Sec: Incoming.Jr.IIT_*CO.

SC Date: 19-07-20
Time: 3HRS Max. Marks: 240

19-07-20_ Incoming.Jr.IIT _*CO SUPER CHAINA_Jee-Adv_CAT-2_SYLLABUS

PHYSICS: PRESENT WEEK (50%):Circular Motion: (Excluding verticle circle): Kinematics
& Dynamics of circular motion (Centrepetal force & Centrifugal force) banking
problems + Angular Velocity of Particle (in general motion) about a point
PREVIOUS WEEK (25%):Friction : A solid surface relatively at rest on another
solid surface, static friction as a force opposing the tendency of relative motion
on the other surface. Limiting friction, coefficient of static friction, Difference
between fs,max/fs and static friction as a self adjusting force, angle of friction.
Direction of static friction, related Numerical problems,Friction as the cause of
motion (walking, vehicles etc). Minimum force required to move a block on a
fixed horizontal surface on another block with horizontal surface,A solid surface
moving relatively on another solid surface. Kinetic friction (Dynamic or sliding
friction). Coefficient of kinetic friction. Direction of Kinetic friction,Cause of
static friction, cause of kinetic friction.
CUMULATIVE(25%):Projectile on Inclined Plane
CHEMISTRY: PRESENT WEEK (50%):Thermodynamics-I: Terms involved in
thermodynamics - System & Surrounding, Extensive and Intensive
Properties,Path and State function, types of processes, First law of
thermodynamics , Reversible and irrevesible processes; Work - expressions for
reversible, irreversible isothermal and adiabatic processes, Heat and Heat
capacity
Thermochemistry: Enthalpy of formation, Enthalpy of combustion, Bomb
calorimetre,Apllication of Hess's law determining ,Enthalpy of formation,
Enthalpy of combustion
PREVIOUS WEEK (25%):Collision Theory, Collision Theory, Arhenius equation
effect of catalyst on rate of reaction, special cases of 1 st order (parallel path
kinetics); kinetics of bacteria and virus ,kinetics of passive layer formation.
Nuclear Chemistry: α, β and γ rays Stability of nuclei with respect to proton-
neutron ratio; Kinetics of decay process and different types of problems of
radioactivity, Brief discussion on fission and fussion reactions
CUMULATIVE(25%):
1) Electron gain enthalpy ionisation enthalpy
2) KTG, Molecular collisions
MATHS: Matrices & Determinants (75%) & Sequence & Series (25%)
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Q’P
Time: 3:00 Hour’s IMPORTANT INSTRUCTIONS Max Marks: 240
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Integer Answer Type 4 0 8 32
Sec – II(Q.N : 9 – 16) Questions with Multiple Option Correct 4 -2 8 32
Questions with Comprehension Type
Sec – II(Q.N : 17 – 20) 4 -2 4 16
(2 Comprehension -2+2=4Q)
Total 20 80

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 21 – 28) Questions with Integer Answer Type 4 0 8 32
Sec – II(Q.N : 29 – 36) Questions with Multiple Option Correct 4 -2 8 32
Questions with Comprehension Type
Sec – II(Q.N : 37 – 40) 4 -2 4 16
(2 Comprehension -2+2=4Q)
Total 20 80

MATHS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 41 – 48) Questions with Integer Answer Type 4 0 8 32
Sec – II(Q.N : 49 – 56) Questions with Multiple Option Correct 4 -2 8 32
Questions with Comprehension Type
Sec – II(Q.N : 57 – 60) 4 -2 4 16
(2 Comprehension -2+2=4Q)
Total 20 80
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Q’P
PHYSICS Max Marks : 80
SECTION – I
(INTEGER ANSWER TYPE )
This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other cases.
1. A large mass M and a small mass m hang at the two ends of string that passes through
a smooth tube as shown in fig. The mass m moves around in a circular path which lies
in a horizontal plane. The length of the string from the mass m to the top of the tube is
of length l and  is the angle, this length makes with the vertical, what should be the
frequency of rotation of the mass m so that M remains stationary if M 16kg,m  4kg,

  1m and g  2 m / s 2 .

