Density and

Concentration Meters
Generation M
DMA 4100/4500/5000 M
::: Unique Density & Concentration Meters
Vibrant Leadership
since 1967

It all started in 1967: Anton Paar launched Continuously advanced generations

the first digital density meter with an of the famously robust DMA density
oscillating U-tube sensor, marking a meters became available, developed in
turning point for density measurement by cooperation with Labor für Messtechnik
replacing old-fashioned hydrometers and Dr. Hans Stabinger GmbH. The current
pycnometers. Hans Stabinger and Hans models provide a patented reference
Leopold, two renowned Austrian scientists, oscillator (AT 399051), a built-in
invented the principle and developed the high-precision platinum thermometer and
prototypes, and Ulrich Santner, then head of full-range viscosity correction.
Anton Paar, took over production: The first
DMA density meter was born. The new Generation M density meters
combine the DMAs’ known excellent
Since then Anton Paar has gained the measuring capabilities with unparalleled
reputation of being a first-rate partner for levels of user confidence and comfort. A
industry and research. The company’s host of new features provides complete
continuous focus on the development confidence in the sample filling and
of innovative products famous for their measurement process and therefore in
high precision and efficiency has made the quality of the measurement results.
Anton Paar the world leader in density
and concentration measurement. At the From groundbreaking innovation in 1967
same time an outstanding sales, service to the latest Generation M, Anton Paar
and application support network has been always exercises vibrant leadership in
established. digital density measurement. Be sure to
go with the leader.
Results of Worldwide Value

Industry Statement Use

Beverages “DMA has been 4 Determination of sugar content (g/L, °Brix), alcohol content (%v/v, °Proof)
established in our industry 4 Determination of extract content (°Plato, °Balling)
for years.” 4 Beer quality control
4 Quality control of soft drinks (°Brix)

Pharma & “DMA complies with our 4 Quality control of raw materials and final products
Cosmetics quality guidelines.” 4 Determination of specific gravity and density (g/cm3, g/mL) of
medicinal formulations
4 Filling volume determination

Petroleum “DMA is absolutely ideal 4 Quality control of raw materials and final products (API, kg/m3)
for our highly viscous 4 Quality control of additives
samples.” 4 Blending checks

Flavors & “Small sample volume 4 Quality control of raw materials and final products (g/cm3)
Fragrances requirements are ideal for 4 Specification checks
us, of course.” 4 Filling volume determination

Chemicals “DMA is astoundingly 4 Quality control of raw materials (°Baumé, g/cm3, kg/m3) and final
resistant - an absolute products
must for our industry.” 4 Concentration determination of acids and bases
(%w/w, %m/m, mol/L)
4 Solids content determination of dispersions
4 Reaction process control

Research and “The temperature scan 4 Determination of partial specific volume

Development saves us a lot of time.” 4 Determination of density gradient for ultracentrifuging
4 Density/temperature profile
4 Determination of molarity (mol/L) and normality (N)

Calibration “We have been using 4 Determination of alcohol content (%v/v, °Proof) for fiscal reasons
Offices, Testing DMA for more than 4 Filling volume determination
Agencies
twenty years.” 4 Stability monitoring of density standards

Biofuels “In short: optimal quality 4 Quality control of raw materials and final products
control for an optimal 4 Production control (%v/v, °Proof, g/cm3)
product.” 4 Blending checks

DMA is also used in the food industry, semiconductor industry, biotechnology, plastics industry, automotive industr
 Countless analytical methods prevail in today’s quality and production control: One
of the easiest, fastest and most significant is density measurement. It requires very
little sample, does not change the sample’s composition and consumes no chemicals.
Density measurement determines concentrations from 0 % to 100 % with the utmost
precision and allows you to always offer first-rate product quality.

