Njeets FT 3 - Jee Adv P 1 - 24042024

Download as pdf or txt
Download as pdf or txt
You are on page 1of 35

FIITJEE – NJEETS (JEE-Advanced)-3

PHYSICS, CHEMISTRY & MATHEMATICS

CPT1-1 Q.P. CODE:0000.0 FT - 3 24/04/2024


BATCHES - 2024 NJEETS (JEE-Advanced) - 3

Time Allotted: 3 Hours Maximum Marks: 183

▪ Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
▪ You are not allowed to leave the Examination Hall before the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B in the OMR. Part-B of OMR to be left
unused.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Two Parts.


(i) Part-A (01-07) – Contains seven (07) multiple choice questions which have One or More correct answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened. Negative Marks: −1 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will
result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result
in −1 marks, as a wrong option is also darkened.
(ii) Part-A (08-13) – Contains six (06) multiple choice questions which have ONLY ONE CORRECT answer
Each question carries +3 marks for correct answer and -1 marks for wrong answer.
(iii) Part-C (01-05) contains five (05) Numerical based questions with single digit integer as answer, ranging
from 0 to 9 (both inclusive) and each question carries +3 marks for correct answer. There is no negative
marking.

Name of the Candidate :_________________________________________________

Batch :________________________ Date of Examination :____________________

Enrolment Number :_____________________________________________________

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 2

Useful Data Chemistry:


Gas Constant = 8.314 J K−1 mol−1
R
= 0.0821 Lit atm K−1 mol−1
= 1.987  2 Cal K−1 mol−1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
= 6.25 x 10-27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66 x 10-27 kg
1 eV = 1.6 x 10-19 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56,
Mn=55, Si = 28 Pb=207, u=197, Ag=108, F=19, H=2, Cl=35.5
Useful Data Physics:
2
Acceleration due to gravity g = 10 m / s

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 3

Section – I (Physics)
PART – A
One or More Than One Correct Type
1 A conducting wire of parabolic shape, y
initially y = x2, is moving with velocity
B
V = V0ˆi in a non uniform magnetic field L
  y  
B = B0 1 +    k̂ , as shown in figure. If V = V0ˆi
 L 
 
V0 , B0, L and  are positive constants and
0 x
 is the potential difference developed L
between the ends of the wire, then the
correct statement(s) is/are:
A. || is proportional to the length of the wire projected on the y-axis.
B. || remains the same if the parabolic wire is replaced by a straight wire, y = x initially, of
length 2 L
1
C. || = B0 V0 L for  = 0
2
4
D. || = B0 V0 L for  = 2
3

2 A thin convex lens is made of two materials with refractive indices n 1 and
n2, as shown in figure. The radius of curvature of the left and right
spherical surfaces are equal. f is the focal length of the lens when n1 = n2
= n. The focal length is f + f when n1 = n and n2 = n + n. Assuming n n2
<< (n – 1) and 1 < n < 2. The correct statement(s) is/are. n1
f n
A. 
f n
n f
B. If  0 then 0
n f
C. For n = 1.5, n = 10-3 and f = 20 cm, the value of |f| will be 0.02 cm (round off to 2nd decimal
place).
f n
D. The relation between and remains unchanged if both the convex surfaces are replaced
f n
by concave surfaces of the same radius of curvature.
space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 4

3 A cylindrical capillary tube of 0.2 mm radius is made by joining two capillaries T 1 and T2 of
different materials having water contact angles of 00 and 600, respectively. The capillary tube is
dipped vertically in water in two different configurations, case I and II as shown in figure. Which
of the following option(s) is (are) correct?
[Surface tension of a water = 0.075 N/m, density of water = 1000 kg/m 3, take g = 10 m/s2]

Case-I T2 Case-II T1
T1 T2

A. For case I, if the joint is kept at 8 cm above the water surface, the height of water column in the
tube will be 7.5 cm. (Neglect the weight of the water in the meniscus)
B. For case I, if the capillary joint is 5 cm above the water surface, the height of water column
raised in the tube will be more than 8.75 cm. (Neglect the weight of the water in the
meniscus)
C. For case II, if the capillary joint is 5 cm above the water surface, the height of water column
raised in the tube will be 3.75 cm. (Neglect the weight of the water in the meniscus)
D. The correction in the height of water column raised in the tube, due to weight of water
contained in the meniscus, will be different for both cases.

