Te-Metals and Non Metal Final Revisor (2022-23)
Te-Metals and Non Metal Final Revisor (2022-23)
Te-Metals and Non Metal Final Revisor (2022-23)
20. The ability of metals to be drawn into thin wire is known as:
[NCERT Exemplar]
(a) Ductility
(b) Malleability
(c) Sonorousity
(d) Conductivity
Ans. (a) Ductility
Explanation :
Ductility is the property which allows the metals to be drawn into thin
wires.
21. The compound obtained on reaction of iron with steam
is/are:
(a) Fe2O3
(b) Fe3O4
(c) FeO
(d) Fe2O3 and Fe3O4
Ans. (b) Fe3O4
Explanation :
Iron does not reacts with the cold and hot water, but it reacts with
steam to form metal oxide and hydrogen.
3 Fe + 4H2O → Fe3O4 + 4H2
(c) Ag2S
(a) A and B
(b) B, C and D
(c) A, C and D
(d) C and D
Ans. (b) B, C and D
Explanation :
In the reactivity series aluminium is above zinc, iron and copper
which makes it more reactive than these elements. Mrignayni would
observe that out of the four solutions, reaction will take place in
solution B, C and D. The reactions are as follows:
In Solution B: Aluminium will displace iron from ferrous sulphate
solution to form aluminium sulphate and iron is precipitated
2FeSO4 (aq) + 2Al (s) → Al2(SO4)3 (aq) + 3Fe (s)
In Solution C: Aluminium will displace Zinc from zinc sulphate
solution to form aluminium sulphate and zinc is precipitated.
2Al (s) + 3ZnSO4(aq) → Al2(SO4)3 (aq) + 3Zn(s)
In Solution D: Aluminium will displace copper from copper sulphate
solution to form aluminium sulphate and copper is precipitated.
2Al(s) + 3CuSO4(aq) → Al2(SO4)3(aq) + 3Cu(s).
(iii)
What is the reason for the surface of aluminium turns into dull colour
after few days as shown in the figure?
(a) Due to the formation of a stable aluminium oxide layer.
(b) Due to the reaction with atmospheric dirt particles.
(c) Due to its ductile nature.
(d) None of the above.
Ans. (a) Due to the formation of a stable aluminium oxide layer.
(iv) Although metals form basic oxides, which of the following metals
form an amphoteric oxide?
(a) Na
(b) Ca
(c) Al
(d) Cu
Ans. (c) Al
(v) Aluminium oxide reacts in the following manner with bases. The
resultant product is:
Al2O3 + 2NaOH →
57. Read the passage carefully and answer the following questions
from (i) to (v):
Metals are lustrous, malleable, ductile and are good conductors of
heat and electricity. They are solids at room temperature, except
mercury which is a liquid. They can form positive ions by losing
electrons to non-metals. Metals combine with oxygen to form basic
oxides. Different metals have different reactivities with water and
dilute acids. Metals above hydrogen in the Activity series can
displace hydrogen from dilute acids. A more reactive metal displaces
a less reactive metal from its salt solution. Metals occur in nature as
free elements or in the form of their compounds. The extraction of
metals from their ores and then refining them for use is known as
metallurgy. The surface of some metals, such as iron, is corroded
when they are exposed to moist air for a long period of time. This
phenomenon is known as corrosion. Non-metals have properties
opposite to that of metals. They are neither malleable nor ductile.
They are bad conductors of heat and electricity, except for graphite,
which conducts electricity.
(i) Which of the following pairs will give displacement reactions?
(a) MgCl2 solution and aluminium metal.
(b) NaCl solution and copper metal.
(c) FeSO4 solution and silver metal.
(d) AgNO3 solution and copper metal.
Ans. (d) AgNO3 solution and copper metal
(ii) An element reacts with oxygen to give a compound with a high
melting point. This compound is also soluble in water. The element is
likely to be:
(a) Calcium
(b) Silicon
(c) Iron
(d) Carbon
Ans. (a) Calcium
(iii) A student placed Zn rod in FeSO4 solution. After 10 hours when
rod was taken out and it was observed that:
(a) Zn rod became thinner.
(b) Zn rod became thicker due to Iron deposition.
(c) Zn rod remains as it was.
(d) Zn rod has holes.
Ans. (a) Zn rod become thinner.
(iv) Formula of cinnabar is:
(a) HgS
(b) HgS2
(c) HgS4
(d) None of these
Ans. (a) HgS
(v) The most abundant metal in the earth's crust is :
(a) Iron
(b) Calcium
(c) Aluminium
(d) Sodium
Ans. (c) Aluminium
58. Read the passage carefully and answer the following
questions from (i) to (v).
