VITEEE

SOLVED PAPER 2019

(memory based)
GENERAL INSTRUCTIONS
• This question paper contains total 125 questions divided into four parts :
Part I : Physics Q. No - 1 to 40
Part II : Chemistry Q. No - 41 to 80
Part III : Mathematics Q. No - 81 to 120
Part IV : English Q. No - 121 to 125
• All questions are multiple choice questions with four options, only one of them is correct.
• For each correct response, the candidate will get 1 mark.
• There is no negative marking for the wrong answer.
• The test is of 2½ hours duration.

4. Radioactive element decays to form a stable

PART - I (PHYSICS)
nuclide, then the rate of decay of reactant is
1. The electric resistance of a certain wire of iron shown by
is R. If its length and radius are both doubled, N N
then
(a) the resistance and the specific resistance,
will both remain unchanged (a) (b)
(b) the resistance will be doubled and the t t
specific resistance will be halved N N
(c) the resistance will be halved and the
specific resistance will remain unchanged (c) (d)
(d) the resistance will be halved and the
specific resistance will be doubled t t
5. The ratio of the energies of the hydrogen atom
2. Two thin lenses are in contact and the focal in its first to second excited states is
length of the combination is 80 cm. If the focal (a) 1/4 (b) 4/9 (c) 9/4 (d) 4
length of one lens is 20 cm, then the power of
6. Which of the following gates will have an output
the other lens will be
of 1?
(a) 1.66 D(b) 4.00 D (c) – 100 D (d) – 3.75 D
1 0
3. If the kinetic energy of a free electron doubles, 1 1
it’s de-Broglie wavelength changes by the factor (A) (B)
1 1 0 0
(a) 2 (b) (c) 2 (d) 0
2 2 1
(C) (D)
(a) D (b) A (c) B (d) C
7. A point charge q is rotated along a circle in the electric (a) 50m, 90m (b) 5m, 9m
field generated by another point charge Q. The work (c) 9m, 5m (d) 90m, 50m
done by the electric field on the rotating charge in 13. An electric dipole is kept in a uniform electric
one complete revolution is field. It experiences
(a) zero (a) a force and a torque
(b) positive (b) a force, but no torque
(c) negative (c) a torque but no net force
(d) zero if the charge Q is at the centre and (d) neither a force nor a torque
nonzero otherwise. 14. A person swims in a river aiming to reach exactly
8. The equivalent capacitance of the combination on the opposite point on the bank of a river. His
of the capacitors is speed of swimming is 0.5 m/s at an angle of 120º
(a) 3.20µF with the direction of flow of water. The speed of
10µF 6µF water is
(b) 7.80µF V (a) 1.0 m/s (b) 0.5 m/s
(c) 3.90µF 4µF
(c) 0.25 m/s (d) 0.43 m/s
(d) 2.16µF
15. A rain drop of radius 0.3 mm has a terminal
9. The half-life period and the mean life period of a
velocity in air is 1 m/s. The viscosity of air is 8 ×
radioactive element are denoted respectively by
10–5 poise. The viscous force on it is
Th and Tm. Then
(a) Th = Tm (b) Th > T m (a) 45.2 × 10–4 dyne (b) 101.73×10–5 dyne
(c) 16.95 × 10–4 dyne(d) 16.95 × 10–5 dyne
(c) Th < Tm (d) Th ³ Tm
16. Consider a pair of insulating blocks with thermal
10. In a common base mode of a transistor, the resistances R1 and R2 as shown in the figure.
collector current is 5.488 mA for an emitter current The temperature q at the boundary between the
of 5.60 mA. The value of the base current two blocks is
amplification factor (b) will be
q2 q1
(a) 49 (b) 50 (c) 51 (d) 48 R2 R1
11. The magnetic field at a distance r from a long
wire carrying current i is 0.4 tesla. The magnetic
field at a distance 2r is (a) (q1q2ÖR1R2) / (q1 + q2) (R1 + R2)
(a) 0.2 tesla (b) 0.8 tesla (b) (q1R1 + q2R2) / (R1 + R2)
(c) 0.1 tesla (d) 1.6 tesla
12. The velocity-time graph of a body moving in a (c) [(q1 + q2) R1R2] / (R12 + R22)
straight line is shown in fig. Find the (d) (q1 R2+ q2R1) / (R1 + R2)
displacement and distance travelled by the body 17. A mass of 0.5 kg moving with a speed of 1.5 m/
in 10 seconds. s on a horizontal smooth surface, collides with
u (m/s) a nearly weightless spring of force constant k =
50 N/m. The maximum compression of the spring
20 A would be
D
10

0 t (s)
2 4 6 8 10
–10 (a) 0.5 m (b) 0.15 m
(c) 0.12 m (d) 1.5m
–20
C
18. A solid sphere is rotating in free space. If the 25. For a series RLC circuit R = XL = 2XC. The
radius of the sphere is increased keeping mass impedance of the circuit and phase difference
same which one of the following will not be between V and I respectively will be
affected ?
(a) Angular velocity 5R 5R
(a) , tan -1 (2) (b) , tan -1 (1/ 2)
(b) Angular momentum 2 2
(c) Moment of inertia
(c) 5X C , tan -1 (2) (d) 5R, tan -1 (1/ 2)
(d) Rotational kinetic energy
19. The Young’s modulus of a perfectly rigid body 26. A man holding a rifle (mass of person and rifle
is together is 100kg) stands on a smooth surface
(a) unity and fires 10 shots horizontally in 5 sec. Each
(b) zero bullet has a mass 10 g with a muzzle velocity of
(c) infinity 800 ms–1. The velocity which the rifle man attains
(d) some finite non-zero constant after firing 10 shots will be
-1 -1
20. The figure below shows currents in a part of (a) 8 ms (b) 0.8 ms
electric circuit. The current i is
(a) 1.7 amp 2 amp
1 amp (c) 0.08 ms -1 (d) – 0.8 ms -1
(b) 3.7 amp 1.3 amp 27. Escape velocity when a body of mass m is thrown
(c) 1.3 amp 2 amp vertically from the surface of the earth is v, what
(d) 1 amp will be the escape velocity of another body of
21. In an electromagnetic wave
i mass 4 m is thrown vertically
(a) power is transmitted along the magnetic (a) v (b) 2v
field (c) 4v (d) None of these
(b) power is transmitted along the electric field 28. A solid cylinder of mass m and radius R rolls
(c) power is equally transferred along the down inclined plane without slipping. The speed
electric and magnetic fields of its C.M. when it reaches the bottom is
(d) power is transmitted in a direction per-
pendicular to both the fields (a) 2 gh
22. A particle covers half of the circle of radius r.
Then the displacement and distance of the (b) 4gh / 3
particle are respectively h
(a) 2pr, 0 (b) 2r, pr
(c) 3 / 4 gh
pr
(c) , 2r (d) pr, r
2
23. A metal ring is held horizontally and bar magnet (d) 4 gh
is dropped through the ring with its length along 29. A block of mass 5 kg resting on a horizontal
the axis of the ring. The acceleration of the falling surface is connected by a cord, passing over a
magnet light frictionless pulley to a hanging block of
(a) is equal to g mass 5 kg. The coefficient of kinetic friction
(b) is less than g between the block and the surface is 0.5. Tension
(c) is more than g
in the cord is : (g = 9.8 m/sec2)
(d) depends on the diameter of ring and length A
of magnet
24. A particle having a mass 0.5 kg is projected under 5 kg
gravity with a speed of 98 m/sec at an angle of
60º. The magnitude of the change in momentum
(in N-sec) of the particle after 10 seconds is 5 kg B
[g = 9.8 m/sec2]
(a) 0.5 (b) 49 (a) 49 N (b) Zero
(c) 98 (d) 490 (c) 36.75 N (d) 2.45 N
30. A and B are two wires. The radius of A is twice
2s
that of B. They are stretched by the same load. (a) p 2 sec (b) sec
Then the stress on B is p
(a) equal to that on A p
(c) sec (d) 2p sec
(b) four times that on A 2
(c) two times that on A 36. Tube A has both ends open while tube B has
(d) half that on A one end closed, otherwise they are identical. The
31. A liquid is allowed to flow into a tube of truncated ratio of fundamental frequency of tube A and B
cone shape. Identify the correct statement from is
the following. (a) 1 : 2 (b) 1 : 4 (c) 2 : 1 (d) 4 : 1
(a) The speed is high at the wider end and low 37. The current in the 1W resistor shown in the
at the narrow end. circuit is
(b) The speed is low at the wider end and high
at the narrow end. 2
(a) A 4W
(c) The speed is same at both ends in a stream 3
line flow. (b) 3 A 1W 6V
(d) The liquid flows with uniform velocity in (c) 6 A
the tube. (d) 2 A 4W
32. A planet revolves in an elliptical orbit around 38. The work done by an uniform magnetic field, on a
the sun. The semi-major and semi-minor axes are moving charge is
r r
a and b. Then the square of time period, T is (a) zero because F acts parallel to v
r r
directly proportional to (b) positive because F acts perpendicular to v
r r
(a) a3 (b) b 3 (c) zero because F acts perpendicular to v
r r
æa+bö
3
æa-bö
3 (d) negative because F acts parallel to v
(c) ç ÷ (d) ç ÷ 39. In Young's double slit experimental setup, if the
è 2 ø è 2 ø
33. The surface of a metal is illuminated with the wavelength alone is doubled, the bandwidth b
light of 400 nm. The kinetic energy of the becomes
ejected photoelectrons was found to be 1.68 b
(a) (b) 2b (c) 3b (d) b
eV. The work function of the metal is (hc = 2
1240 eV.nm) 40. In Young's double slit experiment, the central
(a) 3.09 eV (b) 1.42 eV point on the screen is
(c) 1.51 eV (d) 1.68 eV (a) bright
34. When a system is taken from state i to state f (b) dark
along the path iaf, it is found that Q = 50 cal and (c) first bright and then dark
W = 20 cal. Along the path ibf Q = 36 cal. W (d) first dark and then bright
along the path ibf is
a f PART - II (CHEMISTRY)
41. The work done in ergs for the reversible
expansion of one mole of an ideal gas from a
i b volume of 10 litres to 20 litres at 25°C is
(a) 2.303 × 298 × 0.082 log 2
(a) 14 cal (b) 6 cal (c) 16 cal (d) 66 cal (b) 298 × 107 × 8.31 × 2.303 log 2
35. If the differential equation for a simple harmonic
(c) 2.303 × 298 × 0.082 log 0.5
d2y
motion is 2 + 2y = 0, the time-period of the (d) 8.31 × 107× 298 – 2.303 log 0.5
dt
motion is
42. A Fischer projection of (2R, 3S)-2,3-butanediol
is : - (c) O

