Ejercicio 1 EVL Modificado

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Construcción de un Diagrama P-XY

°T op 25.00 °C

Van Ness Apéndice Tabla B2 (pdf pág 700)


LnP^sat=A−B/(°T+C)

Especie Psat (kPa) A B T C


Acetonitrilo (X) 12.27 14.90 3413.10 25.00 250.52
Acido acetico (Y) 2.07 15.07 3580.80 25.00 224.65 Diagrama EVL
14.00
P_burbuja=P_2^sat+(P_1^sat−P_2^sat )x Y=(xP_1^sat
)/P
12.00
X Y Pb Liquido subenfriado
0.00 0.00 2.07 10.00

0.10 0.40 3.09


8.00
P burbuja
0.20 0.60 4.11
0.30 0.72 5.13 6.00
0.40 0.80 6.15
0.50 0.86 7.17 4.00
0.60 0.90 8.19
0.70 0.93 9.21 2.00
0.80 0.96 10.23
0.90 0.98 11.25 0.00
0.00 0.10 0.20 0.30 0.40 0.50 0.60
1.00 1.00 12.27
X,Y

X Y Pb f1 f2 ϒ1 ϒ2
0.00 0.00 2.07 0.00 2.20109329 1.17658146
0.10 0.40 3.09 1.23 1.86 2.1240746 1.26134407
0.20 0.60 4.11 2.45 1.65 2.04418152 1.35716346
0.30 0.72 5.13 3.68 1.45 1.96147178 1.46613587
0.40 0.80 6.15 4.91 1.24 1.87603387 1.5908867
0.50 0.86 7.17 6.14 1.03 1.78799206 1.73474011
0.60 0.90 8.19 7.36 0.83 1.69751203 1.90195558
0.70 0.93 9.21 8.59 0.62 1.60480691 2.09806334
0.80 0.96 10.23 9.82 0.41 1.51014391 2.33034876
0.90 0.98 11.25 11.04 0.21 1.4138512 2.60856605
1.00 1.00 12.27 12.27 0.00 1.31632519 2.94601331

P_burbuja=∑8_𝑖▒ 〖𝑥 _𝑖 𝛾_𝑖 𝑃^𝑠𝑎𝑡 〗


Y=(xϒP_1^s
at)/P
18.00
X Y Pb f1 f2 ϒ1 ϒ2
0.00 0.00 1.88 0.00 1.88 2.07 0.91 16.00
0.10 0.56 4.47 2.50 1.97 2.03 1.06 14.00
0.20 0.71 6.91 4.89 2.02 1.99 1.22
12.00
0.30 0.78 9.16 7.13 2.03 1.94 1.40
0.40 0.82 11.18 9.21 1.97 1.88 1.59 10.00

P burbuja
0.50 0.86 12.94 11.09 1.85 1.81 1.79 8.00
0.60 0.89 14.41 12.75 1.66 1.73 2.00
0.70 0.91 15.55 14.17 1.38 1.65 2.22 6.00
0.80 0.94 16.35 15.34 1.01 1.56 2.43 4.00
0.90 0.97 16.80 16.26 0.55 1.47 2.65
2.00
1.00 1.00 16.90 16.90 0.00 1.38 2.85
0.00
0.00 0.10
Diagrama EVL
P burbuja

ido subenfriado

Mezcla
P rocio

Vapor sobrecalentado

0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00

X,Y
Diagrama EVL
18.00

16.00

14.00

12.00

10.00
P burbuja

8.00

6.00

4.00

2.00

0.00
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00

X,Y

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