2. In a continuous printing process, paper is drawn into the process at a constant speed v.
Denoting by r, the radius of the paper on the roll at any given time and by b, the
thickness of the paper, an expression for the angular acceleration of the paper roll is
bv2
. Find n.
nr 3

3. A table with smooth horizontal surface is placed in a cabin which moves in a circle of
a large radius R =100 m with   3 rad/s (see figure). A smooth pulley of small radius
is fastened to the table. Two masses m and 2m placed on the table are connected
through a string going over the pulley. Initially the masses are held by a person with
the strings along the outward radius and then the system is released from rest (with
respect to the cabin). Then the magnitude of the initial acceleration of the mass m as
seen from the cabin is n × 100(m/s2). Find n.
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Q’P
4. Two blocks A and B are connected to each other by a string and a spring; the string
passes over a frictionless pulley as shown in the figure. Block B slides over the
horizontal top surface of a stationary block C and the block A slides along the vertical
side of C, both with the same uniform speed. The coefficient of friction between the
surface and blocks is 0.5. K= 2000N/m. If mass of A is 2 kg calculate mass of B.
(Take g = 10 m/s2)

5. A block of mass 3kg is at rests on a rough inclined plane of inclination   30 . The
Force exerted by the plane on the block is x Kgf. Find x.

6. A disc D of mass m = 4.0 kg is tied at one end of a cord of length l = 1.0 m, other end
of which is fixed at the centre of a large circular platform. The platform is maintained
horizontal and rotated about its vertical axis of symmetry. The disc is placed on the
platform as shown. After how much time in seconds the disc is placed, will the cord
break? The maximum tensile force the cord can withstand is Tmax = 100 N, and
coefficient of kinetic friction between the disc and the platform is  k  0.1 .

7. A particle takes 9s and 4s respectively to reach foot of the building when projected
vertically upwards and downwards respectively with same speed from top of the
building. How much time (in s) particle will take to reach foot of the building when it
is dropped from top of the building.
8. A ball released from a certain height, falls in the influence of gravity, strikes the
ground and repeatedly rebounds elastically (Speed does not change in elastic
collision). During a time interval t = 8 s from the instant it is released, it covers a
distance s = 20 m. How many collisions during this time did the ball make with the
ground? Acceleration of free fall is g = 10 m/s2.
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Q’P
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
9. A particle of mass m moves along a circle of radius ‘R’. The modulus of the average
vector of force acting on the particle over the distance equal to a quarter of the circle
is:
A) zero if the particle moves with uniform speed v
2mv 2
B) if the particle moves with uniform speed v
R
2 2mv 2
C) if the particle moves with uniform speed v
R
2 2mv 2
D) more than if speed increases starting from v
R
10. A particle P of mass m is attached to a vertical axis by two strings AP and BP of
length l each. The separation AB = l, P rotates around the axis with an angular velocity
 . The tensions in the two strings AP and PB are T1 and T2 respectively. Then

A) T1  T2 B) T1  T2  m2

C) T1  T2  2mg D) BP will remain taut only if   2g / 


11. A particle A moves along a circle of radius R so that its radius vector r relative to
point O rotates with the angular velocity 0  constant  . Find magnitude of velocity and
total acceleration
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Q’P
A) Speed of the block at A is 20 R

 
B) Speed at block of A is  0 2R sin 
 2

C) Acceleration of the particle of A is 402 R and directed towards AC

D) Acceleration of the particle of A directed toward AO

12. A particle is moving along a circular path of radius R such that radial acceleration of
particle is proportional to t2 then

A) speed of particle is constant

B) Magnitude of tangential acceleration of particle is constant

C) Speed of particle is proportional to time

D) Magnitude of tangential acceleration is variable

13. Your trail leg follows your lead leg as you attack a hurdle. What are directions of
friction on feet of a person during a walk, in one step?

