Scribd Logo
Upload

Welcome to Scribd!

  • 17 views

    3.langmuir Hinselwood Isotherm

    Uploaded by

    anmolbansal1969

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd

    3.langmuir Hinselwood Isotherm

    Uploaded by

    anmolbansal1969
    17 views9 pages

    Original Title

    3.Langmuir Hinselwood Isotherm (1)

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Download as pdf
    17 views9 pages

    3.langmuir Hinselwood Isotherm

    Uploaded by

    anmolbansal1969

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Download as pdf
    You are on page 1of 9
    on between 1 ) tember Q Ne es Tt ext ef sueaction in which whe fsroduet Jess olyee A ° Cane Con (malenic ae? d) % Considew the geste CGongecutive Keachou &- Ape Viste low) WAl> 18) exb( 4?) don each [8] = KCAL [ewes - expl-kt)) ee Keke [ce] = [Ae] (u Ka exbl Kit) “tle? ) Ki SYaidict Me Conc of LO] with hme =~ 1 \. ee ee fasy Slow i tua teeue wn be Alec ct Baud Hew j# will Convest to € aba function ot dime. yy ation sf LA Conecsil 68 A i i 3 J : 5 2 1% a 4 4 4 a 4 6 C @ 8 CI 3 e 4 3 @ @ 3 a 3 2 8 e 9 @ 3 3 3 a 3 a a " a time — q 4 4a ste Ag Kil becomes Guenter the Rint P goes up aud up aud above . a ; K isa 2 Slow ee Th thip , We Slowh foun Bau) i} Heacte dant to give C - the Concereration of Bip vey frna\) Harough out the Heaahon. Concentertatioe dime — Ap Kilig decteapes » Conceterotion of B in veny Very (almest snealig te) rol. Atter gome Hime Cone of B Gato (it becomes ques! Conptaut) and d{8] -0 eet Pearle wcl.O 7 Kila) = ¥.18] [ge Concenteration of —Sieady tote abbueximation. Concestenotion of BL Deacel CUAON Uged ino He: 4# Steady state appsioximavien fails a6 Koon we Ki 2K, becomegtwue- ° ‘he Bteady state appyox tmattor ae Ky Ka a—B ao Write Hhe rate lou fou the buocees diel _ 14 [9] de i > Tderh4y the intewmediore In Hoe Site tows ond obbly Bready Ailate abbriovinahovn OF Ky, WilAbe - a (elles mteimediote « qhe exbueszion of Mote tous fous Sere) io Josieduct ~ OES ia) ~ Koll, = eX fay - 1 ae Ko 44 hie, works Only 4, < Ko Wie Equotion for tre Creo Hon and Congubtion af He @©oe@eeaoeeseseeseeoegegeedvgeguegaeegeeoesgsvesveeseseanamh de oa #t Sunfoce Reaction Medle + (Aoitin Ron] desesbten) Phyaleal mane tousten Stcbs one mot giote Conteelling when pusiface wedction modd)z OMe develebed. Interface ond Tnjwedlace troup post foroceaacé ate fastens Susifece Geaction Hotes _ os. oe Bieb-5 =" ipyis) Rs Syn 910112 indo the €qn-S=- . Subptituting jo = Pa [163] [2 OE)] - Rs [KW] [Ks (2)] S — |'4) bo = Rak K De: Kas je) o) eS Ka Ki Keq pe ene ee ae 13 From Eqn-! &- Peed ot Ser Sd HOt ey sites So= $+(As)4 (@8)+ (CS) \(Os)+ GS) Subz tluting Eqn 9-12 inio tha. So= St Ki(alls) + K(els) 4 Ky (OL EO SO ae 0s) (141 fa) + 404 Hal * Kal) + Ka (2)) Sibstituting Eqn (16) in Eqn (4) => fh = aK RS." | 8 | [\HmALK.® + Kye KeO lL)” aL | 5 Be Ra KS TPR AsKjBHKl4KeD + Vs1)> ~ (Caled fo= Rien ~— Ge ee ts The Gae Hic Hy Co Helo Rae) A tbs) — ee ee [ents ee tek, Kik, So ————(\) (ie bat Ket he bet Us bo +Krls Oeeeoeseeseeseseee S) + ks (06) +, (ey ran eeangagenegeseesdvd OvUaRseseseeses Ae Eveui though the Cenglasit Notations in Eqn (lb)ond Eqvll) iz, ket Same theNalue Of Conptauts Goce - diftue becouze in equilib)! Conceuteriation 1 Coypidened whetie a& in Eqn( 1%) patitial puessusies ave Copaidered Note | Rote Cont xollivg Bleb ip mot ducsed in the Jind | think oF the ‘mechaniem and tote Cont Holling fiep expression 13. give « deuominator. £o we con if the Hate. + Adgosption Contsol = pee 2 R Bleb-| >: A+tS ae (as) (cp) @) ps Ss (RS) Ry es) =n eg —————= Sep? > aiek=3, =: ip the Hate EontBolling ‘S Adsorption 1 A (En -1) (Seb) t= k,AS)= by (Ps) (Rs) from #tep-2 == Ki = tas) = (2S) Bee Gl cay

    You might also like