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    CHEMISTRY

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    Pisces Sand
    The document contains 19 chemistry problems involving calorimetry, enthalpy change, Hess' Law, entropy, Gibbs free energy, and equilibrium constants. The problems calculate temperature changes, enthalpy values, entropy values, Gibbs free energy values, and equilibrium constants for various chemical reactions using provided data and thermodynamic equations.

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    CHEMISTRY

    Uploaded by

    Pisces Sand
    17 views3 pages
    The document contains 19 chemistry problems involving calorimetry, enthalpy change, Hess' Law, entropy, Gibbs free energy, and equilibrium constants. The problems calculate temperature changes, enthalpy values, entropy values, Gibbs free energy values, and equilibrium constants for various chemical reactions using provided data and thermodynamic equations.

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    The document contains 19 chemistry problems involving calorimetry, enthalpy change, Hess' Law, entropy, Gibbs free energy, and equilibrium constants. The problems calculate temperature changes, enthalpy values, entropy values, Gibbs free energy values, and equilibrium constants for various chemical reactions using provided data and thermodynamic equations.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    17 views3 pages

    CHEMISTRY

    Uploaded by

    Pisces Sand
    The document contains 19 chemistry problems involving calorimetry, enthalpy change, Hess' Law, entropy, Gibbs free energy, and equilibrium constants. The problems calculate temperature changes, enthalpy values, entropy values, Gibbs free energy values, and equilibrium constants for various chemical reactions using provided data and thermodynamic equations.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    Chem

    Calorimetry Problems

    1. How many milliliters of water at 23 °C with a density of 1.00 g/mL must be mixed with
    180 mL (about 6 oz) of coffee at 95 °C so that the resulting combination will have a
    temperature of 60 °C? Assume that coffee and water have the same density and the
    same specific heat (4.184 J/g °C).

    2. How much will the temperature of a cup (180 g) of coffee at 95 °C be reduced when
    a 45 g silver spoon (specific heat 0.24 J/g °C) at 25 °C is placed in the coffee and the
    two are allowed to reach the same temperature? Assume that the coffee has the
    same density and specific heat as water.

    3. A 45-g aluminum spoon (specific heat 0.88 J/g °C) at 24 °C is placed in 180 mL (180
    g) of coffee at 85 °C and the temperature of the two become equal. What is the final
    temperature when the two become equal? Assume that coffee has the same specific
    heat as water.

    Enthalpy Change
    4. When 1.34 g Zn(s) reacts with 60.0 mL of 0.750 M HCl(aq), 3.14 kJ of heat are
    produced. Determine the enthalpy change per mole of zinc reacting for the reaction:
    Zn(s)+2HCl(aq)⟶ZnCl(aq)+H2(g)

    5. When 1.42 g of iron reacts with 1.80 g of chlorine, 3.22 g of FeCl2(s) and 8.60 kJ of
    heat is produced. What is the enthalpy change for the reaction when 1 mole of
    FeCl2(s) is produced?
    6. How much heat is produced by burning 4.00 moles of acetylene under standard state
    conditions?
    7. How much heat is produced by combustion of 125 g of methanol (CH3OH) under
    standard state conditions?
    8. How many moles of isooctane must be burned to produce 100 kJ of heat under
    standard state conditions?
    9. What mass of carbon monoxide must be burned to produce 175 kJ of heat under
    standard state conditions?
    10. When 2.50 g of methane burns in oxygen, 125 kJ of heat is produced. What is the
    enthalpy of combustion per mole of methane under these conditions?
    11. A sample of 0.562 g of carbon is burned in oxygen in a bomb calorimeter, producing
    carbon dioxide. Assume both the reactants and products are under standard state
    conditions, and that the heat released is directly proportional to the enthalpy of
    combustion of graphite. The temperature of the calorimeter increases from 26.74 °C
    to 27.93 °C. What is the heat capacity of the calorimeter and its contents?

    Hess' Law
    12. 2CO(g) + O2(g) → 2CO2(g) ΔH = ?

    (i) C(s) + O2(g) → CO2(g) ΔH = -393.5 kJ


    (ii) 2C(s) + O2(g) → 2CO(g) ΔH = -221.0 kJ
    13. 2S(s) + 3O2(g) → 2SO3(g) ΔH = ?

    (i) S(s) + O2(g) → SO2(g) ΔH = -297 kJ


    (ii) 2SO3(g) → 2SO2(g) + O2(g) ΔH = 198 kJ

    14. 4NH3(g) + 5O2(g) → 4NO(g) + 6H2O(g), ΔH = ?

    i) N2(g) + 3H2(g) → 2NH3(g), ΔH = -92 kJ


    ii) 2H2(g) + O2(g) → 2H2O(g), ΔH = -484 kJ
    ii) N2(g) + O2(g) → 2NO(g), ΔH = 181 kJ

    15. Calculate ΔH for the process

    Hg2Cl2(s)⟶2Hg(l)+Cl2(g)

    from the following information:

    Hg(l)+Cl2(g)⟶HgCl2(s)ΔH=−224kJ

    Hg(l)+HgCl2(s)⟶Hg2Cl2(s)ΔH=−41.2kJ

    Entropy
    16. Given the reaction at 298 K;
    4NH3(g)+5O2(g)→4NO(g)+6H2O(l)
    Determine the S

    Gibbs Free Energy, Keq


    17. Given the dissolving of CaCl2(s)

    CaCl2(s)→Ca2+(aq)+2Cl−(aq)(7.E.3)
    the ΔG°f of CaCl2 (s)= -748.1 kJ/mol,
    the ΔH of CaCl2= -795.8 kJ
    ΔSo
    Ca2+=-53.1 J/Kmol,
    CaCl2=104.6 J/Kmol,
    Cl-=56.5
    Calculate the temperature of this reaction.

    18. Assess the feasibility of the reaction below by evaluating ΔSorxn, ΔHorxn, and ΔGorxn
    for this reaction at 25°C. If the reaction is spontaneous, is it enthalpically favored,
    entropically favored or both?
    (NH)4Cl(s)→NH3(g)+HCl(g)

    19. Determine the Kp at 298.15 K for the reaction: 2CO(g)+O2(g)⇌2CO2


    Ama namin, sumasalangit Ka.
    Sambahin ang ngalan Mo.
    Mapasaamin ang kaharian mo
    Sundin ang loob Mo dito sa lupa para nang sa langit.

    Bigyan Mo kami ng aming kakanin sa araw-araw


    At patawarin Mo kami sa aming mga sala
    Para nang pagpapatawad namin sa nagkakasala sa amin.
    At huwag Mo kaming ipahintulot sa tukso
    At iadya Mo kami sa lahat ng masama

    AMEN 👏

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