) min 5–10

HRT in flocculation chamber (minimum–maximum) min 10–20
HRT in sedimentation chamber min 50
Hydraulic load in sedimentation chamber m/h 1.5

The WW coming from the equalization unit is transferred to the clariflocculator which
performs the following operations:
●● Coagulation (with addition of FeCl3 or Al(SO4)3), flocculation (with polymer dosage),
and gravity settling of TSS.
●● De-emulsification and removal of emulsified O&G by means of dosage of specific
de-emulsifier.
●● Chemical removal of phosphorus (if needed).
Due to possible presence of foam in the WW, a defoaming system can be installed
upstream of the clariflocculator in order to reduce the effect. In this case, an antifoaming
agent is dosed in the same tank where pH adjustment and coagulation take place.
The clariflocculator will consist of the following main components:

●● Coagulation tank with rapid mixer for dosage of:
–– ferric chloride (FeCl3) or alum (used as a coagulant) and for phosphorus removal
(if phosphorus chemical precipitation is needed);
–– antifoaming agent to avoid foaming issues;
–– lime solution (Ca(OH)2) or HCl for pH adjustment.
●● Flocculation-sedimentation chambers, as part of the clariflocculator unit, where floccu-
lation and subsequent gravity separation take place. In the flocculation chamber, polymer
(to allow proper flocculation) and de-emulsifier (to transform emulsified O&G into free
O6G) are added.
In the coagulation-flocculation chamber the pH will be adjusted to the optimal operating
value to destabilize the emulsions. The choice between the dosage of Ca(OH)2 and HCl
solutions will be based on the pH of the incoming stream. The operating pH value and the
chemical dosage should be adjusted on the basis of specific jar tests.
A pH set-point control is implemented to provide the inputs to the relative dosing pumps.
A de-emulsifier solution is dosed by means of a dosing pump in order to improve the
emulsion destabilization and the phase separation between oil and water.
If phosphorus removal is needed, it will be achieved by chemical precipitation by dosing
iron salts (FeCl3). Phosphate is incorporated in TSS and removed with the sludge. FeCl3
will be dosed by means of metering pumps controlled with a loop on the incoming flow rate
(the dosage rate will be adjusted on the basis of specific jar tests).
In order to promote the aggregation of larger flocks to be separated in a much more easy
way, a polymer solution will be dosed by means of metering pumps controlled based on the
incoming flow (the dosage rate will be proportional to the incoming flow and determined
with jar tests).
The collected oil will be pumped to the oil/sludge storage tank by means of an external
horizontal centrifugal pump (one duty, one spare). The solids will be scraped into the cen-
tral hopper of the tank and pumped by means of a screw pump (one duty, one spare) to the
oil/sludge storage tank. The clariflocculator effluent will flow by gravity to a pit and will be
fed to the downstream biological unit by means of an external centrifugal pump (one duty,
one spare). The pump will be provided with a VFD receiving inputs from an LIC located in
the pumping pit. The unit will have integral level controls and instrumentation for the
proper automation through a dedicated PLC system.
4.5 Conventional Activated Sludge
The conventional activated sludge (CAS) unit is one of the selected alternatives for the bio-
logical treatment of WW treatment plants. The CAS unit performs two unitary operations:
●● Biological reaction, performed in the anoxic and oxidation treatment tanks.
●● Solid/liquid separation by settling of biological sludge, achieved in a secondary clarifier.
in order to ensure the continuity of the operation of the WWTP. The unit should include:
●● The aerated biological reactor provided with an initial anoxic selector.
●● The secondary clarifier unit.

Table 4.6 summarizes the main process parameters for the biological reactors based on the
activated sludge process.
Table 4.6 Main process parameters for biological reactors.
TSS concentration in aeration g TSS/l 3–4

DO concentration in aeration mg/l 1.5–2.5
F/M ratio in aeration kg CODtot/kg TSS/day 0.20 (max)
Volumetric load in aeration kg CODtot/m3/day 0.8
VSS/TSS ratio 0.8
Sludge age days >15
Anoxic selector HRT min 20
Anoxic/aerobic tanks water level m 5.0–5.5
Biological sludge production (useful to assess WAS flow rate) kg TSS/day 0.25
Phosphorus for bacteria cells synthesis (in WAS) g Ptot/kg TSS 0.01
Nitrogen for bacteria cells synthesis (in WAS) g N/kg TSS 0.12
Mixed liquor suspended solids (MLSS) ppm 3000–4000
Free board m 0.6–1
4.5.2 Sizing of Activated Sludge Treatment Systems

In an activated sludge treatment system based on effluent characteristics we select any of
following units or combination of all units:
●● Activated sludge unit (ASU).
●● Denitrification nitrification biotreater (DNB).
●● Intermittent nitrification/denitrification biotreater (INDB).
Sizing of ASU, DNB, and INDB are discussed below.
4.5.2.1 Sizing of Activated Sludge Unit

In the ASU, organic pollutants are removed biologically by oxidizing the organic matter
into CO2, H2O, and new biomass (sludge). Dependent on the ammonia and total Kjeldahl
H3PO4 NaOH
Influent flow Effluent
Contact Degasifier
Aeration basin
zone
Air
Sludge recycle flow Sludge bleed
Figure 4.1 Schematic diagram of activated sludge unit.
nitrogen (TKN) demand, oxidation of ammonia to nitrate occurs as well. The ASU consists
of the following main process units (see Figure 4.1):
●● Contact zone: In the contact zone the incoming influent is mixed with recycled sludge.
The selector is equipped with a mechanical mixer. The function of the contact zone is to
favor conditions for the development of good settling sludge by promoting floc-forming
organisms over filamentous organisms. The latter are known to cause a bad settling
bulking sludge.
●● Aeration basin: In the aeration basin organic pollutants (BOD, COD) are biologically
oxidized to CO2, H2O, and new sludge using O2. Oxidation of sulfide (to sulfate) and/or
ammonia (to nitrate), called nitrification, may occur as well. The aeration basin is
continuously aerated and mixed so that O2 is supplied and the content is kept homoge-
nous. Aeration/mixing is done by aeration equipment (usually bubble aeration).
Mechanical mixing is normally not required.
●● Degasifier: In the degasifier air bubbles attached to the sludge are released and the
sludge is allowed to flocculate. A slow paddle mixer supports these processes.
●● Clarifier: The sludge water mixture enters the clarifier where sludge and water are sepa-
rated by sedimentation. The settled sludge is recycled; a small amount is discharged. The
treated water, virtually free from solids, is discharged or further treated.
4.5.2.1.1 No Nitrification
Contact zone: Design criterion is contact time. Recommended range 5–15 minutes.
Volume Qinfl Qrec / CTSEL * 60
where
Qinfl, Qrec = Influent or sludge recycle flow in m3/h
CTSEL = Contact time selector in minutes
Aeration basin: Design criterion is food to microorganism (F/M) ratio. Recommended for
extended aeration.
F/M ratio ≤0.15 kg BOD/kg MLVSS/day
Volume BOD / F / M * MLVSS

where
BOD = BOD load in kg/day
MLVSS = Sludge concentration in kg MLVSS/m3
Degasifier: Design criterion is contact time. Recommended range 10–20 minutes.
Volume Qinfl Qrec / CTDEG * 60
where
CTDEG = contact time in degasifier in minutes
Clarifier: Design criteria are surface load, sludge concentration, and sludge volume
index (SVI).
where
SL = 450 / [SVI * MLSS]
A = Qinfl / SL
D = √ [4 * A / (n * Π)]
SL = Surface load
A = Surface
n = Number of clarifiers
4.5.2.1.2 Nitrification
where
Aeration basin: Design criteria are sludge age and F/M ratio.
Recommended F/M ratio ≤0.15 kg BOD/kg MLVSS/day
Recommended sludge age dependent on temperature.
Sludge age Volume 1 = SP * SRT/ MLSS
F/M ratio Volume 2 = BOD (kg/day) / [F/M * MLVSS (kg/m3)]
Actual design volume = Max (volume 1, 2)
SP = Sludge production in kg/day
SRT = Sludge age, sludge retention time in days
MLSS = Sludge concentration in kg MLSS/m3
where
CTDEG = Contact time in degasifier in minutes
Clarifier: Design criteria are surface load, sludge concentration, and SVI.
SL = 450 / [SVI * MLSS]

A = Qinfl / SL
D = √ [4 * A / (n * Π)]
SL = Surface load
A = Surface
4.5.2.2 Sizing of Denitrification/Nitrification Biotreater

In the DNB organic pollutants (BOD) are removed biologically by oxidizing the organic
matter into CO2, H2O, and new biomass (sludge). In addition, nitrogen is removed by nitri-
fication/denitrification. Nitrification and denitrification is carried out in separate reactors.
The DNB consist of the following main process units (see Figure 4.2):
●● Contact zone: In the contact zone the incoming influent is mixed with recycled sludge
and recycled mixed liquor. The contact zone is equipped with a mechanical mixer. The
function of the selector is as in the ASU.
●● Anoxic basin: In the anoxic basin nitrate is denitrified to N2 (denitrification) and BOD
is oxidized to CO2, H2O, and new sludge. BOD is oxidized with NO3 instead of O2. The
anoxic tank is equipped with mechanical mixers.
●● Aeration basin: In the aeration basin BOD not removed in the anoxic tank is oxidized
to CO2, H2O, and new sludge using O2. In addition ammonia is oxidized to nitrate (nitri-
fication). For mixing/aeration, aerators (usually bubble aeration) are used. Mechanical
mixing is normally not required.
Volume Qinfl Qrec Q MLR / CTSEL * 60
where
QMLR = Mixed liquor recycle in m3/h
Anoxic reactor Aerobic reactor

H3PO4 NaOH
NO3 N2 NH4 NO3
BOD CO2, H2O BOD CO2, H2O
Clarifier Effluent
Influent flow
Contact Degasifier
zone
Air
Mixed liquor recycle (NO3)
Sludge recycle (incl. NO3) Sludge bleed
Figure 4.2 Schematic diagram of denitrification/nitrification biotreater unit.

Anoxic basin: Design criteria are denitrification rate and minimal contact time.
Recommended minimal contact time 20–60 minutes. Denitrification rate is dependent on
temperature.
Denitrification rate Volume1 N DENIT / DN-rate * MLVSS
where
Contact time Volume 2 = [Qinfl + Qrec + QMLR] / [CTANOXIC]
Actual design Vol-anox = Max (volume 1, 2)
NDENIT = Amount of N to be denitrified in kg/day
DN-rate = Denitrification rate in kg N/kg MLVSS/day
MLVSS = Sludge concentration in kg MLVSS/m3
CTANOXIC = Contact time in anoxic basin in hours
Aeration basin: Design criterion is aerobic sludge age or total sludge age. Calculated aer-
ation volume is checked with F/M ratio. If F/M ratio is too high the calculated volume is
increased to be in compliance with F/M ratio.
Recommended F/M ratio ≤0.15 kg BOD/kg MLVSS.d. Recommended sludge ages are
dependent on temperature.
4.5.2.2.1 Aerobic Sludge Age
Vol aer SP * SRTAER / MLSS
Check actual F/M ratio = BOD / [(Vol-anox + Vol-aer) * MLVSS) ≤0.15where

SRTAER = Aerobic sludge age in days
MLSS = Sludge concentration in kg MLSS/m3
BOD = BOD load in kg/day
MLVSS = Sludge concentration in kg MLVSS/day
4.5.2.2.2 Total Sludge Age
Vol aer Vol anox SP * SRTTOT / MLSS Vol aer

SP * SRTTOT / MLSS VOL anox
where:
SRTTOT = Total sludge age in days
Volume Qinfl Qrec Q MLR / CTDEG * 60
where
Clarifier: design criteria are surface load, sludge concentration, and SVI.
SL = 450 / [SVI * MLSS]
A = Qinfl / SL
D = √ [4 * A / (n * Π)]
SL = Surface load
A = Surface
4.5.2.3 Sizing of Intermittent Nitrification/Denitrification Biotreater

In the INDB organic pollutants (BOD) are removed biologically by oxidizing the organic
matter into CO2, H2O, and new biomass (sludge). In addition nitrogen is removed by
nitrification/denitrification. Nitrification and denitrification is carried out in one reactor.
The INDB consists of the following main process units (see Figure 4.3):
●● Contact zone: In the contact zone the incoming influent is mixed with recycled sludge. The
selector is equipped with a mechanical mixer. The function of the contact zone is to favor
conditions for the development of good settling sludge by promoting floc-forming organisms
over filamentous organisms. The latter are known to cause a bad settling b ulking sludge.
●● Aeration/anoxic basin: In this basin BOD is oxidized to CO2, H2O, and new sludge
using O2 and/or NO3. In addition, ammonia is oxidized to nitrate (nitrification) and
denitrified to N2. To allow for nitrification and denitrification in one reactor the system
is alternately aerated and not aerated but mixed. For aeration and mixing the basin is
equipped with an aerator (usually bubble aeration) and mechanical mixers.
Contact zone: design criterion is contact time. Recommended range 5–15 minutes.
where
Aeration/anoxic basin: contrary to DNB system, nitrification/denitrification is carried
out in one reactor. This reactor is alternately operating as an aerobic and anoxic reactor.
H3PO4 NaOH
Aeration – anoxic basin
Anoxic period, e.g. 20 min

Influent flow Effluent
Contact Degasifier
Aerobic period, e.g. 40 min
zone
Air
Sludge recycle flow Sludge bleed
Figure 4.3 Schematic diagram of intermittent nitrification/denitrification biotreater unit.