4 A charged shell of radius R carries a total charge Q. Given  as the flux of electric field through a
closed cylindrical surface of height h, radius r and with its center same as that of the shell. Here,
center of the cylinder is a point on the axis of the cylinder which is equidistant from its top and
bottom surfaces. Which of the following option(s) is/are correct?
[0 is permittivity of free space]
A. If h < 8R/5 and r = 3R/5 then  = 0
B. If h > 2R and r > R then  = Q/0
C. If h > 2R and r = 4R/5 then  = Q/50
D. If h > 2R and r = 3R/5 then  = Q/50

5 Let us consider a system of units in which mass and angular momentum are dimensionless. If
length has dimension of L, which of the following statement(s) is/are correct?
A. The dimension of energy is L–2
B. The dimension of force is L–3
C. The dimension of power is L–5
D. The dimension of linear momentum is L-1
space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 5

6 In the circuit shown, initially there is no charge S1 C4 5V 30 


on capacitors and keys S1 and S2 are open. P
The values of the capacitors are C1 = 10 F, C2
= 30 F and C3 = C4 = 80 F. Which of the S2
statement(s) is/are correct? C1 C2 C3
30 
70  10V
Q 100 
A. The key S1 is kept closed for long time such that capacitors are fully charged. Now key S 2 is
closed, at this time, the instantaneous current across 30 resistor (between points P and Q)
will be 0.2 A (round off to 1st decimal place).
B. If key S1 is kept closed for long time such that capacitors are fully charged, the voltage across
the capacitor C1 will be 4V.
C. At time t = 0, the key S1 is closed, the instantaneous current in the closed circuit will be 25
mA
D. If key S1 is kept closed for long time such that capacitors are fully charged, the voltage
difference between points P and Q will be 10 V.

7 One mole of a monatomic ideal gas goes through a V


thermodynamic cycle, as shown in the volume
versus temperature (V – T) diagram. The correct 3
statement(s) is/are: 2V0 2
[R is the gas constant]

V0 4 1

T
3T0/2 2T0 T0/2 T0
1
A. Work done in this thermodynamic cycle (1 → 2 → 3 → 4 → 1) is W = RT0
2
Q1→2 5
B. The ratio of heat transfer during processes 1 → 2 and 2 → 3 is =
Q2 →3 3
C. The above thermodynamic cycle exhibits only isochoric and adiabatic processes.
Q1→2 1
D. The ratio of heat transfer during processes 1 → 2 and 3 → 4 is =
Q3 → 4 2
space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 6

Single Correct Choice Type

8 Consider a spherical gaseous cloud of mass density (r) in free space where r is the radial
distance from its center. The gaseous cloud is made of particles of equal mass m moving in
circular orbits about the common center with the same kinetic energy K. The force acting on the
particles is their mutual gravitational force. If (r) is constant in time, the particle number density
n(r) = (r)/m is
[ G is universal gravitational constant]
3K K
A. B.
r 2 m 2 G 2r 2 m 2 G
K K
C. D.
6r m G
2 2
r m 2 G
2

9. A thin spherical insulating shell of radius R carries a uniformly distributed charge such that the
potential at its surface is V0. A hole with a small area 4R2( << 1) is made on the shell without
affecting the rest of the shell. Which one of the following statements is correct?
A. The magnitude of electric field at a point, located on a line passing through the hole and shell’s
V0
center, on a distance 2R from the center of the spherical shell will be reduced by
2R
V0
B. The magnitude of electric field at the center of the shell is reduced by
2R
1
C. The ratio of the potential at the center of the shell to that of the point at R from center
2
1− 
towards the hole will be
1 − 2
D. The potential at the center of the shell is reduced by 2V0

