Njeets FT 3 - Jee Adv P 1 - 24042024
Njeets FT 3 - Jee Adv P 1 - 24042024
Njeets FT 3 - Jee Adv P 1 - 24042024
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this purpose.
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INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B in the OMR. Part-B of OMR to be left
unused.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
Section – I (Physics)
PART – A
One or More Than One Correct Type
1 A conducting wire of parabolic shape, y
initially y = x2, is moving with velocity
B
V = V0ˆi in a non uniform magnetic field L
y
B = B0 1 + k̂ , as shown in figure. If V = V0ˆi
L
V0 , B0, L and are positive constants and
0 x
is the potential difference developed L
between the ends of the wire, then the
correct statement(s) is/are:
A. || is proportional to the length of the wire projected on the y-axis.
B. || remains the same if the parabolic wire is replaced by a straight wire, y = x initially, of
length 2 L
1
C. || = B0 V0 L for = 0
2
4
D. || = B0 V0 L for = 2
3
2 A thin convex lens is made of two materials with refractive indices n 1 and
n2, as shown in figure. The radius of curvature of the left and right
spherical surfaces are equal. f is the focal length of the lens when n1 = n2
= n. The focal length is f + f when n1 = n and n2 = n + n. Assuming n n2
<< (n – 1) and 1 < n < 2. The correct statement(s) is/are. n1
f n
A.
f n
n f
B. If 0 then 0
n f
C. For n = 1.5, n = 10-3 and f = 20 cm, the value of |f| will be 0.02 cm (round off to 2nd decimal
place).
f n
D. The relation between and remains unchanged if both the convex surfaces are replaced
f n
by concave surfaces of the same radius of curvature.
space for rough work
3 A cylindrical capillary tube of 0.2 mm radius is made by joining two capillaries T 1 and T2 of
different materials having water contact angles of 00 and 600, respectively. The capillary tube is
dipped vertically in water in two different configurations, case I and II as shown in figure. Which
of the following option(s) is (are) correct?
[Surface tension of a water = 0.075 N/m, density of water = 1000 kg/m 3, take g = 10 m/s2]
Case-I T2 Case-II T1
T1 T2
A. For case I, if the joint is kept at 8 cm above the water surface, the height of water column in the
tube will be 7.5 cm. (Neglect the weight of the water in the meniscus)
B. For case I, if the capillary joint is 5 cm above the water surface, the height of water column
raised in the tube will be more than 8.75 cm. (Neglect the weight of the water in the
meniscus)
C. For case II, if the capillary joint is 5 cm above the water surface, the height of water column
raised in the tube will be 3.75 cm. (Neglect the weight of the water in the meniscus)
D. The correction in the height of water column raised in the tube, due to weight of water
contained in the meniscus, will be different for both cases.
4 A charged shell of radius R carries a total charge Q. Given as the flux of electric field through a
closed cylindrical surface of height h, radius r and with its center same as that of the shell. Here,
center of the cylinder is a point on the axis of the cylinder which is equidistant from its top and
bottom surfaces. Which of the following option(s) is/are correct?
[0 is permittivity of free space]
A. If h < 8R/5 and r = 3R/5 then = 0
B. If h > 2R and r > R then = Q/0
C. If h > 2R and r = 4R/5 then = Q/50
D. If h > 2R and r = 3R/5 then = Q/50
5 Let us consider a system of units in which mass and angular momentum are dimensionless. If
length has dimension of L, which of the following statement(s) is/are correct?
A. The dimension of energy is L–2
B. The dimension of force is L–3
C. The dimension of power is L–5
D. The dimension of linear momentum is L-1
space for rough work
V0 4 1
T
3T0/2 2T0 T0/2 T0
1
A. Work done in this thermodynamic cycle (1 → 2 → 3 → 4 → 1) is W = RT0
2
Q1→2 5
B. The ratio of heat transfer during processes 1 → 2 and 2 → 3 is =
Q2 →3 3
C. The above thermodynamic cycle exhibits only isochoric and adiabatic processes.
Q1→2 1
D. The ratio of heat transfer during processes 1 → 2 and 3 → 4 is =
Q3 → 4 2
space for rough work
8 Consider a spherical gaseous cloud of mass density (r) in free space where r is the radial
distance from its center. The gaseous cloud is made of particles of equal mass m moving in
circular orbits about the common center with the same kinetic energy K. The force acting on the
particles is their mutual gravitational force. If (r) is constant in time, the particle number density
n(r) = (r)/m is
[ G is universal gravitational constant]
3K K
A. B.
r 2 m 2 G 2r 2 m 2 G
K K
C. D.
6r m G
2 2
r m 2 G
2
9. A thin spherical insulating shell of radius R carries a uniformly distributed charge such that the
potential at its surface is V0. A hole with a small area 4R2( << 1) is made on the shell without
affecting the rest of the shell. Which one of the following statements is correct?