The effective aerobic volume is then the total volume multiplied by the relative time that
the reactor is aerated.
Design criteria are aerobic sludge age or total sludge. Calculated volume is checked with
F/M ratio. If F/M ratio is too high the calculated volume is increased to be in compliance
with F/M ratio.
Recommended F/M ratio ≤0.15 kg BOD/kg MLVSS.d. Recommended sludge ages are
dependent on temperature.
4.5.2.3.1 Aerobic Sludge Age
Vol aer SP * SRTAER / MLSS

where
SRTAER = Aerobic sludge age in days
MLSS = Sludge concentration in kg/m3
Vol-aer = Required “aerobic volume” in m3
The total reactor volume is the sum of the required aerobic and the anoxic volume. Both
volumes are set by the time (hours/day, minutes/hours) the reactor is aerated (nitrification
time) and not aerated but mixed (denitrification time).
The calculation can be iterative. Define denitrification and nitrification time, calculate
volumes, check if nitrification and denitrification time are sufficient, and correct if needed.
Check nitrification/denitrification:
NiTIME NNIT / MLVSS * VOL tot * NiRATE
DeNTIME NDENIT / MLVSS * VOL tot * DeNRATE
where
NNIT = N to nitrify in kg N/day
NiRATE = Nitrification rate in kg N/kg MLVSS.d
NDENIT = N to denitrify in kg N/day
DeNRATE = Denitrification rate in kg N/kg MLVSS.d
MLVSS = Sludge concentration in kg/m3
Nitrification and denitrification rates are temperature dependent. Check F/M ratio.
F/Mratio BOD / Vol tot * MLVSS 0.15
4.5.2.3.2 Total Sludge Age

Vol tot SP * SRTTOT / MLSS
Vol anox Vol tot * DeNTIME / 24
Vol aer Vol tot Vol anox

where
SRTTOT = Total sludge age in days
Degasifier: design criterion is contact time. Recommended range 10–20 minutes.
where
Clarifier: design criteria are surface load, sludge concentration, and SVI.
SL 450 / SVI * MLSS
where
A = Qinfl/SL
D = √ [4 * A/(n * Π)]
SL = Surface load
A = Surface
4.5.2.4 Sizing of Sludge Recycling in ASU, DNB, and INDB
Qrec Qinfl * MLSS / MLSS recycle MLSS
where
MLSS = Sludge concentration in aeration tank in kg/m3
MLSS-recycle = Sludge concentration sludge recycle = Min (1200/SVI,10) in kg/m3
Qrec = Quantity of recycle flows in m3/h
Qinfl = Quantity of influent flows in m3/h
4.5.2.5 Sizing of Aeration Requirement in ASU, DNB, and INDB

Aeration is needed to supply O2 for the biological process.
ASU Actual Oxygen demand AOD oxygen BOD removal sludge respirration
oxygen nitrification
where
BOD removal = BOD load × BOD factor (BOD factor = 0.6–0.8)
Sludge respiration = Aeration volume × MLVSS × factor (factor = 0.1–0.15)
Nitrification = N to nitrify × 4.57
DNB AOD oxygen BOD removal sludge respiration oxygen nitrificaation
oxygen denitrification
where
Denitrification = N to denitrify × (−2.86)

INDB AOD oxygen BOD removal sludge respiration oxygen nitrificcation
oxygen denitrification
where
Denitrification = N to denitrify × (−2.86)

In CAS treatments, COD/BOD removal is accomplished by biomass which grows in a floc-
culent state suspended in the liquid phase in the bioreactor. The WW inlet is sent to the
biological tank in the initial anoxic selector. The anoxic selector is a first step in the hydrol-
ysis of organic matter, equipped with submerged mixers. The mixed liquor flows by gravity
from the anoxic selector into the oxidation section through submerged openings.
In the following oxidation tank, in order to supply oxygen for biological activity, air is pro-
vided with a set of air lobe blowers (one duty, one standby) and by means of fine bubble
air diffusers installed at the bottom of the tanks that maximize the oxygen transfer into
the mixed liquor.
The amount of air to be provided will be based on a set-point control set on the dissolved
oxygen (DO) meters in the oxidation tank (DO level at 1.5–2.5 mg/l). The DO meter con-
trols the VFD installed on the air blowers. To size the blowers for each specific WWTP, at
first the peak oxygen requirement for biological reaction should be estimated.
The daily peak oxygen requirement for biological reaction should be calculated as follows:
AOR BIO a BOD5REM b MLVSS

where
AORBIO = Oxygen requirement for biological process in kgO2/day
a′ = Coefficient of oxygen demand for synthesis (assumed as 0.5)
BOD5REM = kg BOD5/day removed in the oxidation tank; if the added COD is easily
biodegradable, it can be conservatively assumed that COD = BOD5
b’ = Coefficient of endogenous demand (assumed as 0.24 for peak conditions
at 30 °C)
MLVSS = Total mixed liquor volatile suspended solids under aeration (kgVSS).
The amount of air to be provided by the blowers in standard conditions can be cal-
culated from the peak oxygen requirement with the following equation:
Q AIR c AOR BIO Vr AER
where
c′ = Coefficient for conversion to standard conditions at 20 °C and 1 atm
(assumed as 1.6)
Vr = Ratio oxygen : air (assumed as 0.3 kgO2/Nm3AIR)
ƞAER = Efficiency of the aeration system (assumed as 30%).
The recycle activated sludge (RAS) ratio from secondary clarifier should be 100% so the
concentration in the biological reactor is around half of the concentration of the RAS flow
(ratio between the flow rate of the recycled sludge and the flow rate of the incoming WW
to bioreactor). The mixed liquor TSS concentration in the biological tank should be main-
tained around at 4 gTSS/l.
In order to guarantee conditions suitable for biomass growth and biodegradation, chemi-
cals will be dosed in the biological reactor if necessary (to be assessed on the basis of site-
specific data). Nitrogen and phosphorus will be dosed in the anoxic selector as nutrients for
biomass growth (supplied with commercial urea and phosphoric acid solutions).
The pH in the aeration tank will be controlled through NaOH or HCl (or H2SO4) solution
dosage with a pH control loop based on set-point value at neutral pH in the range 7–7.5.
The pH meter (located in the final part of the aeration tank, close to the outfall to the clari-
fier) is acting on an on–off valve on NaOH and HCl (or H2SO4) loop (if installed at the
facility) or on the VFD of the NaOH and HCl (or H2SO4) metering pump.
4.5.3.1 Secondary Clarifier

The mixed liquor will flow by gravity to the secondary clarifier. Depending on the clarifier
configuration, the mixed liquor enters the clarifier and follows a radial flow or a plug-flow
pattern. Solid/liquid separation takes place by settling of biological sludge from the liquid
stream. Settled sludge is conveyed throughout a bottom scraper mechanism, to a part of the
tank connected to the suction side of the sludge pumps.
Part of the solids collected in the secondary clarifier is pumped back to the anoxic selector
(RAS solids) by means of a set of centrifugal pumps (one duty, one standby) operated at a fixed
flow rate adjustable by operators, so as to keep the desired suspended solids concentration in
the aerobic reactor. The excess sludge (WAS solids) is pumped to the sludge/oil storage tank by
means of a set of screw pumps (one duty, one standby) operated at a fixed flow rate adjustable
by operators. As an alternative, it is possible to operate with only one pump set for RAS and
WAS streams. In this case, WAS pumps are replaced with a flow control valve and a flow
recorder/totalizer. The feasibility of this configuration should be investigated based on specific
hydraulic conditions. Table 4.7 summarizes the main parameters for secondary clarifiers.
Table 4.7 Characteristics of a typical secondary clarifier.
Hydraulic load m/h 0.5

TSS outlet concentration mg/l 15
Water level (min) m 3
4.6 Moving Bed Biofilm Reactor
MBBR is a combination of suspended growth and attached growth process. It uses the
whole tank volume for biomass growth, with simple floating media, which are carriers for
attached growth of biofilms. Biofilm carrier movement is caused by the agitation of air
Pre-anoxic Aeration Aeration

zone zone zone
Screened
Effluent
influent
Nitrate recycle
Waste
Figure 4.4 MBBR technology process flow diagram.
bubbles. This compact treatment system is effective in removal of organic matter as well as
nitrogen and phosphorus, while facilitating effective solids separation. An MBBR technol-
ogy process flow diagram is shown in Figure 4.4.
4.6.1 Working Principles of MBBR Technology

In the MBBR reactor COD/BOD degradation is performed by attached biomass that grows
on the surface of plastic carrier elements. Routine sloughing of biomass from the plastic
media caused by the mixing process is not returned to the reactor in MBBR systems but it
is all wasted at the same rate at which it leaves the reactor. The WW inlet is sent to the
biological tanks in the initial anoxic selector.
The anoxic selector is a first step in the hydrolysis of organic matter, equipped with
submerged mixers. The WW flows by gravity from the anoxic selector into the oxidation
section through submerged openings. In the following oxidation tank in order to supply
oxygen for biological activity, air will be provided with a set of air lobe blowers (one duty,
one standby) and by means of coarse bubble air diffusers installed at the bottom of the
tanks that maximize the oxygen transfer into the mixed liquor.
The amount of air to be provided will be based on a set-point control set on the DO
meters in the oxidation tank (DO level at 2.5–3.5 mg/l). The DO meter controls the VFD
installed on the air blowers. To size the blowers for each specific WWTP, at first the peak
oxygen requirement for biological reaction should be estimated. The daily peak oxygen
requirement for biological reaction should be calculated as follows:
AOR BIO a BOD REM b MLVSS
where
BODREM = kg BOD/day removed in the oxidation tank
b′ = Coefficient of endogenous demand (assumed as 0.24 for peak conditions
at 30 °C)
MLVSS = Total mixed liquor volatile suspended solids under aeration in kgVSS.
The amount of air to be provided by the blowers in standard conditions can be calculated
from the peak oxygen requirement with the following equation:
where
(assumed as 1.6)
The pH meter, located in the final part of the aeration zone, is acting on an on–off valve on
NaOH and HCl (or H2SO4) loop (if installed at the facility) or on the VFD of the NaOH and
HCl (or H2SO4) metering pump.