10. A current carrying wire heats a metal rod. The wire provides a constant power (P) to the rod.
The metal rod is enclosed in an insulated container. It is observed that the temperature (T) in the
metal rod changes with time (t) as
T (t) = T0 (1 + t1/4)
where  is a constant with appropriate dimension while T 0 is a constant with dimension of
temperature. The heat capacity of the metal is
4P(T(t) − T0 )4 4P(T(t) − T0 )
A. B.
4 T05 4 T02
4P(T(t) − T0 )2 4P(T(t) − T0 )3
C. D.
4 T02 4 T04
space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 7

11. In a radioactive sample 40


19 K nuclei either decay into stable 40
20 Ca nuclei with decay constant 4.5 
10-10 per year or into stable 40
18 Ar nuclei with decay constant 0.5 10−10 per year. Given that in this
sample all the stable 40
20 Ca and 40
18 Ar nuclei are produced by the 40
19 K nuclei only. In time t  109
40 40 40
years, if the ratio of the sum of stable 20 Ca and 18 Ar nuclei to the radioactive 19 K nuclei is 99, the
value of t will be
[Given : ln10 = 2.3]
A. 1.15 B. 4.6
C. 9.2 D. 2.3

12. A mass m is hung on an ideal massless spring. Another equal mass is connected to the other
end of the spring. The whole system is at rest. At t = 0, m is released and the system falls freely
under gravity. Assume that natural length of the spring is L0, its initial stretched length is L and
the acceleration due to gravity is g.
What is distance between masses as function of time.
m

k
g

m
2k k
(A) L 0 +(L-L 0 )cos t (B) L 0 +(L-L 0 )cos t
m m
2k 2k
(C) L 0 -2(L+2L 0 )cos t (D) L 0 +(L-L 0 )sin t
m m

13. Wedge is fixed on horizontal surface. Triangular block A of mass M is pulled upward by applying
a constant force F parallel to incline of the wedge as shown in the figure and there is no friction
between the wedge and the block A, while coefficient of friction between A and block B of mass
m is  . If there is no relative motion between A and B then frictional force developed between
A and B is
F
Bm
M
 F+(m+M)g
A sinθ  mcos θ
wedge
 mg
(A) 
  
(m+M)
(B)

 F-(m+M)g sinθ 
(C)   mcosθ (D)  mg/2
 (m+M) 
space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 8

PART – C
(Integer Type)

1 A block of weight 100 N is suspended by


copper and steel wires of same cross sectional 60° 30°
area 0.5 cm2 and, length 3 m and 1 m, Steel wire Copper wire
respectively. Their other ends are fixed on a
ceiling as shown in figure. The angles 1m 3m
subtended by copper and steel wires with
ceiling are 30° and 60°, respectively. If
Block
elongation in copper wire is (  C ) and
elongation in steel wire is (  S ), then the ratio
 C
is ______
 S
[Young’s modulus for copper and steel are 1 × 1011 N/m2 and 2 × 1011 N/m2, respectively.]

2 A particle is moved along a path AB-BC-CD-DE-EF- y


FA, as shown in figure, in presence of a force
( )
A B
F = yiˆ + 2xjˆ N , where x and y are in meter and  = 1.0

– 1 Nm–1. The work done on the particle by this force F


will be x Joule. Then 4x is ……….. D
0.5 C

F E
x
0 0.5 1.0

3 A train S1, moving with a uniform velocity of 108 km/h


108 km/h, approaches another train S2 S2
S1
standing on a platform. An observer O moves 800 m
with a uniform velocity of 36 km/h towards S2,
as shown in figure. Both the trains are blowing
whistles of same frequency 120 Hz. When O is
600 m away from S2 and distance between S1 600 m
and S2 is 800 m, the number of beats heard by
O upto nearest integer is………
36 km/h

[Speed of the sound = 330 m/s]


O

space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 9

4 A liquid at 30°C is poured very slowly into a Calorimeter that is at temperature of 110°C. The
boiling temperature of the liquid is 80°C. It is found that the first 5 gm of the liquid completely
evaporates. After pouring another 80 gm of the liquid the equilibrium temperature is found to be