A. The magnitude of electric field at a point, located on a line passing through the hole and shell’s
V0
center, on a distance 2R from the center of the spherical shell will be reduced by
2R
V0
B. The magnitude of electric field at the center of the shell is reduced by
2R
1
C. The ratio of the potential at the center of the shell to that of the point at R from center
2
1−
towards the hole will be
1 − 2
D. The potential at the center of the shell is reduced by 2V0
10. A current carrying wire heats a metal rod. The wire provides a constant power (P) to the rod.
The metal rod is enclosed in an insulated container. It is observed that the temperature (T) in the
metal rod changes with time (t) as
T (t) = T0 (1 + t1/4)
where is a constant with appropriate dimension while T 0 is a constant with dimension of
temperature. The heat capacity of the metal is
4P(T(t) − T0 )4 4P(T(t) − T0 )
A. B.
4 T05 4 T02
4P(T(t) − T0 )2 4P(T(t) − T0 )3
C. D.
4 T02 4 T04
space for rough work
12. A mass m is hung on an ideal massless spring. Another equal mass is connected to the other
end of the spring. The whole system is at rest. At t = 0, m is released and the system falls freely
under gravity. Assume that natural length of the spring is L0, its initial stretched length is L and
the acceleration due to gravity is g.
What is distance between masses as function of time.
m
k
g
m
2k k
(A) L 0 +(L-L 0 )cos t (B) L 0 +(L-L 0 )cos t
m m
2k 2k
(C) L 0 -2(L+2L 0 )cos t (D) L 0 +(L-L 0 )sin t
m m
13. Wedge is fixed on horizontal surface. Triangular block A of mass M is pulled upward by applying
a constant force F parallel to incline of the wedge as shown in the figure and there is no friction
between the wedge and the block A, while coefficient of friction between A and block B of mass
m is . If there is no relative motion between A and B then frictional force developed between
A and B is
F
Bm
M
F+(m+M)g
A sinθ mcos θ
wedge
mg
(A)
(m+M)
(B)
F-(m+M)g sinθ
(C) mcosθ (D) mg/2
(m+M)
space for rough work
PART – C
(Integer Type)
F E
x
0 0.5 1.0
4 A liquid at 30°C is poured very slowly into a Calorimeter that is at temperature of 110°C. The
boiling temperature of the liquid is 80°C. It is found that the first 5 gm of the liquid completely
evaporates. After pouring another 80 gm of the liquid the equilibrium temperature is found to be
50°C. The ratio of the Latent heat of the liquid to its specific heat will be °C. Then is …..
90
[Neglect the heat exchange with surrounding]
5 A planar structure of length L and width W is made of two different optical media of refractive
indices
n1 = 1.5 and n2 = 1.44 as shown in figure. If L >> W, a ray entering from end AB will emerge from
end CD only if the total internal reflection condition is met inside the structure. For L = 9.6 m, if
the incident angle is varied, the maximum time taken by a ray to exit the plane CD is t × 10 –9 s,
x
where t is x , then is
10
[Speed of light c = 3 × 108 m/s]
n2
A C
Air
n1 W
B D
n2
L
Section – II (Chemistry)
PART – A
One or More Than One Correct Choice Type
Q ⎯⎯⎯⎯
NaOH
PhCH2Br
→S
(A) R is steam volatile
(B) Q gives dark violet coloration with 1% aqueous FeCl3 solution
(C) S gives yellow precipitate with 2, 4-dinitrophenylhydrazine
(D) S gives dark violet coloration with 1% aqueous FeCl3 solution
2. Assuming 2s-2p overlapping is not operative , the diamagnetic species among the following are :-
(A) Be2 (B) B2 (C) C2 (D) N2
3. Which of the following are the correct step(s) involved in the given reaction :-
O
H 3C O
O
⎯⎯⎯⎯
aq NaOH
→
7. With reference to the scheme given, which of the given statement(s) about T, U, V and W is (are)
correct?
O
H 3C
T
LiAlH4
(excess)
+
CrO 3 /H (CH 3 CO)2 O
V U W
(A) T is soluble in hot aqueous NaOH
(B) U is optically active
(C) Molecular formula of W is C10 H18O4
(D) V gives effervescence on treatment with aqueous NaHCO 3
8. In the following reaction sequence , the correct statements regarding F and G are: -
O O
OH ⎯⎯⎯ → E ⎯⎯⎯→ F +G
Heat 2 I
Ph NaOH
*
( * implies 13
C labelled carbon )
(A) Product ‘F’ is a salt of benzoic acid and contains C13 and ‘G’ is CHI3
(B) Product ‘F’ is a salt of benzoic acid and ‘G’ is CHI3 and none of them contains C13
(C) Product ‘F’ is a salt of benzoic acid and ‘G’ is CHI3 and contains C13
(D) Product ‘F’ is a salt of benzoic acid and ‘G’ is CH3I and contains C13
9. The plot of atomic number (y-axis) versus number of neutrons (X-axis) for stable nuclei shows a
curvature towards X – axis from the line of 45 degree slope as the atomic number is increased .