MBBR carrier media fill, specific area of carrier media material, dissolved oxygen (DO) con-
centration in MBBR tank, volumetric load in MBBR tank, MBBR tank water level, phospho-
rus for bacteria cells synthesis (in WAS), nitrogen for bacteria cells synthesis (in WAS), and
temperature are the main process parameters for MBBR technology. Table 4.8 summarizes.
Table 4.8 Main process parameters for MBBR technology.
MBBR carrier media fill % 30–50

2 3
Specific area of MBBR carrier media material m /m 600–800
DO concentration in MBBR tank mg/l 2.5–3.5
3
Volumetric load in MBBR tank kg CODtot/m /day 0.8
MBBR tank water level m 5–6
Temperature inside MBBR tank °C 20–25
Free board m 0.6–1
4.6.2.1 Carrier Media

MBBR carrier media (see Figure 4.5) play very a important role in the success of MBBR
technology. Critical to the success of any biofilm process is to maintain a high proportion
Figure 4.5 MBBR carrier media – high-density polyethylene.
of active biomass in the reactor. When the biomass concentration on MBBR carriers is
presented in terms of an equivalent suspended solids concentration, values typically are
approx. 1000–5000 mg/l suspended solids. Yet, when performance is assessed on a volumet-
ric basis, results show that removal rates can be much higher than those compared with
suspended-growth systems. This added volumetric efficiency with MBBRs can be attrib-
uted to the following:
●● High overall biomass activity resulting from effective control of biofilm thickness on the
carrier resulting from the shear imparted on the carriers by the mixing energy.
●● Ability to retain highly specialized biomass specific to the conditions within each reactor.
●● Acceptable diffusion rates resulting from the turbulent conditions in the reactor.
The net effective biofilm area is a key design parameter with moving-bed reactors, and loading
and reaction rates can be expressed as a function of the surface area offered by the carriers.
Hence, carrier surface area is convenient and commonly used for expressing performance and
loadings of MBBRs often presented as surface area removal rate (SARR) and surface area load-
ing rate (SARL), respectively. The substrate removal rate in MBBRs is zero-order-dependent
when bulk substrate concentrations are high and first-order-dependent when bulk substrate
concentration is low. Under controlled conditions, removal rate (SARR) as a function of load-
ing (SARL) can be expressed by the following surface reaction rate expression:
r rmax * L / K L
where
r = Removal rate in g/m2/day
rmax = Maximum removal rate in g/m2/day
L = Loading rate in g/m2/day
K = Half-saturation constant.
4.6.3 Pre-denitrification MBBRs

Pre-denitrification is required where nitrogen removal is required. The influent to the
MBBR should have a favorable ratio of easily biodegradable COD and ammonia (C : N) to
make efficient use of the anoxic reactor volume. The dissolved oxygen returned in the recycle
flow can have a significant influence on performance with MBBR systems, because elevated
bulk dissolved oxygen levels can be required for the nitrification stage of the MBBR process. This
can place a practical upper limit on the most effective recirculation ratio (Qrcy : Qinf ), whereby a
further increase in the recirculation rate ends up reducing the overall denitrification efficiency.
Where influent WW characteristics are suitable for pre-denitrification, nitrogen removal perfor-
mance typically can range between 50 and 70%, with a Qrcy : Qinf ratio of 1 : 1 to 3 : 1.
4.7 Membrane Bioreactor
An MBR unit is one of the selected alternatives for the biological treatment of WW in treat-
ment plants. The MBR unit performs two unitary operations:
●● Biological reaction, performed in the anoxic and oxidation treatment tanks.
●● Solid/liquid separation achieved through UF membranes submerged in an external aer-
ated reactor that will perform a further oxidation process or through side-stream vertical
membranes with air-lift system.
in order to ensure the continuity of the operation of the WWTP. The unit should include:
●● The aerated bioreactor provided with an initial anaerobic selector.
●● The MBR membranes tank.
●● The MBR back pulse tank.
●● The chemical storage and dosing systems for membranes cleaning.
●● All the electromechanical and I&C equipment (pumps, compressor, piping, valves,
mixers, instruments, etc.) necessary for proper operation.

Table 4.9 summarizes the main process parameters for biological reactors.
Table 4.9 Main process parameters for biological reactors.
TSS concentration in aeration (for submerged membranes) g TSS/l 7

TSS concentration in aeration (for external side-stream g TSS/l 10
membranes, air-lift system)
DO concentration in aeration mg/l 1.5–2.5
F/M ratio in aeration kg CODtot/kg 0.20
MLSS/day (max)
Volumetric load in aeration kg CODtot/m3/day 1.4
VSS/TSS ratio 0.8
Sludge age d >15
Table 4.9 (Continued)
Anoxic selector HRT min ≥20

Anoxic/aerobic tanks water level m 5.0–5.5
Biological sludge production (useful to assess WAS flow rate) kg TSS/kg 0.25
CODoxidized
Membrane design-specific flux (for submerged membranes) l/m2/h 15
2
Membrane design-specific flux (for external side-stream l/m /h 40
membranes, air-lift system)

4.7.2.1 Biological Reactor
For MBR treatments, COD/BOD removal is accomplished by biomass which grows in a
flocculent state suspended in the liquid phase in the bioreactor. The WW inlet is sent to the
biological tanks in the initial anoxic selector. The anoxic selector is a first step in the hydrol-
ysis of organic matter, equipped with submerged mixers. The mixed liquor flows by gravity
from the anoxic selector into the oxidation section through submerged openings.
In the following oxidation tank, in order to supply oxygen for biological activity, air will
be provided with a set of air lobe blowers (one duty, one standby) and by means of fine bub-
ble air diffusers installed at the bottom of the tanks that maximize the oxygen transfer into
the mixed liquor.
The amount of air to be provided will be based on a set-point control set on the DO
meters in the oxidation tank (DO level at 1.5–2.5 mg/l). The DO meter controls the VFD
installed on the air blowers. To size the blowers for each specific WWTP, at first the peak
oxygen requirement for biological reaction should be estimated. The daily peak oxygen
requirement for biological reaction should be calculated as follows:
AOR BIO a BOD5REM b MLVSS
where
BOD5REM = kg BOD5/day removed in the oxidation tank; if the added COD is easily
biodegradable, it can been conservatively assumed that COD = BOD5
b′ = Coefficient of endogenous demand (assumed as 0.24 for peak conditions at 30 °C)
MLVSS = total mixed liquor volatile suspended solids under aeration (kgVSS).
The amount of air to be provided by the blowers in standard conditions can be calculated
from the peak oxygen requirement with the following equation:

where
(assumed as 1.6)
The mixed liquor recycle ratio from the membrane tank (if submerged membranes are
considered) should be 100% so the concentration in the biological reactor is around half
of the concentration of the sludge in the membrane tank (ratio between the flow rate of the
recycled sludge and the flow rate of the incoming WW to bioreactor). The mixed liquor TSS
concentration in the membrane tank should not exceed 11.5 g TSS/l.
The pH meter is acting on an on–off valve on NaOH and HCl (or H2SO4) loop (if installed
at the facility) or on the VFD of the NaOH and HCl (or H2SO4) metering pump.
The mixed liquor is then sent to the following solid/liquid separation unit, which may be
performed by means of two alternative systems:
●● Submerged UF membranes in a separate aeration tank; or
●● Side-stream vertical membranes with air-lift system.
The unit will have integral level controls and instrumentation for the proper automation
through a dedicated PLC system.
4.7.2.2 Submerged Ultrafiltration Membrane Bioreactors

The mixed liquor will be pumped to the UF membrane bioreactor tanks by means of a set
of centrifugal pumps (one duty, one standby) with the suction side connected to the lower
part of the bioreactor so as to segregate eventual free oil in the bioreactor tank and avoid the
fouling of membranes. Each pump will have a dedicated VFD that will receive the signal
from the level meter installed in the oxidation tank, with level control set-point.
The flow will be fed to the membranes by means of a common feed channel provided
with a number of equal length weirs equal to the number of tanks (two or three tanks
should be provided depending on the unit capacity): each tank will contain one membrane
filtering cassette. The type and size of one membrane filtering cassette refers to a typical
product commonly available and highly reliable in the international market. The mem-
brane filtering cassette of hollow fiber type will be immersed in the respective tank and
performs an outside-to-inside filtration.
Permeate will be extracted by means of the vacuum generated by the external centrifugal
suction pumps (one duty per each line and one common standby) and delivered to the fol-
lowing treatment unit. Each permeate pump will be provided with a VFD receiving inputs
from a level meter on the membrane tanks and from a flow meter on the delivery side of
the membrane feed pumps in order to maintain the flow within a specified range.
Characteristics of a typical reference UF membrane bioreactor tank are shown in Table 4.10.
Table 4.10 Characteristics of a typical reference ultrafiltration membrane bioreactor tank.
Membrane tank Length m 2.8

Width m 2.4
Total height m 4.5
Volume of each tank (min) m3 20
Water depth m 3–3.5
Membrane cassette Filtration surface m2 1500
2
Design-specific flux with all installed trains working l/m /h 15
Maximum specific flux with one train in maintenance l/m2/h 25
The number of typical standard cassettes should be calculated on the basis of the follow-
ing parameters:
●● The influent flow to be treated (which is variable for each specific plant).
●● The filtration surface per each cassette, assumed equal to 1500 m2/cassette.
●● The number of modules contained in each cassette, equal to 48 modules/cassette.
●● The design-specific flux admissible by the membranes, which should be set equal to
15 l/m2/h in normal conditions, and should generally not exceed 25 l/m2/h with one cas-
sette out of operation due to the cleaning process.
Therefore the calculation should be performed as follows:
●● Overall surface (m2) required = Influent flow (m3/h) / Specific flux (15 l/m2/h) x 1000 (in
normal operation).
●● Number of cassettes required (n cassettes) = Overall surface (m2) / 1500 (m2/
cassette) + 1.
The presence of the gates at each tank inlet allows the exclusion of one or more of the
tanks when required by the cleaning process or by maintenance purposes; therefore a spare
cassette has been included in the above calculation. The cleaning process should be ena-
bled by a closed gate switch. Table 4.11 shows the operational parameters with two cas-
settes and one cassette.
Each MBR tank is provided with an overflow weir to allow the recycle by gravity of the
concentrated mixed liquor back to the biological reactor. The WAS is extracted from the
membrane tanks and sent by WAS extraction pumps (one duty, one standby) to the sludge
treatment section. Extraction is controlled by means of a flow meter in order to extract
daily the correct amount of excess sludge.
The membrane tanks will be aerated to prevent solids settling and to help dislodge
solids that may remain attached to the surface of the membranes; also the aeration per-
forms a further oxidation process. Aeration will be accomplished by a dedicated lobe
blower (one duty, one standby), included in the unit, which will feed alternatively the
membrane tanks.
Table 4.11 Operational parameters with two cassettes and one cassette (1500 m2 filtering
surface) installed for different flow rates.
Theoretical Operative specific Operative specific flux

membrane surface flux during normal during maintenance
required operation (1 cassette in operation,
Flow rate to membranes @ 15 l/m2/h (2 cassettes) should be <25)
m3/day m3/h m2 l/m2/h l/m2/h
240 10 666.7 3.3 6.7

360 15 1000.0 5.0 10.0
480 20 1333.3 6.7 13.3
600 25 1666.7 8.3 16.6
720 30 2000.0 10.0 20.0
840 35 2333.3 11.7 23.3
960 40 2666.7 13.3 26.7
4.7.2.2.1 Membrane Cleaning

Membranes need to be cleaned on a regular basis. The membrane cleaning procedure will
be completely automatic and controlled by the PLC and consist of the following:
●● Membrane backwashing with permeate.
●● Periodic maintenance chemical cleaning.
●● Recovery cleaning.
The cleaning procedure will be fully automated and different in the details depending on
the selected contractor. The system will allow in general:
●● Membrane backwash using permeate: This is achieved by operation of automatic
open/close valves and back-pulse pump (one duty, one standby).
●● Periodic maintenance cleaning: During normal operation, periodic chemical mainte-
nance cleaning will be required. The anticipated frequency is one chemical cleaning
cycle per week per tank. The membrane cleaning is accomplished by using sodium
hypochlorite solution (200 mg/l) followed by citric acid solution (2000 mg/l). These
chemicals are injected on the discharge side of the back-pulse pump during the back-
wash phase. During the cleaning operation, the respective membrane tank will be offline.
This procedure will have duration of approx. 1 hour and 20 minutes.
●● Recovery cleaning: During recovery cleaning, the membrane tank will be taken out of
service, drained, and then filled with permeate and sodium hypochlorite solution to achieve
about 1000 mg/l sodium hypochlorite concentration. The tank will be drained again and
filled with permeate and citric acid to obtain about 2000 mg/l citric acid solution. The mem-
brane tank will be drained, filled with WW, and then put back online. The recovery cleaning
is not anticipated more than two times per year per membrane system.
The chemicals to be used for membrane cleaning are as follows:
●● Sodium hypochlorite is used as a disinfectant and oxidant in order to eliminate the
microorganisms from the surface of membranes and to eliminate the organic compounds
which could foul the membranes.
●● Citric acid is used to remove the metallic hydroxides that may have formed on the mem-
brane surface during the sodium hypochlorite wash.
The scope of supply for the vendor should include:
●● permeate backwash pumping system (one duty, one standby).
●● pumping system for sodium hypochlorite (one duty, one standby) and for citric acid (one
duty, one standby);
and may include:
●● chemical storage system for both sodium hypochlorite and citric acid.
Detailed procedures for recovery cleaning of the membranes, chemicals, concentrations,
and dosages will be specified by the selected membrane vendor. In general, the cleaning
sequence controlled by the PLC includes:
●● Stop of the permeation in the membrane tank by stopping permeate pumps.
●● Backwash using permeate only.
●● Transfer of the mixed liquor to the biological tanks by means of the overflow
channel.
●● Backwash with the permeate and cleaning solution for cleaning.
●● Placing the membrane tank in service again.
The unit will have integral level controls and instrumentation for proper automation
through a dedicated PLC system.
4.7.2.3 External Side-Stream Ultrafiltration Membranes with Air-Lift System

