FULL TEST-1 SOLU TION S

STANDARD ANSWER KEY

Q 1 2 3 4 5 6 7 8 9 10 11
A 4 4 3 1 1 3 3 1 1 2 1
Q 12 13 14 15 16 17 18 19 20 21 22
A 4 4 1 2 1 1 2 3 1 2 1
Q 23 24 25 26 27 28 29 30 31 32 33
A 4 4 4 2 3 4 1 1 1 4 3
Q 34 35 36 37 38 39 40 41 42 43 44
A 4 4 1 4 1 4 1 3 2 1 2
Q 45 46 47 48 49 50 51 52 53 54 55
A 2 3 2 3 1 4 2 2 1 1 4
Q 56 57 58 59 60 61 62 63 64 65 66
A 3 1 1 4 3 4 4 4 2 4 4
Q 67 68 69 70 71 72 73 74 75 76 77
A 3 2 4 3 2 2 2 2 3 2 4
Q 78 79 80 81 82 83 84 85 86 87 88
A 1 4 3 3 4 4 3 4 3 3 1
Q 89 90 91 92 93 94 95 96 97 98 99
A 4 3 3 2 2 2 2 2 2 4 3
Q 100 101 102 103 104 105 106 107 108 109 110
A 2 1 4 4 1 4 2 1 1 4 4
Q 111 112 113 114 115 116 117 118 119 120 121
A 3 4 1 1 2 2 1 3 3 1 3
Q 122 123 124 125 126 127 128 129 130 131 132
A 2 3 3 2 1 1 3 2 1 4 4
Q 133 134 135 136 137 138 139 140 141 142 143
A 1 4 4 1 2 4 4 4 1 4 2
Q 144 145 146 147 148 149 150 151 152 153 154
A 1 3 3 4 3 4 4 1 2 3 2
Q 155 156 157 158 159 160 161 162 163 164 165
A 4 1 4 3 3 1 4 3 4 2 3
Q 166 167 168 169 170 171 172 173 174 175 176
A 4 4 3 4 2 1 1 3 1 3 2
Q 177 178 179 180
A 1 3 3 3
(1) (4). Ptotal = XA. PA0 + XB. PB0 (11) (1). Hydration enthalpy depends upon ionic
= 0.5 × 400 + 0.5 × 600 = 500 mmHg potential (charge / size). As ionic potential
Now, mole fraction of A in vapour, increases hydration enthalpy increases.
(12) (4).
+ MnO2 + O2(g)
and mole fraction of B in vapour,
YB = 1 – 0.4 = 0.6 MnO2 + 4NaCl + 4H2SO4  MnCl2
(2) (4).Correct order of oxidation state of nitrogen + 4NaHSO4 + 2H2O + Cl2(g)
in oxides of nitrogen is following: (Z) pungent gas
+1 +2 +3 +4 (13) (4).
N2O < NO < N2O3 < NO2 CH3 C H C l2 CHO

C l2 /  H 2O
(3) (3). (Nylon-6) 

Cl Cl Cl
(14) (1).
(4) (1). Distance between two nearest tetrahedral OH N e u tra l
–ve
void = a / 2 F eC l 3 (F eC l 3 te st fo r
p h e n o lic g ro u p )
(5) (1). For K2[HgI4] C H3
RM gX
i = 1 + 0.4 (3 – 1) = 1.8 G rig a rd
+ ve * A c id ic H
R e ac tio n
C–Et reage n t * –C –
(6) (3).
O
O N a O H + I2 gro up
Io d o fo r m + v e (C H I3)
R e a c tio n
te st
due – C H – C H 3 g rou p
10 e– trans for 10 molecules of CO2 so per
OH
molecule of CO2 transfer of e– is '1' (15) (2). K = 2, 8, 8 ,1
(7) (3). Example of E2 elimination and conjugated After removal of one electron, second
diene is formed with phenyl ring in electron we have to remove from another
conjugation which makes it very stable. shell, hence there is large difference
(8) (1).1. Bauxite–AlOx (OH)3–2x, where 0 < x < 1 between first and second ionization
energies.
2. Siderite – FeCO3 (16) (1). Zn + 2HCl  ZnCl2 + H2 
3. Calamine – ZnCO3
Zn + 2NaOH  Na2ZnO2 + H2 
4. Malachite – CuCO3.Cu(OH)2
(17) (1). All statements are correct
(9) (1). Sm3+ (4f5) = yellow colour. B2O3  acidic
(10) (2). Al2O3 & Ga2O3 are amphoteric oxides of
C H 2 –C H 3 C O 2K
In & Tl are basic
(18) (2).