The reason for the above mentioned is(are) :-
(A) Proton – Proton electrostatic repulsions begin to overcome attractive forces involving protons
and neutrons in lighter nuclei.
(B) Proton – Neutron electrostatic repulsions begin to overcome attractive forces involving
protons and neutrons in lighter nuclei.
(C) Proton – Proton electrostatic repulsions begin to overcome attractive forces involving protons
and neutrons in heavier nuclei.
(D) Proton – Neutron electrostatic repulsions begin to overcome attractive forces involving
protons and neutrons in heavier nuclei.
space for rough work
10. 0.1 mole of CH3NH2 (Kb = 5 *10-4) is mixed with 0.08 mole of HCl and diluted to one litre. What
will be the pH concentration in the solution.
(A) 6.9 (B) 10.9 (C) 10.09 (D) 6.09
11. Hybridisation of the complexes formed by the reaction of Ni2+ with Cl- , CN– and H2O respectively
are :
(A) sp3,sp3,dsp2 (B) sp3,sp3,sp3d2 (C) dsp2,sp3,sp3d2 (D) dsp2,dsp2,sp3d2
( i ) NaNH2 ( 2 equivalent )
OH
Br
( ii )
H Y
( iii ) H3O + , (mild) ( Scheme 2 )
N
( iv ) H2 , Pd / C
(v ) CrO3
OH
(C) H (D) H
H H
H 3 CO CH 3 CH 2 O
PART – C
(Integer Type)
1. Compound ‘A’ (molecular formula C3H8O) is treated with acidified potassium dichromate to form
a product ‘B’ (molecular formula C3H6O). ‘B’ forms a shining silver mirror on warming with
ammonical silver nitrate. ‘B’ when treated with an aqueous solution of H 2NCONHNH2. HCl and
sodium acetate gives a product ‘C’ . What is the number of bond in ‘C’
2. Nitrobenzene is formed as the major product along with a minor product in the reaction of
benzene with a hot mixture of nitric acid and sulphuric acid. The minor product consists of
carbon : 42.86%, hydrogen : 2.40% , nitrogen : 16.67%, and oxygen: 38.07%
When 5.5 g of the minor product is dissolved in 45 g of benzene, the boiling point of the solution
is 1.84 °C higher than that of pure benzene. Calculate No. of unit of empirical formula in
molecular formula (Molal boiling point elevation constant of benzene is 2.53 K kg mol-1.)
3. 10% of surface sites are occupied by N2 molecules. The density of surface site is 6.023×1014 cm–
2 and total surface area is 1000 cm2 . The catalyst is heated to 300 K while N is completely
2
dissolved into a pressure of 0.001 atm and the volume of 2.46 cm3 . Find the number of active
sites occupied by each N2 molecule.
4. A 1.0 g sample of Fe2O3 solid of 55.2% purity is dissolved in acid and reduced by heating the
solution with zinc dust. The resultant solution is cooled and made upto 100.0 ml. An aliquot of
25.0 ml of this solution requires 17.0 ml of 0.0167 M of solution of an oxidant for titration.
Calculate the number of electrons taken up by the oxidant in the reaction of the above titration.
5. The total number of geometrical isomers for the complex [Rh(Br)(CO)(PPh 3)(H2O)].
2. In a non−right−angled triangle PQR, let p, q, r denote the lengths of the sides opposite to the
angles at P, Q, R respectively. The median from R meets the side PQ at S, the perpendicular
from P meets the side QR at E, and RS and PE intersect at O. If p = 3 , q = 1, and the radius of
the circumcircle of the PQR equals 1, then which of the following options is/are correct?
A. length of OE =
1
6
B. Radius of incircle of PQR =
2
3
2− 3 ( )
7 3
C. Length of RS = D. Are of SOE =
2 12
3. Let denote a curve y = y(x) which is in the first quadrant and let the point (1, 0) lie on it. Let the
tangent to at a point P intersect the y−axis at YP. If PYP has length l for each point P on , then
which of the following option is/are correct?
1+ 1− x2
A. y = loge − 1− x2 B. xy + 1 − x2 = 0
x
1+ 1− x2
C. y = – loge + 1− x2 D. xy – 1 − x 2 = 0
x
0 1 a −1 1 −1
4. Let M = 1 2 3 and adj M = 8 −6 2 where a and b area real numbers. Which of the
3 b 1 −5 3 −1
following options is/are correct?
