AUTUMN BREAK HOME ASSIGNMENT

KENDRIYA VIDYALAYA (AFS) UTTARLAI

HALF YERALY PRACTICE PAPER (2023-24)

SUBJECT: CHEMISTRY (043) (Set- 1)

MM:70 CLASS 11 Time: 3 hours

General Instructions: Read the following instructions carefully.
a) There are 35 questions in this question paper with internal choice.
b) SECTION A consists of 18 multiple-choice questions carrying 1 mark each.
c) SECTION B consists of 7 very short answer questions carrying 2 marks each.
d) SECTION C consists of 5 short answer questions carrying 3 marks each.
e) SECTION D consists of 2 case- based questions carrying 4 marks each.
f) SECTION E consists of 3 long answer questions carrying 5 marks each.
g) All questions are compulsory.
h) Use of log tables and calculators is not allowed

SECTION A
The following questions are multiple-choice questions with one correct answer. Each question carries 1 mark. There
is no internal choice in this section.
1. The mass of one mole a chloride formed by metal ‘X’ is 111.0 g. Which one could be formula of chloride?
(a) XCl (b) XCl2 (c) XCl3 (d) XCl4
2. Which of the following represents largest number of particles.
(a) Atoms in mole of CH4 (b) Atoms in 0.5 mol of SO3 (c) Atoms in 0.5 mole of CO2 (d) Atoms in 1 mol of CO
3. Two unpaired electron in which of the following ions? [At.No Ti = 22, Cr = 24, Mn = 25, Ni = 28]
(a) Ti3+ (b) Ni2+ (c) Cr2+ (d) Mn2+
4. In which of the following pairs, the ions are isoelectronic?
(a) Na+, Mg2+ (b) Al3+, O– (c) Na+, O– (d) N3–, Cl–
5. The order of screening effect of electrons of s, p, d and f orbitals of a given shell of an atom on its outer shell
electrons is:
(a) f > d > p > s (b) s > p > d > f (c) p < d < s > f (d) f > p > s > d
6. Z = 114 has been discovered recently. It will belong to which of the following family group and electronic
configuration?
(a) Carbon family [Rn] 5f 14 6d10 7s2 7p2 (b) Oxygen family [Rn] 5f 4 6d10 7s2 7p4
14 10 2 5
(c) Nitrogen family [Rn] 5f 6d 7s 7p (d) Halogen family [Rn] 5f 14 6d10 7s2 7p5
7. Which of the following pair consist of only paramagnetic species?
(a) O2, NO (b) O2+, O22– (c) CO, NO (d) O22–, N–
8. Predict the correct order (where bp is bonded paper and lp is lone pair of electrons)
(a) bp – bp > lp – bp > lp – bp (b) lp – bp > bp – bp > lp – lp
(c) lp – lp > lp – bp > bp – bp (d) lp – lp > bp – bp > lp – bp
9. The types of hybrid orbitals of nitrogen in NO2+, NO3– and NH4+ respectively are expected to be
(a) sp, sp3 and sp2 (b) sp, sp2 and sp3 (c) sp2, sp and sp3 (d) sp2, sp3 and sp
10. The correct thermodynamic conditions for the spontaneous reaction at all temperature is
(a) ∆H < 0 and ∆S > 0 (b) ∆H < 0 and ∆S < 0 (c) ∆H < 0 and ∆S = 0 (d) ∆H > 0 and ∆S < 0
11. Which of the following is an endothermic process?
(a) 2H2 + O2 → 2H2O; ∆H = – q kJ (b) N2 + O2 → 2NO – Y kJ
(c) CH4 + 2O2 → CO2 + 2H2O; ∆H = – X kJ mol–1 (d) NaOH + HCl → NaCl + H2O + Z kJ
12. 2NO2(g) ⇋ N2O4 (g) + 60.0 kJ, the increase in temperature
(a) favour the formation of N2O4 (b) favour the decomposition of N2O4
(c) does not affect the equilibrium (d) stops the process
13. Which of the following salts will give highest pH in water?
(a) KCl (b) NaCl (c) Na2CO3 (d) CuSO4
14. Considering the elements F, Cl, O and N, the correct order of their chemical reactivity in terms of oxidizing property
is:
(a) F > Cl > O > N (b) F > O > Cl > N (c) Cl > F > O > N (d) O > F > N > Cl
The following questions given below consist of an "Assertion" (A) and "Reason" (R) Type questions. Use the following
Key to choose the appropriate answer.
(A)If both (A) and (R) are true, and (R) is the correct explanation of (A).
(B)If both (A) and (R) are true but (R) is not the correct explanation of (A).
(C)If (A) is true but (R) is false.
(D) If (A) is false but (R) is true.
15. Assertion(A):The number of significant figures in 507000 is three.
Reason(R): In 507000, all the zeros are significant.
16. Assertion(A) : Formation of Cl– is exothermic whereas formation of O2– is endothermic.
Reason (R) : EA2 of oxygen is endothermic and greater than its exothermic value (EA1) of oxygen.
17. Assertion(A) : The active mass of pure solid and pure liquid is taken unity.
Reason (R): The active mass of pure solids and liquids depends on density and molecular mass. The density and
molecular mass of pure liquids and solids are constant.
18. Assertion(A): All isotopes of a given element show the same type of chemical behaviour.
Reason (R): The chemical properties of an atom are controlled by the number of electrons in the atom .
SECTION B
This section contains 7 questions with internal choice in two questions. The following questions are very short
answer type and carry 2 marks each.
19. Calculate the molarity of NaOH in the solution prepared by dissolving its 4 g in enough water to form 250 ml of the
solution.
20. The percentage of copper in CuCl2? (Atomic mass of Cu = 63.5 u, Cl =35.5 u)
21. (i) State Hund’s maximum multiplicity rule.
(ii) What is the lowest value of n that allows g-orbital to exist?
(OR)
Explain giving reason, which of the following sets of quantum numbers are not possible:

22. Write the general outer electronic configuration of s, p, d and f -block elements.
(OR)
How does electronegativity vary (i) down the group, (ii) across the period from left to right?
23. Why is BeCl2 linear whereas SnCl2 angular molecule?
24. Derive the relationship between CP and CV for an ideal gas.
25. Define the following:
(i) First law of thermodynamics.
(ii) Standard enthalpy of formation..
SECTION C
This section contains 5 questions with internal choice in two questions. The following questions are short answer type
and carry 3 marks each.
26. (i) Give the number of electrons in the species H2+ and O2–.
(ii) Using s, p, d notations, describe the orbital with the quantum numbers:
(a) n = 3, l = 1, m = 0,(b) n = 1, l = 0
(OR)
(i) State Heisenberg’s uncertainty principle.
(ii) An electron has a speed of 40 m s–1 accurate upto 99.99%. What is the uncertainty in locating its position?
[Given, me = 9.11 × 10–31 kg]
27. Give a brief account for the following:
(i) Anions are bigger in size than their parent atom.
(ii) Oxygen has lesser first ionization enthalpy than nitrogen.
28. Arrange the species in each group in order of increasing ionisation energy and give reason:
(i) K+, Cl–, Ar,
(ii) Na, Mg, Al,
(iii) C, N, O
29. What is the hybrid state of
(i) B in BF3,
(ii) S in SF6,
(iii) P in PCl5?
(OR)
Although geometries of NH3 and H2O molecules are distorted tetrahedral, bond angle in water is less than that of
ammonia. Discuss.
30. Define the following:
(a) First law of thermodynamics.
(b) Standard enthalpy of formation.
 SECTION D
The following questions are case-based questions. Each question has an internal choice and carries 4 (1+1+2)
marks each. Read the passage carefully and answer the questions that follow
31. A total of four quantum numbers are used to describe completely the movement and trajectories of each electron within an atom.
The combination of all quantum numbers of all electrons in an atom is described by a wave function that complies with the
Schrödinger equation. Each electron in an atom has a unique set of quantum numbers; according to the Pauli Exclusion Principle,
no two electrons can share the same combination of four quantum numbers. Quantum numbers are important because they can be
used to determine the electron configuration of an atom and the probable location of the atom’s electrons. Quantum numbers are
also used to understand other characteristics of atoms, such as ionization energy and the atomic radius. In atoms, there are a total
of four quantum numbers: the principal quantum number (n), the orbital angular momentum quantum number (l), the magnetic
quantum number (ml), and the electron spin quantum number (ms).
Answer the following questions:
(a) Give the sets of quantum numbers that describe an electron in a 3p orbital
(b) What is the value of azimuthal quantum number for d-subshell ?
(c) Which of the following orbitals are not possible? 2d, 4f, 4g and 6d
(OR)
Give the values of the quantum numbers for the electron with the highest energy in sodium atom.
32. The VSEPR Theory is able to predict geometry of a large number of molecules, especially the compounds of p-block elements
accurately. It is also quite successful in determining the geometry quite-accurately even when the energy difference between
possible structures is very small. Similar to electronic repulsion, orbitals containing electrons also experience electrostatic
repulsion from one another. According to VSEPR theory ''the orbital occupied by electron in the valence shell of the central atom
should be arranged in space in a way that they lie as far away from one another as possible to provide maximum stability to the
molecule. The repulsion between different types of electron pair is not the same in magnitude but it follows the following order –
'' lone-pair-lone pair > lone pair-bond pair > bond pair-bond pair''
Answer the following questions:
(a) State True or False. The shape a molecule occupies allows to minimize repulsions among them and maximize
the space between them. a) True b) False
(b) The shape of H2O according to VSEPR model is……….
(c) Give reason BeF2 is linear while SF2 is angular through both are triatomic.
(OR)
Decreasing order of bond angle among the following species is CH4 >NH3> H2O. Explain.
SECTION E
The following questions are long answer type and carry 5 marks each. Two questions have an internal choice.
33. (i) What is the SI unit of mass? How is it defined? (1)
(ii) Round up the following upto three significant figures: (a) 34.216 (b) 10.4107 (2)
(iii) Calculate the molecular mass of the following : (a) H2O (b) CO2 (c) CH4 (d) NH3 (2)
(OR)
(i) How much copper can be obtained from 100g of copper sulphate (CuSO4) ? (1)
(ii) Express the following in the scientific notation: (a) 0.0048 (b) 234,000 (2)
(iii) How are 0.50 mol Na2CO3 and 0.50 M Na2CO3 different? (2)
34. (i) In a process, 701 J of heat is absorbed by a system and 394 J of work is done by the system. What is the change in
internal energy for the process? (2)
(ii) Given N2(g) + 3H2(g) 2NH3(g) ; ∆rH = – 92.4 kJ mol–1. The standard enthalpy of formation of NH3 gas is? (2)
(iii) For an isolated system, ∆U = 0, what will be ∆S ? (1)
35. (i) The energy associated with first orbit in hydrogen atom is – 2.17 × 10-18 J atom-1. What is the energy
associated with the fifth orbit ?
(ii) Calculate the radius of Bohr’s fifth orbit for hydrogen atom.
(iii) Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 m s-1.

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