CH3 CH3
O
HO H HO H
(a) HO H
(b) H OH
CH3 CH3
(d) O O

CH3 CH3
48. The electrode potentials for
H OH H OH
(c) HO H
(d) H H Cu2+ (aq) + e– ¾¾ ® Cu+(aq)
CH3 +
and Cu (aq) + e ¾¾– ® Cu(s)
CH3
43. Arrange the following particles in increasing are + 0.15 V and + 0.50 V, respectively. The value
order of values of e/m ratio : electron (e), proton of E° 2+ will be :
Cu / Cu
(p), neutron (n) and a-particle (a) - (a) 0.500 V (b) 0.325 V
(a) n, p, e, a (b) n, a, p, e (c) 0.650 V (d) 0.150 V
(c) n, p, a, e (d) e, p, n, a
44. Acidified potassium dichromate is treated with 49. Deep sea divers used to respirate a mixture of
hydrogen sulphide. In the reaction, the oxidation (a) Oxygen and argon
number of chromium (b) Oxygen and helium
(a) Increases from + 3 to +6
(b) Decreases from +6 to +3 (c) Oxygen and nitrogen
(c) Remains unchanged (d) Oxygen and hydrogen
(d) Decreases from +6 to +2 50. The wavelengths of two photons are 2000Å and
45. For the reaction N2 + 3H2 ® 2NH3 4000Å respectively. What is the ratio of their
D[NH 3 ] energies?
if = 2 × 10–4 mol l–1s–1, then value of
Dt (a) 1/4 (b) 4 (c) 1/2 (d) 2
– D[H 2 ] would be 51. Ethylene glycol, on oxidation with per-iodic acid,
gives
Dt
(a) 1 × 10–4 mol L–1s–1 (a) Oxalic acid (b) Glycol
(b) 3 × 10–4 mol L–1s–1 (c) Formaldehyde (d) Glycolic acid
(c) 4 × 10–4 mol L–1s–1 52. What is X in the following change ?
(d) 6 × 10–4 mol L–1s–1
46. The value of Kc for the reaction : O OH OCH 3
A + 3B 2C at 400°C is 0.5. Calculate the X
| |
H2C C - CH3 ¾¾® H 2 C - C - CH3
value of KP | |
(a) 1.64 × 10–4 (b) 1.64 × 10–6 CH3 CH3
(c) 1.64 × 10–5 (d) 1.64 × 10–3
47. Tautomerism is net exhibited by – (a) CH3OH,H 2SO 4

(a) CH = CH – OH +
(b) CH3OH,CH3O N a

(b) O (c) H 2O / H 2SO 4 followed by CH 3OH

(d) CH3MgBr/ H3O+
O
53. In a closed insulated container, a liquid is stirred 59. The reaction 2NO(g) + O2 (g) ® 2NO2(g) is of
with a paddle to increase its temperature. In this first order. If volume of reaction vessel is reduced
process, which of the following is true ?
to 1/3, the rate of reaction would be
(a) ΧE < W < Q < 0 (a) 1/3 times (b) 2/3 times
(b) ΧE ¹ 0, Q < W < 0 (c) 3 times (d) 6 times
(c) ΧE < W ¹ 0,Q < 0 60. Which are the starting materials for the
preparation of?
(d) ΧE < Q ¹ 0, W < 0
54 At low pressure, the van der Waal's equation is O
reduced to
PVm a
(a) Z= = 1- NO2
RT VRT
PVm b
(b) Z= = 1+ P
RT RT
(c) PVm = RT (a)

PVm a
(d) Z= = 1-
RT RT
55. Copper sulphate solution reacts with KCN to (b)
give
(a) Cu(CN)2 (b) CuCN
(c) K2 [Cu(CN)4] (d) K3[Cu(CN)4]
56. For the reaction
1
H2 (g) + O2 (g) ® H2O(l), DH = -285.8 kJ mol-1
2 (c)
DS = -0.163 kJ mol-1K -1.
What is the value of free energy change at
27°C for the reaction ?
(d) Any of the three
(a) –236.9 kJ mol–1 (b) –281.4 kJ mol–1
(c) –334.7 kJ mol–1 (d) +334.7 kJ mol–1 61. Which element gives maximum number of
oxides?
CH3
K Cr O CH MgI (a) V (b) Cr (c) Mn (d) Fe
57. A ¾ ¾2¾2¾7¾
® B ¾ ¾ 3¾ ¾® CH 3 –C – CH3,
dil.H 2SO 4 H 2O 62. An organic compound 'A' has the molecular
OH formula C3 H6O, it undergoes iodoform test.
the reactant A is When saturated with dil. HCl it gives 'B' of
(a) CH3CHOHCH3 (b) CH3COCH3 molecular formula C9H14O. A and B respectively
(c) C2H5OH (d) CH3COOH are
58. Bragg's law is given by the which of the (a) Propanal and mesitylene
following equation? (b) Propanone and mesityl oxide
(a) nl = 2q sin q (b) nl = 2d sin q (c) Propanone and 2,6-dimethyl-2,
q d 5-heptadien-4-one
(c) 2nl = d sin q (d) n = sin q (d) Propanone and mesitylene oxide
2 2
 (a) CH3 – CH2 – Br
(b) CH3 – CH2 – NH2
63. .
O
||
Here Z is (c) CH3 – CH2 – C– Br
OH 14 (d) CH3 – CH2 – CH2 – NH2
CH2
(a) 68. Calculate the energy needed to convert three
moles of sodium atoms in the gaseous state to
sodium ions. The ionization energy of sodium is
OH
14 CH2 495 kJ mol–1–
(b) (a) 1485 kJ (b) 495 kJ
(c) 148.5 kJ (d) None
69. The uncertainty in position and velocity of a particle
are 10–10 m and 5.27 × 10–24 ms–1 respectively.
(c) Calculate the mass of the particle is (h = 6.625 ×
10–34 Js) –
(a) 0.099 kg (b) 0.99 g
(c) 0.92 kg (d) None
70. Choose the complex which is paramagnetic
(d)
(i) [Fe (H2O)6]2+ (ii) K3 [Cr(CN)6]
64. Calculate the entropy change in melting 1 mole (iii) K3[Fe(CN)6] (iv) K2 [Ni(CN)4]
of ice at 273K, DHof = 6.025 kJ/mole- (a) (i) , (ii) and (iii) (b) (i), (iii) and (iv)
(a) 11.2 JK–1 mol–1 (b) 22.1 JK–1 mol–1 (c) (ii), (iii), and (iv) (d) (i), (ii) and (iv)
(c) 15.1 JK–1 mol–1 (d) 5.1 JK–1 mol–1 71. Phosphine is generally prepared in the
65. The rate constant is doubled when temperature laboratory :
increases from 27 oC to 37 oC. Activation energy (a) By heating phosphorus in a current of
in kJ is
hydrogen
(a) 34 (b) 54 (c) 100 (d) 50
(b) By heating white phosphorus with an
NaOH
66. In the reaction, C6 H 5 OH ¾¾¾¾ ® (A) aqueous solution of caustic potash
CO 2 HCl
(c) By decomposition of P2H4 at 110°C
¾¾¾¾¾¾¾ ®(B) ¾¾¾ ®(C), the com- (d) By heating red phosphorus with an aqueous
140°C,(4 - 7)atm
pound (C) is solution of caustic soda
(a) Benzoic acid (b) Salicylaldehyde 72. In a hydrogen – oxygen fuel cell, combustion of
(c) Chlorobenzene (d) Salicylic acid hydrogen occurs to :
67. Starting from propanoic acid, the following re- (a) Produce high purity water
actions were carried out (b) Create potential difference between the two
Propanoic acid electrodes
SOCl NH Br + KOH (c) Generate heat
¾¾¾¾
2 ® X ¾¾¾
3 ® Y ¾¾¾¾¾
2 ®Z
(d) Remove adsorbed oxygen from electrode
What is the compound Z?
surfaces
73. Among the following molecule 79. An endothermic reaction with high activation
(i) XeO3 (ii) XeOF4 (iii) XeF6 energy for the forward reaction is given by the
Those having same number of lone pairs on Xe diagram.
are