1
A. (adj M) −1
+ adj M −1
=–M B. If M = 2 , then – + = 3
3
C. det(adj M2) = 81 D. a+b=3
space for rough work
5. Define the collections {E1, E2, E3, …….} of ellipses and {R1, R2, R3, …} of rectangles as follows:
x 2 y2
E1 : + = 1;
9 4
R1 : rectangle of largest area, with sides parallel to the axes, inscribed in E 1;
x 2 y2
En : ellipse 2 + 2 = 1 of largest area inscribed in Rn – 1, n > 1;
a n bn
Rn: rectangle of largest area, with sides parallel to the axes, inscribed in E n, n > 1.
Then which of the following options is/are correct?
N
A. ( area of R n ) 24, for each positive integer N
n =1
5
B. The distance of a focus from the centre in E9 is
32
C. The eccentricities of E18 and E19 are NOT equal
1
D. The length of latus rectum of E9 is
6
x + 5x 4 + 10x 3 + 10x 2 + 3x + 1,
5
x 0;
x − x + 1,
2
0 x 1;
6. Let f : R → R by given by f ( x ) = 2 3
x − 4x 2 + 7x − ,
8
1 x 3; .
3 3
10
( x − 2 ) log e ( x − 2 ) − x + , x 3.
3
Then which of the following options is/are correct?
A. f has a local maximum at x = 1 B. f is NOT differentiable at x = 1
C. f is onto D. f is increasing on (– , 0)
7. ( )
Let L1 and L2 denote the lines r = i + −i + 2j + 2k , R and r = 2i − j + 2k , R respectively. ( )
If L3 is a line which is perpendicular to both L1 and L2 and cuts both of them, then which of the
following options describe (s) L3?
2
( ) (
A. r = 4i + j + k + t 2i + 2j − k , t R
9
) 1
B. r = 2i + k + t 2i + 2j − k , t R
3
( ) ( )
2
( ) (
C. r = 2i − j + 2k + t 2i + 2j − k , t R
9
)
D. r = t 2i + 2j − k , t R ( )
space for rough work
8. Suppose a, b denote the distinct real roots of the quadratic polynomial x 2 + 20x – 2020 and
suppose c, d denote the distinct complex roots of the quadratic polynomial x 2 – 20x + 2020. Then
the value of
ac(a – c) + ad(a – d) + bc(b – c) + bd(b – d)
(A) 0 (B) 8000 (C) 8080 (D) 16000
9. If the function f : R → R is defined by f(x) = |x|(x – sin x), then which of the following statements is
TRUE?
(A) f is one-one, but NOT onto (B) f is onto, but NOT one-one
(C) f is BOTH one-one and onto (D) f is NEITHER one-one NOR onto
11. Let a, b and be positive real numbers. Suppose P is an end point of the latus rectum of the
x2 y2
parabola y2 = 4x, and suppose the ellipse +
= 1 passes through the point P. If the
a2 b2
tangents to the parabola and the ellipse at the point P are perpendicular to each other, then the
eccentricity of the ellipse is
1 1 1 2
(A) (B) (C) (D)
2 2 3 5
12. Let C1 and C2 be two biased coins such that the probabilities of getting head in a single toss are
2 1
and , respectively. Suppose is the number of heads that appear when C1 is tossed twice,
3 3
independently, and suppose is the number of heads that appear when C2 is tossed twice,
independently. Then the probability that the roots of the quadratic polynomial x 2 – ax + are real
and equal, is
40 20 1 1
(A) (B) (C) (D)
81 81 2 4
space for rough work
PART – C
(Integer Type)
3. Five persons A, B, C, D and E are seated in a circular arrangement. If each of them is given a hat
of one of the three colours red, blue and green, then the number of ways of distributing the hats
such that the persons seated in adjacent seats get different coloured hats is , then is
6
n n
k n Ck k 2
= 0 holds for some positive integer n. Then Ck
n n
Suppose det
k =0 k =0
4.
n n (where
k =0 k + 1
n
Ck k
Ck 3
n k
k = 0 k =0
is G.I.F.) equals. ____
1 10 7 k 7 ( k + 1) 3
5. The value of sec−1 sec + sec + in the interval − 4 , 4 equals ____
4 k =0 12 2 12 2
FIITJEE NJEETS
JEEA
JEE (ADV) -2024
NJEETS - 3 Paper Code
Conduction Date: 24/04/2024
PAPER - 1
SET-A
ANSWER KEY
Section – I (Physics)
PART – A
1. A, B, D 2. B, C, D 3. A, C, D 4. A, B, D
5. A, B, D 6. B, C 7. A, B 8. B
9. C 10. D 11. C 12. A
13. C
PART – C
1. 2 2. 3 3. 8 4. 3
5. 5
Section – II (Chemistry)
PART - A
1. AD 2. ABD 3. BC 4. BCD
5. BCD 6. ABC 7. ACD 8. C
9. C 10. B 11. C 12. B
13. A
PART - C
1. 2 2. 2 3. 1 4. 6
5. 3
Section – III (Mathematics)
PART – A
1. B, C, D 2. A, B, C 3. A, B 4. A, B, D
5. A, D 6. A, B, C 7. A, B, C 8. D
9. C 10. A 11. A 12. B
13. C
PART – C
1. 1 2. 3 3. 5 4. 6
5. 0
Section – I (Physics)
PART – A
1. A, B, D
Sol. These is no change in flux through the loop y
OABO due to the movement of loop. So
A B
potential difference developed in curved L
wire and the straight wire OA is same.
