The Hartridge Building

Network 421
Radclive Road
Buckingham
MK18 4FD
United Kingdom
Tel: +44 (0)1280 825600
Fax: +44 (0)1280 825601
Email: sales@hartridge.com
Web: www.hartridge.com
SAFETY DATA SHEET
Hartridge ISO4113 AW2 Cal Fluid
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND
COMPANY/UNDERTAKING

Product identifier
Trade name: Viscor 1487 AW-2

Relevant identified uses of the substance or mixture and uses advised against

Identified uses: Specialties fluid

Uses advised against: No uses advised against identified.

Details of the supplier of the safety data sheet

PRODUCT NAME Hartridge ISO4113 AW2 Cal Fluid

PRODUCT NO. 8802011-20
INTERNAL ID 8802011-20
APPLICATION Calibration Fluid
SUPPLIER Hartridge Limited
The Hartridge Building, Network 421,
Radclive Road, Gawcott.
Buckingham, England.
MK18 4FD
Tel: ++44 (0) 1280-825600
Fax: ++44 (0) 1280-825601
Enq : sales@hartridge.com

CONTAINER SIZE 20 Litres

2 HAZARDS IDENTIFICATION
Classification of the substance or mixture

The product has been classified and labelled as hazardous according to regulation (EU) 1272/2008 (CLP).

Classification according to Regulation (EC) No 1272/2008 as amended.

Health Hazards
Skin irritation Category 2 H315: Causes skin irritation.

Aspiration Hazard Category 1 H304: May be fatal if swallowed and enters airways.

Environmental Hazards
Chronic hazards to the aquatic Category 3 H412: Harmful to aquatic life with long lasting effects.
environment

Hazard summary
Physical Hazards: Can form flammable vapour-air mixtures during the application.

HART MSDS-004 – Iss 2 Page 1

Review date: 02/07/2018
 The Hartridge Building
Network 421
Radclive Road
Buckingham
MK18 4FD
United Kingdom
Tel: +44 (0)1280 825600
Fax: +44 (0)1280 825601
Email: sales@hartridge.com
Web: www.hartridge.com
Health Hazards:

Skin Contact: At long or repeated contact with skin it may cause dermatitis due to the
degreasing effect of the solvent.

Ingestion: If ingested, material may be aspirated into the lungs and cause
chemical pneumonitis. Treat appropriately.

Label elements
Labelling (REGULATION (EC) No 1272/2008)
Hazard pictograms:

Signal Words: Danger

Hazard Statement(s): H304: May be fatal if swallowed and enters airways.

H315: Causes skin irritation.
H412: Harmful to aquatic life with long lasting effects.

Precautionary Statement
Prevention: P262: Do not get in eyes, on skin, or on clothing.
P273: Avoid release to the environment.

Response: P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or

doctor/physician.
P331: Do NOT induce vomiting.

Disposal: P501: Dispose of contents/container to an appropriate treatment and disposal facility in

accordance with applicable laws and regulations, and product characteristics at time of
disposal.

Supplemental label information

EUH208: Contains Calcium Sulfonate. May produce an allergic reaction.

EUH066: Repeated exposure may cause skin dryness or cracking.

Other hazards: By handling of mineral oil products and chemical products no particular hazard is known
when normal precautions (item 7) and personal protective equipment (item 8) are kept.
The product may not be released into the environment without control.

3 COMPOSITION/INFORMATION ON INGREDIENTS
Mixtures

General information: Mixture based on severely refined mineral base oils with corrosion preventive
agents and volatile hydrocarbons.

HART MSDS-004 – Iss 2 Page 2

Review date: 02/07/2018
 The Hartridge Building
Network 421
Radclive Road
Buckingham
MK18 4FD
United Kingdom
Tel: +44 (0)1280 825600
Fax: +44 (0)1280 825601
Email: sales@hartridge.com
Web: www.hartridge.com
Chemical Name Concentration* Identifier Reach Notes
Registration No.
Mixture of hydrocarbons, 20,00 - <50,00% EINECS: 265-149-8
disaromatized, low viscous
Base oil, low viscous 10,00 - <20,00% EC: 934-956-3 01-2119827000-58
Base oil, low viscous 10,00 - <20,00% EINECS: 265-148-2 01-2119489867-12
Calcium Sulfonate 1,00 - <5,00% EINECS: 263-093-9 01-2119488992-18
Barium compounds 1,00 - <5,00% EINECS: 263-140-3
Phenolic antioxidant agent 0,10 - <0,25% EINECS: 204-884-0 01-2119490822-33

*All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
PBT: persistent, bioaccumulative and toxic substance.
vPvB: very persistent and very bioaccumulative substance.