Ans. Most of the metals do not react with HNO3 because nitric acid
is a strong oxidising agent. Hence, when metals (except Mn and Mg)
are treated with nitric acid; hydrogen gas is not liberated. Only
magnesium and manganese can produce hydrogen gas with very
dilute nitric acid.
67. Why is carbon not used for reducing aluminium from
aluminium oxide.
Ans. Carbon is not used for reducing aluminium from aluminium
oxide because aluminium has greater affinity for oxygen than for
carbon, therefore carbon cannot reduce alumina (Al2O3) to
aluminium.
68. Give reason for the following:[Board Question]
(i) Aluminium oxide is considered as an amphoteric oxide.
(ii) Ionic compounds conduct electricity in molten state.
Ans. (i) Amphoteric oxides are the oxides that behave as both acidic
and basic oxides and neutralize both acids and bases. Thus,
aluminium oxide (Al2O3) reacts with hydrochloric acid to form
aluminium chloride and water. With sodium hydroxide solution it
forms sodium aluminate (NaAlO2) and water. Hence, it is called as
amphoteric oxide.
(ii) lonic compounds are bound to each other with strong attraction
force. Thus, in their solid form, their ions are not mobile. On the other
hand, when in molten state these ions become mobile and act as
carriers for charge and hence conduct electricity.
69. Give reasons:
(i) Platinum, gold and silver are used to make jewellery.
(ii) Sodium, potassium and lithium are stored under oil.
(iii) Aluminium is a highly reactive metal, yet it is used to make
utensils for cooking.
(iv) Carbonate and sulphide ores are usually converted into oxides
during the process of extraction.
Ans. (i) Platinum, gold, and silver are used to make jewellery
because they are very lustrous. Also, they are very less reactive and
do not corrode easily.
(ii) Sodium, potassium, and lithium are stored in kerosene because
they are very reactive metals and react very vigorously with air as
well as water. They are kept immersed in kerosene oil in order to
prevent their contact with air and moisture.
(iii) Aluminium is a highly reactive metal but it is resistant to
corrosion. The reason for this is that aluminium reacts with oxygen
present in air to form a thin layer of aluminium oxide. This oxide layer
is very stable and prevents further reaction of aluminium with
oxygen. It is light in weight and a good conductor of heat. Therefore,
it is used to make utensils for cooking.
(iv) Carbonate and sulphide ores are usually converted into oxides
during the process of extraction because metals can be easily
extracted from their oxides as compared from their carbonates and
sulphides.
70. Answer the following questions:
(i) Explain why, metals usually do not liberate hydrogen gas with
dilute nitric acid.
(ii) Name two metals which can, however, liberate hydrogen gas
from very dilute nitric acid.
(iii) Why do calcium starts floating when added to water?[Board
Question]
Ans. (i) Metals do not liberate hydrogen gas with nitric acid because
nitric acid is a strong oxidizing agent. So, as soon as hydrogen gas
is formed in the reaction between a metal and dilute nitric acid, the
nitric acid oxidizes this hydrogen to water.
(ii) Magnesium and manganese.
(iii) When calcium reacts with water, bubbles of H2(g) and a white
precipitate of Ca(OH)2 are formed. Calcium starts floating because
the bubbles of hydrogen gas which are formed during the reaction
stick to the surface of the calcium metal and make it lighter. As a
result, calcium starts floating on water.
Ca(s) + 2H2O(l) → Ca(OH)2 + H2(g)
Ans. When reactive metals react with dilute hydrochloric acids, gives
a salt and hydrogen gas. The reaction between iron and dil. H2SO4:
Fe + H2SO4 → FeSO4 + H2
Acidic in nature
83. Why are the heating elements of electric toasters and
electric irons made of an alloy rather than a pure metal?[Board
Question]
Ans. The resistivity of an alloy is generally higher than that of its
constituent metals. Alloys do not oxidise (burn) readily at higher
temperatures. Therefore, conductors of electric heating devices,
such as toasters and electric irons, are made up of an alloy rather
than pure metal.
84. Given reasons:[Board Question]
(i) Platinum, gold and silver are used to make jewellery.
(ii) Metals like sodium and potassium are stored under oil.
Ans. (i) Platinum, gold and silver are used to make jewellery
because of its bright and shiny surface. This property is called
metallic lustre.
(ii) Metals like sodium and potassium are stored under oil because
they are very reactive in nature, they react with oxygen present in air.
Thus, to prevent their oxidation they are kept in the oil.
85. State the following:
(i) A green layer is gradually formed on a copper plate left exposed
to air for a week in a bathroom. What could this green substance be?
(ii) Name the metal which has low melting point and can melt with
heat of your palm?
(iii) Which gas is liberated when a metal reacts with an acid? How
will you test the presence of this gas?
(iv) Name the metal which reacts with a very dilute HNO3 to evolve
hydrogen gas?
(v) Name two metals which are found in nature in the free state?