For = 0, = 2B0 V0 L V = V0ˆi
y
L 2
B
For = 2, = B0 1 + 2 V0 dy
0 L 0 L x
4
= B0 V0 L
3
2. B, C, D
Sol. When n1 = n2 = n
1 2
= ( n − 1) …(i)
f R
When, n1 = n and n 2 = n + n
1 1 1
= ( n − 1) + ( n + n − 1) …(ii)
f + f R R
So from equation (i) and (ii)
1 1 1
− = − ( n )
f f + f R
f 1
= − ( n )
R
2
f
f n n
So =− −
f 2 ( n − 1) 2n
3. A, C, D
Sol. When T1 is in contact with water
2T cos 1
then h = = 7.5cm 8cm .
rg
But in option (B) height is insufficient.
When T2 is in contact with water
2T cos 2
then h = = 3.75 cm 5cm
rg
Volume of water in the meniscus depends upon the angle of contact.
4. A, B, D
Option (B)
Option (A)
h > 2R
3R
8R 5
h
5
Sol. r>R
Option (D)
37°
Q
h > 2R = ( 2 ) 2 (1 − cos 37 )
40
3R
r=
5
5. A, B, D
Sol. M 0 L0 T 0 = ML2 T −1
L2 = T
10 F 80 F
Q
40
V10F = 5 = 4V
40 + 10
VP − VQ = 4V
t = 0 , key S is closed
5
i= = 25 mA
70 + 100 + 30
0.5 V
i1 i2
− + 30 i1 + i2
+ 0V 5V
4V −
− 30 0.5 V
+
70 10 V
– 70i1 + 30 i2 – 6 = 0
– 30i1 – 60 i2 + 6 = 0
i2 = 0.11 A
7. A, B
RT0 P
Sol. Wcycle = P0 V0 =
2
(T0) (2T0)
Q1→ 2 nC p ( 2 − T1 )
T 5 5
= = − = 2P0
nCV ( T3 − T2 ) 1 2
Q 2 →3 3 3
Q1→ 2 nC p ( T2 − T1 )
= =2 4 3
Q 2 →3 nC V ( T4 − T3 ) P0
(T0/2) (T0)
T
V0 2V0
8. B
1 d(gr 2 )
Sol. = . . . (i)
4Gr 2 dr
mv2
Because = mg
r
1 mgr
so mv2 = K =
2 2
so from equation (i)
1 d 2k K
= r =
4Gr 2 dr m 2Gmr 2
K
so, =
m 2Gm2 r 2
9. C
4R 2 V
Sol. V0 = = 0 0
4 0 R R
1 2 V0 0
so V at R/2 = v0 - R 2 = V0 (1 − 2)
40 R R
1 1 V0 0 4R 2
and V at centre = V0 - = V0 (1 - )
40 R R
10. D
dT
Sol. At equilibrium, C =P
dt
dT T0 − 34
= t
dt 4
4P 34
So heat capacity C = t
T0
T ( t ) − T0 1
From the given equation = t4
T0
(T ( t ) − T )
3
3
So t 4 =
0
3 T03
4 4 (
T ( t ) − T0 )
4P 3
So C =
T0
11. C
12. A
Sol. In CM fram both the mass execute SHM with
k 2k
= = SHM
m
Initially particles are at extreme
2k
Distance = L0 + ( L − L0 ) cos t
m
13. C
F-(m+M)g sinθ
Sol. a=
(m+M)
So, f=ma cos
F-(m+M)g sinθ
a= m cos
(m+M)
PART – C
1. 2
Sol. TS sin 30 = TC sin 60 TS
TC
T A Y
C
= C C S S = 2.00 30
S AC YC TS S 60
100
2. 3
1
Sol. w AB = ydx = −1
0
0.5
w BC = 2xdy = +1
1
0.5
w CD = ydx = +0.25
1
0
w DE = 2xdy = +0.5
0.5
w EF = w FA = 0
Wnet = 0.75
3. 8
330 + 10cos53 30 m/s
Sol. f1 = 120 S2
330 − 30cos37 S1
800 m 37
330 + 10
f 2 = 120
330
fb = f1 − f2 = 8.128Hz = 8.13 Hz 600 m
53
10 m/s
O
4. 3
Sol. 5 (s )(50) + 5L = C (30) …(i)
80 (s )( 20) = C (30) …(ii)
from (i) and (ii)
L
= 270C
S
270.00
5. 5
Sol. 1.5sin C = 1.44sin 90
24 = 1.44
sin C =
25 = 1.5
x 25
= = x x
sin C 4
total length for light to travel
25
= 9.6 = 10m
4
time = = 5 10−8 s 50 10−9 s
c /1.5
t = 50.00
Section – II (Chemistry)
PART - A
1. AD
Sol.
