CT Questions Gate-2 1705573442620

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Previous Year GATE Questions | CHEMICAL TECHNOLOGY

POLYMER
1. [GATE:1991]
Column I Column II
(A)Phenol formaldehyde. (I)Suspension polymerization.
(B)Nylon. (II)Emulsion polymerization.
(C)High purity polyvinylchloride (III) Solution polymerization.
(D)Styrene-Butadiene rubber. (IV) Bulk polymerization.

2. Styrene-Butadiene rubber is commercially manufactured by : [GATE:1996]

a. Bulk polymerisation b. Suspension polymerisation


c. Solution polymerisation d. Emulsion polymerisation

3. The organic acid monomer in Nylon 66 is – [GATE:1999]

A) sebacic acid B) terephthallic acid


C) adipic acid D) benzoic acid
4. Match each polymer mentioned in the left-hand column with the corresponding chemical nature
listed in the right-hand column. [GATE:1999]

Column I Column II
I) Perspex A) Polysaccharide
II) Rayon B) Polyamide
C) Polyacrylate
D) Polyester
E) Polyether
F) Polyolefin
5. ‘Nylon 66’ is so named because [GATE:2003]

a) the average degree of polymerizaon of the polymer is 1966

b) the number of carbon atoms between two nitrogen atoms are 6

c) the number of nitrogen atoms between two carbon atoms are 6

d) the polymer was first synthesized in 1966

6. Idenfy the group in which all the polymers menoned can be used to make fibers [GATE:2003]

a) Butadiene copolymers, Polyamides, Urea aldehydes

b) Cellulose derivaves, Polyisoprene, Polyethylene

c) Cellulose derivaves, Polyamides, Polyurethanes

d) Polypropylenes, Polyvinyl-chloride, Silicones

7. Match the product in Group I with the nature of the reaction in Group II [GATE:2004]

Group I Group II
P. Polyethylene 1 Condensaon polymerizaon
Q. Nylon 2 Addion polymerizaon
R. Polystyrene
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(A) P-1, Q-1, R-2 (B) P-2, Q-2, R-1

(C) P-1, Q-2, R-1 (D) P-2, Q-1, R-2

8. Match the product in Group I with the raw materials in Group II [GATE:2004]

Group I Group II
P. Urea 1. Ammonia and carbon dioxide
Q. Polyester 2. Dimethyl terephthalate and ethylene glycol
3. Ammonia and carbon monoxide
4. Hexamethylene diamine and adipic acid
(A) P-1, Q-4 (B) P-3, Q-2 (C) P-4, Q-3 (D) P-1, Q-2

9. Which of the following is NOT employed in the commercial production of linear polyvinyl chloride?
[GATE:2005]

(a) Emulsion polymerization (b) Suspension polymerization

(c) Addition polymerization (d) Condensation polymerization

10. Match the raw materials in Group II with the products in Group I Group I Group II. [GATE:2005]

Group I Group II
(P) Nylon – 66 (1) Chlorodifluro methane
(Q) Terylene (2) Dimethyl terephthalate and ethylene glycol
(3) Acetylene and hydrogen cyanide
(4) Hexamethylene diamine and adipic acid
(a) P-3, Q-4 (b) P-4, Q-3 (c) P-4, Q-2 (d) P-1, Q-2

11. Pair the following polymers with their chain characterizes [GATE:2006]

Group I Group II
P.HDPE 1. Very few branches
Q.LDPE 2. Short and regular branches
R.LLDPE 3. High branching with bot short and long chain
branches
(A) P-1, Q-2, R-3 (B) P-2, Q-1, R-3 (C) P-1, Q-3 R-2 (D) P-2, Q-3, R-1

12. Match the synthetic fibres in Group 1 with their classification in Group 2. [GATE:2007]

Group I Group II
P. Rayon 1) polyamide
Q. Orlon 2) polyester
R. Dacron 3) cellulose
4) acrylic
A) P-2, Q-3, R-1, B) P-3, Q-4, R-2, C) P-3, Q-1, R-3, D) P-3, Q-3, R-4,