50°C. The ratio of the Latent heat of the liquid to its specific heat will be  °C. Then is …..
90
[Neglect the heat exchange with surrounding]

5 A planar structure of length L and width W is made of two different optical media of refractive
indices
n1 = 1.5 and n2 = 1.44 as shown in figure. If L >> W, a ray entering from end AB will emerge from
end CD only if the total internal reflection condition is met inside the structure. For L = 9.6 m, if
the incident angle  is varied, the maximum time taken by a ray to exit the plane CD is t × 10 –9 s,
x
where t is x , then is
10
[Speed of light c = 3 × 108 m/s]
n2
A C
Air
n1 W

B D
n2
L

space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 10

Section – II (Chemistry)
PART – A
One or More Than One Correct Choice Type

1. The incorrect statements about the following reaction sequence is (are) :-


Cumene (C9H12 ) ⎯⎯⎯⎯ () 2
→ P ⎯⎯⎯⎯⎯ →Q ( major ) + R (min or )
i O
CHCl3 / NaOH
( ii )H O+ 3

Q ⎯⎯⎯⎯
NaOH
PhCH2Br
→S
(A) R is steam volatile
(B) Q gives dark violet coloration with 1% aqueous FeCl3 solution
(C) S gives yellow precipitate with 2, 4-dinitrophenylhydrazine
(D) S gives dark violet coloration with 1% aqueous FeCl3 solution

2. Assuming 2s-2p overlapping is not operative , the diamagnetic species among the following are :-
(A) Be2 (B) B2 (C) C2 (D) N2

3. Which of the following are the correct step(s) involved in the given reaction :-
O
H 3C O
O

⎯⎯⎯⎯
aq NaOH

(A) Nucleophilic substitution (B) Nucleophilic addition


(C) Dehydration (D) Electrophilic addition

4. The following is (are) endothermic reaction (s)


(A) Combustion of methane (B) Decomposition of water
(C) Dehydrogenation of ethane to ethylene (D) Conversion of graphite to diamond

5. The correct option(s) about entropy (S) is(are)


[R= gas constant, F = Faraday constant, T=Temperature]
dEcell R
(A) For the reaction, M (s ) + 2H + (aq ) ⎯⎯
→H2 ( g ) + M 2+ (aq ) , if = ¸then the entropy
dT F
change of the reaction is R (assume that entropy and internal energy changes are
temperature independent).
(B) The cell reaction, Pt (s ) | H2 ( g,1 bar ) | H + (aq,0.01 M ) || H + (aq,0.1 M ) | H2 (g,1 bar ) | Pt (s ) ,
is in an entropy driven process.
(C) For recemisation of an optically active compound , S>0.
2+ 2+
(D) S>0, for Ni ( H2O )6  → Ni ( en )3 
+ 3en ⎯⎯ + 6H 2O (where en = ethylenediamine).
space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 11

6. The nitrogen oxide(s) that contain(s) N − N bond(s) is(are)


(A) N2O (B) N2O3 (C) N2O4 (D) N2O5

7. With reference to the scheme given, which of the given statement(s) about T, U, V and W is (are)
correct?
O

H 3C
T
LiAlH4
(excess)
+
CrO 3 /H (CH 3 CO)2 O
V U W
(A) T is soluble in hot aqueous NaOH
(B) U is optically active
(C) Molecular formula of W is C10 H18O4
(D) V gives effervescence on treatment with aqueous NaHCO 3

Single Correct Choice Type

8. In the following reaction sequence , the correct statements regarding F and G are: -
O O

OH ⎯⎯⎯ → E ⎯⎯⎯→ F +G
Heat 2 I
Ph NaOH
*
( * implies 13
C labelled carbon )
(A) Product ‘F’ is a salt of benzoic acid and contains C13 and ‘G’ is CHI3
(B) Product ‘F’ is a salt of benzoic acid and ‘G’ is CHI3 and none of them contains C13
(C) Product ‘F’ is a salt of benzoic acid and ‘G’ is CHI3 and contains C13
(D) Product ‘F’ is a salt of benzoic acid and ‘G’ is CH3I and contains C13