A) Forward on lead leg B) Backward on lead leg

C) Forward on trail leg D) Backward on trail leg

 
14. At a particular instant of time, position vector r , velocity vector  and angular
position  of a particle traversing a path AB are shown in the figure. Here  is the
angle made by the velocity vector with the positive x-axis. Which of the following
statements is/are correct?
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Q’P
d  sin     
A) Modulus of angular velocity is 
dt r

d 2
B) Modulus of tangential component of acceleration is r 2
dt

d
C) Modulus of normal component of acceleration is 
dt

d
D) Modulus of normal component of acceleration is 
dt

15. A particle moves in a circle of radius r with angular velocity  . At some instant its
 
velocity is v and radius vector with respect to center of the circle is r . At this

particular instant centripetal acceleration a c of the particle would be
         
A)   v B) v   C)    r  D) v   r  

16. A uniform rope is tied between a nail A on the wall and a nail B on the ground. The
rope without touching the ground anywhere assumes a curved shape known as
"catenary". Tangents at the ends A and B of this catenary make angles  and  with
the vertical respectively. Which of the following conclusions can you make?

A) Horizontal component of the tensile force in the rope is uniform.

B) Vertical component of the tensile force increases with height.

C) Angle  can be greater than angle  .

D) Angle  cannot assume a value of 0 .

Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Q’P
SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONE OR MORE is/are
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
Paragraph for Question Nos. 17 to 18:
Radius of curvature at a point is the radius of a circle which touches a curve at a given
point and has the same tangent and curvature at that point. A projectile is thrown with
speed 20 m/s at an angle 60° with horizontal. Consider g =10 m/s2.
17. Mark correct alternatives.
A) Radius of curvature at highest point is 10m.
B) Radius of curvature at highest point is 20m.
C) Radius of curvature at starting point is 40m.
D) Radius of curvature at starting point is 80m.
18. Mark correct alternatives.
A) Magnitude of net acceleration at starting point is 10 m/s2.
B) Magnitude of tangential acceleration at starting point is 10 m/s2.
C) Magnitude of net acceleration at highest point is 10 m/s2.
D) Magnitude of centripetal acceleration at highest point is 10 m/s2.
Paragraph for Question Nos. 19 to 20:

The slipping starts between the blocks when the force of 25 N acts on 2kg block. Take
g = 10 m/sec2, a2 is acceleration of 2 kg block and a3 is acceleration of 3 kg block.
19. Select the correct graph of acceleration of blocks with force F is

A) B) C) D)

20. Acceleration of both the blocks when 40N force acts on a 2 kg block is
A) a2=5 m/s2 B) a2=12.5 m/s2 C) a3=5 m/s2 D) a3=7.5 m/s2
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Q’P
CHEMISTRY: Max. Marks: 80
SECTION – I
(INTEGER ANSWER TYPE)
This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.
21. The independent modes of vibration of a polyatomic non-linear gas molecule with
atomicity ‘n’ is. 3n – x, then x value is?

22. A certain mass of a gas is expanded from (1 L, 10 atm) to (4 L, 5 atm) against a

constant external pressure of 1 atm. initial temperature of gas is 300 K and the heat
capacity of process is 50J / C , H (in kJ) of the process. If H  x kJ  7.7 kJ , then
‘x’ value is?

23. 1000 gm water is heated from 27C to 47C at a constant pressure of 1 bar. The
coefficient of volume expansion of water is 0.002 / C (per g) and the molar volume
of water at 0C is 18.00cm3 / mol . The magnitude of work done (in J) by water is:

24. The external pressure 2 atm is applied on frictionless movable piston, fitted in a vessel
containing 100 g of X(l) at 450 K. Now heat is supplied keeping pressure constant till
40 g of X is evaporated to from X(g) at 500 k (boiling point). Assume vapour of X(l)
behaves like an ideal gas. The internal  U  energy for overall process is

n kJ  60.7 kJ , then ‘n’ value is

Given:

Molar heat capacity of X(l) = 60 J/mole K; H  vaporisation = 30 kJ/mol; R = 8.3 J/mol-K

At weight of X = 20 g/mol.
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Q’P
25. Some amount of diatomic van der Waals’s gas is kept in a rigid container of volume
20 litre and subjected to change in temperature from 300 K to 400 K. If 30 kcal of heat
310
is required and enthalpy change of the process is observed to be kcal, then the
9
310 xn
number of moles of the gas (n) and the H related as  30  , Find ‘x’
9  20  0.1n 
value.