13. Match each of the following techniques of polymerizaon in Group I, with the corresponding process
characteristics in Group II [GATE:2010]

Group I Group II
P. Bulk I. Polymer with very high molecular weight can be
obtained
Q. Solution II. Heat removal is crucial but very difficult
R. Suspension III. Small amount of undesired low molecular weight
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polymer is formed
S. Emulsion IV. Polymer concentraon in the product stream is low
(A) P-I, Q-II, R-III, S-IV (B) P-II, Q-I, R-III, S-IV

(C) P-I, Q-II, R-IV, S-III (D) P-III, Q-II, R-IV, S-I

14. Match each of the polymers in Group I, with the raw material in Group II from which they are made
[GATE:2010]

Group I Group II
P. Polyster I. Ethylene glycol
Q. Polyamide II. Adipic Acid
R. Viscose Rayon III. Cellulose
S. Epoxy Resin IV. Bisphenol
(A) P-I, Q-II, R-III, S-IV (B) P-II, Q-I, R-III, S-IV

(C) P-I, Q-II, R-IV, S-III (D) P-III, Q-II, R-IV, S-I

15. Match the polymerizaon mechanisms in Group I with the corresponding polymers in Group II.
[GATE:2011]

Group I Group II
P. Chain growth/addition polymerization I. Polyethylene
Q. Step growth / condensation polymerization II. Polyvinyl chloride
III .Polyethylene terephthalate
(A) P – III ; Q – I, II (B) P – I, II ;Q – III, (C) P – II, III, Q – I (D) P – I, Q –II, III

16. Match the polymer in Group I to the polymer characteristic in Group II [GATE:2012]

Group I Group II
P. Polyethylene I. Elastomer
Q. Phenol-formaldehyde polymer II. Fiber
R. Polyisoprene III. Thermoplastic
S. Polyster IV. Thermosetting Polymer
(A) P-III, Q-IV, R-I, S-II (B) P-IV, Q-II, R-III, S-I

(C) P-III, Q-II, R-I, S-IV (D) P-IV, Q-III, R-I, S-II

17. Match the raw materials of Groups 1 and 2 with the final products of Group 3 [GATE:2014]

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18. Match the polymer mentioned on the le with the catalyst used for its manufacture given on the right
[GATE:2015]

Group I Group II
(I) Low density Polyethylene (P) Ziegler-Natta catalyst
(II) High density Polyethylene (Q) Traces of Oxygen
(III) Polyethylene Terephthalate (R) Butyl Lithium
(IV) Polyvinyl Chloride (S) Antimony
(A) I-Q, II-R, III-S, IV-P (B) I-S, II-P, III-Q, IV-R

(C) I-Q, II-P, III-S, IV-R (D) I-S, II-R, III-P, IV-Q

19. Match the polymerization processes in Group-1 with the polymers in Group-2 [GATE:2017]

Group I Group II
P) Free radical polymerizaon I) Nylon 6.6
Q) Ziegler Naa polymerizaon II) Polypropylene
R) Condensaon polymerizaon III) Poly vinyl chloride
Choose the correct set of combinations

(A) P-I, Q-II, R-III (B) P-III, QII, R-I (C) P-I, Q-III, R-II (D) P-II, Q-I, R-III

20. Polyvinyl chloride is produced by [GATE:2018]

(A) co-polymerization (B) addition-type kinetics

(C) reacting chlorine with polyethylene (D) reacting hydrochloric acid with polyethylene

21. Choose the correct statement In viscose rayon manufacturing process, [GATE:2018]

(A) carbon disulphide used as reactant for xanthate formation is regenerated in a later step

(B) caustic soda used as reactant for steeping of cellulose is regenerated in a later step

(C) sulphuric acid is used in steeping process of cellulose

(D) the spun viscose rayon is haredened in an alkali bath

22. The combination that correctly matches the polymer in Group-1 with the polymerization reaction
type in Group-2 is [GATE:2019]