Description Standards

Anton Paar’s long standing experience as a measuring specialist for the 4 AOAC, international
beverage industry (soft drinks, beer, spirits, etc.) and the highly precise results 4 OIV, international
DMA delivers in next to no time have established it as the benchmark for this 4 ASBC, TTB (USA)
field. 4 MEBAK, EBC international

DMA meets the strict regulations in the pharmaceutical and cosmetic industries 4 European and US
– with electronic signatures, various user levels and internal write protection. Pharmacopoeia
4 21CFR part 11
4 cGLP/GMP

A thorough, fast viscosity correction and a measuring range up to 90 °C make 4 DIN 51757, ISO 12185
DMA the perfect density meter for highly viscous samples such as bitumen, 4 ASTM D 1250, ASTM D 4052,
heavy fuel oil, or crude oil. ASTM D 5002, ASTM D 5931

Since DMA only requires a minimal amount of expensive sample for its density
measurement in order to deliver highly precise results after very short measuring
times, the instrument is highly valued in the flavors & fragrances industry.

DMA is renowned worldwide for its robustness. The chemical industry relies 4 ISO 2811-3, ISO 15212
on it. Apart from this, all common density/concentration tables are stored in
the instrument, and new substances are easily programmed as a table or a
polynomial. The use of DMA has considerably reduced the workload in the
chemical industry.

The main reasons for R&D departments to choose DMA are the great accuracy, 4 ISO 15212
the small sample volume requirement and the temperature scan by means
of the reference oscillator: The automatic temperature change right down to
one-hundredth-steps guarantees easy, time-saving work.

With density measurement results as accurate as up to 0.000005 g/cm3, a 4 AOAC, international

temperature accuracy of 0.01 °C and a sample volume requirement of only 4 OIV, international
1 mL, DMA is the high-precision reference instrument with the least sample 4 ASBC, TTB (USA)
consumption for calibration offices. 4 HM Revenue and Customs

Bioethanol producers use DMA because its unprecedented accuracy assures 4 EN 14214, ISO 12185
considerable savings. The biodiesel industry chooses the instrument for its 4 ASTM D 4806, ASTM D 4052
robustness and thorough, fast viscosity correction.

ry, battery production.

Generation M –
A Step Ahead

Imagine a density meter that you can be sure about. Be sure

that the sample is filled correctly, the measurement is performed
to the highest standards and the results leave no room for
doubt. With Generation M, Anton Paar continues its leadership in
providing the most accurate digital density meters on the market.

Generation M density meters embody decades of experience.

They build on the robust design and renowned features of past
DMA generations: the integrated reference oscillator, built-in
high precision platinum thermometer, and full-range viscosity
correction. Generation M features all of this – and more.

These new features of Generation M provide complete

confidence in the sample filling and measurement process
and therefore in the outstanding quality of the measurement
results:

FillingCheck™: Your density meter automatically detects filling

errors or bubbles in the sample, alerts you and documents the
incident. You can be sure of correct sample filling, whatever the
conditions.

U-View™: Check the sample filling process on screen or recall

stored images of the entire filled-in sample any time later. The
stored images allow you to later verify correct sample filling and
measurements, particularly when using automatic sampling
systems. So you can safely walk away and let the instrument do
the work.

ThermoBalance™ eliminates the need for multi-temperature

calibrations and allows you to quickly perform accurate
measurements at very different temperatures. It compensates
for drifts due to temperature stress, even when filling samples
at temperatures very different from the measuring temperature,
and provides stable readings over extended periods of time.
Generation M density meters are the only instruments to provide
you with all of these capabilities.

Compliance: Generation M fully complies with 21 CFR Part 11

and cGLP/GMP requirements. All adjustments, measurement
results and reports are completely protected and passwords
are verified based on specific password rules. Reports can be
electronically signed. You can export measuring and adjustment
data including date and time, serial number, user name, sample
identification and other vital information.
The following features of Generation M density meters
provide you with the highest levels of comfort and ease
of use:

User-friendliness: The easy-to-use touchscreen allows you

to perform your tasks quickly and efficiently. Save time with
the favorites button to access your most frequently needed
menu functions. Assign different user levels to prevent
any accidental changes. Symbols on the screen show
you vital information, such as measurements in progress,
FillingCheck™ alerts and the current status of an automatic
sample changer/measuring module.

Adaptable configurations: Use the soft keys below the

touchscreen, a mouse or an external keyboard if you are
working in a harsh environment. Enter sample identifications
through a keyboard, a bar code reader, or via other means.
Connect a large PC monitor or touchscreen to read the
results or operate the instrument from afar. Choose from
common density units such as g/cm3, kg/m3, pound/gallon
and employ “customer tables” to calculate concentrations in
units such as % w/w, % v/v.