The mixed liquor will be pumped to the membranes by means of a set of centrifugal pumps
(one duty, one standby), with the suction side connected to the lower part of the bioreactor
so as to segregate eventual free oil in the bioreactor tank and avoid fouling of membranes.
Each pump will have a dedicated VFD that will receive the signal from the level meter
installed in the oxidation tank, with level control set-point.
With external, air-lift system configuration, the membranes are placed vertically out-
side the bioreactor and are not submerged in a specific tank. The membranes are con-
tinuously aerated at the bottom of the modules by means of a dedicated blower (one
duty, one standby), included in the unit. The aeration will create turbulence that will
provide high flux rates and very low transmembrane pressures. Air mixes with the
influent mixed liquor and raises the flow through the inner side of the tubular mem-
branes. Therefore air injection is the driving force for sludge recirculation to the biore-
actor, so that the feed pump will be used only to overcome hydraulic losses and will be
a low pressure type. This will result in lower energy consumption than for submerged
MBR systems.
External side-stream membranes are provided in compact modules equipped with tubu-
lar type membranes, where filtration is performed with inside-to-outside configuration.
Table 4.12 shows typical reference external side-stream UF membranes.
The WAS is extracted from the recirculation loop and sent by WAS extraction pumps (one
duty, one standby) to the sludge treatment section. Extraction is controlled by means of a
flow meter in order to extract daily the correct amount of excess sludge.
Table 4.12 Ultrafiltration membranes specification.
Number of modules per unit installed 6

Membrane area for each module m2 55
2
Total membrane area m 330
Module diameter mm 0.8
Generally, the advantages of the external air-lift system over submerged configura-
tion are:
●● Lower energy consumption;
●● Ease in maintenance and cleaning procedures;
●● Prevention of fouling on the membrane surface due to air injection.
4.7.2.3.1 Membrane Cleaning

Membranes need to be cleaned on a regular basis. The membrane cleaning procedure will
be completely automatic and controlled by the PLC and will consist of a combination of
forward flushing and periodic backflushing. In general, the cleaning sequence controlled
by the PLC includes:
●● Stop of the permeation.
●● Backwash using permeate only.
●● Transfer of the mixed liquor to the biological tanks.
●● Backwash with the permeate and cleaning solution for cleaning.
●● Placing the membrane tank in service again.
A permeate storage tank is needed in order to store permeate for backwash operations,
performed by means of a backwash pump (one duty, one standby). Periodic chemical main-
tenance cleaning is required. Therefore chemicals (sodium hypochlorite and hydrochloric
acid) are injected on the discharge side of the back-pulse pump during the backwash phase.
The unit will have integral instrumentation for proper automation through a dedicated
PLC system.
4.8 Chlorination Unit
A chlorination unit is adopted as a standard unit in WWTPs. The chlorination basin is

aimed at removing residual biological activity in order to prevent biofouling in downstream
additional tertiary treatments and for the oxidation of residual organics and inorganics by
means of sodium hypochlorite dosage.
in order to ensure the continuity of the operation of the WWTP.
The chlorination basin will include:

●● One chlorination tank.
●● All the electromechanical and I&C equipment (metering pumps, mixers, piping, valves,
instruments, etc.) necessary for proper operation.

Table 4.13 summarizes the main process parameters for the chlorination tank.
Table 4.13 Main process parameter for chlorination basin.
Parameter Unit Value
HRT in chlorination basin min 30

Disinfection by means of sodium hypochlorite is installed in order to:
●● remove residual biological activity in order to prevent biofouling in downstream addi-
tional tertiary treatments; and
●● oxidize residual organic and inorganic compounds.
The process water coming from the biological treatment (or from the granular activated
carbon [GAC] unit, if included upstream) will be fed to the chlorination basin where it gets
mixed with sodium hypochlorite solution dosed by a metering pump (one duty, one
standby). In order to maximize the contact, the basin is provided with one vertical mixer
(one duty, one in stock) to ensure complete homogenization.
Sodium hypochlorite dosage will be adjusted to achieve a residual free chlorine concen-
tration that does not affect the downstream treatments, as UF membranes (concentrations
to be verified with UF vendors). A chlorine meter based on a set-point control value should
be installed in order to monitor residual free chlorine concentration in treated water.
Liquid sodium hypochlorite will be stored at the site in corrosion-resistant vessels, pro-
tected from direct sunlight and excessive heat. The amount of chemical stored must be
carefully evaluated depending on its usage, because NaOCl progressively loses its strength.
Design of NaOCl storing facility will also account for generation and diffusion of chlo-
rine fumes.
4.9 Pressure Sand Filter
Pressure sand filter (PSF) polishing treatment is a selected tertiary treatment of WW treat-
ment facilities. The PSF unit performs further removal of residual TSS from WW by filtra-
tion on sand beds. The PSF should be applied downstream of the biological treatment unit
only if the chosen technology for biological treatment is a CAS or MBBR system. No PSF
treatment is needed if the chosen biological option is an MBR system.
A sparing philosophy will be adopted considered to have, for each of the most critical
rotating equipment, a 1 + 1 philosophy, with an installed spare that can be automatically
switched into operation in case of failure of the main one, in order to ensure the continuity
of the operation of the WWTP.
The filtration on the sand media will be performed into a number of fixed-bed columns,
organized to achieve an in-series contact process; the number of filters will depend on the
plant size and should in any case include two sand filters in parallel (as minimum) in order
to guarantee at least one operating filter during maintenance activities of the other one.
The PSF unit should include:
●● PSF filters.
●● The backwash system.
●● The treated water pumping station.
●● All the electromechanical and I&C equipment (pumps, piping, valves, instruments, etc.)
necessary for proper operation.

Table 4.14 summarizes the main process parameters for PSF filters.
Table 4.14 Main process parameters for PSF unit.
Minimum filtering bed depth m 1.2

Minimum height of cylindrical section m 1.5
Maximum operative pressure drop bar 0.8
Hydraulic load m/h 9–12

WW from the upstream treatment will be fed in FIC (centrifugal pump equipped with
VFD) to the PSF filters. The PSF filter stage will allow further reduction of the residual TSS
load present in the biological effluent.
Water to be treated will be applied to the top of the vertical bed cylindrical filter and with-
drawn at the bottom. The sand bed will be held in place with an underlying drain system at the
bottom of the column. The feed system should allow homogeneous feeding of the filtering bed
through the sand media and water percolation through the bed should avoid the formation of
preferred filtering paths and consequent “dead zones” within the filtration bed.
Filtered water from the PSF unit will then be stored in a dedicated tank and pumped by
means of centrifugal pumps (one duty, one standby) to the following UF unit. PSF filtrate
tank sizing should take into account the UF filtrate production pauses due to the
backwashing and chemical cleaning cycles.
Decay of the filtration capacity of the sand bed due to its progressive saturation will be
monitored by a differential pressure controller (if excess suspended matter is accumulated,
the head loss through the filter increases until a maximum predetermined limit [1 bar] that
will activate filter backwashing). However, automatic backwashing is normally activated

once per day on a time-based logic (typically 15 minutes of backwashing).
As on option, a further control can be performed by an in-line TSS analyzer installed on
the filtered water line. The sand bed will have to be backwashed when the TSS value and/
or the pressure drop increases to the set high limit for the effluent quality.
Backwashing will allow the expansion of the sand layer so that the solids captured during
normal operation can be released and separated from the sand. Backwashing water will be
sent back to the equalization tank of the WWTP. The water used for the backwashing will
be taken from the UF filtered water storage tank.
The sand filters configuration will be constituted by a minimum of two filters in parallel
which will be set up and provided with automatic valves in order to allow automatic
switch of the operating units order within the filtration cycle: in case one PSF filter is out
of operation or in backwashing, a valve will divert the total flow to the other one to ensure
continuous water filtration. This is the optional case. Normally one PSF will be in opera-
tion. The unit will have integral instrumentation for the proper automation through a
dedicated PLC system.
4.10 Activated Carbon Filter
Activated carbon filter (ACF) polishing treatment is an optional tertiary treatment in WW

treatment facilities. The ACF unit performs WW polishing through adsorption of soluble
residual organic BOD/COD on ACF media. The ACF adsorption process should be
performed as optional treatment upstream RO for water reuse (to avoid RO membrane
fouling) only if BOD concentration downstream of the biological treatment exceeds 30 ppm.
To avoid clogging of the ACF due to TSS/turbidity, the ACF needs to be installed on the
downstream side:
●● If the chosen biological option is an MBR system, the ACF unit is installed directly down-
stream of the MBR, polishing the MBR permeate.
●● If the chosen biological option is an MBBR or a CAS system, the ACF unit will be installed
downstream of the PSF and UF units.

The ACF unit will be provided with a sparing philosophy considered to have, for each of
the most critical rotating equipment, a 1 + 1 philosophy, with an installed spare that can be
automatically switched into operation in case of failure of the main one, in order to ensure
the continuity of the operation of the WWTP. Sparing one will be optional. Normally one
ACF filter will be in operation.
Adsorption on activated carbon media is the heart of the process; contacting between
WW and the ACF will be performed in a number of fixed-bed columns, organized to
achieve an in-series contact process; the number of contact columns will depend on the
plant size and should in any case include two carbon filters (as minimum), with the possi-
bility to have each of them interchangeable as a first/second one in order to:
●● Allow the complete saturation of the first contact column (and substitution of not com-
pletely saturated ACF), having the second one in series as a guard.
●● Guarantee at least one operating filter during maintenance/carbon replacement activities
of the other one.
The ACF unit should include:

●● The ACF contact columns.
●● The treated water pumping station.
●● All the electromechanical and I&C equipment (pumps, piping, valves, instruments, etc.)

Table 4.15 summarizes the main process parameters for the ACF.
Table 4.15 Main process parameters for GAC filters.
Carbon adsorption rate kg COD/kg GAC 0.25

HRT min 15
Maximum operative pressure drop bar 0.8
Hydraulic load m/h 9–10

The WW inlet will be fed directly under pressure from the upstream treatment unit to the
ACF filters. The ACF filter stage will allow the operator to further reduce the residual part
of the organic matter present in the upstream treatment effluent. Water to be treated will
be applied to the top of the column and withdrawn at the bottom. The carbon will be held
in place with an underlying drain system at the bottom of the column.
The decay of the adsorption capacity of the carbon due to its progressive saturation will
be monitored by an in-line TOC analyzer installed on the filtered water line. The carbon
bed will have to be replaced when the TOC value increases to the set high limit for the
effluent quality.
The ACF filter train will be set up and provided with automatic valves in order to allow
automatic variation of the operating units order within the filtration cycle; this will
allow the operator to organize as terminal element the filter that has been subjected to the
most recent carbon charge renew. In case one ACF filter is out of operation, a valve will
divert the total flow to the other one. ACF filtered water will be stored in a dedicated tank
and sent to further downstream units.
Backwashing operations should be performed in order to limit the head loss buildup due
to the removal of particulate suspended solids within the carbon column. The backwash
phase will be manually initiated through head loss measurement. Filter backwashing may
also be performed on a fixed time basis (typically once per day for 10 minutes). Backwash
can be performed with either:
●● filtrate water from a UF filtrate storage tank, if a UF unit is installed upstream; or
●● net water, if no UF unit is installed upstream.
The organic matter content and the temperature of the influent will determine the
carbon saturation limit and consequently the actual carbon consumption. The carbon
will be periodically regenerated and replaced to ensure effective BOD removal. The
unit will have integral instrumentation for proper automation through a dedicated
PLC system.
4.11 Ultrafiltration
A UF unit is one of the tertiary treatments selected in WWTP. UF treatment has to be
installed downstream of the PSF when upstream biological treatment is performed
with CAS or MBBR. No UF treatment is needed when MBR is adopted as biological
treatment.
The UF unit performs pressure-driven separation of particulate and microbial contami-
nants from the pretreated WW stream. The unit will be provided in one single line but with
a sparing philosophy considered to have, for each of the most critical rotating equipment,
a 1 + 1 philosophy, with an installed spare that can be automatically switched into operation
in case of failure of the main one, in order to ensure the continuity of the operation of the
WWTP. The UF unit should include:
●● The UF membrane separation system.
●● UF permeate water storage tank.
●● Backwash pumping unit.
●● Cleaning in place (CIP) unit.
●● Blower unit for backwashing.
●● Chemical storage and dosing systems for membranes cleaning (chemically enhanced
backwash [CEB] or CIP).
●● All the electromechanical and I&C equipment (pumps, compressor, mixers, instruments,
etc.) necessary for proper operation.