Group I Group II
P) Nylon I) Condensation polymerization
Q) Polypropylene II) Ring opening polymerization
R) Polyester III) Addition polymerization
(A) P-II, Q-I, R-III (B) P-I, Q-III, R-II (C) P-III, Q-II, R-I (D) P-II, Q-III, R-I

23.
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PETROLEUM

24. Catalyst for platforming of petroleum feedstock is, [GATE:1990]

(A)Pt + Re
(B) Pt + Rh
(C) Pt
(D) Pt + CO

25. Select the appropriate name from the right hand column against the processes mentioned:
[GATE:1992]

(I) H2 from light petroleum stock (A) Pyrolysis


(II) High octane gasoline from naphtha (B) Catalytic cracking
(III) Gasoline from gas oil (C) Platforming
(IV) Petroleum coke from residue (D) Stream reforming of naphtha
26. Which of the following fuels has the highest calorific value per unit mass? [GATE:1994]
(A) Coal
(B) Kerosene
(C) Natural gas
(D) Furnace oil

27. [GATE:1994]

(I) Catalytic cracking (A) Kerosene


(II) Catalytic reforming (B) Gasoline
(C) Aromatics
(D) Diesel

28. Match the reactions with names. [GATE:1994]

(I) CO + H2O = CO2 + H2. (A) Boudard reaction


(II) CH4 + H2O = CO + 3H2 (B)Water gas shift reaction
(C) Water gas reaction
(D) Steam reforming

29. During coking of coal, the ash content (percentage) [GATE:1995]

(A) increases (B) decreases (C) remains constant

30. [GATE:1995]

(I) catalytic reforming (A) high speed diesel


(II) smoke point (B) kerosene
(C) gasoline

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31. [GATE:1997]

i) LPG A) CO, CO2, H2


ii) Synthesis gas B) C2H4, C3 H8
C) C3 H8, C4H10
D) CO, H2

32. Which of the following gaseous fuels is likely to have the highest Gross Calorific value? [GATE:1998]

A) Sewage Gas B) LPG

C) Producer Gas D) Natural Gas

33. The gas which contributes the maximum to the heating value of natural gas is [GATE:1999]

A) CO B) CO2 C) H2 D) CH4

34. In petroleum refining, the process used for conversion of hydrocarbons to aromatics is [GATE:2000]

A) catalytic cracking B) catalytic reforming


C) hydrotreating D) alkylation

35. Synthesis gas is a mixture of [GATE:2001]

A) CO and H2, B) N2 and H2

C) H2, CH4 and CO, D) CO2 and H2

36. In the fluid catalytic cracker (FCC), the cracking reaction is – (A) – and the regeneration is – (B) –
[GATE:2001]

A) (A) Exothermic (B) Endothermic B) (A) Exothermic (B) Exothermic

C) (A) Endothermic (B) Endothermic D) (A) Endothermic (B) Exothermic

37. The average boiling point of aviation turbine fuel is closest to that of [GATE:2002]

A) Lubricating oils B) LPG C) Diesel D) Kerosene

38. In a refinery, petroleum crude is fractionated into gas fraction, light ends, intermediate distillates,
heavy distillates, residues and by products. The group of products including gas oil, diesel oil and
heavy fuel oil belongs to the fraction. [GATE:2003]

a) heavy distillates b) intermediate distillates

c) light ends d) residues,

39. The order of preference for feedstock to a catalytic reformer is [GATE:2003]

a) catalytic naphtha coking naphtha virgin naphtha

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b) Coking naphtha virgin naphtha catalytic naphtha

c) virgin naphtha catalytic naphtha coking naphtha

d) virgin naphtha coking naphtha catalytic naphtha

40. The proper arrangement of the petroleum fractions, in the order of their boiling points is
[GATE:2004]
(A) lubricating oils > diesel > petrol > LPG
(B) lubricating oils > petrol > diesel > LPG
(C) petrol > lubricating oils > diesel > LPG
(D) petrol > diesel > LPG > lubricating oil
41. Match the feed in GROUP-I with process in GROUP-II [GATE:2005]