Automatic air adjustments: Rest assured that the local air

pressure for air adjustments is correctly accounted for.

Convenient data handling: Store your results in the

instrument for as long as you want, and use the various
interfaces for data export via memory stick, printer or
Ethernet services. Reports are provided in popular formats
such as PDF, TXT and XLS.

Plug and Play sample changers: Space-saving

automatic sample changers manage sample viscosities
up to 35,000 mPa.s. Select an automatic sample changer
according to the characteristics of your samples, plug it in
and the density meter automatically recognizes it. Measure
large numbers of samples automatically and perform your
other important tasks while the instrument works for you.
FillingCheck™ will alert you if any problem has occurred,
while U-View™ allows you to verify results at a later time.
 Five Steps
to Success

(1) Select method:

Select the desired measuring method. There are
ten industry-specific methods provided which can
be adapted to your specific needs. When selecting
a different method leads to a change in measuring
temperature, ThermoBalance™ achieves stable
readings in minimal time.

(2) Enter sample identification:

Enter a sample name or number via touchscreen
or a connected keyboard or bar code reader. You
can pre-configure the sample list before carrying
out measurement series, particularly when using an
automatic sample changer.

(3) Fill sample:

Fill the sample into the measuring cell. FillingCheck™
automatically detects filling errors or air bubbles in the
filled-in sample and alerts you. With the models
DMA 4500 M and DMA 5000 M, U-View™
displays live images of the sensor with the
filled-in sample and stores images in the
memory for later verification.

(4) Start measurement:

Start the measurement with the push of
a button – the results are ready in next to
no time. You can observe the readings
throughout the measurement on the screen.
Errors related to sample viscosity are
continuously corrected.

(5) Read the results:

Read the results directly from the display, the printout
or a connected PC monitor. The results can also be
transferred to a PC, LIMS or data storage device.
Measuring Density
and Concentration

Anton Paar’s DMA density meters combine the

groundbreaking oscillating U-tube principle, the integrated
reference oscillator, highly accurate platinum thermometers
and a full-range viscosity correction to provide exceptional
measurement performance. The new features of DMA
Generation M add an outstanding level of user confidence
and comfort.

This is how the density measurement works:

The oscillating U-tube sensor is filled with 1 mL of sample.

The instrument electronically excites the U-tube sensor
to simultaneously oscillate at the fundamental resonant
frequency and its harmonics. The oscillation characteristics
are measured, with the integrated reference oscillator
providing the pace. The reference oscillator is positioned in
close thermal contact with the oscillating U-tube. This unique
positioning enables the reference oscillator to compensate for
all drifts arising from temperature stress applied to the U-tube
sensor. From these measurements the density is determined
with utmost accuracy and the viscosity influence is corrected.

The following DMA models are available:

DMA 4100 M
4 Accuracy of density measurement: 0.0001 g/cm3
4 FillingCheck™
4 ThermoBalance™
4 Temperature scan

DMA 4500 M
4 Accuracy of density measurement: 0.00005 g/cm3
4 FillingCheck™
4 U-View™
4 ThermoBalance™
4 Temperature scan

DMA 5000 M
4 Accuracy of density measurement: 0.000005 g/cm3
4 FillingCheck™
4 U-View™
4 ThermoBalance™
4 Temperature scan
Automatic Sample Filling

The Plug and Play sample changers of Generation M

are designed to fit into the density meter, which saves
you space on the lab bench. Measure large numbers of
samples automatically and perform your other important
tasks while the instrument works for you. FillingCheck™
will alert you if any problem has occurred, while
U-View™ allows you to verify results any time later.

Use the sample list to assign a separate method to

each sample, if required. Interrupt the pre-configured
sequence to insert a priority sample whenever you want,
thus providing you with unprecedented flexibility and
efficiency.

These Xsample filling equipments from Anton

Paar will meet your specific requirements:

Xsample 22 Sample Filling Unit

With peristaltic pump. For low-viscous samples and
non-corrosive samples.