Potential energy
(a) (i) and (ii) only (b) (i) and (iii) only
(c) (ii) and (iii) only (d) (i), (ii) and (iii) R P
74. An alkene of molecule formula C 9 H18 on (a)
ozonolysis gives 2, 2-dimethylpropanal & 2-
butanone, then the alkene is Reaction coordinate

(a) 2, 2, 4-trimethyl -3-hexene

(b) 2, 2, 6-trimethyl -3-hexene

Potential energy
(c) 2, 3, 4-trimethyl -2-hexene
(d) 2, 2-dimethyl -2-heptene
75. Glucose when heated with CH3OH in presence (b) R
P
of dry HCl gas gives a- and b-methyl glucosides
Reaction coordinate
because it contains:
(a) An aldehyde group
(b) A - CH2OH group
(c) A ring structure
(d) Five hydroxyl groups
76. When acetylene is passed into methanol at 160- (c)
200ºC in the presence of a small amount of
potassium methoxide under pressure, the
following is formed –
(a) Polyvinyl alcohol
(b) Divinyl ether
(c) Dimethyl ether
(d) Methyl vinyl ether (d)
77. Which compound can exist in a dipolar (zwitter
ion) state ?
(a) C6H5CH2CH(N=CH2)COOH
80 . The volume of a closed reaction vessel in which
(b) (CH3)2CH.CH(NH2)COOH
the following equilibrium reaction occurs is
(c) C6H5CONHCH2COOH
halved :
(d) HOOC.CH2CH2COCOOH
78. A coordination complex compound of cobalt has 2SO2(g) + O2(g) 2SO3(g)
the molecular formula containing five ammonia As a result,
molecules, one nitro group and two chlorine
atoms for one cobalt atom. One mole of this (a) The rates of forward and backward
compound produces three mole ions in an reactions will remain the same.
aqueous solution; on reacting with excess of
(b) The equilibrium will not shift.
AgNO3, AgCl is precipitated. The ionic formula
for this complex would be: (c) The equilibrium will shift to the right.
(a) [Co(NH3)5(NO2)]Cl2
(d) The rate of forward reaction will become
(b) [Co(NH3)5 Cl] [Cl(NO2)]
double that of reverse reaction and the
(c) [Co(NH3)4 (NO2) Cl] [(NH3)Cl] equilibrium will shift to the right.
(d) [Co(NH3)5] [NO2)2Cl2]
 PART - III (MATHEMATICS) 1 2
(a) 2
+
81. If tan q = n for some non-square natural 1 + 25 x 1 + x2
number n, then sec 2q is : 5 2
(a) a rational number (b) 2
+
1 + 25 x 1 + x2
(b) an irrational number
(c) a positive number 5
(c)
(d) none of the above 1 + 25x 2
x y 1
82. If z = x + iy, z1 / 3 = a – ib, then – = k ( a2 – (d)
a b
1 + 25x 2
2
b ) where k is equal to
(a) 1 (b) 2 (c) 3 (d) 4 é0 c - bù éa 2 ab ac ù
83. If the coordinates at one end of a diameter of the ê ú ê ú
89. If A = ê- c 0 a ú and B = ê ab b2 bc ú ,
circle x2 + y2 – 8x – 4y + c = 0 are (–3, 2), then the ê ac
êë b - a 0 úû bc c 2 úú
coordinates at the other end are ëê û
(a) (5, 3) (b) (6, 2) (c) (1, –8) (d) (11, 2) then AB is equal to
84. The system of linear equations : x + y + z = 0, 2x (a) B (b) A (c) O (d) I
+ y – z = 0, 3x + 2y = 0 has : 90. A circle has radius 3 and its centre lies on the
(a) no solution
(b) a unique solution line y = x - 1 . The equation of the circle, if it
(c) an infinitely many solution passes through (7, 3), is
(d) None of these (a) x 2 + y 2 + 8 x - 6 y + 16 = 0
-1 + 3i
85. If w = then (3 + w + 3w2)4 is (b) x 2 + y 2 - 8 x + 6 y + 16 = 0
2
(a) 16 (b) – 16 (c) 16w (d) 16w2 (c) x 2 + y 2 - 8 x - 6 y - 16 = 0
86. If the lines 3x – 4y + 4 = 0 and 6x – 8y – 7 = 0 are
tangents to a circle, then radius of the circle is (d) x 2 + y 2 - 8 x - 6 y + 16 = 0
91. At how many points between the interval (–¥, ¥)
3 2 1 5
(a) (b) (c) (d) is the function f (x) = sin x is not differentiable.
4 3 4 2 (a) 0 (b) 7 (c) 9 (d) 3
87. The position vector of A and B are 92. If vector equation of the line
2iˆ + 2jˆ + kˆ and 2iˆ + 4jˆ + 4kˆ x - 2 2y - 5
= = z + 1, is
2 -3
The length of the internal bisector of ÐBOA of
triangle AOB is r æ 5 ö æ 3 ö
r = ç 2iˆ + ˆj - kˆ ÷ + l ç 2iˆ - ˆj + pkˆ ÷ then p is
è 2 ø è 2 ø
136 136
(a) (b) equal to
9 9 (a) 0 (b) 1 (c) 2 (d) 3