GROUP-I GROUP-II
P. Gas oil (1) Acetylene
Q. Residual crude (2) Ethylene
(3) Coking
(4) Cracking

42. In a fluid catalytic cracking unit, the nature of the reactions occurring in the reactor and the
regenerator is
(A) Reactor – Exothermic, Regenerator – Exothermic [GATE:2006]
(B) Reactor – Exothermic, Regenerator – Endothermic
(C) Reactor – Endothermic, Regenerator – Exothermic
(D) Reactor – Endothermic, Regenerator – Endothermic
43. Which of the following is desirable in gasoline but undesirable in kerosene? [GATE:2007]

(A) Aromatics (B) Mercaptans

(C) Naphthenic Acid (D) Paraffins

44. Which ONE of the following is NOT a major constituent of crude oil? [GATE:2008]
(A) Paraffins (B) olefins
(C) Naphthenes (D) Aromatics
45. Which ONE of the following process sequences is used in the production of synthesis gas?
[GATE:2008]
(A) Desulphurization  steam reforming  hot K2CO3 cycle
(B) Steam reforming  Desulphurization  Hot K2CO3 cycle
(C) Hot K2CO3 cycle  Steam reforming  Desulphurization
(D) Hot K2CO3 cycle  Desulphurization  Steam reforming
46. In petroleum refining operations, the process used for converting paraffins and naphthenes to
aromatics is
(A) Catalytic reforming (B) Catalytic cracking [GATE:2009]
(C) Hydrocracking (D) Alkylation
47. The active component of catalysts used in steam reforming of methane to produce synthesis gas is

(A) Nickel (B) Iron [GATE:2009]

(C) Platinum (D) Palladium

48. Which ONE of the following sequences is arranged according to INCREASING calorific value?
[GATE:2011]
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(A) Producer gas, Natural gas, Water gas (B) Natural gas, Producer gas, Water gas
(C) Producer gas, Water gas, Natural gas (D) Water gas, Natural gas, Producer gas
49. Hydrotreating is used for [GATE:2011]

(A) removal of water from crude oil, (B) treatment of crude oil with water

(C) improving octane number of gasoline, (D) removal of sulphur and nitrogen from
petroleum fractions

50. Zeolite ZSM-5 is added to commercial FCC catalyst for [GATE:2011]


(A) promoting SO2 reduction (B) promoting CO oxidation
(C) improving tolerance to metal content in feed (D) enhancing Octane number
51. In petroleum refining, catalytic reforming is used to convert [GATE:2012]

(A) Paraffins and naphthenes to aromatics (B) Gas oil to Diesel and gasoline

(C) Paraffins to hydrogen and carbon monoxide (D) Light olefins to gasoline

52. The final boiling points of gasoline, diesel, atmospheric gas oil (AGO) and lubricating oils vary as
[GATE:2012]
(A) gasoline > diesel > AGO > lubricating oils (B) lubricating oils > AGO > diesel > gasoline
(C) AGO > lubricating oils > diesel > gasoline (D) lubricating oils > diesel > AGO > gasoline
53. The main unit processes used for the production of hydrogen from natural gas are stream
reforming (SR), pressure swing adsorption (PSA), low temperature water gas shift reaction (LT
WGS) and high temperature water gas shift reaction (HT WGS). The correct sequence of these in the
plant is [GATE:2012]
(A) SR; LT WGS; HT WGS; PSA (B) PSA; SR; LT WGS; HT WGS