(vi) Name one metal which has a low melting point?
(vii) Name the metal which is the poorest conductor of heat?
(viii) What name is given to those metal oxides which show basic as
well as acidic behaviour?
(ix) Name two metals which form amphoteric oxides.
(x) Write the names and formulae of a metal hydride and a non-
metal hydride.
(xi) Which of the two metals is more reactive: copper or silver?
(xii) Which metal foil is used for packing some of the medicine
tablets?
(xiii) Name two metals which are found in nature in the free State.
[NCERT]
(xiv) Name an alloy of lead and tin.
(xv) What is an amalgam?
(xvi) Name two metals which are highly resistant to corrosion.
(xvii) Which metal becomes black in the presence of hydrogen
sulphide gas in air?
(xviii) Give an example of an elementary substance which is a good
conductor of electricity but it is not a metal.
(xix) Name a common metal which is highly resistant to corrosion.
(xx) What chemical process is used for obtaining a metal from its
oxide?
(xxi) Name a non-metal which is lustrous and a metal which is non-
lustrous?
Ans. (i) It is due to the formation of basic copper carbonate.
(ii) Gallium
(iii) Hydrogen gas is liberated. When a burning matchstick is brought
near to it, hydrogen gas will burn explosively with ‘pop’ sound.
(iv) Magnesium
(v) Gold and Silver
(vi) Caesium
(vii) Lead
(viii) Amphoteric oxides
(ix) Aluminium and zinc
(x) Sodium hydride, Hydrogen sulphide
(xi) Copper
(xii) Aluminium foil
(xiii) Gold and silver, are found in the free state in nature.
(xiv) Solder is an alloy of lead and tin.
(xv) An alloy of mercury metal with one or more other metals is
known as an amalgam.
(xvi) Gold and platinum are highly resistant to corrosion.
(xvii) Silver metal becomes black in the presence of hydrogen
sulphide gas in air.
(xviii) Graphite
(xix) Aluminium
(xx) Reduction.
(xxi) Iodine is a non- metal which is lustrous, whereas lead is a non-
lustrous metal.
A No reaction Displacement
B Displacement No reaction
Cu2+ + 2e– → Cu
Copper iron Electrons Copper
(From electrolyte) (From cahtode) (Deposits on cathode)
2. At anode:
Cu – 2e– → Cu2+
Copper atom Electrons Copper iron
(From impure anode) (Given to anode) (Goes into electrolyte)
93. Answer the following questions:
(i) List in tabular form three chemical properties on the basis of which
we can differentiate between a metal and a non-metal.[Board
Question]
(ii) Give reasons for the following :
(a) Most metals conduct electricity well.
(b) The reaction of iron (III) oxide [Fe2O3] with heated aluminimum is
used to join cracked machine parts.
Ans. (i) Difference between Metals and Non-metals:
Sr.
Metal Non-metals
No.
Ans. (i) K+
2, 8, 8, 1 2, 8, 7
(ii) K → K+ + e–
Cl + e– → Cl–
(ii) The reaction of calcium with water is exothermic but the heat
evolved is not sufficient for the hydrogen to catch fire. Calcium starts
floating because the bubbles of hydrogen gas formed stick to the
surface of the metal.
Ca(s) + 2H2O(l) → Ca(OH)2(aq) + H2(g)
Potassium react violently with cold water and its reaction is so violent
and exothermic that the evolved hydrogen immediately catches fire.
2K(s) + 2H2O(l) → 2KOH(aq) + H2(g) + heat energy
104. Define the terms :[Board Question]
(i) Mineral
(ii) Ore
(iii) Gangue
Ans. (i) Mineral: It is a naturally occurring substance from which
metal may or may not be extracted profitably or economically,
example, Al cannot be extracted profitably from mica.
(ii) Ore: A naturally occurring solid material from which a metal or
valuable mineral can be extracted profitably. Example, zinc blende is
an ore of zinc from which zinc can be extracted profitably.
(iii) Gangue: It is a rocky material which is present along with the
mineral in the ore, example. FeO is gangue in extraction of copper.
105. Answer the following questions:
(i) Write the electron-dot structures for sodium, oxygen and
magnesium. [NCERT]
(ii) Show the formation of Na2O and MgO by the transfer of
electrons.
(iii) What are the ions present in these compounds?
Ans. (i) Electron – dot structure for Sodium (2, 8, 1):
(iii) Ions present in these compounds are Mg2+, O2– and Na+.