20 217 ( x + 7) - 3 (2 x - 3)
(c) (d) 93. Evaluate lim .
3 9 x ®2 3 ( x + 6) - 2 3 (3x - 5)
17 17 34 26
4x 2 + 3x dy (a) (b) (c) (d)
88. If y = tan -1 -1 = 9 18 23 7
+ tan , then
1 + 5 x2 3 - 2x dx
94. The radius of a right circular cylinder increases at dy
the rate of 0.1 cm/min, and the height decreases at 98. If sin y = x sin (a + y), then is equal to :
dx
the rate of 0.2 cm/min. The rate of change of the
volume of the cylinder, in cm3/min, when the sin a sin 2 (a + y)
radius is 2 cm and the height is 3 cm is (a) (b)
sin (a + y) sin a
8p 3p 2p (c) sin (a + y) (d) None of these
(a) –2p (b) - (c) - (d)
5 5 5 9x
99. ò (27e + e12x )1/3dx is equal to
95. If a, b, c are in A. P., then the value of
(a) (1/4) (27 + e3x)1/3 + C
x ∗1 x∗2 x∗a (b) (1/4) (27 + e3x)2/3 + C
x∗2 x ∗3 x∗b (c) (1/3) (27 + e3x)4/3 + C
is:
x∗3 x∗4 x∗c (d) (1/4) (27 + e3x)4/3 + C
100. The area under the curve y = | cos x – sin x |,
(a) 3 (b) – 3
p
(c) 0 (d) None of these 0£ x£ , and above x-axis is :
2
(a) 2 2 (b) 2 2 - 2
3
96. The solution of sin x = – is
2 (c) 2 2+2 (d) 0
101. The conic represented by
4p
(a) x = np + (–1)n , where n Î Z x = 2 (cos t + sin t), y = 5 (cos t – sin t) is
3
(a) a circle (b) a parabola
2p (c) an ellipse (d) a hyperbola
(b) x = np + (–1)n , where n Î Z
3 r r 2 rr r r
( ) ( )
2
102. If a ´ b + a.b = 676 and b = 2 , then a is
3p
(c) x = np + (–1)n , where n Î Z
equal to
3
(d) None of the these (a) 13 (b) 26
(c) 39 (d) None of these
97. The equation y 2 + 3 = 2(2 x + y ) represents a 103. The equation of the plane which bisects the
parabola with the vertex at angle between the planes 3x – 6y + 2z + 5 = 0 and
4x – 12y + 3z – 3 = 0 which contains the origin is
æ1 ö
(a) ç , 1÷ and axis parallel to y-axis (a) 33x – 13y + 32z + 45 = 0
è2 ø
(b) x – 3y + z – 5 = 0
æ 1ö (c) 33x + 13y + 32z + 45 = 0
(b) ç1, ÷ and axis parallel to x-axis
è 2ø (d) None of these
104. A wire 34 cm long is to be bent in the form of a
æ1 ö æ3 ö quadrilateral of which each angle is 90°. What is
(c) ç , 1÷ and focus at ç , 1÷
è2 ø è2 ø the maximum area which can be enclosed inside
the quadrilateral?
æ 1ö æ3 ö (a) 68 cm2 (b) 70 cm2
(d) ç1, ÷ and focus at ç , 1÷
è 2ø è2 ø (c) 71.25 cm2 (d) 72. 25 cm2
 111. If f (x) = x3 + bx2 + cx + d and 0 < b2 < c, then in
sin x (-¥, ¥),
105. If ò sin(x - a) dx = Ax + B log sin(x - a) + C, (a) f (x) is a strictly increasing function
then value of (A, B) is (b) f(x) has local maxima
(c) f (x) is a strictly decreasing function
(a) (- cos a, sin a ) (b) (cos a, sin a) (d) f (x) is bounded
112. The solution of the differential equation
(c) (- sin a, cos a) (d) (sin a, cos a )
106. The equation of the chord of the hyperbola
2 2
{1+ x (x 2
+ y2 ) } dx + { ( x 2
) }
+ y 2 –1 y dy =
25 x - 16 y = 400 that is bisected at point 0 is
(5, 3) is:
y2 1 2
( )
3/ 2
(a) 135 x – 48 y = 481(b) 125 x – 48 y = 481 (a) x2 + + x + y2 =C
2 3
(c) 125 x – 4 y = 48 (d) None of these
y2 1 2
( )
1/ 2
(b) x – + x + y2 =C
p /3 3 2
1
107. Value of ò dx is
1 + cot x y2 1 2
( )
3/ 2
p /6 (c) x – + x + y2 =C
2 3
p p (d) None of these
(a) (b)
6 12 xdy
113. The integrating factor of - y = x 4 - 3 x is
dx
12
(c) (d) None of these
p 1
(a) x (b) log x (c) (d) –x
108. Th e domain of the function f (x) = x
114. It is given that the events A and B are such that
1
is : 1 1 2
| x – 2 | – ( x – 2) P ( A) = , P( A | B ) = an d P ( B | A) = .
4 2 3
(a) (– ¥, 2] (b) (2, ¥) Then P(B) is
(c) (–¥, 2) (d) [2, ¥)
1 1 2 1
109. Six identical coins are arranged in a row. The (a) (b) (c) (d)
6 3 3 2
number of ways in which the number of tails is
115. Let f : R ® R, g : R ® R be two functions such
equal to the number of heads is
that
(a) 20 (b) 9 (c) 120 (d) 40 f(x) = 2x – 3, g(x) = x3 + 5. The function (fog)–1 (x)
110. Let f be the function defined by is equal to
1/ 3 1/ 3
æ x+7ö æ 7ö
ì x 2 -1 (a) ç ÷ (b) çx- ÷
ï 2 , x ¹1 è 2 ø è 2ø
f ( x ) = í x - 2 | x - 1 | -1 1/ 3 1/ 3
ï æ x-2ö æ x-7ö
î1 / 2, x =1 (c) ç ÷ (d) ç ÷
è 7 ø è 2 ø
(a) The function is continuous for all values of x 116. The inverse of the statement (p Ù ~ q) ® r is
(b) The function is continuous only for x > 1 (a) ~ (p Ú ~q) ® ~ r (b) (~p Ù q) ® ~ r
(c) The function is continuous at x = 1 (c) (~p Ú q) ® ~ r (d) None of these
(d) The function is not continuous at x = 1
117. The value of x in the interval [4, 9] at which the 123. Find the antonym of the word AMELIORATE
(a) Improve (b) Depend
function f (x) = x satisfies the mean value
(c) Soften (d) Worsen
theorem is
124. Find the meaning of the given idiom
13 17 21 25 A bolt from the blue
(a) (b) (c) (d)
4 4 4 4 (a) An unpleasant event
3 (b) An inexplicable event
118. The value of the integral ò-1 (| x | + | x - 1 |)dx (c) A delayed event
is (d) An unexpected event
125. Read the passage and answer the given question
9 There seems to be no chilly distance existing
(a) 4 (b) 9 (c) 2 (d)
2 between the German students and the professor,
119. Let a, b, c, be in A.P. with a common difference d. but, on the contrary, a companionable
intercourse, the opposite of chilliness and
Then e1 / c , e b / ac , e1 / a are in : reserve. When the professor enters a beer hall
(a) G.P. with common ratio ed in the evening where students are gathered
(b) G.P with common ratio e1/d together, these rise up and take off their caps
2 2 and invite the old gentleman to sit with them
(c) G.P. with common ratio e d /( b -d ) and partake. He accepts, and the pleasant talk
(d) A.P. and the beer flow for an hour or two, and by and
120. If the second term in th e expansion by the professor, properly charged and
æ ö
n
C3 n comfortable, gives a cordial good night, while
ç13 a + a ÷ is 14a5/2, then = the students stand bowing and uncovered, and
ç ÷ n
a -1
C2 then he moves on his happy way homeward
è ø
(a) 4 (b) 3 (c) 12 (d) 6 with all his vast cargo of learning afloat in his
hold. Nobody finds fault or feels outraged. No
PART - IV (ENGLISH) harm has been done.
121. In the given sentence, find out which part has What does the author mean by the phrase 'no
an error. The letter of that part will be your chilly distance'?
answer. If there is no error, mark (d) as your (a) Professor's home is not very far from the
answer. beer hall.
She is a brilliant teacher (a)/ but of her three (b) Students and the professor are very
children (b)/ neither has any merit. (c)/ No error friendly with each other.
(d) (c) The weather is not very chilly in Germany.
122. Find the synonym of the word IMPECCABLE (d) The professor being very strict scares the
(a) Remarkable (b) Unbelievable students quite a few times as in the beer
(c) Flawless (d) Displeasing hall.
 SOLUTIONS
PART - I (PHYSICS)
N
r l1
1. (c) R1 = , now l2 = 2l1 and r2 = 2r1
A1

A1 = pr12
t
A 2 = p(r2)2 = p (2r1)2 = 4p r12 = 4A1

rl 2 5. (c) Ist excited state corresponds to n = 2

R2 = 2nd excited state corresponds to n = 3
A2
1
r(2 l1 ) r l1 R1 As E µ 2
\ R2 = = = n
4 A1 2 A1 2
\ Resistance is halved, but specific E1 n 22 32 9
\ = = =
resistance remains the same. E 2 n12 2 2 4

100 100 6. (d) (A) is a NAND gate so output is

2. (d) P2 = P - P1 = - = -3 .75 D
80 20 1´ 1 = 1 = 0
3. (d) de-Broglie wavelength, (B) is a NOR gate so output is

h h 0 +1 = 1 = 0
l= =
p 2.m.(K.E) (C) is a NAND gate so output is
0 ´1 = 0 = 1
1
\ lµ (D) is a XOR gate so output is
K. E
0Å0 = 0
If K.E is doubled, then de-Br oglie 7. (a) Work done in displacement of charge,
W = qDV
l where DV = potential difference between
wavelength becomes
2 the displacement of charge
Hence, work done in complete rotation is
4. (c) No. of nuclide at time t is given by
zero.
N = N o e - lt 8. (a) Equivalent capacitance of two parallel
capacitors 10 mF and 6 mF = (10 + 6)mF = 16 mF
Where, N o = initial nuclide This 16 mF capacitor is in series combination
Thus this equation is equivalent to with 4mF capacitor,
\ Equivalent capacitance of the entire
y = ae - kx
16 ´ 4 64
So correct graph is in option (c) combination = = = 3.2 mF
16 + 4 20
 13. (c) In a uniform electric field, net force = 0, but
0.693 1
9. (c) Half life, Th = , Tm = torque ¹ 0.
l l
14. (c) Let the speed of water = ur
Clearly, Th < Tm .
Speed of swimmer = vr = 0.5 m/sec
Angle between vr and ur is 120°. Then
10. (a) Ic = 5.488 mA, Ie = 5.6 mA