Classification

Chemical Name Identifier Classification

Mixture of hydrocarbons, EINECS: 265-149-8
disaromatized, low viscous
Base oil, low viscous EC: 934-956-3 CLP: Asp. Tox. 1;H304

Base oil, low viscous EINECS: 265-148-2 CLP: Asp. Tox. 1;H304, Acute Tox. 4;H332, Skin Irrit.
2;H315, Aquatic Chronic 2;H411
Calcium Sulfonate EINECS: 263-093-9 CLP: Skin Sens. 1B;H317

Barium compounds EINECS: 263-140-3 CLP: Acute Tox. 4;H302, Acute Tox. 4;H332

Phenolic antioxidant agent EINECS: 204-884-0 CLP: Aquatic Acute 1;H400, Aquatic Chronic 1;H410, Skin
Irrit. 2;H315

CLP: Regulation No. 1272/2008.

For the wording of the listed risk phrases refer to section 16.

4 FIRST-AID MEASURES

General advice: Instantly remove any clothing soiled by the product.

Description of first aid measures

Inhalation: Supply fresh air; consult doctor in case of symptoms.

Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do,
remove contact lenses. Get medical attention.

Skin contact: Immediately flush with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash contaminated clothing before reuse.
Get medical attention. Wash with water and soap; pay attention: skin
degreasing product.

Ingestion: Call a physician or poison control centre immediately. Rinse mouth. Never give
liquid to an unconscious person. If vomiting occurs, keep head low so that
stomach content doesn't get into the lungs.

HART MSDS-004 – Iss 2 Page 3

Review date: 02/07/2018
 The Hartridge Building
Network 421
Radclive Road
Buckingham
MK18 4FD
United Kingdom
Tel: +44 (0)1280 825600
Fax: +44 (0)1280 825601
Email: sales@hartridge.com
Web: www.hartridge.com

Protection of First-aiders: Use personal protective equipment.

Most important symptoms and effects, both acute and delayed

Causes skin irritation. If ingested, material may be aspirated into the lungs and cause chemical pneumonitis.
Treat appropriately. Headache.

Indication of any immediate medical attention and special treatment needed, if necessary

Hazards: No data available

Treatment: Get medical attention if symptoms occur.

High pressure injection injuries require prompt surgical intervention and possibly
steroid therapy, to minimise tissue damage and loss of function.
Because entry wounds are small and do not reflect the seriousness of the
underlying damage, surgical exploration to determine the extent of involvement
may be necessary. Local anaesthetics or hot soaks should be avoided because
they can contribute to swelling, vasospasm and ischaemia. Prompt surgical
decompression, debridement and evacuation of foreign material should be
performed under general anaesthetics, and wide exploration is essential.

5 FIRE-FIGHTING MEASURES
General Fire Hazards: Use water spray to keep fire-exposed containers cool.

Extinguishing media
Suitable extinguishing media: CO2, fire extinguishing powder or fog like water spraying. Extinguish larger fires with
alcohol resistant foam or spray water with suitable surfactant added.

Unsuitable extinguishing media: Water with a full water jet.

Special hazards arising from the substance or mixture

Specific hazards during
firefighting: Can form explosive vapour-air mixtures at higher temperatures.

Advice for firefighters

Special protective equipment
for firefighters: Self-contained breathing apparatus and full protective clothing must be worn in
case of fire.

Specific extinguishing methods: Move container from fire area if it can be done without risk. Dispose of fire
debris and contaminated firefighting water in accordance with official
regulations. Collect contaminated firefighting water separately. It must not enter
drains.

HART MSDS-004 – Iss 2 Page 4

Review date: 02/07/2018
 The Hartridge Building
Network 421
Radclive Road
Buckingham
MK18 4FD
United Kingdom
Tel: +44 (0)1280 825600
Fax: +44 (0)1280 825601
Email: sales@hartridge.com
Web: www.hartridge.com
6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

General Information: Do not touch damaged containers or spilled material unless wearing appropriate
protective clothing. Keep unauthorized personnel away. In case of spills, beware
of slippery floors and surfaces. Keep away from sources of ignition - No
smoking.

