QUIZ (CHEMISTRY)

HYDROCARBONS
NAME: ………………................ M.MARKS: M.Time: minutes SUB: CHEMISTRY
1. In the reaction CH3CHCH3 Br2
 X (major product ) X would be
 hv
CH3

CH3 CH3
(A) (B)
CH3CH CH3CBr
CH2Br CH3
CH3 CH3
(C) (D)
CH2CCH3 CH2CCH2
Br Br Br Br

2. The compound with the highest boiling point is

(A) n-Hexane (B) n-Pentane
(C) 2,2 Dimethyl propane (D) 2-Methyl butane

2 4 dil H SO
3. CH3CCH   
  X, X would be
HgSO4

O

(A) CH3CCH3 (B) CH3CH2CHO
O O
 
(C) CH3CCH (D) none of the above

H2 Pd / BsSO4
   X
Quinoline

4. CH3CCCH3
NaNH2
  Y
Na

(A) both X and Y are Cis-2-butenes (B) X is cis-2-butene and Y is trans -2-butene
(C) X is trans 2-butane and Y cis-2-butene (D) None

HCl
5. CH3CCH  X
2 equivalent s

(A) CH3CHCH3 (B) CH3CHCH2

Cl Cl Cl
Cl
Cl
(C) CH3CCH3 (D) CH3CH2CH
Cl Cl
Cl

6. Na / ether

Cl (1 molecule)

(A) (B)

(C) (D)
 QUIZ (CHEMISTRY)

7. , A when subjected to monobromination (in presence of h) product will be :

(A)
Br

(A) (B)

Br
Br Br
Br

(C) (D)

8. A mixture of ethyl bromide and n-propylbromide is subjected to Wurtz reaction. The hydrocarbon
that will not be formed is
(A) n-butane (B) n-propane (C) n-pentane (D) n-hexane
9. What will be product formed

(
i ) Br2 / light
 NBS
A  B
( ii ) ( CH 3 )3 COK CCl4
( CH 3 )3 COH
Br
(A)  (B)
Br
A= , B= A= , B= 
Br Br
(C)  (D) 

A= , B=  A=  , B=  

10. CH3CH=CH OH + HBr gives

(A) CH3CHBrCH2 OH (B) CH3CHBrCH2 Br

(C) CH3CH2CHBr OH (D) CH3CH2CHBr Br

11. Ethylene can be prepared by electrolysis of an aqueous solution

(A) Sodium acetate (B) Sodium succinate (C) Sodium fumarate (D) Sodium propionate
12. Addition of HBr on CHCCH2CH=CH2 and CHCCH=CH2 separately gives
(A) CH2=CCH2CHBrCH2 & CH2=CCH=CH2

Br
(B) CH2=CCH2CHBrCH2 & CH2 =CCH=CH2
 
Br Br
(C) CH=CCH2CHCH3 & CH2 =CCH=CH2
 
Br Br
(D) None
 QUIZ (CHEMISTRY)
13. A Hydrocarbon absorbs only one molecule of H2 upon catalytic hydrogenation, Upon ozonolysis
the hydrocarbon gives
H H
 
O=CCH2CH2CH2 CH2C=O. The hydrocarbon is
(A) Benzene (B) Cyclohexene (C) Cyclohexane (D) 2,3, methyl cyclobutane
14. What are the major products obtained from the following structures by dehydration?

CH2OH,
OH

(A) & (B) & 

(B) & (D) None of these

15. Predict the product formed

CH3
KMnO OH 
4
 A
H

(B)
(A) CH3C(CH2)3CCH3
CH3C(CH2)4COOH  
 O O
O
(D)
CH3C(CH2)4CH3
(C) 
HCOO (CH2)4COOH O

16. Which is the most suitable reagent among the following to distinguish compound (3) from the rest
of the compounds?
(I) CH3 C  C  CH3 (II) CH3 CH2  CH2  CH3 (III) CH3 CH2 C  CH (IV) CH3 CH  CH2
(A) Bromine in carbon tetrachloride (B) Bromine in acetic acid solution
(C) Alk. KMnO4 (D) Ammonical silver nitrate
17. Which one of the following compounds will react with methylmagnesium iodide?
(A) CH3CH2CH2CH2CH3 (B) CH3 CH  CH  CH  CH2
(C) CH3  C  C  CH2 CH3 (D) CH3 CH2 CH2 C  CH