Ic r
a= u u 1
Ie sin q = r Þ = or u = 0.25 ms–1
v 0.5 2
5.488
a= B u C
5.6

a direction of flow
b= = 49 v
(1 - a) of river
30º
11. (a) Magnetic field due to long wire,
120º
m0i 1
B= or B µ A
2pr r
When r is doubled, the magnetic field
15. (a) Radius of drop, r = 0.3 mm = 0.03 cm
becomes half, i.e., now the magnetic field
will be 0.2 T. Terminal velocity, v = 1 m/s = 100 cm/sec
12. (a) Viscosity of air, h = 8 × 10–5 poise
Viscous force, f = 6 phrv
F = 6 × 3.14 × (8 ×10–5) × 0.03 ×100 = 4.52
u (m/s)
×10–3 dyne
16. (d) Rate of transmission of heat
20 A
Temperature difference
=
D Thermal Resistance
10 (1)
(3) dQ d q
0 t (s) \ =
2 4 6 8 10 dt R
(2)
–10 dQ (q - q2 ) q1 - q
Here, = =
dt R2 R1
–20
C
q - q2 q1 - q
Þ =
R2 R1
Total distance covered in 10 s = Area 1 +
Area 2 + Area 3 Þ R1q - R1q2 = R2 q1 - R2q
1 1 1
Þ ´ 6 ´ 20 + ´ 2 ´ 20 + ´ 2 ´10 = 90 m Þ q( R1 + R2 ) = R2 q1 + R1q2
2 2 2
Total displacement in 10s = Area 1 – Area 2 ( R2 q1 + R1q2 )
\ q=
+ Area 3 ( R1 + R2 )
1 1 1
Þ ´ 6 ´ 20 - ´ 2 ´ 20 + ´ 2 ´ 10 = 50 m
2 2 2
17. (b) Apply law of conservation of energy, 25. (b) Given, R = XL = 2XC
1 1
mv2 = kx 2 Z = R 2 + (X L - X C ) 2
2 2
Þ mv = kx2 or 0.5 × (1.5)2 = 50×x2
2 = (2X C )2 + (2X C - X C ) 2
\ x = 0.15 m
18. (b) Taking the same mass of sphere if radius is = 4X 2C + X 2C
increased then moment of inertia, angular
(XL–XC)
velocity and rotational kinetic energy will
change but according to law of
conservation of momentum, angular Z

momentum will not change.

19. (c) For a perfectly rigid body strain produced
is zero for the given force applied, so f
R
Y = stress/strain = Infinite (¥)
20. (a) According to Kirchhoff’s first law,
At junction A, iAB = 2 + 2 = 4 A 5R
= 5X C = [Q R = 2XC]
At junction B, iAB = iBC + 1 Þ iBC = 4 – 1 = 2
3A (X L - X C ) (2X C - X C )
tan f = =
2A R 2X C
iAB 1A
1.3 A 1 -1 æ 1 ö
A B tan f = ; f = tan çè ÷ø
iBC 2 2
2A C
i 26. (d) According to the law of conservation of
momentum,
At junction C, i = iBC – 1.3 = 3 – 1.3 = 1.7A P(initial) = P(final)
21. (d) Þ mu1 + Mu2 = mv1 + Mv2
22. (b) When a particle cover half of circle of radius Þ 0 + 0 = 10 × 10 × 10–3 × 800 + [100 – 10 ×
r, then displacement is AB = 2r 10 × 10–3]v
Distance = half of circumference of circle =
-800
pr Þv= Þ -0.8m / sec
999
B Negative sign indicates that the velocity is
opposite to the direction of bullets.
r
pr 27. (a) Escape velocity does not depend upon the
r mass of the body.
28. (b) By energy conservation
A
(K.E )i + (P.E )i = (K.E ) f + (P.E ) f
23. (b) As the magnet falls, the magnetic flux linked
(K.E )i = 0, (P.E ) i = mgh, (P.E ) f = 0
with the ring increases. This induces emf in
the ring which opposes the motion of the (K.E)f = ½Iω2 + ½mvcm
2
falling magnet, so a < g. For solid cylinder, moment of inertia,
24. (b) Change in momentum = F × t I = ½mR2
= mg × 10
(K.E )i + (P.E )i = (K.E ) f + (P.E ) f
Þ 0.5 × 9.8 × 10
Þ 49 N-sec
 32. (a) The square of the period of planet is directly
æ v2 ö
so, mgh = ½(½mR ) ç cm2
+ ½mv 2cm proportional to the cube of the semi-major
2 ÷
è R ø axis of the elliptical orbit.
Þ T2 µ a3
Þ vcm = 4gh / 3
29. (c) For block A, 33. (b) Energy of incident light, E = 12400
T – mN = 5a and N = 5g l (Å)

1240
E= = 3.1 eV
N 400
Q E = W0 + Kmax
A a Þ 3.1 = W0 + 1.68
T
5 kg Þ W0 = 1.42 eV
mN
a 34. (b) For path iaf,
T
Q = 50 cal
W = 20 cal
5 kg 5 kg B
By first law of thermodynamics,
DU = Q - W = 50 – 20 = 30 cal.
For path ibf
a f
For block B,
5g – T = 5a
i b
Þ T = 36.75N, a = 2.45 m/sec2
Force 1 Q' = 36 cal
30. (b) Stress = \ Stress µ 2 W' = ?
Area πr
or, W' = Q' – DU'
2 Since, the change in internal energy does
S B æ rA ö
= ç ÷ = (2)2 Þ S B = 4 S A not depend on the path, therefore
S A è rB ø
DU ' = 30 cal
31. (b) The theorem of continuity is valid.
\ W' = Q' – DU ' = 36 – 30 = 6 cal.
\ A1v1r = A2v2r 35. (a) The differential equation of simple
As the density of the liquid can be taken as harmonic motion is
uniform.
d2y d2y
+ 2 y = 0 or = –2 y ...(i)
A2 dt 2 dt 2
A1 Standard equation of simple harmonic
motion is

d2y
\ A1v1 = A2v2 = –w2 y ...(ii)
dt 2
Þ Smaller the area, greater the velocity. Comparing eq. (i) and (ii),
w2 = 2 or w = 2
 2p lD
As we know, w = 39. (b) Fringe width, b =
T d

2p 2p When l alone is doubled then fringe width

\ Time period, T = = = p 2 sec becomes
w 2
36. (c) Fundamental freq. for, (2l )D
b' = = 2b
d
v
Tube A Þ f A = 40. (a) In the normal adjustment of YDSE, Path
2L
difference between the waves at central
v location is always zero. So maxima is
Tube B Þ f B = obtained at central position. Central point
4L
on the screen is bright.
Now,
PART - II (CHEMISTRY)
fA v 4L 2
= ´ =
f B 2L v 1 V2
41. (b) W < 2.303 nRT log
fA : fB = 2 : 1 V1

37. (d) Two 4W resistors are in parallel

20
combination. Their equivalent resistance < 2.303´1´8.314´10 7 ´ 298 log
10

4 ´ 4 16 < 298´107 ´8.31´ 2.303log 2

= = = 2W
4+4 8
\ Total resistance of the

4W 42. (a)
4W
i
43. (b)
1W 6v i

Electron Proton Neutron a -particle

network = 2 + 1 = 3W
e 1 unit 1 unit zero 2 units
m 1/1837 unit 1 unit 1 unit 4-units
6
\ Current through 1W resistor, i = = 2A e/m 1837 1 zero 1/2
3
38. (c) Force on moving charge while moving in 44. (b) Decreases from +6 to +3.
r r r r
magnetic field is; F < q (v ´ B) where F K 2 Cr2 O7 + 4H 2 SO 4 ® K 2 SO 4 + Cr2 (SO4 )3 + 4H 2 O + 3O
r éë H 2S + [O ] ® S + H 2 O ùû ´ 3
is perpendicular to v .
rr +6
Work done/sec = F.v = Fv cos90º = 0 K 2 Cr2 O7 + 4H 2SO4 + 3H 2S ®
+3
K 2SO 4 + Cr2 (SO4 )3 + 7H 2 O + 3S
45. (b) N2 + 3H2 ® 2NH3 46. (a) Kp = Kc [RT]Dng Dn = 2 – 4 = – 2

