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    Volumetric Analysis

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    ponveeraventhanp
    The document describes two experiments to determine the molarity and strength of a potassium permanganate solution using titration. The first experiment uses a 0.05 M Mohr's salt solution and determines the molarity as 0.0098 M and strength as 1.54g. The second experiment uses a 0.025 M oxalic acid solution and determines the molarity as 0.0104 M and strength as 1.64g.

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    Volumetric Analysis

    Uploaded by

    ponveeraventhanp
    25 views5 pages
    The document describes two experiments to determine the molarity and strength of a potassium permanganate solution using titration. The first experiment uses a 0.05 M Mohr's salt solution and determines the molarity as 0.0098 M and strength as 1.54g. The second experiment uses a 0.025 M oxalic acid solution and determines the molarity as 0.0104 M and strength as 1.64g.

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    Volumetric analysis (1)

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    The document describes two experiments to determine the molarity and strength of a potassium permanganate solution using titration. The first experiment uses a 0.05 M Mohr's salt solution and determines the molarity as 0.0098 M and strength as 1.54g. The second experiment uses a 0.025 M oxalic acid solution and determines the molarity as 0.0104 M and strength as 1.64g.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    25 views5 pages

    Volumetric Analysis

    Uploaded by

    ponveeraventhanp
    The document describes two experiments to determine the molarity and strength of a potassium permanganate solution using titration. The first experiment uses a 0.05 M Mohr's salt solution and determines the molarity as 0.0098 M and strength as 1.54g. The second experiment uses a 0.025 M oxalic acid solution and determines the molarity as 0.0104 M and strength as 1.64g.

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    EXPERIMENT NO - 1

    AIM:-

    To determine the molarity and strength of given KMnO4 solution by 0.05 M


    Mohr’s salt solution
    Theory:-

    Ionic equation is MnO4 -- + 8H+ + 5Fe2+ Mn2+ + 5Fe3+ + 4H2O


    Potassium permanganate acts as a powerful oxidising agent in redox
    titrations. It acts as good oxidizing agent in acidic medium in which
    permanganate ion is reduced to manganese ions.
    Short procedure:-

    Burette solution: Potassium permanganate solution


    Pipette solution: Ferrous Ammonium Sulphate
    Indicator : Self Indicator (KMnO4)
    Acid to be added : Dil. Sulphuric acid (4N)
    Temperature : Room temperature
    End point : Colourless changes to pink colour
    Molarity of Ferrous ammonium sulphate is 0.05 M
    Calculation of the amount of FAS

    Molar mass of FAS is 392g


    Volume of solution of Mohr’s salt = 100 ml
    Molarity of Mohr’s salt solution = Mass/molar mass X 1000/100
    0.05 = Mass/392 X 10
    Mass = 0.05x392/10
    Mass of FAS is 1.96g
    Observation Table:-

    KMnO4 VS FAS Indicator : Self (KMnO4)


    S.NO Volume of FAS in Burette Reading Volume of Concordant
    ml initial Final KMnO4 in ml value in ml
    1 20 0 20.3 20.3
    2 20 0 20.3 20.3 20.3

    Calculations:-

    Volume of potassium permanganate V1 = 20.3 ml


    Molarity of potassium permanganate M1 = ?
    Volume of ferrous ammonium sulphate V2 = 20 ml
    Molarity of ferrous ammonium sulphate M2 = 0.05M
    Using Molarity equation a M1V1 = b M2V2
    5 x M1 x 20.3 = 1 x 0.05 x 20
    M1 = 0.0098 M
    Molarity of potassium permanganate is 0.0098 M
    Strength calculation:-

    Strength of KMnO4 = Molarity of KMnO4 X Molar mass of KMnO4


    = 0.0098 X 158
    = 1.54g
    Result:-
    Molarity of potassium permanganate solution is 0.0098 M
    Strength of potassium permanganate solution is 1.54g.
    EXPERIMENT NO - 2

    AIM:-

    To determine the molarity and strength of given KMnO4 solution by 0.025 M


    Oxalic acid solution
    Theory:-

    Ionic equation is
    5 COO-- + 2 MnO4-- + 16H+ 10CO2 + 2Mn2+ + 8H2O
    COO
    Potassium permanganate acts as a powerful oxidising agent in redox
    titrations. Oxalic acid acts as an reducing agent .
    Short procedure:-

    Burette solution: Potassium permanganate solution


    Pipette solution: Oxalic acid solution
    Indicator : Self Indicator (KMnO4)
    Acid to be added : Dil. Sulphuric acid (4N)
    Temperature : 60 – 70 oC
    End point : Colourless changes to pink colour
    Molarity of Oxalic acid is 0.025 M
    Calculation of the amount of Oxalic acid

    Molar mass of Oxalic acid is 126g


    Volume of solution of Oxalic acid = 100 ml
    Molarity of Oxalic acid solution = Mass/molar mass X 1000/100
    0.025 = Mass/126 X 10
    Mass = 0.025x126/10
    Mass of Oxalic acid is 0.315g

    Observation Table:-

    KMnO4 VS OXALIC ACID Indicator : Self (KMnO4)


    S.NO Volume of oxalic Burette Reading Volume of Concordant
    acid in ml initial Final KMnO4 in ml value in ml
    1 20 0 19.2 19.2
    2 20 0 19.2 19.2 19.2

    Calculations:-

    Volume of potassium permanganate V1 = 19.2 ml


    Molarity of potassium permanganate M1 = ?
    Volume of Oxalic acid solution V2 = 20 ml
    Molarity of Oxalic acid solution M2 = 0.025M
    Using Molarity equation a M1V1 = b M2V2
    5 x M1 x 19.2 = 2 x 0.025 x 20
    M1 = 0.0104 M
    Molarity of potassium permanganate is 0.0104 M
    Strength calculation:-

    Strength of KMnO4 = Molarity of KMnO4 X Molar mass of KMnO4


    = 0.0104 X 158
    = 1.64g
    Result:-
    Molarity of potassium permanganate solution is 0.0104 M
    Strength of potassium permanganate solution is 1.64g

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