OH OH OH
CHO
( i )O2
⎯⎯⎯⎯
( ii ) H3O+
→ ⎯⎯⎯⎯⎯→
CHCl3 / NaOH
+
P Q ( major )
CHO
O CH 2Ph
OH R ( min or )
CHO CHO
⎯⎯⎯⎯→NaOH
PhCH2 Br
S
Q is steam volatile not R.
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2. ABD
Sol. 2-s-2p not operative means cases of O2 & F2 in NOT where 2s and 2p are considered at
sufficient distance a part.
Then energy order is:-
1s *1s 2s 2* s 2 px ( 2 py 2 pz ) ( *2 py *2 pz ) *2 px
Configurations:-
1s *1s 2s 2* s 2px 2py *2py *2px 2pz *2pz
Be2 2 2 2 2
B2 2 2 2 2 2
C2 2 2 2 2 2 1 → Paramagnetic
N2 2 2 2 2 2 2
3. BC
Sol.
O O
O CH 2
Ph C CH 2 CH 2 C CH3 +OH − ⎯⎯
→
O
Ph
Carbanion
OH
O − H2O O
⎯⎯⎯
H2O
→ Ph ⎯⎯⎯ →Ph
Dehydration
4. BCD
Sol. Theoretical
5. BCD
Sol. Conceptual
6. ABC
Sol. The structures of these oxides are
N N O O O
N N
(a)
O
(b)
O O O
O
N N N N
O O O O O
(c ) (d )
7. ACD
Sol. (a) Undergoes an ester hydrolysis in hot aqueous alkali as
O
CH3 O
O
( )
⎯⎯⎯⎯→
NaOH aq
Hot
HO ONa
H3C
Soluble in aquoues NaOH
T
T + LiAlH4 ⎯⎯
→HO OH
(Optically inactive )
“U” No chiral carbon optically inactive
(c) U on treatment with excess of acetic anhydride forms a diester as
OCOCH3
U + (CH3CO )2 O ⎯⎯
→
Excess OCOCH3
H3C
C10 H18O4 (W )
(d) U on treatment with CrO3 H + undergo oxidation to diacid which given effervescence
with NaHCO3
O
O ( )
⎯⎯⎯⎯→
NaOH aq
Hot
H3C
Soluble in aquoues NaOH
T
CH3
T + LiAlH 4 ⎯⎯
→ HO OH
(Optically inactive )
CH2
OH
U + CrO3 ⎯⎯⎯
H
→
+
⎯⎯⎯⎯
NaHCO3
→ CO2
COOH
H3C
V
Single Correct
8. C
Sol.
O O
O
*
OH ⎯⎯⎯
→ Ph * ⎯⎯⎯→ Ph − COONa + CHI3
Heat I2
Ph C CH 3 NaOH
* E F G
9. C
Sol. Theoretical
10. B
Sol.
CH3NH2 + HCl ⎯⎯ →CH3NH3+Cl −
0.1 0.08 0
0.02 0 0.08
As it is a basic buffer, so
0.08
p (OH ) = pK b + log = − log5 10−4 + log4
0.02
= 3.30 + 0.602 = 3.902
pH = 14 − p (OH ) = 14 − 3.902 = 10.09
11. C
Sol. Here, Ni2+ has d8 configuration with CN- as strong ligand.
3d 4s 4p
dsp 2
in strong ligand field gives dsp2 hybridisaton.
d8 configuration
Hence square planar geometry.
→NiCl 4
2−
Ni 2+ + 4Cl − ⎯⎯
3d 4s 4p
dsp 2
d configuration in weak ligand field gives sp3 hybridisaton.
8
4s 4p 4d
sp 3 d 2
2+
Therefore, Ni ( H2O )6 has octahedral geometry.
12. B
Sol. Iodoform test the compound containing −COCH3 or
−CH (OH ) group will undergo iodoform test.
H ⎯⎯⎯⎯⎯ →
NaNH2 C
1 equivalent
OH
Br
+
⎯⎯⎯
H3O
→
NaNH2 (1eq ) mild
O OH
⎯⎯⎯⎯
H2 ,Pd / C
→ CrO3
OH O
Y
Me CH3
Thus, X and Y are functional isomers of each other and Y gives iodoform test due to the presence
of CH3CO group as Indicated.