C O 2H
= 425.9 + 100.5 – 126.4 = 400 Scm2 mol–1

2
 = 50 S cm2 mol–1

= 1.66 × 10–2 M/min

(25) (4). 2/5 air escaped from vessel,
(19) (3).
O M e (+R effect) M e (+I, + H effect) C l (–I > +R ) C N (–I, –R)  3/5 air remain is vessel. P, V constant
n1T1 = n2T2
> > >
R in g e – R in g e – n1 (300) = T2  T2 = 500 K
d en sity is d en sity is
h ig h e st. le a st.
(M o r e is th e e – d e n sity a t rig h t fa ste r (26) (2).
is th e re ac tio n to w a rd s E A S )

(20) (1). In electrophoresis precipitation occurs at (a) H2SO4 + 2NaOH  Na2SO4 + 2H2O
the electrode which is oppositely charged 400 × 0.1 = 40 400 × 0.1= 40
therefore (1) is correct. 20 0

(21) (2). = 2480.3 K  [H+] =

(22) (1).  pH = 1.3, so (a) is correct
N H2 NC
. (b)

O
So ionic product of water is temp.
CN
CN O dependent
Pd/C/H2 hence (b) is correct.
H
(c) Ka = 10–5, pH = 5  [H+] = 10–5
N
CH3

OH
(23) (4). N2(g) + O2(g)  2NO(g) NH2
.
so (c) is correct.
(d) Le-chatelier's principle is applicable to
common –Ion effect so option (d) is
N2O4(g)  2NO2 (g) wrong.
(27) (3).
CH3
|
O HO  C  CH 3 O CH3
|
N2(g) + 3H2(g)  2NH3(g) (a) C H 3
C H3 – C – O – C2H5 CH3 – C – O – C – CH3
O CH3
H2N – NH2
(24) (4). 2N2O5(g)  4NO2(g) + O2(g) CH3 – C – NH – NH2
t = 0, 3.0 M
t = 30, 2.75 M N CH3
CH3
(28) (4). C H 3
Nitrogen is sp3 hybrid and pyramidal
no back-bonding i.e.more basic

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 S iH 3 (36) (1).
H 3 Si N

(b) S iH 3
Nitrogen sp2
hybrid and planar due to back
bonding and less basic because lone pair is
not available for donation. (37) (4). The maximum prescribed concentration of
Cu in drinking water is 3 ppm.
(29) (1). 8g NaOH, mol of NaOH = = 0.2 mol (38) (1). Noradrenaline is a neutro transmitter and it
belongs to catecholamine family that
18g H2O, mol of H2O = = 1 mol fanctions in brain & body as a harmone &
neutro transmitter.
 XNaOH = (39) (4).
C H3 7
H3C C H
5 6
Molality = 4 C
3
(30) (1). H2SO4 + 2NH3 (NH4)2SO4
2 C H3
10mL of 1M H2SO4 = 10m mol
C H2
[M × V(mL) = m mol] 1
NH3 consumed = 20m mol 3,5-Dimethyl-4-propylhept-1-en-6-yne
Longest carbon chain, including multiple
Acid used for the absorption of ammonia
bonds, and numbering starts from double
= 20 – 10 m mol
bond.
= 10 mL of 2N (or 1 M) H2SO4
(40) (1). B C
Al Si
Ga < Ge
= 37.33% Along the period electronegativity
(31) (1). HCl with Na2CO3 increases.
Eq. of HCl = Eq. of Na2CO3 (41) (3). C (graphite) + O2 (g)  CO2 (g) ...(1)
rHº = x kJ /mol
;
C (graphite) + ½ O2 (g)  CO (g) ...(2)
Eq of HCl = Eq. of NaOH rHº = y kJ /mol
CO (g) + ½ O2(g)  CO2(g) ...(3)
V = 25 ml rH° = z kJ mol–1
(32) (4). I2(s)  I2(g): H1 = 24 cal/g at 200°C (1) = (2) + (3)
x=y+z
H2 = H1 + CPrxn (T2 – T1)
(42) (2). cis–[PtCl2(NH3)2] is used in chemotherapy
= 24 + (0.031 – 0.055) × 50
to inhibits the growth of tumors.
= 24 – 1.2 = 22.8 Cal/g
(33) (3). For strongest oxidising agent, standard
reduction potential should be highest. (43) (1).CF3– CH = CH2
(34) (4). The highest oxidation state of U and Pu is
6+ and 7+ respectively.
(35) (4). Seliwanoff's test is used to distinguished
aldose and ketose group.