Table 4.16 summarizes the main process parameters for the UF unit.
Table 4.16 Main process parameters for UF unit.
Molecular weight cut-off μm 0.03

Membrane design-specific flux l/m2/h 60
Module diameter m 0.225
Module length m 1.5
Module volume liters 35
UF membrane area m2 33

Process WW from PSF is passed through UF.
●● A suitable number of micro-strainers, 100 μm filtration grade, remove coarser materials
in order to protect the UF membranes installed downstream.
●● UF membranes installed in one train will remove particles greater than 0.03 μm, which
should be sufficient to remove grazing microorganisms and potential biological contami-
nation, if needed.
The UF system requires backwash, cleaning, and flushing cycles automatically managed
by a dedicated control panel. During these cycles, WW will be produced and it will be sent
back to the equalization tank. Since PSF filtered water fills in continuous mode the storage
tank, it should be sized to account for the UF train service interruptions due to backwash-
ing and CEB and CIP cycles (see sections below).
UF permeate is sent to a storage tank in which three pump sets are installed: one delivers
the stream to the downstream treatment, the second one is dedicated to the backwash of
the UF membranes, and the third one pumps the permeate water to the PSF unit for filter
washing operations and to GAC filters (if installed downstream) for washing operations.
Since the GAC and PSF units require different water flow rates depending on GAC and PSF
filter volume, the latter pump set should be equipped with VFD controlled by an FIC or,
alternatively, a flow control valve can be installed for flow regulation. Moreover, the UF
permeate storage tank should be sized to account for the above-cited permeate uses and for
permeate production interruptions due to backwashing, CEB, and CIP cycles.
4.11.2.1 Configuration and Operation

The following sections describe a typical UF configuration and operation mode, and
include an overview of backwashing and cleaning cycles.
4.11.2.1.1 Membrane Configuration

The modules consist of hollow fiber, polyvinylidene fluoride (PVDF) polymer membranes
which are installed in a pressurized vertical “shell-and-tube” design that eliminates the
need for separate pressure vessels. The membrane operative configuration is outside-in,
dead-end flow. Outside-in flow configuration is tolerant of wide ranging feed water quali-
ties and allows air scour cleaning. Dead-end flow offers higher recovery and energy savings.
There are four connections on each UF module. The flow enters the module through the
side port located on the bottom end cap. The air feed is located on the bottom of the end cap
and is used for air scouring on the outside of the fiber during cleaning. The concentrate
(discharges flow from outside of fiber) and permeate ports (inside of fiber) are located on
the top cap.
4.11.2.1.2 Membrane Normal Operation

Normal operation of the UF system refers to the routine operating sequence of a system
and includes the operating and backwash steps. At initial start-up, the modules are flushed
using “forward flush” to remove any residual chemicals or trapped air from the module.
The flush occurs on the outside of the fibers and does not filter the feed water. After the
Table 4.17 UF membranes typical operating conditions.
Maximum operating feed pressure bar 2.5

Maximum operating TMP bar 1.5
2
Backwash flux l/m /h 100–300
Permissible temperature range °C 1–40
“forward flush,” the modules can be placed in the operating mode. An operating cycle
ranges from 20 to 60 minutes. While operating, 100% of the feed water is converted to per-
meate. As contaminants are removed during the operating phase, the transmembrane pres-
sure (TMP) will rise. At the end of the preset operating cycle time, a backwash sequence is
triggered in order to remove particulate fouling from the membranes. Moreover, a control
system on TMP set at a specific set-point value activates the backwash procedure if the
TMP exceeds the fixed limit value that can reduce system efficiency before the preset cycle
time. UF membranes typical operating conditions are shown in Table 4.17.
4.11.2.1.3 Backwash
During backwash mode, a small quantity of the produced permeate is pumped back through
the membranes with a backwash pump (one duty, one standby). In this process the fouling
layer at the surface of the membrane caused by particulate matter is disrupted and the pores
are cleaned. The frequency and the duration of the backwash are adjustable for the system.
The backwash mode may include an air scour, and always includes draining, backwash
through the top drain, backwash through the bottom drain, and a forward flush.
Water backwash is operated in 24 cycles/day, 1 minute/cycle. The main steps of back-
washing are as follows:
●● The air scour step, when included, is used to loosen particulates deposited on the outside
of the membrane surface. Air is introduced on the outside of the fibers and displaced
feed flow/concentrate is allowed to discharge through the top of the module for disposal.
After 20–30 seconds of air scour the module is drained by gravity to remove dislodged
particulates.
●● If the air flush is not included, the backwash sequence is started by simply draining
the module by gravity to remove the concentrated feed water before starting any
backwashing.
●● After draining, the first backwash step is performed. Permeate flow is reversed from the
inside of the fiber to the outside and backwash flow is removed from the module housing
through the top drain on the module. A top draining backwash is performed first to
remove contaminants in the area of greatest concentration.
●● The second backwash step is performed to remove contaminants through the bottom of
the module housing. Permeate flow is reversed from the inside of the fiber to the outside
and backwash flow is removed from the module housing through the bottom drain on
the module for efficient removal of heavier materials. The two steps of backwash can be
repeated numerous times depending on the degree of fouling.
●● After backwash is complete, a forward flush is performed to remove any remaining con-
taminants and remove any air trapped on the outside of the fibers. After backwash, the
modules are returned to the operating mode.
More detailed procedures for operating conditions of the membranes will be specified by
the selected vendor.
4.11.2.1.4 Membrane Shutdown

The backwash mode of the membranes should be operated also each time one module is shut
down, in order to prevent the membrane irreversibly losing flux because of dry-out. Indeed,
UF systems are designed to run continuously and membrane systems perform better when
operated continuously. When the UF train is shut down, the system must be cleaned using
air-scour and backwashed with permeate water to prevent bacterial growth in the UF system.
The water used for backwash before shutdown should not contain chemicals. Any feed
water and backwash chemical dosing used should be stopped before the last cleaning and
shutdown. After cleaning, all valves on the UF system should be closed to seal the system.
In general, if the modules are shut down for more than 48 hours, preservatives like
sodium bisulfite should be added to the backwash flow. Table 4.18 summarizes the recom-
mended steps for membrane maintenance for different shutdown durations. Detailed pro-
cedures for shutdown of the membranes will be specified by the selected vendor.
Table 4.18 UF skids shutdown summary.
Storage duration Recommended steps
0–48 hours Air scour and backwash, close all valves

>2 days to 7 days Air scour and backwash, close all valves, perform 30–60 minutes of operations
daily or air scour, backwash, add preservative, then close all valves
>7 days to Add preservative and renew preservative every three months
90 days
>90 days Consult manufacturer
4.11.2.1.5 Chemically Enhanced Backwash

CEB operations are quick-maintenance cleaning procedures used to remove biological,
organic, and inorganic fouling from the membranes. CEB has the aim to extend the operat-
ing times between major cleanings (CIP) and is performed with a frequency dependent on
the feed water quality. On high-quality feed waters a CEB may not be required since simple
backwash is enough to clean the membranes. The CEB process occurs automatically, but
the frequency can be adjusted after gaining operating experience. CEB is performed using
UF permeate, and an acid or base combined with an oxidant is added to more effectively
clean contaminants from the membrane surface.
The following are common CEB chemicals (to be confirmed by the vendor):
●● An oxidant – sodium hypochlorite (NaOCl) for removal of biological fouling.
●● An oxidant and base – sodium hypochlorite (NaOCl) and sodium hydroxide (NaOH) for
removal of organic fouling.
●● An acid – hydrochloric acid (HCl) or citric acid for removal of inorganic fouling.
CEB follows the steps of a normal backwash with the following differences:
●● A chemical is dosed into the backwash water.
●● A soak step is added after the second backwash step. The soak is performed for 5–20 min-
utes in order to allow time for the chemical to react with contaminants that have attached
to the membrane surface or penetrated the fiber wall. Intermittent air scour can be
applied during the soak step.
After the soak a routine backwash is performed to remove any remaining particulates
and residual chemicals. Detailed procedures for CEB cleaning of the membranes, chemi-
cals, concentrations, and dosages will be specified by the selected membrane vendor.
4.11.2.1.6 Cleaning in Place

A CIP operation is a complete cleaning process which includes backwash and chemi-
cal recycling to clean the fibers. CIP is an “on demand” operation and is performed
manually by the operator. CIP consists of an extensive chemical soak and is recom-
mended when the TMP cannot be lowered by either simple backwash or CEB opera-
tions. The frequency of CIP is dependent on the feed water quality but can range from
one to three months.
The chemicals used for CIP are usually the same used for CEB (to be confirmed by the
vendor):
●● An oxidant – sodium hypochlorite (NaOCl) for removal of biological fouling.
●● An oxidant and base – sodium hypochlorite (NaOCl) and sodium hydroxide (NaOH) for
removal of organic fouling.
●● An acid – hydrochloric acid (HCl) or citric acid for removal of inorganic fouling.
Compared to CEB, for CIP operations HCl and NaOH are dosed at higher concentrations.
and dosages will be specified by the selected membrane vendor.
The typical CIP cycle is as follows:
●● Prior to CIP, the routine backwash steps are performed. The backwash steps are repeated
three to eight times to remove contaminants or foulants not requiring chemical removal.
●● After completing the backwash steps, the module is drained by gravity to remove excess
water and prevent dilution of the CIP chemicals.
●● CIP chemicals are recycled on the outside of the module for 30 minutes through the CIP
tank. A small chemical permeate stream will also be collected and recycled to the CIP tank.
●● A soak follows the initial recycle step for 60 minutes or longer depending on the degree
of fouling that has occurred.
●● After the soak step, CIP chemicals are again recycled on the outside of the module for
30 minutes.
●● When the recycle is completed an air scour is performed and then the module is drained
to remove concentrated chemicals.
●● The two steps of backwash and a forward flush are performed to remove any remaining
contaminants on the outside of the fibers.
After CIP and at the start of the operating step, permeate may be used to remove residual
chemicals held in the fiber or module.
The CIP steps described above are for a single alkali or acid chemical solution. If acid and
alkali cleaning are required, the CIP steps would be repeated for each chemical solution.
and dosages will be specified by the selected membrane vendor.
4.12 Reverse Osmosis
An RO treatment unit is part of the tertiary treatments of WWTPs used to reduce dissolved
salts from treated WW. The RO unit may include:
●● a single-stage RO system; or
●● a double-stage system, consisting of two RO subunits that perform the following
operations in series:
–– a first RO stage for the treatment of the WW coming from the upstream treatments;
–– a second RO stage for the treatment of the brine produced in the first RO stage.
The latter option should be considered if there is the need to maximize water reuse, and
a further concentration of the brine generated by the first RO stage is required in order to
minimize the brine stream to be disposed of.
The RO unit will be provided in one single line but with a sparing philosophy considered to
spare that can be automatically switched into operation in case of failure of the main one, in
order to ensure the continuity of the operation of the WWTP. The RO unit should include:
●● One cartridge filter of 5 μm.
●● High pressure pumping unit.
●● First-stage RO treatment system.
●● Second-stage RO treatment system (optional).
●● Antiscalant dosage system.
●● Sodium metabisulfite dosage system.
●● Acid dosing system (hydrochloric/sulfuric acid).
●● Permeate/CIP buffer tank.
●● Permeate/CIP pumping system.
●● All the electromechanical and I&C equipment (pumps, instruments, etc.) necessary for
proper operation.

Table 4.19 summarizes the main process parameters for the RO unit. The dimensions of
each RO membrane would be 8 x 40 inches, and RO vessels will contain six RO membranes.
Table 4.19 Main process parameters for RO unit.
Module diameter m 0.2

Module length m 1.0

The unit consists of a single-stage RO system or of a double-stage system depending on the
chosen option for the treatment of the first RO brine stream. The second-stage RO treat-
ment option should be considered if there is the need to maximize water reuse and further
concentration of the brine generated by the first RO stage in order to minimize the brine
stream to be disposed. Upstream of the first-stage RO membranes the following products
will be used:
●● Antiscalant as scale inhibitor.