13. A
Sol. The required reaction can be obtained in the following way
Cu + + e− ⎯⎯→Cu + G = −0.15F ( G = −nFE)
2+ − +
In + e ⎯⎯
→In G = +0.40F
+ 3+ −
In ⎯⎯
→In + 2e G = −0.84F
2+ 2+ 3+ +
On adding, Cu + In ⎯⎯ →In + Cu E = −0.59F
Now we know that −nFE = −0.59F
0.0591 0.0591
Ecell = Ecell
0
− log KC ; Ecell = 0, thenEcell
0
= log KC
n n
0.0591
0.59 = = 10; KC = 1010
0.0591
Integer Type :-
1. 2
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Sol.
+
C3 H8O ⎯⎯⎯⎯⎯
K2Cr2O7 / H
→C3 H6O ⎯⎯⎯⎯⎯
amm. AgNO3
→ Silver mirror
( A) (B )
H2NCONHNH2 .HCl
(C )
Reaction of (B) indicates that it is an aldehyde which should be C2H5CHO or CH3CH2CHO ,
Hence C should be CH3CH2CH = NNHCONH2
2. 2
Sol.
Rh Rh
Br PPh3
Rh
OC H2O
10 − 10
1− 1−
= 10 10
( − )
(10 −) − (10 − ) 10
= =
(10 − ) (10 −)( − ) 89
bn n + n
(A) n = = 10 + 10
n =1 10 n =1 10
n
1− 1−
10 10
(10 − ) + (10 − )
=
(10 − ) (10 − )
10 ( + ) − 2 12
= =
100 − ( + )10 + 89
n n
r − r
(C) a1 + a2 + a3 + ... + an = ar =
r =1 r =1 −
(1 − n ) (1 − ) n
−
1− 1−
=
−
( − ) (1 − n ) − (1 − ) (1 − n )
=
( − ) (1 − ) (1 − )
( − ) − n (1 + ) + n (1 + )
=
− ( − )
( − ) − n + 2 + n + 2
= ; As 1 + x = x2
− ( − )
n + 2 − n + 2
= −1 + = −1 + a n + 2
−
2. A, B, C
Sol. By sine rule P
sin P 1 3
= sinP = P = 60º or 120º
P 2R 2
sin 1 1
= sin = = 30º , 150º
2 2R 2 S 1
so only possible combination, P = 120º & Q = 30º R = 30º O
(C) Length of RS (PR)2 + (QR)2 = 2 (RS2 + PS2) RS =
7
E
2 Q 3 R
3
(A) One PQR = ½ PQ . PR sin 120º = PE = ½ Circum radius = 1
4
OE = 1/3 PE = 1/6
3
2
2
(B) r = = = 4 =
3
=
3
(2 − 3)
s p+q+r 3 + 2 2(2 + 3) 2
dy 1− x2 1− x2
= dy = dx , 1 – x2 t2, – x dx = t dt
dx x x
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−t 2
dy = dt
1− t2
1
y = 1dt + dt
1 − t 2
1 1+ t
y = t − n +c
2 1− t
1 1 + 1 − x
y = 1− x2 − +c
2 1 − 1 − x 2
y is passing through (1, 0) so c = 0
1 1 + 1 − x 2
y = 1− x2 − n
2
2 1 − 1 − x
1+ 1− x2
y = 1 − x 2 − n
x
As curve y = y(x) lies in the first quadrant so option A and B will only satisfy.
so AB are correct.
4. A, B, D
Sol. M adj M = |M| I a = 2, b = 1
0 1 2
M = 1 2 3 |M| = – 2
3 1 1
M M 2M
(A) (adj M)–1 + (adj M–1) = (|M| M–1)–1 + |M–1| M = + = =–M
M M M
1 −1 1 −1 1 1
(B) M = 2 = − 8 −6 2 2 = −1
1
2
3 −5 3 −1 3 1
= 1, = – 1, = 1 – + = 3
(C) |adj M2| = |M2|2 = |M|4 = 16
(D) a = 2, b = 1, a + b = 3
5. A, D
Sol. Area of Rn = 2a cos 2b sin
=2ab sin 2
which will be maximum when = 45º
Rn |max = 2ab
a b
E1 3 2
3 2
E2
2 2
3 2
E3
( 2) ( 2)
2 2
3 2
En
( 2) ( 2)
n −1 n −1
6 6
< 2 6 + + + ....
2 4
1
12 1 + + ....