18. HgSO4 / H2 SO4

 X
1-pentyne

BH3 .THF / H2 O2 , OH
  Y
X and Y can be distinguished by:
(A) silver-mirror test (B) iodoform test (C) both of these (D) none of these

19. 
CH3 CH2 C  CH   A
 CH3 C  CCH3 , A and B are:
B

(A) alcoholic KOH and NaNH2 (B) NaNH2 and alcoholic KOH
(C) NaNH2 and Lindlar (D) Lindlar and NaNH2
20. The most reactive alkene towards the addition of HBr is
CH3
CH3

(A) (B)
O 2N
OH
CH3 CH3

(C) (D)
HO
 QUIZ (CHEMISTRY)
21. Which of the following will undergo faster dehydro-bromination?
Br Br

(A) (B)

Br Br

(C) (D)

3 Na  liq. NH
2 Br
22. In the reaction, Me  C  C  Et     P (pure or mixture)
the product P is:
(A) A pure compound which is optically inactive due to internal compensation
(B) A binary mixture which is optically inactive due to external compensation
(C) A binary mixture which is optically active
(D) A pure compound which is optically inactive due to absence of chiral reaction

23. C 6 H5

H3C H alcoholic KOH

E
 A. A is
2
Br H

C 6 H5
H3C C 6 H5 H3C C6 H5

(A) (B)
H C 6 H5 H5 C6 H
H CH3

(C) (D) None is correct

H5 C6 C6 H5

Paraffin
24. 2-butyne + NaNH2   X + NH3 , X will be
(A) sodium salt of 2-butyne (B) sodium salt of 1-butyne
(C) 2-butyne (D) 1-butyne

25.
conc. H2 SO4 Pt / H2
   A   B


A and B are
(A)
,

(B)
,

(C)
,

(D)none

26. The addition of Br2 to trans–2–butene produces

(A) (+) 2, 3 –dibromobutane (B) (-) 2, 3–dibromobutane
(C) rac –2, 3 –dibromobutane (D) meso–2. 3–dibromobutane

27. Cl3CCH=CH2 + HOBr  Y,

Y would be
(A) Cl3CCH(OH)CH2Br (B) Cl3CCH(Br)CH2OH
(C) Cl3CCH(Br)CH2Br (D) Cl3CCH(OH)CH2OH
 QUIZ (CHEMISTRY)
H2 / Ni HBr Me2NH 3 CH I
28. CH3CCCH3   CH3CH=CHCH3  U   V   W
AgOH / AgI Br2
   X  Y
 AlC.KOH & NaNH 2
X and Y would respectively be Y
(A) 1-butene and 1-butyne (B) 1-butyne and 1-butene
(C) 1-butane and 1-butene (D) none of the above

H O di / H SO
29. What is the end product of the following sequence of operations CaC2 2 A 
2

4

Hg2 
Ni / H2
B    C
(A) methyl alcohol (B) ethyl alcohol
(C) acetaldehyde (D) ethylene

30. In the following sequence the product D is

HBr HBr AlC.KOH NaNH2
CHCH   A  B   C   D
(A) ethanol (B) ethane
(C) ethyne (D) ethenal


QUIZ (CHEMISTRY)
ANSWERS
HYDROCARBONS
1. B 2. A 3. A 4. B

5. C 6. B 7. B 8. B

9. C 10. C 11. C 12. A

13. B 14. A 15. A 16. D

17. D 18. C 19. A 20. C

21. D 22. A 23. B 24. B

25. D 26. D 27. B 28. A

29. B 30. C