●● Sodium metabisulfite to reduce oxidizing agents present in WW (since a chlorination
basin is installed upstream of the RO treatment). An oxidation reduction potential (ORP)
control should be installed in-line to control the sodium metabisulfite dosage.
●● Acid dosing for reduction of biofouling.
A single stage of filtration cartridge acts as a safety barrier to protect the membranes
from TSS fouling and a 5-μm cartridge filter is installed for this purpose. The system should
be provided with an automatic flushing and manual CIP unit.
The RO unit will therefore include a permeate buffer tank to store permeate for cleaning
purposes (flushing and CIP). Every time the plant stops, a flushing will be done, displacing
the brine from the membranes with permeate and avoiding potential scaling.
When necessary, CIP provides in-line cleaning to the RO vessels to restore their operat-
ing conditions. CIP chemicals are prepared in the same permeate buffer tank and dosed
upstream of the first-stage RO vessels. Generally, CIP is done not more than four times a
year (once every three months).
4.12.2.1 First-Stage RO Treatment

The inlet WW coming from previous sections is fed by means of high-pressure centrifugal
pump (one duty, one spare) to the first-stage RO unit membranes. The permeate from the
first-stage RO unit is sent to the treated water storage tank. The brine generated from the
first-stage RO can be:
●● Directly discharged to sea, brackish water, or river (if permitted by local regulations).
●● Blended with fresh/treated water and reused for gardening or toilet flushing.
●● Sent to an evaporation pond (for warm climates).
●● Treated with a second RO stage and subsequently treated with an evaporator followed by
a crystallizer.
The first-stage RO membrane will be 8 inches in diameter by 40 inches in length.

Table 4.20 shows the characteristics of first-stage RO membranes. Therefore the calcula-
tion should be performed as follows:
●● RO permeate flow (m3/h) = Inlet flow rate (m3/h) x RO recovery (70%);

●● Number of membranes (n) required = RO permeate flow (m3/h)/Design-specific flux
(15 l/m2/h)/Membrane surface area (37 m2/membrane) x 1000 (in normal operation);
●● Number of vessels required (n vessels) = Number of elements required (n) / Number of
elements per each vessel (6 membranes/skid).
Table 4.20 Characteristics of First Stage RO Membranes.
Design-specific flow for RO (with all skids in operation) l/m2/h 17–20

RO membrane surface m2 37
Membranes contained in one RO vessel n 6
4.12.2.2 Second-Stage RO Treatment

The second-stage RO unit is fed with the brine produced from the first-stage RO treatment,
in order to obtain concentrated RO brine, enhancing the overall desalination treatment
process. The permeate streams from both RO stages go into the common permeate storage
tank which receives also the overhead from the evaporator unit. The brine produced from
the second-stage unit is sent to the evaporator with crystallizer unit where a further con-
centration of the brine will be performed. The second-stage RO membrane will be 8 inches
in diameter by 40 inches in length. Table 4.21 shows the characteristics of second-stage RO
membranes. Therefore the calculation should be performed as follows:
●● Second-stage RO permeate flow (m3/h) = first-stage RO brine flow rate (m3/h) × second-
stage RO recovery (55%).
●● Number of membranes (n) required = Permeate flow (m3/h)/Design-specific flux (15 l/
m2/h)/Membrane surface area (37 m2/membrane) × 1000 (in normal operation).
●● Number of vessels required (n vessels) = Number of elements required (n)/Number of
elements per each vessel (6 membranes/skid).
The total volume of RO vessels (first stage + second stage), useful to determine the flush-
ing and chemical cleaning volume and therefore the permeate/CIP tank volume, is calcu-
lated as:
Total RO modules volume m 3 Membrane volume 0.03 m 3

number of first stage RO membranes n number of second stage ROmembbranes n
Table 4.21 Characteristics of Second Stage RO Membranes.
Design-specific flow for RO (with all skids in operation) l/m2/h 15

2
RO membrane surface m 37
Membranes contained in one RO vessel n 6
4.12.3 Membrane Cleaning

RO membranes are widely used for salty water treatment. The use of RO membranes in
water desalination and WW reclamation, reuse, and recycling has increased over the past
few years. However, a major impediment is membrane fouling. During normal operation
over a period of time, RO membrane elements are subject to fouling by suspended, organic,
or inorganic materials that may be present in the feed water. Common examples of
foulants are:
●● Calcium carbonate scale.
●● Sulfate scale of calcium, barium, or strontium.
●● Metal oxides (iron, manganese, copper, nickel, aluminum, etc.).
●● Polymerized silica scale.
●● Inorganic colloidal deposits.
●● Mixed inorganic/organic colloidal deposits.
●● Natural organic matter (NOM).
●● Man-made organic material (e.g. antiscalant/dispersants, cationic polyelectrolytes).
●● Biological matter (bacterial bioslime, algae, mold, or fungi).
The entry of these foulants in RO systems causes fouling of membranes. The fouling
leads to increase in the differential pressure from feed to concentrate and finally leads to
membrane flux declination and mechanical damage of the membrane. Foulants removal
through chemical cleaning is therefore a major objective of the membrane chemical
cleaning process.
4.12.3.1 Chemical Cleaning Requirement

Membranes of RO systems must be cleaned with suitable chemicals in any of the following
circumstances:
●● When the normalized permeate flow drops by 10%.
●● When the normalized salt passage increases by 5%.
●● When the normalized differential pressure increases by 15%.
RO chemical cleaning frequency will vary by site. A rough rule of thumb as to an accept-
able cleaning frequency is once every three to five months. It is important to clean the
membranes when they are only lightly fouled, not heavily fouled.
4.12.3.2 Chemical Cleaning Sequence

Normally three kinds of RO chemical cleaning are recommended: acid cleaning, alkaline
cleaning, and sanitizing. The recommended sequence is given below:
●● Acid cleaning and flushing.
●● Alkaline cleaning and flushing.
●● Sanitizing and flushing.
4.12.3.3 Cleaning Chemicals

Acid cleaners and alkaline cleaners are the two standard cleaning chemicals. Acid cleaners
are used to remove inorganic precipitates including iron, while alkaline cleaners are used
to remove organic fouling including biological matter. It is recommended that RO perme-
ate should be used for the cleaning solutions. Table 4.22 lists suitable RO cleaning chemicals
along with recommended concentrations.
Table 4.22 Recommended RO cleaning chemicals.
Concentration by
Chemical weight (%) Foulant
Sodium hydroxide (NaOH) 0.1 Biological and organic

Tetrasodium salt of ethylene Diamine t etra- 1.0 Biological and organic
acetic acid (Na4EDTA)
Sodium salt of dodecylsulfate (Na-DDS) 0.025 Biological, organic,
and silica
Hydrochloric acid (HCl) 0.2 Inorganic
Sodium hydrosulfite (Na2S2O4) 1.0 Inorganic and iron
Phosphoric acid (H3PO4) 0.5 Inorganic and iron
Sulfamic acid (NH2SO3H) 1.0 Metal oxides
Hydrogen peroxide 0.25 Bacterial (E. coli)
4.12.3.4 Flow and Pressure of Chemical Solutions

Flow rate and pressure of circulated chemical solutions during chemical cleaning of RO
membranes play a very important role. Table 4.23 lists required flow and pressure during
chemical cleaning of RO membranes.
Table 4.23 Recommended flow and pressure of RO chemical cleaning solution.
Membrane diameter (inches) Flow rate per pressure vessel (m3/h) Pressure (bar)
2.5 0.7–1.2 1.5–3.5

4 1.8–2.3 1.5–3.5
8 6.0–9.0 1.5–3.5
4.12.3.5 Temperature and pH Range of Chemical Solutions

Temperature and pH of circulated chemical solutions during chemical cleaning of RO
membranes also play a very important role. Table 4.24 lists required temperature and pH
range during chemical cleaning of RO membranes.
Table 4.24 Recommended temperature and pH range of RO chemical cleaning solution.
Temperature (°F) Operating pH range Cleaning pH range
20–120 3–11 2–12
4.12.3.6 Chemical Cleaning Equipment

RO chemical cleaning systems consist of a mixing tank, cleaning pump, and micron car-
tridges. The successful cleaning of an RO on-site requires well-designed RO cleaning
equipment. It is recommended to clean a multistage RO one stage at a time to optimize
RO Membranes
Pump
Mixing tank
Filter
Reject flow
Permeate flow
Figure 4.6 General arrangement of RO chemical cleaning equipment.
Table 4.25 Size and material of constructions of RO chemical cleaning equipment.
Equipment Size Material of construction
Mixing tank 20% more to the volume of pressure vessel HDPE/PP/FRP

Cleaning pump Flow SS-316/PP
Cartridges filters 10 μm
HDPE, High-density polyethylene; FRP, fiber reinforced polymer; SS, stainless steel; PP, polypropylene.
cross-flow cleaning velocity. The source water for chemical solution make-up and rinsing
should be clean RO permeate or deionized (DI) water and be free of hardness, transition
metals (e.g. iron), and chlorine. Components must be corrosion proof. The general arrange-
ment of RO chemical cleaning equipment is shown in Figure 4.6. Table 4.25 lists size and
material of constructions for RO chemical cleaning equipment.
4.12.3.7 Chemical Cleaning and Flushing Procedures

In the RO plant the RO membrane can be cleaned in place in the pressure tubes by recircu-
lating the cleaning solution across the high-pressure side of the membrane at low pressure
and relatively high flow.
●● Flush the pressure tubes at low pressure (3.5 bar or 50 psi) by pumping clean water (RO
permeate or DI quality and free of hardness, transition metals, and chlorine) from the
cleaning tank.
●● Mix a fresh batch of the selected cleaning solution in the cleaning tank. The dilution water
should be clean water of RO permeate or DI quality and be free of hardness, transition
metals, and chlorine. The temperature and pH should be adjusted to their target levels.
●● Circulate the cleaning solution through the pressure tubes for approximately one hour or
the desired period of time. At the start, send the displaced water to drain so you do not
dilute the cleaning chemical, and then divert up to 20% of the most highly fouled clean-
ing solution to drain before returning the cleaning solution back to the RO cleaning tank.
For the first five minutes, slowly throttle the flow rate to one-third of the maximum
design flow rate. This is to minimize the potential plugging of the feed path with a large
amount of dislodged foulant. For the second five minutes, increase the flow rate to two-
thirds of the maximum design flow rate, and then increase the flow rate to the maximum
design flow rate. If required, readjust the pH back to the target when it changes more
than 0.5 pH units.
●● An optional soak and recirculation sequence can be used, if required. The soak time can
be from one to eight hours depending on the manufacturer’s recommendations. Caution

should be used to maintain the proper temperature and pH. Also note that this does
increase the chemical exposure time of the membrane.
●● Upon completion of the chemical cleaning steps, a low-pressure cleaning rinse with
clean water (RO permeate or DI quality and free of hardness, transition metals, and chlo-
rine) is required to remove all traces of chemical from the cleaning skid and the RO skid.
Drain and flush the cleaning tank; then completely refill the cleaning tank with clean
water for the cleaning rinse. Rinse the pressure tubes by pumping all of the rinse water
from the cleaning tank through the pressure tubes to drain. A second cleaning can be
started at this point, if required.
●● Once the RO system is fully rinsed of cleaning chemical with clean water from the clean-
ing tank, a final low-pressure clean-up flush can be performed using pretreated feed
water. The permeate line should remain open to drain. Feed pressure should be less than
60 psi (4 bar). This final flush continues until the flush water flows clean and is free of
any foam or residues of cleaning agents. This usually takes 15–60 minutes. The operator
can sample the flush water going to the drain for detergent removal and lack of foaming
by using a clear flask and shaking it. A conductivity meter can be used to test for removal
of cleaning chemicals, such that the flush water to drain is within 10–20% of the feed
water conductivity. A pH meter can also be used to compare the flush water to drain to
the feed pH.
1) Once all the stages of a train are cleaned, and the chemicals flushed out, the RO can be
restarted and placed into a service rinse. The RO permeate should be diverted to drain
until it meets the quality requirements of the process (e.g. conductivity, pH).
4.13 Evaporator with Crystallizer
An evaporator with crystallizer unit is one alternative treatment for brine management
within the WW treatment facilities. Such a unit treats the brine produced in the second-
stage RO treatment and other high TDS WW not able to be treated with biological processes.
The unit will be provided with one treatment line unless specific plant size requires more
than one line to be installed. A sparing philosophy will be adopted considered as having, for
each of the most critical rotating equipment, a 1 + 1 philosophy, with an installed spare that
can be automatically switched into operation in case of failure of the main one, in order to
ensure the continuity of the operation of the WWTP. The unit should include:
●● Atmospheric thin film evaporator (or tubular falling film-type evaporator).
●● Vapor compression crystallizer (optional).
●● Preheating heat exchangers for both units.
●● Distillate storage tanks.
●● Distillate pumps.
●● Concentrate storage tanks.
●● Concentrate pumps.
●● Chemicals storage and dosage for chemical cleaning.
●● All the electromechanical and I&C equipment (pumps, piping, valves, compressor,
mixers, instruments, etc.) necessary for proper operation.