Environmental precautions
General Information: Avoid release to the environment. Prevent further leakage or spillage if safe to
do so. Prevent from spreading (e.g. by binding or oil barriers). Environmental
manager must be informed of all major spillages. Do not allow to enter drainage
system, surface or ground water.

Methods and materials for containment and cleaning up

Methods for cleaning up: Absorb with liquid-binding material (sand, diatomite, acidbinders, universal
binders, sawdust). Dispose of the material collected according to regulations.
Stop the flow of material, if this is without risk.

Reference to other sections: See Section 8 of the SDS for Personal Protective Equipment. See Section 7 for
information on safe handling See Section 13 for information on disposal.

Dike for later disposal. Prevent entry into waterways, sewer, basements or
confined areas. Stop the flow of material, if this is without risk.

7 HANDLING AND STORAGE

Precautions for safe Handling

Advice on safe handling: Avoid contact with skin. Wash hands thoroughly after handling. Do not eat, drink
or smoke when working with the product. Take usual precautions when handling
mineral oil products or chemical products. Use only in well-ventilated areas.
Risk of vapour concentration on the floor and in low-lying areas. Prevent
formation of aerosols. Observe good industrial hygiene practices. Provide
adequate ventilation.

Conditions for safe storage, including any incompatibilities

Technical measures/Storage
conditions: Store locked up. Local regulations concerning handling and storage of water
polluting products have to be followed. The precautions for storing and handling
of flammable liquids have to be kept. Local regulations for common storage of
flammable liquids have to be followed. Do not heat up to temperatures close to
the flash point..

Specific end use: Not applicable.

Storage class: 10, Combustible liquids

HART MSDS-004 – Iss 2 Page 5

Review date: 02/07/2018
 The Hartridge Building
Network 421
Radclive Road
Buckingham
MK18 4FD
United Kingdom
Tel: +44 (0)1280 825600
Fax: +44 (0)1280 825601
Email: sales@hartridge.com
Web: www.hartridge.com
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits

Chemical name Type Exposure Limit Values Source

Barium compounds - as TWA 0,5 mg/m3 UK. EH40 Workplace Exposure Limits
Ba (WELs) (12 2011)

Protective Equipment:

Process Conditions: Provide eyewash station.

Engineering measures Provide adequate ventilation. Ventilation rates should be matched to conditions.
If applicable, use process enclosures, local exhaust ventilation, or other
engineering controls to maintain airborne levels below recommended exposure
limits. If exposure limits have not been established, maintain airborne levels to
an acceptable level.

Individual protection measures, such as personal protective equipment

General Information Wash hands before breaks and after work. Use personal protective equipment
as required. Personal protection equipment should be chosen according to the
CEN standards and in discussion with the supplier of the personal protective
equipment. The usual precautionary measures should be adhered to in handling
the chemicals or the mineral oil products.

Eye/Face Protection Safety glasses (EN 166) recommended during refilling. Avoid contact with eyes.

Skin and body protection Wear suitable protective clothing. Protective shoes or boots. Long sleeved
clothing.

Hand Protection Material: Nitrile butyl rubber (NBR).

Min. Breakthrough time: >= 480 min
Recommended thickness of the material: >= 0,38 mm
Avoid long-term and repeated skin contact. Suitable gloves can be
recommended by the glove supplier. Use skin protection cream for preventive
skin protection. Protective gloves, where permitted in acc. to safety directions.
The exact break through time has to be found out by the manufacturer of the
protective gloves and has to be observed.

Other: Do not carry cleaning cloths impregnated with the product in trouser pockets.
Wear suitable protective clothing.

Respiratory protection Ensure good ventilation/exhaustion at the workplace. Avoid breathing vapour/
aerosol.

Thermal hazards: Not known.

Hygiene measures Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing to remove contaminants. Discard contaminated footwear
that cannot be cleaned.

HART MSDS-004 – Iss 2 Page 6

Review date: 02/07/2018
 The Hartridge Building
Network 421
Radclive Road
Buckingham
MK18 4FD
United Kingdom
Tel: +44 (0)1280 825600
Fax: +44 (0)1280 825601
Email: sales@hartridge.com
Web: www.hartridge.com

Environmental Controls: No data available.