[Given: b  0.1L mol1 , a  1.25atm  L2 / mol2 ]

26. Among the following how many of them have standard enthalpy of formation is zero

Co(s), CO(s), CO(g), H(g), Br2(g), H2O(l), I2(g), Na(vapour)

dB
The reaction: 2A  B  C  D follows the rate law.  k  A   B . Calculate the
1 2
27.
dt
value of (x + y).

Half-life
 A 0   104 M  B0   104 M
(Sec.)

1. 500 2 10

2. 500 4 x

3. 2 250 8

4. 4 500 y

28. An imaginary engine, is capable of expanding the gas upto 1013 times. If the engine
expands the gas up to the maximum possible extent isothermally at 300 K, then work
done by gas is x, whereas if the engine expands upto the maximum possible extent
adiabatically, at an initial temperature of 300 K, the temperature falls to – 160.6 K and
the work done by gas is y. If the gas is He and all processes are reversible in nature, if
x  ln1013 
  n  4  , then ‘n’ value is?  The value of  0.065 
y  460.6 
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Q’P
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
29. Correct statement is/are

A) when energy is transferred to the surroundings as heat, the transfer stimulates

disordered motion of the atoms in the surroundings

B) when system does work, it stimulates orderly motion in the surroundings

C) if  is the electric potential and ‘dq’ is the change in charge then electrical work is
.dq

D) if ‘n’ is the surface tension and ‘dr’ is the change in area, then surface expansion
work is n.dr

30. Correct statement is/are

A) During isothermal expansion if attractions are dominant in a real gas, the internal
energy increases with volume because the molecules become further apart an average
B) During isothermal expansion if repulsions are dominant in a real gas then internal
energy decreases
 dU   dU 
C) dU    dV  C V dT , for an ideal gas   0
 dV T  dV T

 dU   dU 
D) dU    dV  C V dT , for an real gas   is considered as internal pressure
 dV T  dV T
 which is not equal to zero

31. Which of the following statement(s) are incorrect?

A) Combustion of methane in an adiabatic rigid container will cause no change in

temperature of the system

B) It is possible to have both adiabatic reversible and adiabatic irreversible processes

between two states

C) For a reaction involving only ideal gases, occurring at constant temperature there
will be no change in internal energy always

D) P-V work is always non-zero when there is change in volume

Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Q’P
32. If a molecule moves with velocities 2  105 , 3  105 and 4  105 m/s along x, y and z
direction, then RMS velocity is
 4  9  16   1010  2  3  4  105
2

A) B)
3 3
 2  3  4  1010
2

C) D)  4  9  16   1010
2
33. Which comparisons are TRUE as per diagram?

A) P2  P1 B) V4  V3 C) T2  T4 D)  P1V1    P3V4 
34. For an ideal gas undergoing expansion – compression process. The relationships
which holds good are:
 U   H   U 
A)   0 B)    CP C)    CV D) C V  C P  R
 P T  T  V  T  P
35. Correct order is/are
A) I.E. of Be > B, but I.E, of Sr < In
B) EA, of Cl > F, but EA, of O < S
C) IE, of N > O, but IE, of As < Se
D) In periodic table, the metal with highest electron affinity is Cl
36. The graph given below represents the number of particles N t disintegrating per
second from a radioactive element with time:

Which of the following representations do not hold good for this curve?(Use the value
of e3  20 )
A) N t  1000e0.05t B) N t  200e20t C) N t  3e0.05t D) N t  20e 0.05t
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Q’P
SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choice A), B), C) and D) for its answer, out of which ONE OR MORE is/are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -2 in all other cases.
Paragraph for Question Nos. 37 to 38:

Nuclei of a radioactive element ‘A’ are being produced at a constant rate,  . The
element has a decay constant,  . At time t = 0, there are N 0 nuclei of the element
37. Which of the following has more activity
A) 1 mole of radium B) 1 mole of radium sulphate
C) 1 mole of radium phosphate D) all have same
38. A sample contains 0.1 gram-atom of radioactive isotope AZ X  t1/2  5days  . How many
number of atoms will decay during eleventh day? [ N A = Avogadro’s number]

  0.6935 11 
0.69310
  6.93511 0.69310

A) 0.1 e e 5  B) 0.1 e e 5 
   
  0.6935 11 
0.69310
  6.93511 
C) 0.1 e  e 5  NA D) 0.1 e  e0.69310  N A
   
Paragraph for Question Nos.39 to 40:
Collision cross-section is an area of an imaginary sphere of radius  around the
molecule within which the centre of another molecule cannot penetrate.
The volume swept by a single molecule in unit time is

If N* is the number of molecules per unit volume, then the number of molecules
within volume V is


N  VN*   2 u N *
Hence, the number of collision made by a single molecule in unit time will be

 
Z  N   2 u N *

In order to account for the movements of all molecules, we must consider the average
velocity along the line of centres of two colliding molecules instead of the average
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Q’P
velocity of a single molecule. If it is assumed that, on an average, molecules collide
while approaching each other perpendicularly, then the average velocity along their
centres is 2u as shown below.

Number of collision made by a single molecule with other molecules per unit time is
given by

 
Z1  2 u rel N*  2 2 uN *

The total number of biomolecular collisions Z11 per unit volume per unit time is given
by

Z11 
1
2
 Z1N * or Z11 
1
2
 
2 2 uN * N* 
1
2
 2 uN*2

If the collision involve two unlike molecules then the number of collisions Z12 per
unit volume per unit time is given as
 8kT 
Z12  12
2
  N1N 2
  
Where N1 and N 2 are the number of molecules per unit volume of the two types of
molecules, 12 is the average diameter of the two molecules and  is the reduced
mass. The mean free path is the average distance travelled by a molecule between two
successive collisions. We can express it as follows:
Average dis tan ce travelled per unit time u
 
No. of collisions made by a sin gle molecule per unit time Z1
OR
u 1
 
2 2 uN * 2 2 N *
39. If ‘d’ is the collision diameter then collision frequency ‘z’ is correctly represented as
A) z  d 2 B) z   / d C) z   / d D) z  2d
40. If C is relative mean speed then, correct relation is (  = mean free path)
Z Z
A) C  Zd B) C  Z C) C  D) C 
 d
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Q’P
MATHEMATICS Max. Marks: 80
SECTION – I
(INTEGER ANSWER TYPE)
This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.
2 5
41. Let A is symmetric and B is a skew symmetric matrix, such that A  B    , then
7 6
2
A is a three digit number, its units digit is ________

42. Let B be a skew symmetric matrix of order 3  3 with real entries. Given I  B and
I  B are non-singular matrices. If A   I  B  I  B  , where det  A  0 , then find the
1

value of det  2 A  det  adj A

43. Let A, A* denote the matrix of order 3  3 and its adjoint respectively where
 m2  1 1  m 1  m 
 
A*   1  m m 2  1 1  m  , m  1, 2 ; for m  2 , second row, third column element of
 1  m 1  m m 2  1
 

the matrix ‘A’ is  K where K is equal to

tr  AB  BA  
3

44. Let A and B be 3  3 matrices, which satisfies det  AB  BA     (where ' tr '


stands for trace of the matrix = Sum of principle diagonal entries of square matrix)