-D[N 2 ] 1 D[H 2 ] 1 D[NH3 ] T = 673K, Kc = 0.5,

=- = R= 0.082 L. atm. mol–1 K–1
Dt 3 Dt 2 Dt
Kp = 0.5 × (0.082×673)–2
-D[H2 ] 3 D[NH3 ] 3
\ = ´ = ´ 2 ´ 10-4 = 1.64 × 10– 4 atm.
Dt 2 Dt 2

= 3 × 10–4 mol L–1S–1

47. (d) (a)

(b)

(c)

(d) O O cannot tautomerise

o o 49. (b) An oxygen- helium mixture is used for

48. (b) Cu 2+ + 1e - ® Cu + ; DG1 = - n1E1 F ]
artificial respiration in deep sea diving
instead of air because nitrogen present in
Cu + + 1e - ® Cu ; DG o2 = - n 2E o2F
air dissolves in blood under high pressure
when sea diver goes into deep sea. When
Cu 2+ + 2e - ® Cu DG ° = DG1o + DG 2o
he comes to the surface nitrogen bubbles
out of the blood due to decrease in
– nE° F = –1 n 1 E1o F + (–1) n2 E o2 F pressure, causing pain. This disease is
called "bends".
– nE° F = –F (n1 E1o + n2 E o2 F )
c
50. (d) E1 = h. ; E2 = h. c
l1 l2
n1E1o + n2Eo2 0.15 ´1+ 0.50 ´1
E° = = = 0.325
n 2 E1 hc l 2 l 2 4000
= ´ = = =2
E 2 l1 hc l1 2000
51. (c) K Cr O
57. (a) CH3CHOHCH3 ¾¾¾¾¾
2 2 7
® CH3COCH3
C H 2OH dil.H2SO4
A B
| + HIO4 ® 2HCHO + HIO3 + H 2O
CH2OH
CH MgI
¾¾¾¾
3 ®(CH 3 )3 COH
52. (a) H 2O

58. (b) nl = 2d sin q

59. (c) For following reaction, 2NO(g) + O2(g)
® 2NO2(g)
When the volume of vessel is reduced to
1
then concentration of reactant becomes
53. (c) As the system is closed and insulated, no 3
heat enters. or leaves the system, i.e. Q = 0; three times.
[ ΧE < Q ∗ W < W. The rate of reaction for first order reaction
is proportional to the concentration. So rate
54. (a) When pressure is low
of reaction will increase three times.
é a ù 60. (c) (a) Nitration is difficult to be carried out,
ê P + 2 ú ( V - b ) = RT further the –NO 2 group will go to
ë V û
m-position to the > C = O group
a ab (b) Nitrobenzene, being deactivated toward
or PV = RT + Pb - + electrophilic substitution will not undergo
V V2
Friedal Craft reaction.
PV a (c) Benzene easily undergoes Friedal Craft
or = 1-
RT VRT reaction forming the required product.
61. (c) Among the transition metals, Mn forms
a maximum no. of oxides.
Z=-
VRT MnO Mn 3O 4 Mn 2O3 MnO 2 Mn 2O 7
basic amphoteric amphoteric amphoteric acidic
æ PV ö
çQ RT = Z ÷ 62. (c) The compound A with formula C3 H6 O
è ø gives iodoform test, it is propanone. It
forms a compound B having carbon atoms
three times to the number of carbon atoms
55. (d) CuSO 4 + 2KCN ® Cu ( CN ) 2 + K 2SO 4
in propanone, it is 2, 6-dimethyl-2,
2Cu ( CN ) 2 ® Cu 2 ( CN ) 2 5-heptadien-4-one.
or 2CuCN + CN – CN dil. HCl
cyanogen CH3 - C = O + CH3 - C- CH3 + O = C - CH3 ¾¾¾¾
®
| || |
O CH3
CuCN + 3KCN ® K3 éëCu ( CN)4 ùû CH3
(A)
colourless
56. (a) DG = DH - TDS, T = 27 + 273 = 300 K CH3 - C = CH - C - CH = C - CH3
| || |
DG = (–285.8) – 300 (–0.163) = –236.9 kJ CH3 O CH3
mol–1 (B)
2, 6-Dimethyl-2, 5-heptadien-4-one
63. (b) 68. (a) Energy needed to convert 1 mole of
sodium (g) to sodium ions = 495 kJ
\ Energy needed to convert 3 moles of
Na (g) to Na+ ions = 495 × 3 = 1485 kJ
69. (a) According to Heisenberg’s uncertainty
principle,
h
Dx . m Dn =
4p
h
or m =
4p Dx. Dn
DH f 6025J mol -1 =
64. (b) DSf = = = 22.1 JK–1
T 273K 6.625 ´ 10-34 Js
mol–1 4 ´ 3.143 ´ 10-10 m ´ 5.27 ´10 -24 ms -1
K2 Ea é 1 1 ù K2 Q [J = Kgm2s2]
65. (b) log = ê - ú ; If =2
K1 2.303R ë T1 T2 û K1 = 0.099 kg.
Ea é 1 1 ù 70. (a) (i) [Fe (H2O)6]2+
log 2 = -
2.303 ´ 8.314 êë 300 310 úû 3d 4s 4p 4d

æ 300 ´ 310 ö ×× ×× ×× ×× ×× ××
Ea = 0.3010 × 2.303 × 8.314 ç ÷
è 10 ø 3 2
sp d , Paramagnetic
= 53598.59 Jmol–1 = 54 kJ
66. (d) Treatment of sodium salt of phenol with (ii) [Cr(CN)6]3–
CO2 under pressure brings about substi-
tution of the –COOH group for the hydro-
gen of the ring. This is called as Kolbe's
reaction

(iii) [Fe(CN)6]3–

(iv) [Ni(CN)4]2–

SOCl 2
67. (b) CH 3CH 2 COOH ¾¾¾¾ ® CH 3CH 2 COCl
+SO 2 +HCl
(X) Thus complexes (i), (ii) and (iii) are paramagnetic
CH 3 CH 2 COCl + NH 3 ® CH 3 CH 2 CONH 2 + HCl
(Y) species.
CH3CH2CONH2 + Br2 / NaOH ® CH3CH2NH2 + CO2
Ethylamine, (Z)
71. (b) P4 + 3NaOH + 3H2O ® PH3 + 3NaH2PO2 75. (c) A ring structure
White Phosphine

72. (b) In hydrogen–oxygen fuel cell, following

reactions take place to create potential H–C–OH
difference between the two electrodes. H–C–OH
2H2 (g) + 4OH– (aq) ® 4H2O (l) + 4e– HO–C–H O HCl
+ CH3OH––––– ®
O2 (g) + 2H2O(l) + 4e- ® 4OH - (aq) H–C–OH
Overall reaction = 2H2 (g) + O 2 (g) ® 2H 2O(l) H–C