4
 Due to higher e– withdrawing nature of CF3 (52) (2).For same range angle of projection will be 
group. It follow anti markovnikoff product. & 90 – .
u u
(44) (2). C2O42– (oxalato) : Bidentate
H2O (aqua) : Monodentate  90 – 

(45) (2).

As for shortest wavelengths both n2 and

m2 are .
(53) (1). Numerical aperture of the microscope is

given as, NA =
Now if m1 = 3 & n1 = 1 it will justify the Where d = minimum separation between
statement hence Lyman and Paschen (2) is two points to be seen as distinct
correct.
(46) (3). Potential difference between two faces
perpendicular to x-axis will be
= 2.4 × 10–7 m = 0.24 µ m
(54) (1).
(47) (2). N1 = N0 e–10t
A
N2 = N0e–t 6 0°
O Vacuum
glass
9t = 1 t = 1/ 9 3 0°
B
(48) (3). v = 2f (2 – 1)
From Snell's law
v = 2 × 480 × (70 – 30) × 10–2
v = 960 × 40 × 10–2 1.sin 60° = µ sin30° 
v = 38400 × 10–2 m/s = 384 m/s Optical path = AO + µ (OB)
(49) (1). P = I2R = 2a + 2b
4.4 = 4 × 10–6 R
R = 1.1 × 106  (55) (4). Energy =
= f × 3 × 106
f=3
(50) (4). Energy of photon = = 12.75 eV E = 9 × 106 J

Electron will excite to n = 4 (56) (3).

Since 'R'  n2
 Radius of atom will be 16a0
(51) (2). For adiabatic process : TV–1 = constant
For diatomic process : –1 =
 x = 2/5 = 0.33 × 10–3 = 3.3 × 10–4

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(57) (1). = 6 × 1014 × 2
f = 6 × 1014
C=f

(61) (4). Q = 2 (BE of He) – (BE of Li)

= 2 × (4 × 7.06) – (7 × 5.60)
Energy of photon = = 2.475 eV = 56.48 – 39.2 = 17.3 MeV
(62) (4). i = e ; r1 = r2 = A/2 = 30°
From Einstein's equation By Snell's law,
KEmax = E – 
eVs = E –  1 × sin i = ; i = 60°
eVs = 2.475 – 2 (63) (4). Since unpolarised light falls on P1
eVs = 0.475 eV Intensity of light transmitted from P1 = I0 / 2
Vs = 0.475 V = 0.48 volt Pass axis of P2 will be at an angle of 30º with P1
20m /s f f0 20m /s
 Intensity of light transmitted from
A (observer) B (source)
(58) (1). P2 = cos2 30º =
Applying Doppler effect for sound
Pass axis of P3 is at an angle of 60º with P2
 Intensity of light transmitted from
(v0 and vs is taken  when approaching P3 = cos2 60º = 
each other)
(64) (2).
; f0 = 2250 Hz v0 v0 /4 v

(59) (4). Since height of water column is constant. 2k g m 2k g m

R e st
Q in By conservation of linear momentum :

Qout
 ....... (1)
Water inflow rate (Qin) = water outflow rate Since collision is elastic
Qin = 10–4 m3s–1 Vseparation = vapproch
Qout = Au = 10–4 ×  .......(2)
10–4 = 10–4
Equating (2) and (1)
h = (1/20) m = 5cm

(60) (3). Orbital velocity,

(65) (4). Suppose M is mass and a is side of larger
triangle, then M/4 and a/2 will be mass
and side length of smaller triangle.

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 
(66) (4). y = 5 [sin (3t) + cos (3t)]
(69) (4). For first lens,
For second lens,

3 2
V = 70 cm
 /3 (70) (3). Given initial velocity u = 0 and
Amplitude = 10 cm acceleration is constant

(67) (3). At saturation state, VCE becomes zero a

iC
O t
At time t, v = 0 + a t  v = at
iB C 10 00 
B Also x = 0 (t) + at2 x = at2
E

VB 10 V
x
v

O t O t
Graph (a) ; (b) and (d) are correct.
Now current gain factor (71) (2). Velocity of wave on string

= 40 m / s

(68) (2). Since mass of the object remains same.