where  is equal to

3, when i  j  det  adj  adjA   

Let A   aij 33 be such that aij  then 
1
45.  equal to
0, otherwise  5  K

({}denote fractional function) where K is equal to

46. If the sequence 1, 2, 2, 4, 4, 4, 4, 8, 8, 8, 8, 8, 8, 8, 8, ….. where ‘n’ conseentire terms

has value ‘n’ then 1025th term is a four digit number abcd , the matrix A is defined as

a b  adj  3 A 
 c d  then calculate .
  4
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Q’P
47. Let a be the number of polynomials with integer coefficients such that the curve
passes through  2, 2  ,  4, 5  and also let bcd be the three digit number equal to

x3 y 3 z 3 x y z
3
 3  3 , where x, y , z are non zero real numbers such that    7 and
y z x y z x

y z x b a
   9 . Calculate .
x y z c d

48. If the system of equations x  ky  3z  0 , 3x  ky  2 z  0 , 2 x  3 y  4 z  0 has non-trivial

6xy
solution, then is equal to
z2

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
49. Choose the correct statement(s) for same order square matrices A and B

A)  I  A1   A  A  I  , I  A1  0, A  I  0
1 1

B)  I  AB  A  A  I  BA  ; A  0, I  AB  0, I  BA  0
1 1

C) If ‘B’ is an orthogonal matrix such that B   I  A  I  A  , then A must be a

1

symmetric matrix.

D) If A is a skew-symmetric matrix, then  I  A  I  A  is an orthogonal matrix.

1

50. The set of equations x  y  3z  2 , 2 x  y  z  4 , x  2 y   z  3 has

A) Unique solution for   0

B) Unique solution for   8

C) Infinite number of solutions for   8

D) No solution for   8

51. Let P and Q be 3  3 matrices such that P  Q . If P3  Q3 and P 2Q  Q 2 P , then

det  P 2  Q 2  is less than or equal to

A) 1 B) 0 C) 1 D) 2
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Q’P
52. Which of the following statement(s) is/are INCORRECT?

A) Every skew-symmetric matrix is non-invartiable

B) If A and B are two 3  3 matrices such that AB  0 , then atleast are of A and B must
be null matrix.

C) If A is a 2  2 matrix, then adj  adjA   A

D) If A and B are two square matrices of order 3 such that A  5 and B  2 , then

10  AB  equals 100

53. If a, b, c are in AP and a 2 , b 2 , c 2 in H.P., then which of the following could hold true?

a
A)  , b, c are in G.P B) a  b  c
2

C) a3 , b3 , c3 are in G.P D) a 2 , b 2 , c 2 are in G.P

54. If three 3  3 invertiable matrices A, B, C are idempotent, involuntary and orthogonal

matrices respectively, then which of the following is/are true?

A)  ABC    ABT C  B) If  ABC    CBA  , then BC  CB

1 T 1 1

C) adj  2 AB 1C   8


D) adj  3 A1 BC 1   9adj  C  BT  A   
1 T

1 1 1  2 1 1
55. Let matrix A  1 1 1 and B   1 2 1 then
1 1 1  1 1 2 

A)  A  B   A2005  B 2005 B)  A  B   A2005  B 2005

2005 2005

C)  3 A  7 B   3n1  3n A  7n B  , n  N D)  3 A  7 B   32 n A  3n 7 n B, n  N
n n

56. System of equations x  3 y  2 z  6 , x   y  2 z  7 and x  3 y  2 z   has

A) Unique solution if   2,   6 B) Infinitely many solutions if   4,   6

C) No solution if   5,   7 D) No solution if   3,   5
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Q’P
SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choice A), B), C) and D) for its answer, out of which ONE OR MORE is/are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -2 in all other cases.
Paragraph for Question Nos. 57 to 58:

Let P be an odd prime number and TP be the following set of 2  2 matrices.

 a b  
TP   A    ; a, b, c  0,1, 2,3,..., P  1
 c a 

57. The number of A in TP such that A is either symmetric or skew-symmetric or both,

and det  A  divisible by P is

A)  P  1 B) 2  P  1 C)  P  1  1
2 2
D) 2 P  1

58. Which of the following is/are correct?

A) The number of A in TP such that the trace of A is not divisible by P but det  A  is
divisible by P is  P  1
3