9. The plot of atomic number (y-axis) versus number of neutrons (X-axis) for stable nuclei shows a
curvature towards X – axis from the line of 45 degree slope as the atomic number is increased .
The reason for the above mentioned is(are) :-
(A) Proton – Proton electrostatic repulsions begin to overcome attractive forces involving protons
and neutrons in lighter nuclei.
(B) Proton – Neutron electrostatic repulsions begin to overcome attractive forces involving
protons and neutrons in lighter nuclei.
(C) Proton – Proton electrostatic repulsions begin to overcome attractive forces involving protons
and neutrons in heavier nuclei.
(D) Proton – Neutron electrostatic repulsions begin to overcome attractive forces involving
protons and neutrons in heavier nuclei.
space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 12

10. 0.1 mole of CH3NH2 (Kb = 5 *10-4) is mixed with 0.08 mole of HCl and diluted to one litre. What
will be the pH concentration in the solution.
(A) 6.9 (B) 10.9 (C) 10.09 (D) 6.09

11. Hybridisation of the complexes formed by the reaction of Ni2+ with Cl- , CN– and H2O respectively
are :
(A) sp3,sp3,dsp2 (B) sp3,sp3,sp3d2 (C) dsp2,sp3,sp3d2 (D) dsp2,dsp2,sp3d2

12. Consider only the major product formed in each step :


( i ) NaNH2 ( excess )
( ) 3 2( )
⎯⎯⎯⎯⎯⎯⎯⎯
( iii )CH3 I (1 equivalent ) →
ii CH CH I 1 equivalent
H X
( Scheme 1)
HO M ( iv ) H2 , Lindlar ' s catalyst

( i ) NaNH2 ( 2 equivalent )
OH
Br
( ii )
H Y
( iii ) H3O + , (mild) ( Scheme 2 )
N
( iv ) H2 , Pd / C
(v ) CrO3

then what is the major Product ‘Y’ :-


(A) (B) O

OH
(C) H (D) H

H H
H 3 CO CH 3 CH 2 O

13. Find the equilibrium constant for the reaction,


In2+ + Cu2+ → In3+ + Cu+ at 298 K
given : ECu2+ /Cu+ = 0.15V ;EIn0 2+ /In+ = −0.40V ,EIn0 3+ /In+ = −0.42V
(A) KC = 1010 (B) KC = 1012 (C) KC = 10 (D) KC = 1020

space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 13

PART – C
(Integer Type)

1. Compound ‘A’ (molecular formula C3H8O) is treated with acidified potassium dichromate to form
a product ‘B’ (molecular formula C3H6O). ‘B’ forms a shining silver mirror on warming with
ammonical silver nitrate. ‘B’ when treated with an aqueous solution of H 2NCONHNH2. HCl and
sodium acetate gives a product ‘C’ . What is the number of  bond in ‘C’

2. Nitrobenzene is formed as the major product along with a minor product in the reaction of
benzene with a hot mixture of nitric acid and sulphuric acid. The minor product consists of
carbon : 42.86%, hydrogen : 2.40% , nitrogen : 16.67%, and oxygen: 38.07%
When 5.5 g of the minor product is dissolved in 45 g of benzene, the boiling point of the solution
is 1.84 °C higher than that of pure benzene. Calculate No. of unit of empirical formula in
molecular formula (Molal boiling point elevation constant of benzene is 2.53 K kg mol-1.)

3. 10% of surface sites are occupied by N2 molecules. The density of surface site is 6.023×1014 cm–
2 and total surface area is 1000 cm2 . The catalyst is heated to 300 K while N is completely
2
dissolved into a pressure of 0.001 atm and the volume of 2.46 cm3 . Find the number of active
sites occupied by each N2 molecule.