106. A man went door to door posing as a goldsmith. He
promised to bring back the glitter of old and dull gold
ornaments. An unsuspecting lady gave a set of gold bangles to
him which he dipped in a particular solution. The bangles
sparkled like new but their weight was reduced drastically. The
lady was upset but after a futile argument the man beat a hasty
retreat. Can you play the detective to find out the nature of the
solution he had used?[NCERT]
Ans. The man must have dipped the gold metal in the solution of
aqua regia - a 3 : 1 mixture of conc. HCl and conc. HNO3. Aqua
regia is a fuming, highly corrosive liquid. It dissolves gold in it. After
dipping the gold ornaments in aqua regia, the outer layer of gold gets
dissolved and the inner shiny layer appears. As a result, the weight
of gold ornament reduced.
107. A metal X combines with a non-metal Y by the transfer of
electrons to form a compound Z:
(i) State the type of bond in compound Z.
(ii) What can you say about the melting and boiling point of
compound Z?
(iii) Will this compound dissolve in kerosene or petrol?
(iv) Will this compound be a good conductor of electricity?[Board
Question]
Ans. (i) Compound Z has an ionic bond.
(ii) Melting and boiling point of the compound is high.
(iii) No, compound will not dissolve in kerosene or petrol.
(iv) Yes, the compound is a good conductor of electricity.
108. What is cinnabar? How is metal extracted from cinnabar?
Explain briefly.[Board Question]
Ans. Cinnabar is HgS. It contains metal mercury. Mercury is
obtained by roasting cinnabar. HgO formed is thermally unstable and
gives mercury.
2HgS(s) + O2(g) → HgO(s) + SO2(g)
or
HgS + O2 → Hg + SO2
Ans. (i)
2 8 7 2, 8, 8, 2
Ca → Ca2+ + 2e–
(ii) The colour of solution will turn to blue. Copper displaces silver
from silver nitrate solution. Silver gets deposition of silver on copper
coin.
Cu(s) + 2AgNO3(aq) → Cu(NO3)2 (aq) + 2Ag(s)
S. Corrosion Rancidity
No.
S. Malleability Ductility
No.
Al + FeSO4 → (Al)2SO4 + Fe
151. An aqueous solution of zinc sulphate was taken in four
test tubes. Zinc, iron, copper and aluminium pieces were
dropped into separate test tubes. In which test tube reaction
will be observed?
Ans. Reaction will take place only in (IV) test tube. Al is more
reactive than Zn.
152. A cleaned aluminium foil was placed in an aqueous
solution of zinc sulphate. When the aluminium foil was taken
out of the zinc sulphate solution after 15 minutes, its surface
was found to be coated with a silvery grey deposit. From the
given observation, what can be concluded?
Ans. Surface of aluminium foil was found to be coated with a silvery
grey deposit due to the formation of aluminium sulphate as
aluminium is more reactive than zinc.
153. Consider the following table given below and answer the
questions with reasons :
4. IV No reaction No reaction
(i) Which metals are more reactive than iron?
(ii) Which metals are more reactive than copper?
(iii) Which of the following is correct?
(a) Metal IV is least reactive.
(b) Metal I is least reactive.
(c) Metal II is least reactive.
(d) Metal I is most reactive.
(iv) Which metals are least reactive?
Ans. (i) Metal II is more reactive than iron as only this displaces iron
from iron sulphate solution.
(ii) Metal II and I are more reactive than copper as both of them
displace copper from copper sulphate solution.
(iii) Metal IV does not displace any metal from iron sulphate and
copper sulphate solutions. Therefore, the correct option is (a).
(iv) Metal III and IV are least reactive as both of them cannot
displace copper or iron from their respective solutions.
154. Give reasons for following:
(i) Copper is used for making electrical circuits but brass is not.
(ii) Steel is used for making utensil but pure iron is not.
Ans. (i) Copper is pure metal and its electrical conductivity is high,
whereas brass is an alloy of copper and zinc hence, it is not very
good conductor of electricity. Thus, copper is used for making
electrical circuits.
(ii) Pure iron is soft and stretches easily, hence it cannot be used for
making utensils as on heating during cooking the utensils will change
shape. Whereas, steel is an alloy of iron containing Fe, Ni and Cr.
Steel has modified properties, i.e., it is hard, retains shape on
heating and does not change its shape. Thus, steel is used for
making utensils but pure iron is not rusted.
155. Mr. Joe has a long-cherished wish of wearing a golden
frame spectacle. He expressed his wish in front of his chemist
daughter. His daughter was overwhelmed to hear her father’s
wish and decided to set up the experiment herself to get the
golden frame. Suggest the rough set up of experiment with a
diagram.
Ans. She can take an aluminium frame for spectacles which would
behave as cathode where Au metal would get deposited and a small
bar made of gold can be used as anode. Both the electrodes are
dipped in a suitable electrolyte. Both the electrodes are cannoted
through the outer circuit.
156. From the given table, answer the following
questions :
1. Lustrous Non-lustrous
2. Hard Soft
3. Ductile Non-ductile
4. Malleable Non-mallaeable