B) The number of A in TP such that the trace of A is not divisible by P but det  A  is
divisible by P is  P  1
2

C) The number of A in TP such that det  A  is not divisible by P is P3  P 2

D) The number of A in TP such that det  A  is not divisible by P is P 2  P

Paragraph for Question Nos. 59 to 60:

Let ‘r’ be the number of identical terms in the two AP’s form the sequence of identical
terms, it will be an AP, then the rth term of this AP make tr  the smaller of the last
term of the two AP’s
59. The number of terms common to two AP’s 3, 7, 11, ….., 407 and 2, 9, 16,..709 is

A) 21 B) 28 C) 35 D) 14

60. The value of largest term common to the sequence 1, 11, 21, 31,… upto 100 terms and
31,36,41,46,.. upto 100 terms, is

A) 281 B) 381 C) 471 D) 521

Sec:Incoming.Jr.IIT _*COSC CAT-2 Date: 19-07-20
Time: 3HRS 2015-P2 Max.Marks:240
KEY SHEET

PHYSICS
1 1 2 2 3 3 4 4 5 3

6 5 7 6 8 8 9 CD 10 BCD

11 AC 12 BC 13 BC 14 AD 15 AC

16 ABD 17 AD 18 ACD 19 A 20 BC

CHEMISRTY
21 6 22 8 23 4 24 6 25 4

26 1 27 7 28 9 29 ABCD 30 ABCD

31 ABCD 32 D 33 ABCD 34 ABC 35 AB

36 ABC 37 C 38 C 39 A 40 B

MATHS
41 6 42 7 43 1 44 3 45 5

46 9 47 7 48 5 49 ABD 50 BD

51 ABD 52 ABD 53 AB 54 ACD 55 ABC

56 BCD 57 D 58 BC 59 D 60 D
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Key & Sol’s
SOLUTIONS
PHYSICS
1. The mass m is acted by two forces
(i) weight mg a mass M (ii) Tension T is the string
T cos   mg; Tsin   mr2 and T  Mg
r   sin ; Mgsin   m   sin   2
Mg 1 Mg
2  ;n
m 2 ml
2r
2. Radius reduces by b in time
v
r bv  dr  bv 
 or   r  
z 2r  dt 2r 
 v

 v
r 
r
 v

r
 v 
   2 r
r  
v  bv  bv 2
or    2  2  
r  r  2r 3
d 2 
now   2  
dt
3.

By Newton’s second law, we can write

 2m  2R  T   2m  a ....... i 
and T  m2 R  ma ....... ii 
After simplifying, above equation, we get a  3000m / s 2
m
4. T  Rx  m A g; T  m Bg  m B  A  4kg

6. The tensile force in the cord and the frictional force provide the centripetal and the
tangential accelerations respectively.
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Key & Sol’s
1
7. h  ut 2  gt 22
2
1
 ht 2   ut1t 2  gt 22 t1
2
1
h  gt1t 2
2
1 2 1
gt  gt1t 2
2 2
1
h   ut1  gt12
2
 t  t 1t 2  9  4  6
gt 2  2s
8. 8
4s
Average speed of any one-way motion of the ball whether upwards or downwards can
be approximately taken as the average speed for the given interval without appreciably
sacrificing accuracy. Using this idea, you may find an integral or non-integral solution
for the number of collisions. If you find a non-integral solution, the number of
collision must be its integral part, because the fractional part corresponds to the last
incomplete trip.
 
 vfinal  vinitial 
9. a average   
 time elapsed 
 
  i  j  2  2 2
ˆ ˆ
 
R  R
 
 2 

Average force = m × average acceleration

2v 2 2
 m
R
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Key & Sol’s
10. ABP equilateral, T1 ,T2 tensions along PA and PB respectively.
T1 cos 60  T2 cos 60  mg; T1  T2  2mg
T1 sin 60  T2 sin 60  m   sin 60  2
T1  T2  m2; if T2  0
T1  2mg  2  2g
2g
if   BP will be taut

12. a r t 2 ; v 2  krt 2 ; v  kr t
dv
 kr  constant
dt
u2 u 2 cos 2 
17, 18. R 0  RP 
g cos  g
P u  cos 
u  20 m / s

 g  10 m / s 2
0
19, 20. a 0  5m / s 2 , f r  15N
  2 g  3  a 0
  0.75
Maximum acceleration of 3kg block is 5 m/s2.