the net reaction is the same as burning CH2– OH

(combustion) of hydrogen to form water. Glucose

73. (d) XeO3: H OCH3

C
(CHOH)3 O
CH
CH2OH
XeOF4:
a-Methyl glucoside

76. (d) When acetylene is passed into methanol

at 160-200ºC in the presence of a small
amount (1-2%) of potassium methoxide
and under pressure just high enough to
prevent boiling, methyl vinyl ether is
XeF6:
formed.
The mechanism is believed to involve
nucleophildic attack in the first step.
HC º CH + CH3 O¯® C¯H = CH OCH3
CH OH
3 ®
¾¾¾¾ CH2 = CHO CH3 + CH3O¯
CH3 CH3 Methyl vinyl ether
| | 77. (b)
74. (a) CH3 - C - CHO + O == C - CH 2CH3
| ˆˆ† (CH3 ) 2 - CH.CH - COO –
(CH3 ) 2 .CH.CH - COOH ‡ˆˆ
CH3 | |
NH2 NH3+
78. (a) The most probable complex which gives
three mole ions in aqueous solution may
be [Co (NH3)5 NO2] Cl2.
CH3 CH3 79. (c) Endothermic reactions are those which
| | involve absorption of heat. High activation
CH3 - C - CH = C - CH 2CH3 energy means potential energy of product
|
CH3 must be much greater than reactants.
2,2,4 trimethyl-3-hexene
 [SO 3 ]2 a -3 b+ 2
80. (d) Kc = \ = 4 and = 2 Þ a = 11, b = 2
[SO 2 ]2 [O 2 ] 2 2
Thus, the coordinates of the other end of
If volume is reduced to half, Kc will
diameter are (11, 2)
decrease to half. Thus, to maintain the
84. (c) The system is homogenuous system.
equilibrium, the reaction should shift in the
\ it has either unique solution or infinite
forward direction, i.e. towards right. Also,
many solution depend on |A|
to attain equilibrium back, the rate of
forward direction will become double the 1 1 1
rate of backward direction. \ |A| = 2 1 -1 = 2 × 1 + 1 (– 3) + (4 – 3)
3 2 0
PART - III (MATHEMETICS)
=2–3+ 1=0
1 - tan2 q 1- n 1+ n
81. (a) cos 2q = = Þ sec 2q = -1 + 3i
2
1 + tan q 1 + n 1- n 85. (c) Let w =
2
Since, n is non-square natural number \ n ¹ 1 Now, 1 + w + w2 = 0, and w3 = 1
then (3 + w + 3w2)4 = (3 + w + 3w2 + 2w – 2w)4
1+ n
\ sec 2q = = rational number = (3 + 3w + 3w2 – 2w)4 = [3 (1 + 2 + w2) – 2w]4
1- n
= (0 – 2w)4 = 16w4 = 16w (Q w3 = 1)
86. (a) The diameter of the circle is perpendicular
82. (d) z1 / 3 = a - ib Þ z = (a - ib)3
distance between the parallel lines (tangents)
\ x + iy = a 3 + ib3 - 3ia 2 b - 3ab2 . Then 3x – 4y + 4 = 0 and

x 7
x = a 3 - 3ab 2 Þ = a 2 - 3b 2 3x – 4y – = 0 and so it is equal to
a 2

y 4 7/ 2 3
y = b 3 - 3a 2 b Þ = b 2 - 3a 2 + = . Hence radius is
b 9 + 16 9 + 16 2

x y 3
So, - = 4(a 2 - b 2 ) .
a b 4
87. (a) We have,
83. (d) The centre of the given circle is C º (4, 2)
Let A º (-3, 2) OA = | 2î + 2 ĵ + k̂ |= 3 ; OB =| 2î + 4 ĵ + 4k̂ |= 6
Since the internal bisector
divides opposite side in the

C B
A B(a, b )
(–3, 2) (4, 2)
C

O A
If (a, b) are the coordinates of the other end of
the diameter, then, as the middle ploint of the ratio of adjacent sides
diameter is the centre,
 Since the circle passes through the point
AC 3 1 (7, 3), therefore, the distance of the centre
\ = =
BC 6 2 from this point is the radius of the circle.
where OC is the bisector of ÐBOA . \ 3 = (h - 7)2 + (k - 3)2
\ Position vector of C is
Þ 3 = (h - 7)2 + (h - 1 - 3)2
2(2î + 2ˆj + k̂ ) + (2î + 4ˆj + 4k̂ ) 2î + 8 ˆj + 2k̂
= [using (i)]
2 +1 3
Þ h = 7 or h = 4
For h = 7, we get k = 6 and for h = 4, we get
8 136 k=3
\ OC = 2î + ĵ + 2k̂ =
3 9 Hence, the circles which satisfy the given
conditions are:
4x 2 + 3x ( x - 7)2 + ( y - 6)2 = 9
88. (c) y = tan -1 + tan -1
1 + 5x 2 3 - 2x
or x 2 + y 2 - 14 x + 12 y + 76 = 0
2 2 2
+x and ( x - 4) + ( y - 3) = 9 or
5 x - x
= tan -1 + tan -1 3
1 + 5x × x 2 x2 + y2 - 8x - 6y +16 = 0
1- × x
3 91. (a) The function f (x) = sin x is differentiable
for all x Î R. Therefore the number of points
2 in the interval (–¥, ¥) where the function is
= tan -1 5 x - tan -1 x + tan -1 + tan -1 x
3 not differentiable are zero.
x - 2 2y - 5
dy 5 92. (a) The given line is = = z + 1,
Þ = 2 -3
dx 1 + 25 x 2
5
y-
c - bù éa 2 ab ac ù x-2 2 = z +1
é0 Þ =
ê úê ú 2 3 0
89. (c) AB = ê- c 0 a ú ê ab b 2 bc ú -
2
êë b - a 0 úû ê ac bc c 2 ú
ëê úû
This shows that the given line passes through
æ 5 ö
the point ç 2, , -1÷ and has direction ratios
é abc - abc b 2 c - b 2 c bc 2 - bc 2 ù è 2 ø
ê 2 2 ú
AB = ê- a c + a c - abc + abc - ac + ac ú æ -3 ö
ê a 2 b - a 2 b ab 2 - ab 2 abc - abc ú çè 2, , 0÷ø . Thus, given line passes through
êë úû 2
the point having position vector
r 5
é0 0 0ù a= 2iˆ + ˆj - kˆ and is parallel to the vector
= ê0 0 0 ú = O 2
ê ú
êë0 0 0úû r æ 3 ö
b = ç 2iˆ - ˆj - 0kˆ ÷ . So, its vector equation is
è 2 ø
90. (d) Let the centre of the circle be (h, k).
Since the centre lies on the line y = x – 1 r æ 5 ö æ 3 ö
\ k=h–1 … (i) r = ç 2iˆ + ˆj - kˆ ÷ + l ç 2iˆ - ˆj - 0kˆ ÷ .
è 2 ø è 2 ø
Hence, p = 0
93. (c) We have
x +1 x + 2 x+a
1
( x + 7) - 3 (2 x - 3) æ 0 ö = 2x + 4 2x + 6 2x + 2b
L = lim ç form ÷ 2
x ®2 3 ( x + 6) - 2 (3 x - 5) è
3 0 ø x+3 x+4 x+c

Let x – 2 = t such that when x ® 2, t ® 0. Then

x +1 x + 2 x+a
1
1 1 = 2x + 4 2x + 6 2x + (a + c)
(t + 9) 2 - 3(2t + 1) 2 2
æ0 ö x+3 x+4 x+c
L = lim ç form ÷
1 1 0
t ®0 è ø
(t + 8) 3 - 2(3t + 1) 3 [using equation (i)]

x +1 x + 2 x + a
1
= 1
1 1
0 0 0 = .0=0
æ t ö2 2 2
ç1 + ÷ - (2t + 1) 2
x+3 x+4 x+c
3 9ø æ0 ö
= lim è 1 ç form ÷
2 t ®0 1 è0 ø
æ t ö3 [Applying R2 ® R2 – (R1 + R3) ]
ç 1 + ÷ - (3t + 1) 3
è 8ø
3 p
96. (a) We have, sin x = – = –sin
1t 1 1 2 3
- (2t ) -1
3 2 9 2 3 18 34
= lim = = . 4p
2 t ®0 t 1 1 2 1 23 Hence, sin x = sin , which gives
- (3t ) -1 3
83 3 24
94. (d) Given V = pr2h. 4p
x = np + (–1)n , where n Î Z.
Differentiating both sides, we get 3
97. (c) The given equation can be rewritten as
dV æ dh dr ö æ dh dr ö
= pç r2 + 2r h ÷ = pr ç r + 2h ÷
dt è dt dt ø è dt dt ø æ 1ö
(y – 1)2 = 4 ç x - ÷ which is a parabola
è 2ø
dr 1 dh 2
= and =-
dt 10 dt 10 æ1 ö
with its vertex ç , 1÷ axis along the line
æ æ 2ö è2 ø
dV æ 1 ö ö pr
= pr ç r ç - ÷ + 2 h ç ÷ ÷ = (- r + h)
dt è è 10 ø è 10 ø ø 5 y = 1, hence axis parallel to x-axis.
Thus, when r = 2 and h = 3, æ1 ö æ3 ö
Its focus is ç + 1, 1÷ , i.e., ç , 1÷ .
dV p(2) 2p è2 ø è2 ø
= ( -2 + 3) = .
dt 5 5 98. (b) Given, sin y = x sin (a + y)
95. (c) Given a, b, c are in A.P.
sin y
\ 2b = a + c ....(i) Þ x=
sin(a + y)
x +1 x + 2 x + a On differentiating w.r. to y, we get
Now, x + 2 x + 3 x + b
dx d é sin y ù
x +3 x + 4 x +c =
dy dy êë sin(a + y) úû
[Applying R2 ®2 R2]
 Eliminating t from (i) and (ii), we have
sin (a + y) cos y - sin y cos (a + y)
=
sin 2 (a + y) x2 y2 x2 y2
+ =2 Þ + = 1, which is an
4 25 8 50
sin a dy sin 2 (a + y) ellipse.
= 2 Þ = .
sin (a + y) dx sin a r r rr
( ) + ( a.b )
2 2
102. (a) Since, a ´ b = 676
ò
9x 12x 1/3
99. (d) Let I = (27e +e ) dx
r r r r
( ) + ( a . b cos q)
2 2
= ò e3x (27 + e3x )1/3 dx Þ a . b sin qnˆ = 676
Put 27 + e3x = t Þ 3e3x dx = dt
r2 r2
1 1 t 4 /3
2
(
2
Þ a . b sin q + cos q = 676 )
\ I=
3 ò t1/ 3dt = ´
3 4 /3
+C
r2 2 r2
Þ a ( 2 ) = 676 Þ a = 169
1
= (27 + e3x ) 4 /3 + C r
4
Þ a = 13
103. (d) Equation of plane bisecting the angle
100. (b) y = | cos x – sin x |
containing origin is (making constant term of
same sign)
Y
–3x + 6 y – 2 z – 5 é 4 x –12 y + 3z – 3 ù
=+ê
2 ú
f(x) = cos x g(x) = sin x
32 + 62 + 22 2 2
ë 4 + 12 + 3 û