Table 4.26 summarizes the main process parameters for the evaporator with crystallizer.
Table 4.26 Main process parameters for evaporator with crystallizer.
Parameter Units Value Notes
TDS concentration in mg/l 100 Overhead stream has to be blended with RO

overhead permeate and should be suitable for reuse
within the facility
Specific heat requirement kW/m3 90
(assuming feed at 25 °C) feed

4.13.2.1 Process Waste Water Preheating
The brine coming from the second-stage RO unit will be preheated in a battery of heat
exchangers in which the evaporation overhead will be fed in countercurrent. During this
phase the evaporation overhead will release part of its thermal energy to the incoming brine,
allowing an energy saving in the overall process. The operation temperature maintained
inside the evaporator is around 90 °C, and so – considering some thermal losses – the over-
head will leave the evaporators at a temperature of around 80 °C. The energy recovery will
depend on the heat exchanger sizing. Depending on the plant size a further energy saving can
be achieved by including a secondary heat exchange battery in order to recover the thermal
energy of the concentrated brine; this flow will be lower in terms of flow rate compared with
the overhead but also its temperature will be around 80 °C at the outlet from the evaporator.
4.13.2.2 Evaporator
The second-stage RO brine, after preheating, will be fed to a mechanical falling film evapo-
rator (or a thin film type), provided with a mechanical vapor recompression system to
recover latent heat of evaporation. The following description applies for a mechanical
falling film evaporator with mechanical vapor recompression.
The operation of the evaporation unit is based on the mechanical compression evapora-
tion process, which allows aqueous components to be evaporated, while non-volatile com-
ponents are retained in the concentrate. The produced overhead is virtually free from TDS
(<100 mg/l) and can be sent to the treated water storage together with the RO permeate.
Filling of the unit will be driven by the vacuum created by the compressor.
The main steps of the evaporation are as follows:

●● The preheated brine flow fed to the evaporator sump will be circulated through heat
transfer tubes internal to the machine where the outcoming overhead flow releases heat
to the brine.
●● Part of the brine evaporates, while the remaining brine flows in a falling film into the
brine sump and is then recirculated by a centrifugal pump inside the tubes; part of the
brine is blown down.
●● The mechanical compressor will generate a negative pressure on the suction side where
the vapor will be withdrawn and will increase the vapor pressure and temperature on the
delivery side.
●● The high-temperature vapor will be delivered by the compressor to the main vessel heat
exchanger, where it will condensate, releasing thermal energy to the evaporating brine
falling inside the tubes, and then it will leave the evaporator as distillate.
●● The distillate is pumped back to the preheater where it releases part of the heat to the
incoming brine flow.
The condensation of the overhead will allow the establishment of a natural circulation of
the evaporating fluid between the suction side and the delivery side of the compressor due
to difference in density. Before the compression stage the vapor will be purified by means
of mist eliminators.
During the evaporation phase the distillate will leave the machine continuously; when
the setup conditions are attained, the evaporation phase will be over, and the concentrated
brine will be delivered outside the machine. At that point a new heating phase will take
place and the process can restart. For plants having a size like the ones of Unilever, evapo-
rators are not usually operated continuously 24 h/day but are operated in batch mode. The
contractor should in any case verify the best solution according to the specific case.
The heating phase duration is around 40 minutes, while the evaporation phase duration
can be largely variable: the more the influent WW will be concentrated, the less the evapo-
ration phase will last.
The distillate is collected in a pumping pit and sent to the treated water storage tank,
while the brine is collected in a buffer tank provided with mixer and can then be sent:
●● To crystallizer, if further brine concentration is required; or
●● To evaporation ponds, if available; and
●● To offsite disposal.
During evaporator operation, vents will be withdrawn from the machine and sent to atmos-
phere; depending on the plant size, a further heat exchanger battery can be considered in
order to condensate part of the vents and recover further thermal energy from the process.
The vent condensate will be mixed with the overhead. The unit will have integral level con-
trols and instrumentation for the proper automation through a dedicated PLC system.
4.13.2.2.1 Evaporator Cleaning

The evaporator operation will require chemical washing cycles to remove scaling from
heating surfaces. Generally, only an acid washing cycle is considered for plant performance
maintenance; however, the vendor will specify the chemicals, frequencies, and dosages
specific for the selected unit.
4.13.2.3 Crystallizer (Optional)

The concentrated brine from the evaporator may be sent to a vapor compression crystal-
lizer in order to enhance brine concentration if there is the need to recover further distillate
for reuse, and obtain a smaller flow of very concentrated brine to dispose offsite. The pro-
cess of the vapor compression crystallizer is summarized as follows:
●● The brine from the evaporator is fed to the crystallizer where it is preheated in a shell and
tube heat exchanger where the vapor leaving the crystallizer releases heat to the influent
brine stream; the brine is maintained under pressure, avoiding evaporation of the brine
and preventing scaling formation on the tubes.
●● The preheated brine enters the crystallizer with a specific angle in a way that it creates a
vortex when entering the crystallizer; here, some of the brine evaporates, promoting the
formation of crystals from the remaining brine.
●● The brine is partially blown down and the remaining is recirculated to the preheater,
while the overhead vapor is passed through a mist eliminator and then is compressed by
a compressor.
●● The compressed vapor exchanges heat with the influent brine stream in the shell and
tube preheater and condenses in distillate.
The distillate is collected in a pumping pit and pumped to the treated water storage tank,
while the brine is stored in a buffer tank provided with mixer and can then be sent to evapo-
ration ponds, if available, and to offsite disposal.
4.14 Filter Press
A filter press (FP) is used for sludge dewatering. The other option considered for sludge
dewatering is sludge drying beds, which may be considered only for warm and dry climates
and if high surfaces are available.
The sludge and oil streams produced in the WWTP will be stored in the sludge/oil com-
mon storage tank; sludge thickening (may be considered as optional) will not be considered
as a standard process given that both sludge and oil streams are collected in the same tank.
The sludge is then pumped from the storage tank to the following dewatering unit, which
includes a sludge dewatering filter press that will perform the solid/liquid separation; the
dewatered slurry will be sent to optional further treatment (conditioning) and then to reuse
or disposal; on the other hand, the separated supernatant will be recirculated to the equali-
zation unit to be reprocessed in the WWTP.
The filter press unit will be provided in one single line but with a sparing philosophy
considered to have, for each of the most critical rotating equipment, a 1 + 1 philosophy,
with an installed spare that can be automatically switched into operation in case of failure
of the main one, in order to ensure continuity of the operation of the WWTP. The unit
should include:
●● Sludge/oil storage tank.
●● Sludge/oil aeration system (piping and perforated pipes).
●● Sludge/oil aeration blowers.
●● Sludge/oil feed pumps.
●● Plate and frame filter press.

●● Filtrate storage tank.
●● Filtrate pumps.
●● Air scour blowers.
●● Screw conveyors.
●● All the electromechanical and I&C equipment (piping, valves, instruments, etc.) neces-
sary for proper operation.

Table 4.27 summarizes the main process parameters for the filter press dewatering unit.
Table 4.27 Main process parameters for filter press unit.
TSS concentration in filtrate mg TSS/l 100

TSS concentration in dewatered sludge % 25

4.14.2.1 Aerated Storage Tank
The sludge and oil streams incoming to the dewatering unit will be fed to a single aerated stor-
age tank; this tank will allow a three- to four-day storage time in order to allow the sludge
dewatering and conditioning process to be operated only 40 h/week (8 h/day, 5 days/week).
In order to avoid the formation of septic conditions within the tank and consequent odor
problems, and to avoid solids settling, the storage tank will be equipped with an aeration
system. The aeration will be provided with a dedicated lobe compressor and the relative
piping. Inside the tank an appropriate number of perforated pipes (with 10-mm-diameter
holes) will provide the oxygen transfer to the sludge.
Level instruments and alarms will be included for tank level control. The sludge will be
withdrawn from the tank and fed to downstream treatments by screw pumps (one duty,
one standby), also operated at variable speed by a VFD controlled by the filter press logics.
The pump on duty will feed the filter press. This will allow the flow rate fed to the filter
press to be changed following the operation rates of the machine.
4.14.2.2 Dewatering Unit – Plate and Frame Filter Press

The plate and frame filter press will receive the sludge and oil stream from the aerated stor-
age tank through screw pumps. Before entering the machine the sludge will be eventually
conditioned with an organic polymer that will enhance the filtration process; the dosage of
this chemical will be performed with an in-line connection. The type of polymer and the
operative dosage need to be adjusted with specific jar tests.
The filter press will be of fixed-volume, recessed-plate type; it consists of a series of
rectangular plates, recessed on both sides, which are supported face to face in a vertical
position on a frame with a fixed and movable head. A filter cloth is hung or fitted over
each plate. The plates are held together with sufficient force to seal them to withstand
the pressure applied during filtration. Hydraulic rams are provided to hold the
plates together.
This filtration technology will allow treating effectively slurries containing oil independ-
ent of their settling propensity.
The filter press operation will be batched and divided into cycles, each of them including
the following seven phases:
1) Filter closing.
2) Chambers filling.
3) Retention of the press under pressure causing slurry filtration.
4) Plate pack opening.
5) Plates shifting.
6) Cake detachment from the plates and consequent collection of the cake in the convey-
ing hopper placed beneath the filter press.
7) Slurry feed channel air scour.
After those operations the filter press is ready for a new cycle. The indicative duration of
the cycle is 30–50 minutes, depending on the characteristics of the sludge.
After filtration, dewatered slurry will be discharged from the panels onto a conveying
screw hopper, and from there to an inclined screw conveyor. The screw will break the slurry
cake and convey the material to the (eventual) downstream sludge conditioning unit. The
capacity of the conveying hopper will be equivalent to the capacity of the filter press in one
cycle. If sludge conditioning is provided, the hopper will have also a buffer function, stor-
ing the dewatered slurry for regular feed to the downstream units. The screw motors will
be equipped with VFD for regular operation and soft starting.
For plants in which no sludge conditioning will be provided, the filter press can be
installed on a raised structure above a dewatered sludge collection container that will be
periodically emptied. The filtrate will be collected in a dedicated pumping pit and sent back
to the equalization unit by means of centrifugal pumps (one duty, one spare). The filter
press will be equipped with a scour blower (one duty, one spare); this equipment will be
operated at the end of each cycle for the air scouring of the feed channel, to allow cake
detachment. As an alternative, a service air net can be used for this purpose if it can guar-
antee the pressure requirement of the equipment.
All the operation phases will be fully automated and difference in the details will depend
on the selected contractor. An automatic control should be installed to ensure that the filter
press stops operations in case the slurry feed pump turns off. The unit will have integral
level controls and instrumentation for proper automation through a dedicated PLC system
included in the unit.
4.14.2.2.1 Periodical Washing

A periodical automatic high-pressure washing cycle with clean water should be performed
indicatively every three to ten working days, this also depending on the filterability characteris-
tics of the sludge. To avoid clean water usage, treated water from the WWTP will be used. The
wash water will be collected in the filtrate storage tank and sent back to the equalization unit.
4.15 Belt Press
A belt press (BP) (or belt filter press) performs sludge dewatering by squeezing the sludge
between two filter belts which go through a system of rolls, introducing shear and com-
pression forces in order to separate the water from the sludge, thereby reducing sludge
moisture content. This filtration technology allows effectively treating sludges indepen-
dently from their settling capability.
The dewatered sludge can be sent for further treatment for reusing or simply being dis-
posed of off-site; the separated liquid will be instead discharged to the WW sewer net and
returned to the equalization tank.
The belt press unit will be provided in one single line but with a sparing philosophy con-
sidered to have, for each of the most critical rotating equipment, a 1 + 1 philosophy with an
installed spare that can be automatically switched into operation in case of failure of the
main one, in order to ensure the continuity of the operation of the WWTP. The belt press
unit should include:
●● Sludge storage tank (like a gravity thickener).
●● Sludge aeration system (piping and perforated pipes).
●● Sludge feed pumps (progressive cavity pumps – one duty, one standby).
●● Belt press.
●● Screw conveyors for dewatered sludge.
●● Dewatered sludge storage roll-off bin.
●● Polymer solution preparation tank.
●● Polymer solution dosing pumps.
●● All the electromechanical and I&C equipment (piping, valves, instruments, etc.)