2
1
< 12 < 24
1
1−
2
(B) b2 = a2(1 – e2)
for equation
2 2
2 3
8
=
8
(1 − e92 )
( 2) ( 2)
4 5
e92 = 1 − =
9 9
5
e9 =
3
Distance between centre and focus = ae
3 5 5
= =
( 2 ) 3 16
8
6. A, B, C
Sol. Range will contain set
x 5 + 5x 4 + 10x 3 + 10x 2 + 3x + 1 x0 → ( −, 1)
3
x2 − x +1 0 x 1 → 4 , 1
f(x) = 2 3 8 1
x − 4x 2 + 7x − 1 x 3 → 3 , 1
3 3
10 1
( x − 2) n ( x − 2) − x + x3 → ,
3 3
5 ( x 4 + 4x 3 + 6x 2 + 4x + 1) − 2 x0
2x − 1 0 x 1
f(x) =
2x − 8x + 7
2
1 x 3
(
n x−2 ) x3
(A) f (1) f (1+ ) & f (1) f (1− ) so f ( x ) has local max. at x = 1
(B) L.H.D. = 2 are R.H.D. = – 2, f is not differentiable at x = 1
(C) f is containing (–, ), so f is onto
(D) f(x) = 5 (x + 1)4 – 2 is changing sign in (–, 0), so if is not increasing
7. A, B, C
= e − e ) − ( e − e ) − e + 3e1− − ( e0 + 3e0 )
1 ( 0 0 −1 1 1 −1
2 2
1 1 1 3
= e − − 3 + − 4
2 e 2 3
1 1
= − ( 3 − 2) + e −
2 e
1 1
= (2 − 3 ) + e −
2 e
11. A
Sol. Given a, b, R+
2 y2
As P lies on ellipse + =1
a2 b2
P(, 2)
b2 −
So equation of tangent at P to ellipse ss, m =
a2 2
(Slope of tangent for parabola at P) (Slope of tangent at P for ellipse) = –1
b2
− 2 = −1 , b2 = 2a2
2a
1 1
e = 1− =
2 2
12. B
2 1
Sol. For C1 P ( h ) = , for C2 P ( h ) = , given roots of the equation x2 – x + = 0 equal real roots
3 3
2 = 4
= 2 and = 1 ==0
2 2 2
2 1 2 1 2 16 4 20
So required probability = 2C1 + = + =
3 3 3 3 3 81 81 81
13. C
Sol. 0 y 2 sin 2x, 0 x
2
(, 2 sin 2) (, 2 sin 2)
(, 0) (, 0)
for rectangle 2 sin 2 = 2 sin 2 + =
2
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Perimeter = 2( – ) + 4 sin 2 = 2 − − + 4sin2
2
= 4 – + 4 sin 2
dp 1
= 4 + 8cos 2 = 0 , cos2 = − , =
d 2 3
d2p
= −16sin2 0 so P is max
d2
2
So, area of rectangle = ( – )2 sin 2 = − 2sin
3 6 3
3
= 2 =
6 2 2 3
PART – C
1. 1
/ 2
3 cos d
I= (
cos + sin )
5
0
/ 2
3 sin
= ( d
cos + sin )
5
0
/ 2 / 2
d 3d
2I = 3 =
( cos + sin ) cos (1 + tan )
4 4
2
0 0
/ 2
3 sec 2 d
I= (
tan )
4
2 0 1+
1
Let 1 + tan = t sec2 d = dt
2 tan
3 2 ( t − 1) 3 2 2
2 1 t 4
I= dt = +
2 −2t 2 3t 3 1
3 2 2 1
= − = = 0.5
2 2 3 2
2. 3
c (a + b)
Sol. =3 2
a+b
a a + b b + ( + ) a b
=3 2
3 2
6 + 6 + ( + ) 3 = 18
+=2
( c − ( a b ) ) c = 2 a 2 + 2 b 2 + 2 a b − ( a b ) c
= 62 + 62 + 6 (as c is linearly dependent on a & b )
= 6 ( + ) − , max = 1
2
min. ( c − ( a b ) ) c = 18
3. 5
4. 6
n n
k n Ck k 2
k =0 k =0
Sol. n n
=0
n
Ck k n
Ck 3 k
k =0 k =0
n ( n + 1)
n ( n + 1) 2n − 2
2 =0
n 2n −1 4n
1
2n − 2
n ( n + 1) 2 n −1 2 =0
n +1
n 2
1
1
n ( n + 1) 22n −3 2 =0
n 8
n = 0, –1, 4 n = 4
4 4 4
C 1 1 ( 5 ) 31
k +k1 = 5 5
Ck +1 =
5
2 −1 =
5
= 6.2
k =0 k =0
5. 0
1 10 7 k 7 ( k + 1)
Sol. sec −1 sec + sec +
4 k =0 12 2
12 2
1 10 7 k 7 k
= sec−1 − sec + cosec +
4 k =0 12 2 12 2
1 10 1
= sec −1 −
2 k =0 7
sin ( −1)
k
6
1 1
= sec −1 − = sec −1 (1) = 0
2 7
sin
6