–3x + 6 y – 2 z – 5 4 x – 12 y + 3z – 3
or =
X 7 13
O p/4 p/2 or 67x – 162y + 47z + 44 = 0.
104. (d) Let one side of quadrilateral be x and
another side be y so, 2(x + y) = 34
or, (x + y) = 17 … (i)
We know from the basic principle that for a
p /4 given perimeter square has the maximum
Required area = 2 ò (cos x - sin x ) dx area, so, x = y and putting this value in
0 equation (i)

é 2 ù 17
p/4 x=y=
= 2 [ sin x + cos x ]0 =2ê - 1ú 2
ë 2 û
17 17 289
= (2 2 - 2) sq. units Area = x . y = ´ = = 72.25
2 2 4
101. (c) From given equations
sin x sin(x - a + a)
x
= cos t + sin t … (i)
105. (b)
ò sin(x - a) dx = ò sin(x - a)
dx
2
sin(x - a ) cos a + cos( x - a) sin a
y
5
= cos t – sin t … (ii) = ò sin(x - a )
dx
 Adding (i) and (ii), we get
ò
= {cos a + sin a cot( x - a)}dx
p /3
sin x + cos x
= (cos a )x + (sin a) log sin(x - a) + C 2I = ò cos x + sin x
dx
p /6
\ A = cosa, B = sin a
106. (b) The equation of the chord, having mid-point p /3
p /3 p p p
x 2
y 2 Þ 2I = ò 1.dx = [ x ]p/6 = 3 - 6 = 6 Þ I = p/12
as (x1, y1), of the hyperbola 2
- = 1 is p /6
a b2
given by ì x – 2, x ³ 2
108. (c) |x – 2| = í
T = S1 ..... (i) î 2 – x, x < 2
xx1 yy1
where, T = - - 1 and ì0, x ³ 2
a 2
b2 Þ |x – 2| – (x – 2) = í
î4 – 2 x, x < 2
x12 y12 Þ given expression is defined for (– ¥, 2)
S1 = - -1 109. (a) Required number of ways
a2 b2
According to the question, 6! 720
= = = 20
(x1, y1) = (5, 3) and a2 = 16, b2 = 25 3!3! 6 ´ 6
as 25x2 – 16y2 = 400
x 2 -1 x +1
2 2 5x 3 y 25 9 110. (d) For x < 1, f ( x ) = =
Þ x - y =1\ – = – 2
x + 2x - 3 x+3
16 25 16 25 16 25
[Using (i)] 1
\ lim f (x ) =
Þ 125x – 48y = 625 – 144 Þ 125x – 48y = 481 x ®1 - 2
p /3
1 x 2 -1 x +1
107. (b) I = ò 1 + cot x
dx For x > 1, f ( x ) =
2
x - 2x + 1
=
x -1
p /6

\ lim f ( x ) = ¥
p /3
sin x x ®1+
=
ò sin x + cos x
dx … (i)
\ the function is not continuous at x = 1.
p /6
111. (a) f ( x ) = x3 + bx 2 + cx + d , 0 < b 2 < c

æp ö \ f '( x ) = 3x 2 + 2bx + c
p /3 sin ç - x÷
è2 ø Discriminant = 4b2 – 12c = 4(b2 – 3c) < 0
Then, I = ò æp ö æp ö
dx
p /6 sin ç - x ÷ + cos ç - x ÷ \ f '( x ) > 0 " x Î R
è2 ø è2 ø
Thus, f (x) is strictly increasing " x Î R
112. (c) Rearranging the equation, we have
p /3
cos x
Þ I= ò
p /6
cos x + sin x
dx … (ii)
dx – y dy + (x 2
)
+ y 2 (xdx + y dy) = 0

Þ dx – y dy +
1
2
(x 2
)
+ y 2 d(x2 + y2) = 0
 On integrating, we get
f (b) – f (a) 1 1
f ¢(c) = Þ = Þ c = 25
x–
y2
2
+
1
2 ò {
t dt = C, t = ( x2 + y 2 )} 118. (b) We have
b–a 2 c 5 4

ì- x - ( x - 1) = -2 x + 1, if x £ 0
y2 1 2
( )
3/ 2
or x – + x + y2 =C ï
| x | + | x - 1 |= í x - ( x - 1) = 1, if 0 £ x £ 1
2 3
ï x + x - 1 = 2 x - 1, if x ³ 1
î
dy
113. (c) Since x - y = x 4 - 3x
dx 3

dy y
ò
\ (| x | + | x - 1|)dx
\ - = x3 - 3 -1
dx x
0 1 3
Hence
1
= ò -1(-2x + 1)dx + ò 0 1dx + ò1 (2x - 1)dx
- ò dx 1
IF = e ò
Pdx
=e x = e - log x = 0 3
= éë - x + x ùû + [ x ] 0 + éë x - x ùû = 9
x 2 1 2
-1 1
1
114. (b) P(A) = 1/4, P(A/B) = , P(B/A) = 2/3 119. (c) a, b, c are in A.P. Þ 2b = a + c
2
By conditional probability, Now,
P(A Ç B) = P(A) P(B/A) = P(B)P(A/B) 2
e1/ c ´ e1 / a = e (a + c) / ac = e 2b / ac = (e b / ac )
1 2 1 1
Þ ´ = P ( B ) ´ Þ P( B ) = \ e1/c , e b/ac , e1/a in G.P. with common ratio
4 3 2 3
115. (d) We have, f(x) = 2x – 3, g(x) = x3 + 5
e b / ac
(fog)x = f(x3 + 5) = 2(x3 + 5) – 3 = 2x3 + 7 = = e (b -a ) / ac = e d /( b -d )( b + d )
1/ c
Let y = (fog)x = 2x3 + 7 e
2
1/ 3 1/ 3 d /( b -d 2 )
æ y-7ö -1 æ x -7 ö =e
Þ x =ç ÷ Þ ( fog ) x=ç ÷
è 2 ø è 2 ø [Q a, b, c are in A.P. with common
difference d \ b – a = c – b = d]
116. (c) The inverse of the proposition (p Ù ~ q)
® r is 5
~ (p Ù ~ q) ® ~ r º ~ p Ú ~ (~q) ® ~ r 120. (a) We have T2 = 14 a2
º~pÚq®~r
1 3 5
117. (d) (i) f (x) = x is continuous in [4, 9] Þ n C1 (a 13 ) n -1 (a 2 ) = 14a 2

1 n -1 3 5
(ii) f ¢(x) = +
2 x Þ na 13 2 = 14a 2 Þ n = 14
Thus f(x) is differentiable in (4, 9)
n 14
(iii) f(4) ¹ f(9). All the three conditions of LMV C3 C3 12
Þ = = =4
n 14 3
theorem satisfied then there exist at least one C2 C2
c Î (4, 9) such that.
 124. (d) The idiom 'a bolt from the blue' means 'an
PART - IV (ENGLISH) event or a piece of news which is sudden
121. (c) 'Neither' is used for two things. For more and unexpected; a complete surprise'.
than two things, 'none' is used. 125. (b) The second part of the first sentence clearly
122. (c) Impeccable means 'in accordance with the states that the German students and the
highest standard; faultless'. professor are quite friendly with each other
123. (d) Ameliorate means 'make (something bad or and no strict relation whatsoever is seen
unsatisfactory) better. between them which is generally seen
between a professor and his students.