4. A 1.0 g sample of Fe2O3 solid of 55.2% purity is dissolved in acid and reduced by heating the
solution with zinc dust. The resultant solution is cooled and made upto 100.0 ml. An aliquot of
25.0 ml of this solution requires 17.0 ml of 0.0167 M of solution of an oxidant for titration.
Calculate the number of electrons taken up by the oxidant in the reaction of the above titration.

5. The total number of geometrical isomers for the complex [Rh(Br)(CO)(PPh 3)(H2O)].

space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 14

Section – III (Mathematics)


PART – A
One or More Than One Correct Type
1. Let  and  be the roots of x2 – x – 1= 0, with  > . For all positive integers n, define
a n − n
an = , n  1 , b1 = 1 and bn = an – 1 + an + 1, n  2. Then which of the following options
 −
is/are correct?

b 8
A.  nn = B. bn = n + n for all n  1
n =1 10 89

a 10
C. a1 + a2 + a3 + ….. + an = an + 2 – 1 for all n  1 D.  10nn =
89
n =1

2. In a non−right−angled triangle PQR, let p, q, r denote the lengths of the sides opposite to the
angles at P, Q, R respectively. The median from R meets the side PQ at S, the perpendicular
from P meets the side QR at E, and RS and PE intersect at O. If p = 3 , q = 1, and the radius of
the circumcircle of the PQR equals 1, then which of the following options is/are correct?

A. length of OE =
1
6
B. Radius of incircle of PQR =
2
3
2− 3 ( )
7 3
C. Length of RS = D. Are of SOE =
2 12

3. Let  denote a curve y = y(x) which is in the first quadrant and let the point (1, 0) lie on it. Let the
tangent to  at a point P intersect the y−axis at YP. If PYP has length l for each point P on , then
which of the following option is/are correct?
 1+ 1− x2 
A. y = loge   − 1− x2 B. xy + 1 − x2 = 0
 x 
 
 1+ 1− x2 
C. y = – loge   + 1− x2 D. xy – 1 − x 2 = 0
 x 
 
0 1 a   −1 1 −1
4. Let M = 1 2 3  and adj M =  8 −6 2  where a and b area real numbers. Which of the
 
 3 b 1   −5 3 −1
following options is/are correct?
  1 
A. (adj M) −1
+ adj M −1
=–M B. If M    =  2 , then  –  +  = 3
    3
C. det(adj M2) = 81 D. a+b=3
space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 15

5. Define the collections {E1, E2, E3, …….} of ellipses and {R1, R2, R3, …} of rectangles as follows:
x 2 y2
E1 : + = 1;
9 4
R1 : rectangle of largest area, with sides parallel to the axes, inscribed in E 1;
x 2 y2
En : ellipse 2 + 2 = 1 of largest area inscribed in Rn – 1, n > 1;
a n bn
Rn: rectangle of largest area, with sides parallel to the axes, inscribed in E n, n > 1.
Then which of the following options is/are correct?
N
A.  ( area of R n )  24, for each positive integer N
n =1

5
B. The distance of a focus from the centre in E9 is
32
C. The eccentricities of E18 and E19 are NOT equal
1
D. The length of latus rectum of E9 is
6
 x + 5x 4 + 10x 3 + 10x 2 + 3x + 1,
5
x  0;

 x − x + 1,
2
0  x  1;

6. Let f : R → R by given by f ( x ) =  2 3
x − 4x 2 + 7x − ,
8
1  x  3; .
 3 3
 10
 ( x − 2 ) log e ( x − 2 ) − x + , x  3.
 3
Then which of the following options is/are correct?
A. f has a local maximum at x = 1 B. f is NOT differentiable at x = 1
C. f is onto D. f is increasing on (– , 0)

7. ( )
Let L1 and L2 denote the lines r = i +  −i + 2j + 2k ,   R and r =  2i − j + 2k ,   R respectively. ( )
If L3 is a line which is perpendicular to both L1 and L2 and cuts both of them, then which of the
following options describe (s) L3?
2
( ) (
A. r = 4i + j + k + t 2i + 2j − k , t  R
9
) 1
B. r = 2i + k + t 2i + 2j − k , t  R
3
( ) ( )
2
( ) (
C. r = 2i − j + 2k + t 2i + 2j − k , t  R
9
)
D. r = t 2i + 2j − k , t  R ( )
space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 16

