11 B Quiz-2

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11 B Chemistry Quiz-2
Thermodynamics and Equilibrium

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1.What happens to the internal energy of the system if Work is done on the
system?
(1 Point)

Increases

Decreases

Remains the same

Become zero

2. (1 Point)
𝐹𝑜𝑟 𝑡ℎ𝑒 𝑟𝑒𝑎𝑐𝑡𝑖𝑜𝑛 2𝐶𝑙(𝑔) → 𝐶𝑙2 (𝑔) 𝑤ℎ𝑎𝑡 𝑎𝑟𝑒 𝑡ℎ𝑒 𝑠𝑖𝑔𝑛𝑠 𝑜𝑓 ∆ 𝐻 𝑎𝑛𝑑 ∆For
𝑆?the reaction 2Cl(

Both ∆H and ∆S are positive

Both ∆H and ∆S are negative

∆H is positive and ∆S is negative

∆S is positive and ∆H is negative

3. (1 Point)
𝑊ℎ𝑎𝑡 ℎ𝑎𝑝𝑝𝑒𝑛𝑠 𝑡𝑜 𝑡ℎ𝑒 𝑝𝐻 𝑜𝑓 0.05𝑀 𝐶𝐻3 𝐶𝑂𝑂𝐻 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛 𝑖𝑓 0.05𝑀 𝐶𝐻3 𝐶𝑂𝑂𝑁𝑎 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛

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Increases

Decreases

Doesn't change

Becomes neutral

4. What is the effect of increasing pressure on Kp of the reaction


(1 Point)
𝐶𝑂 (𝑔) + 2𝐻2 (𝑔) ⇋ 𝐶𝐻3 𝑂𝐻 (𝑔) CO(g) + 2H2(g) ⇋ CH3OH(g)

Increases

Decreases

Remains the same

May increase or decrease

5. (1 Point)
𝑇ℎ𝑒 𝑐𝑜𝑛𝑗𝑢𝑔𝑎𝑡𝑒 𝑏𝑎𝑠𝑒 𝑜𝑓 𝐻𝐶𝑂 −3The
𝑖𝑠 conjugate base of HCO3− is

𝐶𝑂 3 CO3

𝐻2 𝐶𝑂 3 H2CO3

𝐶𝑂 −3 CO3−

𝐶𝑂 2−
3 CO32−

6. The relationship between Kp and Kc for the reaction


(1 Point)
2𝑁𝑂𝐶𝑙(𝑔) ⇋ 2𝑁𝑂(𝑔) + 𝐶𝑙2 (𝑔) 2NOCl(g)⇋2NO(g)+Cl2(g)

𝐾𝑝 = 𝐾𝑐 (𝑅𝑇) Kp = Kc(RT)

𝐾𝑐 = 𝐾𝑝 (𝑅𝑇) Kc = Kp(RT)

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−1
𝐾𝑝 = 𝐾𝑐(𝑅𝑇) Kp = Kc(RT)−1

𝐾𝑐 = 𝐾𝑝𝑅𝑇 −1 Kc = KpRT−1

7. According to second law of thermodynamics


(1 Point)

Energy of an isolated system is constant

Enthalpy of an isolated system increases during every spontaneous process

Entropy of an isolated system increases during every spontaneous process

Energy can neither be created nor destroyed

8. (1 Point)
𝑝𝐻 𝑜𝑓 0.001𝑀 𝐻𝑁 𝑂 3 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛pH
𝑖𝑠 of 0.001M HNO3 solution is

0.1

10−3 10−3

9.Calculate Enthalpy of formation of HCl if bond enthalpy of H-H, Cl-Cl and H-Cl
are 437kJ/mol, 244 kJ/mol and 433 kJ/mol respectively.
(1 Point)

-185kJ/mol

-92.5kJ/mol

248kJ/mol

124kJ/mol

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10. Example of an intensive property


(1 Point)

mass

volume

number of moles

temperature

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