(C) SR; HT WGS; LT WGS; PSA (D) PSA; HT WGS; LT WGS; SR

54. Catalytic cracking is [GATE:2014]


(a) a hydrogen addition process (b) a carbon rejection process
(c) an exothermic process (d) a coking process
55. Which ONE of the following statement is CORRECT? [GATE:2014]
(a) The major components of biodiesel are triglycerides
(b) Biodiesel is essentially a mixture of ethyl esters
(c) Biodiesel is highly aromatic
(d) Biodiesel has a very low aniline point
56. Select the WRONG statement regarding water gas shift converters from the list below:
[GATE:2015]
(a) Inter-stage cooling is provided between the two stages of shift converters.
(b) Usually high temperature shift (HTS) reactor has a iron-based catalyst and low temperature shift (LTS)
reactor has a copper-based catalyst
(c) HTS reactor is followed by LTS reactor
(d) LTS reactor is followed HTS reactor
57. India has no elemental sulphur deposits that can be economically exploited. In India, which one of
the following industries produces elemental sulphur as a by-product? [GATE:2016]

(A) Cost carbonization plants (B) Petroleum refineries.

(C) Paper and pulp industries (D) Iron and steel making plants

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58. Producer gas is obtained by [GATE:2019]

(A) passing air through red hot coke (B) thermal cracking of naphtha

(C) passing steam through red hot coke (D) passing air and steam through red hot coke
59. In petroleum refining operations, the process used for converting paraffins and naphthenes to
aromatics is [GATE:2019]

(A) alkylation (B) catalytic reforming (C) hydrocracking (D) isomerization

60. [GATE:2020]

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Natural Products
Sulphuric Acid, Nitric acid & Phosphoric Acid

61. Indicate the most appropriate material for the handling of the chemicals as given below:
[GATE:1992]

Chemicals Materials

(I) Dilute Sulphuric acid (A) Karbate


(II) Concentrated hydrochloric acid (B) Nickel

(III) Wet chlorine (C) Lead

(IV) Concentrated caustic soda (D) Titanium

62. Double contact double absorption process is used for the manufacture of __________

[GATE:1994]

63. A suitable material of construction to use with fuming sulphuric acid is


[GATE:1996]

A) carbon steel B) stainless steel type 304

C) nickel D) monel

64. The preferred material of construction for storage tanks for 98% sulphuric acid is
[GATE:1998]

A) Aluminium B) Lead

C) Stainless steel 316 D) Mild steel

65. In the converter of the contact process for the manufacture of H2SO4, the equilibrium
conversion of SO2 (a) with increase in the temperature and (b) with increase in the mole
ratio of SO2 to air. [GATE:2001]
A) (a) increases (b) decreases B) (a) decreases (b) increases
C) (a) increases (b) increases D) (a) decreases (b) decreases

Paper and Pulp


66. In the sulphite process for paper manufacturing, the ‘cooking liquor’ is [GATE-2007]
(a) magnesium bisulphate and sulphur dioxide in acid medium
(b) magnesium sulphite and magnesium dicabonate
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(c) sodium sulphite and magnesium sulphite
(d) sodium sulphite and sodium bisulphate and sulphur dioxide
67. Two paper pulp plants P and Q use the same quality of bamboo as a raw material. The chemical
used in their digester are as follows : [GATE-2016]
Plant P Plant Q
NaOH Yes No
Na2S Yes No
Na2CO3 Yes Yes
NaHCO3 No Yes
Na2SO3 No Yes
Which one of the following statements is CORRECT ?
(a) Plant P and Plant Q both use the Sulfite process
(b) Plant P and Plant Q both use the Kraft process
(c) Plant P uses Sulfite process
(d) Plant P uses Kraft process
68. In Kraft process, the essential chemical reagents used in the digester are
[GATE-2019]

(A) caustic soda, mercaptans and ethylene oxide

(B) caustic soda, sodium sulphide and soda ash

(C) quick lime, salt cake and dimethyl sulphide

(D) baking soda, sodium sulphide and mercaptans

Sugar Industry

67. One of the steps during refining of cane sugar consists of addition of hydrated lime to the
sugar syrup followed by carbonation of the resulting solution. The purpose of this step is to
[GATE-2001]