9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance

Physical state: liquid

Form: liquid
Colour: Pale yellow
Odour: Characteristic
Odour Threshold: Not applicable for mixtures.
pH: not applicable

Freezing point: Not applicable for mixtures.

Boiling Point: 175 °C
Flash Point: 75 °C
Evaporation Rate: Not applicable for mixtures.
Flammability (solid, gas): Value not relevant for classification .
Flammability Limit - Upper (%)–: Not applicable for mixtures.
Flammability Limit - Lower (%)–: Not applicable for mixtures.
Vapour pressure: Not applicable for mixtures.
Vapour density (air=1): Not applicable for mixtures.
Density: 0,82 g/cm3 (15 °C)
Solubility(ies)
Solubility in Water: Insoluble in water
Solubility (other): No data available.
Partition coefficient (n-octanol/water): Not applicable for mixtures.
Auto-ignition Temperature: Value not relevant for classification .
Decomposition Temperature: Value not relevant for classification .
Kinematic viscosity: 2,5 mm2/s (40 °C)
Explosive properties: Value not relevant for classification .
Oxidizing properties: Value not relevant for classification .

Other Information: No data available.

10 STABILITY AND REACTIVITIES

Reactivity Stable under normal use conditions.

Chemical stability Stable under normal use conditions.

Possibility of hazardous reactions Stable under normal use conditions.

Conditions to avoid Stable under normal use conditions.

Incompatible materials Strong oxidizing substances. Strong acids. Strong bases.

Hazardous decomposition products Thermal decomposition or combustion may liberate carbon oxides and
other toxic gases or vapours.

HART MSDS-004 – Iss 2 Page 7

Review date: 02/07/2018
 The Hartridge Building
Network 421
Radclive Road
Buckingham
MK18 4FD
United Kingdom
Tel: +44 (0)1280 825600
Fax: +44 (0)1280 825601
Email: sales@hartridge.com
Web: www.hartridge.com
11 TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Principle Routes of Exposure

Inhalation No data available.
Ingestion No data available.
Eye Contact Causes skin irritation.
Skin Contact No data available.

Information on toxicological effects

Acute toxicity

Oral
Product: ATEmix: 23.299 mg/kg
Specified substance(s)
Mixture of hydrocarbons, LD 50 (Rat): > 2.001 mg/kg
disaromatized, low
viscous
Base oil, low viscous LD 50 (Rat): > 5.000 mg/kg
Calcium Sulfonate LD 50 (Rat): > 16.000 mg/kg

Dermal
Product:
Not classified for acute toxicity based on available data.

Specified substance(s)
Mixture of hydrocarbons, LD 50 (Rat): > 2.001 mg/kg
disaromatized, low
viscous
Base oil, low viscous LD 50 (Rabbit): > 2.001 mg/kg
Calcium Sulfonate LD 50 (Rat): > 4.000 mg/kg

Inhalation
Product: ATEmix: 8,91 mg/l
Dusts, mists and fumes

Specified substance(s)
Base oil, low viscous LC 50 (Rat, 4 h): > 1,78 mg/l
Dusts, mists and fumes

Skin Corrosion/Irritation:
Product: Based on available data, the classification criteria are met.

Serious Eye Damage/Eye Irritation:

Product: Based on available data, the classification criteria are not met.

Respiratory or Skin Sensitization:

Product: Skin sensitizer: Based on available data, the classification criteria are not met.
Respiratory sensitizer: Based on available data, the classification criteria are not
met.

Germ Cell Mutagenicity

Product: Based on available data, the classification criteria are not met.

Carcinogenicity

HART MSDS-004 – Iss 2 Page 8

Review date: 02/07/2018
 The Hartridge Building
Network 421
Radclive Road
Buckingham
MK18 4FD
United Kingdom
Tel: +44 (0)1280 825600
Fax: +44 (0)1280 825601
Email: sales@hartridge.com
Web: www.hartridge.com
Product: Based on available data, the classification criteria are not met.

Reproductive toxicity
Product: Based on available data, the classification criteria are not met.

Specific Target Organ Toxicity - Single Exposure

Product: Based on available data, the classification criteria are not met.

Specific Target Organ Toxicity - Repeated Exposure

Product: Based on available data, the classification criteria are not met.

Aspiration Hazard
Product: May be fatal if swallowed and enters airways.