Table 4.28 summarizes the main process parameters for the belt press dewatering unit.
Table 4.28 Main process parameters for belt press unit.
TSS concentration in filtrate mg TSS/l 100–300

Dryness of dewatered sludge %
Primary sludge 25–30
Biological sludge 12–20
Mixed primary/biological sludge 20–28
Belt speed m/h 50–150
Loading per meter kg TSS/m/h

The sludge streams from upstream units will be stocked in a dedicated storage tank (poten-
tially a gravity thickener) or fed directly from the producing units to the belt press.
The sludge will be fed to the belt press by means of screw pumps (one duty, one standby),
equipped with a VFD controlled by the belt press logics.
Before entering the machine the sludge will be conditioned with an organic polymer that
will enhance the dewatering process. The type of polymer and the operative dosage need to
be adjusted with specific jar tests. The dewatering belt press is intended to produce dewa-
tered cake with a high solids content. Conditioned sludge will first enter a gravity drainage
stage to remove free-draining water.
Following the gravity section, the sludge will enter a low-pressure section, with the top
belt being solid and the bottom belt being a sieve where further water removal occurs. As a
last step, the sludge will go through a high-pressure zone of belts with a serpentine or sinu-
soidal configuration to increase shears and pressures. Basically, belts are fed through the
rollers and water is squeezed out of the sludge. When the belts pass through the final pair
of rollers in the process, the filter cloths are separated and the filter cake is scraped off on
an inclined screw conveyor and dropped into a roll-off bin for further treatment or dis-
posal. The filtered liquid will be discharged into a centrate chute that is piped to the WW
sewer net.
A pneumatically adjustable belt tensioning system will allow adjustment while the press
is in operation. The unit will have integral level controls and instrumentation for proper
automation through a dedicated PLC system included in the unit.
A periodical automatic high-pressure total washing cycle with clean water should be
performed indicatively every three to ten working days, this also depending on the charac-
teristics of the sludge. Water for cleaning sprays will be filtered plant effluent or utility
water with a TSS level of 10–20 mg/l. The water pressure supplied to the belt press should
be a minimum of 8 bar (120 psi). The wash water will be discharged to the WW sewer net.
4.16 Centrifuge
A centrifuge unit is an equipment for continuous sludge dewatering. The centrifuge is fed
with sludge stored in the sludge storage tank or in the sludge thickener (in some applica-
tions it could be fed directly from the biological unit). The sludge enters to the rotating
bowl of the centrifuges, where, by centrifugal force, it is separated into a concentrated cake
and a dilute stream called “centrate.” The cake is then discharged by a screw feeder into a
screw conveyor and then is sent to reuse or final disposal. The centrate is usually recircu-
lated in the equalization tank or into the biological system.
The centrifuge unit will be provided in one single line but with a sparing philosophy
considered to have a bypass system that can be automatically switched into operation in
case of failure of the centrifuge, in order to ensure the continuity of the operation of the
WWTP. The unit should include:
●● Sludge storage tank.
●● Sludge feed pumps.
●● Sludge aeration system (piping and perforated pipes).

●● Sludge aeration blowers.
●● Sludge centrifuge decanter.
●● Screw conveyors.
●● Dewatered sludge storage tank.
●● Polymer solution preparation tank.
●● Polymer solution dosing pumps.
●● All the electromechanical and I&C equipment (piping, valves, instruments, etc.) neces-
sary for proper operation.

Table 4.29 summarizes the main process parameters for the centrifuge dewatering unit.
Table 4.29 Main process parameters for centrifuge unit.
TSS concentration in centrate mg TSS/l 100

Dryness of dewatered sludge %

The centrifuge will receive the sludge and oil stream from the sludge storage tank (or grav-
ity thickener) through progressive cavity feed pumps. Before entering the machine the
sludge will be conditioned with an organic polymer that will enhance the dewatering pro-
cess; the dosage of this chemical will be performed with an in-line connection. The type of
polymer and the operative dosage need to be adjusted with specific jar tests.
The centrifuge should be continuously fed with sludge conditioned with polymer by
individual sludge feed pumps. The sludge is fed into the center of the equipment where
the solids are thrown against the wall of the bowl which is rotating at high speeds, thus
generating high centrifugal forces. The solids deposited against the bowl continuously
move to one end of the machine by an internal screw conveyor which rotates at a dif-
ferent speed. The solids are then discharged into an inclined screw conveyor and
dropped into a roll-off bin. The clarified liquid continuously overflows through adjust-
able weirs at the other end of the machine and is discharged to the WW sewer net.
All the operation phases will be fully automated and difference in the details will depend
on the selected contractor. An automatic control should be installed to ensure that the cen-
trifuge stops operations in case the slurry feed pump turns off. The unit will have integral
level controls and instrumentation for proper automation through a dedicated PLC system
included in the unit.
A periodical automatic high-pressure total washing cycle with water free of solids (reuse
or clean water) should be performed indicatively every three to ten working days, this also
depending on the characteristics of the sludge.
4.17 Gravity Thickener
A gravity thickener, installed upstream of the dewatering unit, will be used to remove part
of the water and to concentrate the solids content of the sludge by gravity settling, thus
reducing the volumes of sludge to be handled by downstream units. In addition, the thick-
ener can provide storage capacity for the sludge, allowing the non-continuous operation of
downstream dewatering units. This is the reason why the gravity thickener is mostly found
as the first step of the solids management process. It performs the following operations:
●● Increases the solid content of the sludge (i.e. increases the TSS concentration, with effi-
ciency to be determined based on the upstream TSS content and based on HRT, by
removing a portion of the liquid fraction by gravity separation).
●● Sludge volume reduction as a consequence of the above process.
The unit will be provided in one single unit. The gravity thickener should include:
●● Centrifugal feed pump.
●● Thickener tank.
●● Moving bridge or equivalent sludge collecting mechanism.
●● Thickened sludge extraction pump (progressing cavity type).
●● Torque monitoring system.
●● Depending on the final destination of the supernatant, a dedicated pump station could
be required.
●● All other electromechanical and I&C equipment (pumps, compressor, mixers, piping,

Table 4.30 summarizes the main process parameters for the gravity thickener.
Table 4.30 Main process parameters for gravity thickener.
Solid loading (minimum–maximum) kg TSS/m2/day

Chemical sludge (iron salts) 10–50
Chemical sludge (lime) 100–300
Combined primary and biological sludge 40–60
(Continued )
Table 4.30 (Continued)
Thickener overflow rate m3/m2/day

Thickened sludge dryness (minimum–maximum) %
Chemical sludge (iron salts) 3–4
Chemical sludge (lime) 10–15

The sludge extracted from the primary clarifier, secondary clarifier, or chemical/physical
treatments is transferred to the gravity thickener which performs the following operations:
●● Gravity settling of TSS.
●● Collection of concentrated sludge from the bottom hopper, by means of rotation scraper.
●● Sludge extraction from the hopper.
●● Clarified water discharging to WW drain.
Gravity thickening is one of the most common methods to increase the solids content of
the sludge and it is accomplished in a tank similar in design to a conventional sedimenta-
tion tank. Normally, a circular tank is used and dilute sludge is fed to a center feed well.
The feed sludge is allowed to settle and compact, and the thickened sludge is withdrawn
from the conical hopper bottom. Conventional sludge-collecting mechanisms with deep
trusses or vertical pickets stir the sludge gently, thereby opening up channels for water to
escape and promoting densification. The supernatant flow that results is drawn off and
returned to the WWTP equalization (if present) or gradually mixed with the influent WW
fed to the plant head. The thickened sludge is pumped out from the hopper and sent to the
dewatering unit.
The unit will be provided with a torque control system on the motor of the moving sludge
collecting mechanism to avoid excessive torque. A level meter will trip the sludge extrac-
tion pump to protect the equipment to avoid running dry.
Further Reading
Chaubey, M. (2002a). Treatment of dairy effluent with fixed film bioreactor technology. Indian
Journal of Environmental Protection 23 (4): 361–363.
Chaubey, M. (2002b). Computer design of wastewater treatment plant using fixed film
bioreactor technology. Journal of Industrial Pollution Control 18 (1): 107–117.
Chaubey, M. (2005a). Water reuse is better alternative than sea water desalination. Arab Water
World Journal XXIX (3): 22–23.
Chaubey, M. (2005b). Technological assessment of water treatment technologies. Arab Water
World Journal XXIX (5): 34–36.
Chaubey, M. (2006a). Innovative methods of pre-treatment of reverse osmosis membranes.
Arab Water World Journal XXX (8).
Chaubey, M. (2006b). Fouling prevention techniques of reverse osmosis systems. Water
Digest I (1).
Chaubey, M. (2016). Assessment of aerobic biological technologies for wastewater treatment of
F.M.C.G. industries. Water Digest 2016: 30–36.
Chaubey, M. (2018). Design considerations of wastewater treatment plants with MBBR
technology. Water Digest, January 2018: 52–56.
Chaubey, M. and Kaushika, N.D. (2004). Field study of reverse osmosis process in wastewater
treatment. Environmental Pollution Control Journal 7 (1): 6–11.
Culp, W. and Williams, H. (1980). Wastewater Reuse and Recycling Technology. Park Ridge, NJ:
Noyes Data Corporation.
James M. Montgomery, Inc (1985). Water Treatment, Principle & Design. New York: Wiley.
Metcalf & Eddy, Inc (2004). Wastewater Engineering: Treatment and Reuse, 4e.
Zhongxiang, Z. and Yi, Q. (1991). Water saving and wastewater reuse and recycle in China.
Water Science Technology 23: 2135–2140.

Design Considerations

Uploaded by

Copyright:

Available Formats

Design Considerations

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Design Considerations

Uploaded by

Copyright:

Available Formats

103

Wastewater Treatment Technologies: Design Considerations, First Edition. Mritunjay Chaubey.

This chapter provides brief descriptions of design considerations of various wastewater

4.1.1 Process Parameters

Table 4.1 Main process parameters for screening unit.

Liquid depth of screen chamber 1.2 m

4.1.2 Process Description

The equalization unit will have the following functions:

4.2.1 Process Parameters

Table 4.2 Main process parameters for equalization tank.

Equalization tank capacity Based on 12–24 h HRT

4.2.2 Process Description

4.3 ­Dissolved Air Flotation

4.3.1 Process Parameters

Table 4.3 Main process parameters for DAF units.

Parameter Units Value

HRT in DAF unit min 50

4.3.2 Process Description

Table 4.4 Chemicals application with pH range.

Chemical Dosage range (mg/l) pH

Lime (Ca(OH)2) 150–500 9–11

4.4.1 Process Parameters

Table 4.5 Main process parameters for clariflocculators.

Parameter Units Value

HRT in coagulation chamber (minimum–maximum) min 5–10

4.4.2 Process Description

The clariflocculator will consist of the following main components:

4.5 ­Conventional Activated Sludge

4.5.1 Process Parameters

Table 4.6 Main process parameters for biological reactors.

Parameter Units Value

TSS concentration in aeration g TSS/l 3–4

4.5.2 Sizing of Activated Sludge Treatment Systems

4.5.2.1 Sizing of Activated Sludge Unit

Influent flow Effluent

Sludge recycle flow Sludge bleed

Figure 4.1 Schematic diagram of activated sludge unit.

Volume Qinfl Qrec / CTSEL * 60

Volume BOD / F / M * MLVSS

Volume Qinfl Qrec / CTDEG * 60

Volume Qinfl Qrec / CTSEL * 60

Volume Qinfl Qrec / CTDEG * 60

SL = 450 / [SVI * MLSS]

4.5.2.2 Sizing of Denitrification/Nitrification Biotreater

Volume Qinfl Qrec Q MLR / CTSEL * 60

Anoxic reactor Aerobic reactor

Sludge recycle (incl. NO3) Sludge bleed

Figure 4.2 Schematic diagram of denitrification/nitrification biotreater unit.

Denitrification rate Volume1 N DENIT / DN-rate * MLVSS

4.5.2.2.1 Aerobic Sludge Age

Vol aer SP * SRTAER / MLSS

Check actual F/M ratio = BOD / [(Vol-anox + Vol-aer) * MLVSS) ≤0.15where

4.5.2.2.2 Total Sludge Age

Vol aer Vol anox SP * SRTTOT / MLSS Vol aer

Volume Qinfl Qrec Q MLR / CTDEG * 60

4.5.2.3 Sizing of Intermittent Nitrification/Denitrification Biotreater

Volume Qinfl Qrec / CTSEL * 60

Anoxic period, e.g. 20 min

Sludge recycle flow Sludge bleed

Figure 4.3 Schematic diagram of intermittent nitrification/denitrification biotreater unit.

4.3 Dissolved Air Flotation

4.5 Conventional Activated Sludge

4.6 Moving Bed Biofilm Reactor

4.7 Membrane Bioreactor

4.9 Pressure Sand Filter