Xsample 122 Sample Changer

With peristaltic pump. For low-viscous samples and
non-corrosive samples. Magazine for 24, 48 or 96
sample vials.

Xsample 52 Sample Handling Unit

With piston pump for measuring samples with
completely diverse features in direct succession.

Xsample 352 Filling and Rinsing Unit

With piston pump and overpressure for precise filling
of highly viscous or highly volatile samples. Heated
version available: Xsample 352 H

Xsample 452 Sample Changer

With piston pump and overpressure for precise filling
of highly viscous or highly volatile samples. Magazine
for 24, 48 or 96 sample vials. Heated version
available: Xsample 452 H

Xsample 510 Sample changer for packages

Fully automatic filling from up to 18 different package
types in a single measuring cycle.
Anton Paar for You

Combined forces Substantiated expertise

The density meters and sample changers are produced Regular training - in which both application topics as well as technical
by Anton Paar and advanced in close cooperation with questions are covered - ensures that the service personnel and sales
Dr. Hans Stabinger, the inventor of the oscillating U-tube. staff of Anton Paar are always up-to-date, valuable partners to Anton
The research and development team is geared to state-of- Paar customers.
the-art science and practice. Over 40 years of experience,
powerful instruments and a contemporary operational
concept – made by Anton Paar. Custom-tailored after-sales service for you

A sales and service network of trained technicians is dedicated to

Vast application knowledge customer support. The Anton Paar service team is always available,
simply place your call.
Anton Paar customers benefit from the vast and profound
application knowledge of Anton Paar’s specialists. New
applications are continuously developed. Density standards provided by Anton Paar

Ultra pure water standards are manufactured by Anton Paar and

available upon request to guarantee high quality density adjustments.

Company Structure

Company headquarters
Anton Paar GmbH
Austria

Countries with individual

subsidiary, sales office
or joint venture

Sales operated
by sales partners

Direct sales by

www.anton-paar.com
Anton Paar
Specifications

DMA 4100 M DMA 4500 M DMA 5000 M

Measuring range Density 0 to 3 g/cm3

Temperature 0 to 90 °C (32 to 194 °F)
Pressure 0 to 10 bar (0 to 145 psi)

Accuracy Density 0.0001 g/cm3 0.00005 g/cm3 0.000005 g/cm3

Temperature 0.05 °C (0.09 °F) 0.03 °C (0.05 °F) 0.01 °C (0.02 °F)

Repeatability Density 0.00005 g/cm3 0.00001 g/cm3 0.000001 g/cm3

std. dev. Temperature 0.02 °C (0.04 °F) 0.01 °C (0.02 °F) 0.001 °C (0.002 °F)

Typical measuring time/sample* 30 s 40 s

U-View™ No Yes

FillingCheck™ Yes

ThermoBalance™ Yes

Full range viscosity correction Yes

Minimal sample volume Approx. 1 mL

Wetted materials PTFE, borosilicate glass

Dimensions (L x W x H) 482 x 340 x 231 mm (19 x 13.4 x 9.1 inches)

Weight 22.5 kg (49.6 lbs)

Power supply AC 100 to 240 V; 50 to 60 Hz; 50 to 80 VA

Display 6.5 inches, TFT Touchscreen 640 x 480 Px

Controls Touchscreen, softkeys, optional keyboard, mouse and bar code reader

Communication interfaces 4 x USB, Ethernet, VGA, CAN, 2 x S-Bus, RS-232

Internal storage 1000 measuring results (ring buffer option); 512 MB SD-card (upgrade capability up to 8 GB)

Temperature scan; Adjustment

Special functions Temperature scan
at high density/viscosity

* After temperature equilibration

 Photos: Croce & Wir

Anton Paar® GmbH

Anton-Paar-Str. 20
A-8054 Graz
Austria - Europe
Tel: +43 (0)316 257-0
Fax: +43 (0)316 257-257
E-mail: info@anton-paar.com
Web: www.anton-paar.com

Instruments for:
Density & concentration
measurement

Rheometry & viscometry

Sample preparation

Microwave synthesis

Colloid science

X-ray structure analysis

Refractometry

Polarimetry
Specifications
High-precision temperature subject to change
measurement without notice.

01/11 C76IP001EN-E