Weight of object will be proportional to 'g' Now, wavelength of wave
(acceleration due to gravity) Separation between successive nodes,
Given
40
Also, gsurface = (M is mass planet, G
a
is universal gravitational constant, R is (72) (2). f 
radius of planet) 40 + f = m (R) .......(i)
2
40 × R – f × R = mR 
40 – f = mR ...... (ii)

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 From (i) and (ii),

(73) (2). (78) (1). KE = q V

A ;
A
AB A  B =A  B
Y ( A  B) A (79) (4).
A B A B A
B
B
(74) (2). Fthrust – mg = ma
F th ru s t
m = 5000 kg, a = 20 m/s2
 Fthrust = 150000 N
a (80) (3).
Fthrust = Urel ×
E
 (–800) × = 150000
mg 
qE

  –187.5 kg/s mg

(75) (3).
(81) (3).
Y
/6
 15 0 g
(1/2, 3/2)
A /2

50 g = m 1 60 º m 2 = 1 00 g
0 0.5 m 1.0 m
V(t) = 220 sin (100t) volt
The co-ordinates of the centre of mass
Time taken,

(76) (2). Path difference = d sin  d

= 0.1 × (1/40) mm = 2500 nm
or bright fringe, path difference must be
integral multiple of .
 2500 = n1 = m2  Co-ordinate =
 1 = 625, 2 = 500 (from m = 5)
(for n = 4) (82) (4). Magnetic field at ‘O’ will be done to ‘PS’
and ‘QN’ only
(77) (4). 4F2 + 9F2 + 12F2 cos  = R2
i.e. B0 = BPS + BQN  Both inwards
4F2 + 36 F2 + 24 F2 cos = 4R2
4F2 + 36 F2 + 24 F2 cos  Let current in each wire = i
= 4 (13F2 + 12F2cos ) = 52 F2 + 48F2cos 

8
 Tension T' = RT
or  i = 20 A

(83) (4). Electric field of equitorial plane of dipole

At P, ; At P' ,

(84) (3).

 

(85) (4).

(86) (3).  = C
C = / 
C = [ML2T–2]
(87) (3). Q = A T4,

(88) (1).

Various forces acting on the system are

shown in the figure. For vertical
equilibrium of the system, fB = 100 N +
20 N = 120 N
i.e., frictional force applied by the wall on
the block B is 120 N.
(89) (4).

T ' c o s    T 'c o s
 
(90) (3). 2T'sin  = T d  T'

2T' = T (2. R)
2 T 's in 

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(91) (3) (92) (2) (93) (2)
(94) (2) (95) (2) (96) (2)
(97) (2) (98) (4) (99) (3)
(100) (2)
(101) (1). Due to intake of alcohol cerebrum is first
affected but most affected part is
cerebellum.
(102) (4) (103) (4) (104) (1)
(105) (4) (106) (2) (107) (1)
(108) (1) (109) (4)
(110) (4). Sarcoplasmic reticulum is less extensive in
red muscles in comparison to white
muscles.
(111) (3) (112) (4) (113) (1)
(114) (1) (115) (2) (116) (2)
(117) (1) (118) (3) (119) (3)
(120) (1) (121) (3) (122) (2)
(123) (3) (124) (3) (125) (2)
(126) (1) (127) (1) (128) (3)
(129) (2) (130) (1) (131) (4)
(132) (4) (133) (1) (134) (4)
(135) (4) (136) (1) (137) (2)
(138) (4) (139) (4) (140) (4)
(141) (1) (142) (4) (143) (2)
(144) (1) (145) (3) (146) (3)
(147) (4) (148) (3) (149) (4)
(150) (4) (151) (1) (152) (2)
(153) (3) (154) (2) (155) (4)
(156) (1) (157) (4) (158) (3)
(159) (3) (160) (1) (161) (4)
(162) (3) (163) (4) (164) (2)
(165) (3) (166) (4) (167) (4)
(168) (3) (169) (4) (170) (2)
(171) (1) (172) (1) (173) (3)
(174) (1) (175) (3) (176) (2)
(177) (1) (178) (3) (179) (3)
(180) (3)

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