Other Adverse Effects: No data available.

12 ECOLOGICAL INFORMATION
Toxicity

Acute toxicity
Product: Based on available data, the classification criteria are not met.

Fish
Specified substance(s)
Mixture of hydrocarbons, LC 50 (Fish, 96 h): > 101 mg/l
disaromatized, low
viscous
Base oil, low viscous LC 50 (Fish, 96 h): 1,13 - 65 mg/l

Chronic ToxicityProduct: Based on available data, the classification criteria are met.

Persistence and Degradability

Biodegradation
Product: Not applicable for mixtures.

Bioaccumulative Potential
Product: Not applicable for mixtures.

Mobility in Soil: Not applicable for mixtures.

Results of PBT and vPvB The product does not contain any substances fulfilling the PBT/vPvB criteria.
assessment:

Other Adverse Effects: Harmful to aquatic life with long lasting effects.

Water Hazard Class (WGK): WGK 2: water-endangering.

13 DISPOSAL CONSIDERATIONS

Waste treatment methods

General information Dispose in accordance with all applicable regulations.

HART MSDS-004 – Iss 2 Page 9

Review date: 02/07/2018
 The Hartridge Building
Network 421
Radclive Road
Buckingham
MK18 4FD
United Kingdom
Tel: +44 (0)1280 825600
Fax: +44 (0)1280 825601
Email: sales@hartridge.com
Web: www.hartridge.com

Waste Disposal Methods Discharge, treatment, or disposal may be subject to national, state, or local
laws.

European Waste Codes 13 07 03*: other fuels (including mixtures)

Remarks: Disposal should be in accordance with applicable regional, national, and local laws and regulations.
Classification of waste is always the responsibility of the end user.
Hazardous Waste (England and Wales) Regulations 2005.

14 TRANSPORT INFORMATION

ADR/RID
UN Number: –
UN Proper Shipping Name: –
Transport Hazard Class(es)
Class: Non-dangerous goods
Label(s): –
Hazard No. (ADR): –
Tunnel restriction code: –
Packing Group: –
Environmental hazards: –
Special precautions for user: –

IMDG
UN Number: –
UN Proper Shipping Name: –
Transport Hazard Class(es)
Class: Non-dangerous goods
Label(s): –
EmS No.: –
Packing Group: –
Environmental hazards: –
Special precautions for user: –

IATA
UN Number: –
Proper Shipping Name: –
Transport Hazard Class(es):
Class: Non-dangerous goods
Label(s): –
Packing Group: –
Environmental hazards: –
Special precautions for user: –

14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: not applicable.

HART MSDS-004 – Iss 2 Page 10

Review date: 02/07/2018
 The Hartridge Building
Network 421
Radclive Road
Buckingham
MK18 4FD
United Kingdom
Tel: +44 (0)1280 825600
Fax: +44 (0)1280 825601
Email: sales@hartridge.com
Web: www.hartridge.com
15 REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture:

EU Regulations

Regulation (EC) No. 2037/2000 Substances that deplete the ozone layer: none

Regulation (EC) No. 850/2004 on persistent organic pollutants: none

Chemical safety assessment: No Chemical Safety Assessment has been carried out.

16 OTHER INFORMATION

Revision Information: Vertical lines in the margin indicate an amendment.

Wording of the R-phrases and H-statements in section 2 and 3

H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H332 Harmful if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

Other information: The classification is in line with current EC lists. It is expanded,

however, by information from technical literature and by information
furnished by supplier companies. The classification results from the
Conventional Method mentioned in regulation EU 1272/2008 (CLP).
Disclaimer:
The data contained in this safety data sheet are based on our current knowledge and experience and are given to
the best of our knowledge and belief. It characterizes the product only with regard to safety requirements for
handling, transport and disposal. The data do not describe the product's properties (tech. product specification).
Neither should any agreed property nor the suitability of the product for any specific technical application be
deduced from the data contained in this safety data sheet. Modifications on this document are not allowed. The
data are not transferable to other products. In the case of mixing the product with other products or in the case of
processing, the data in this safety data sheet are not necessarily valid for the new-made material. It is the
responsibility of the recipient of the product to observe federal, state and local law. Please contact us to obtain up-
to-date safety data sheets. This document was issued electronically and has no signature.

HART MSDS-004 – Iss 2 Page 11

Review date: 02/07/2018