A) Adjust the pH of the syrup

B) Reduce the viscosity of the syrup

C) Remove the coloring matter from the syrup

D) Improve the rate of crystallization of sugar

68. Multiple effect evaporators are used in manufacturing of [GATE-2004]


P. paper Q. superphosphate R. sugar S. fats
(A) P and Q (B) P and R (C) P and S (D) R and S

69. Which one of the following process sequence is used in the sugar industry?
[GATE-2008]

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(A) Ca2HPO4/ Lime treatment → Crystallization → Crushing
(B) Ca2HPO4/ Lime treatment → Multiple stage evaporation → Crystallization
(C) Crushing→ Crystallization→ Ca2HPO4/ Lime treatment
(D) Multiple stage evaporation → Crystallization →Ca2HPO4/ Lime treatment
70. The molecular formula of the predominant chemical compound in commercial sugar
is[GATE-2018]
(A) C12H22 O11 (B) C12H24O12 (C) C6H10O5 (D) C6H12O6

Fertilizer Industry

71. Triple superphosphate is manufactured by reacting –


[GATE-2000]

A) phosphate rock with phosphoric acid

B) phosphate rock with sulphuric acid

C) phosphate rock with nitric acid

D) ammonium phosphate with phosphoric adid

72. Prilling tower is found in the flow sheet for the manufacturing of [GATE-2004]
(A) Ammonia (B) Urea (C) Superphosphate (D) Triple superphosphate
73. For making superphosphate by acidulation of phosphate rock, use of nitric acid is desirable
because [GATE-2010]
(A) nitric acid is less expensive than sulphuric acid
(B) the availability of nitrogen enhances the value of the superphosphate
(C) the process produces non-hygroscopic superphoshate
(D) the process produces superphosphate having higher phosphorurs content then the sulphuric
acid
74. Match the chemical written on the left with the raw material required to produce them
mentioned on the right [GATE-2015]
Column I Column II
P. Single Superphosphate (SSP) I Rock phosphate + Sulfuric Acid + Ammonia
Q. Triple Superphosphate (TSP) II Brine
R. Diamonium phosphate (DAP) III Rock phosphate + Sulphuric Acid
S. Caustic soda IV Rock phosphate + Phosphoric Acid

69. [GATE-2020]

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HYDROGENATION OF OIL

75. Hydrogenation of edible oils is done to, [GATE-1993]

(A) decrease the number of unsaturated bond

(B) lower the melting point of oil

(C) increase the thermal conductivity of oil

(D) enable the oil to be packed in tin containers

76. Match the appropriate catalyst with the process. [GATE-1994]


(I) Hydrogenation of vegetable oils (A) Iron
(II) Ammonia synthesis (B) Platinum
(C) Nickel
(D) Zeolites

77. Which one of the following is not likely to be a constituent of vegetable oils ?
[GATE-1999]

A) citric acid B) oleic acid

C) stearic acid D) glycerol

78. For the hydrogenation of oils, (a)is commonly used as catalyst, and -(b)-is a catalyst poison.
[GATE-2001]
A) (a) Platinum (b) Sulphur B) (a) Palladium (b) Oxygen
C) (a) Nickel (b) Sulfur D) (a) Nickel (b) Oxygen

Soap & Detergent

79. A bio-degradable detergent is one which, [GATE-1993]

(A) is manufactured using biotechnology

(B) contains straight chain alkyl benzene

(C) contains branch chain alkyl benzene

(D) is easily decomposed by microorganisms

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80. Which of the following is a detergent ? [GATE-2005]
(A) Benzene hex chloride (B) Cellulose nitrate
(C) Polyvinyl chloride (D) Alkyl benzene sulphonate

Chlor-alkali Industry

81. Solvay process is used for the manufacture of, [GATE-1994]

(A). Caustic soda

(B) Soda ash

(C) Caustic potash

(D) Soda lime

70. [GATE-2020]

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