F  f r  m 2a 2
40  15  2  a 2
a 2  12.5 m / s 2
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Key & Sol’s
CHEMISTRY
21. (3N – 6)
1  10 4  5
22.   T  600K
300 T
q  50  300  15kJ
100
w  1 4  1    0.3kJ
1000
U  14.7 kJ
100
H  14.7   20  10    15.7 kJ
1000
23. Vr C  V0C 1  t 
  coefficient of volume expansion, t = temperature in C
V27C  1000 1  0.002  27   1054mL
V47C  1000 1  0.002  47   1094mL
w   P V
1  1094  1054 
w bar litre
1000
4 4
w bar litre =  100J  4J
100 100
24. U  Q  w
U  n CP T  nH vap  w
m

100 60 40
U    50   30  n g RT
20 1000 20
2  8 .3  5 0 0
U  15  60   6 6 .7 k J  6 6 7 0 J
1000
25. dH  dU  d  PV   dU  V dP (V constant)

For van der Waals’ gas P  nR T an 2

 2
 V  nb  V
nR dT
dP 
 V  nb 
nRdT
 dH  dU  V 
 V  nb 
nR  T
H  U  V 
 V  nb 
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Key & Sol’s
310 n  2  100
 103  30  103  20 
9  20  0.1n 
310 4n
 30   20
9  20  0.1n 
26. Conceptual
r1  k ' B
2
27.
t1/2  a1n
1
x 4
  x 5
10  2 
r2  k" A 
1

t1/2  a11
y=2
x+y=7
x 300R ln1013
28.   13
y 3 R 460.6
 
2
29. orderly motion of atoms of surrounds = work
 dU 
30.     t  internal pressure
 dV T
For real gas  t  0
31. one adiabatic process possible
32. C  U 2x  U 2y  U z2
33. Conceptual
34. CP  CV  R
35. EA is high for Cl
36.   20e 0.0 Nt
37. Ra 3  PO 4 2
38. Activity of [11th day – 10th day]
39. Z  d 2
40. C  Z
Narayana IIT Academy 19-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-2_Key & Sol’s
MATHS
41. A  24

AT   I  B   I  B
1
42.
AAT  1  A  1 as A  0 

A   det  A*   A* 
1
43.
44. Conceptual.
 n 12
45. adj  adj A   A
46. abcd  1024
47. a  0, bcd  157
33
48.  0k 
2
I  A 
1 1
  AA1  A1     A  I  A1   A  A  I 
1 1 1
49.
50. Conceptual.
51. P  Q P2  Q2  0
52. Conceptual.
a  c 2 2a 2 c 2
53. b ,b  2 2
2 a c
 b 2  ac  or  2b 2  ac  0 .
54. A  A1  AT  I , B  B 1 and C T  C 1
55. AB  BA  0
56. Conceptual.
57. A is symmetric  b  c
det A  a 2  b 2 is divisible by P
(i) a  b is divisible by P if a  b , the P cases are possible
(ii) a  b is divisible by P if a  b  P  P  1 cases are possible.
A is skew symmetric of a  0, b  c  0  A  b 2
Can never be divisible by P
 2 P  1 cases are possible.
58. (B) a 2  bc is divisible by P, a  0
a, b can be chosen in P  1 , P  1 ways ‘c’ can be chosen in 1 way.  P  1 ways.
2

(C) Required cases  P 3   P  1   2 P  1  P 3  P 2

2

59 & 60.
Required sequence (A.P) has common difference as L.C.M of 4 and 7 = 28