Single Correct Choice Type

8. Suppose a, b denote the distinct real roots of the quadratic polynomial x 2 + 20x – 2020 and
suppose c, d denote the distinct complex roots of the quadratic polynomial x 2 – 20x + 2020. Then
the value of
ac(a – c) + ad(a – d) + bc(b – c) + bd(b – d)
(A) 0 (B) 8000 (C) 8080 (D) 16000

9. If the function f : R → R is defined by f(x) = |x|(x – sin x), then which of the following statements is
TRUE?
(A) f is one-one, but NOT onto (B) f is onto, but NOT one-one
(C) f is BOTH one-one and onto (D) f is NEITHER one-one NOR onto

10. Let the function f : R → R and g : R → R be defined by


f ( x ) = e x −1 − e − x −1 and g ( x ) = ( ex −1 + e1−x ) .
1
2
Then the area of the region in the first quadrant bounded by the curves y = f(x), y = g(x) and x = 0
is
(A) ( 2 − 3 ) + ( e − e−1 ) (B) ( 2 + 3 ) + ( e − e−1 )
1 1
2 2
(C) ( 2 − 3 ) + e + e−1 ) (D) ( 2 + 3 ) + ( e + e−1 )
1( 1
2 2

11. Let a, b and  be positive real numbers. Suppose P is an end point of the latus rectum of the
x2 y2
parabola y2 = 4x, and suppose the ellipse +
= 1 passes through the point P. If the
a2 b2
tangents to the parabola and the ellipse at the point P are perpendicular to each other, then the
eccentricity of the ellipse is
1 1 1 2
(A) (B) (C) (D)
2 2 3 5

12. Let C1 and C2 be two biased coins such that the probabilities of getting head in a single toss are
2 1
and , respectively. Suppose  is the number of heads that appear when C1 is tossed twice,
3 3
independently, and suppose  is the number of heads that appear when C2 is tossed twice,
independently. Then the probability that the roots of the quadratic polynomial x 2 – ax +  are real
and equal, is
40 20 1 1
(A) (B) (C) (D)
81 81 2 4
space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 17

13. Consider all rectangles lying in the region


  
( x, y )  R  R : 0  x  and 0  y  2sin ( 2x ) 
 2 
and having one side on the x-axis. The area of the rectangle which has the maximum perimeter
among all such rectangles, is
3   3
(A) (B)  (C) (D)
2 2 3 2

PART – C
(Integer Type)

1. The value of the integral


/ 2
3 cos 
2  d equals ____
0 ( cos  + sin  )
5

2 Let a = 2iˆ + ˆj − kˆ and b = ˆi + 2jˆ + kˆ be two vectors. Consider a vector c = a + b , ,   . If the


( c − ( a  b))  c
projection of c on the vector ( a + b ) is 3 2 , then the minimum value of equals
6
____

3. Five persons A, B, C, D and E are seated in a circular arrangement. If each of them is given a hat
of one of the three colours red, blue and green, then the number of ways of distributing the hats

such that the persons seated in adjacent seats get different coloured hats is  , then is
6
 n n

 k  n Ck k 2 
 = 0 holds for some positive integer n. Then  Ck 
n n
Suppose det  
k =0 k =0
4.
 n n    (where
k =0 k + 1
n
  Ck k 
 Ck 3 
n k

 k = 0 k =0 
 is G.I.F.) equals. ____

 1 10  7 k   7 ( k + 1)      3 
5. The value of sec−1   sec  +  sec  +   in the interval  − 4 , 4  equals ____
 4 k =0  12 2   12 2 

space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 18

FIITJEE NJEETS
JEEA
JEE (ADV) -2024
NJEETS - 3 Paper Code
Conduction Date: 24/04/2024
PAPER - 1
SET-A
ANSWER KEY

Section – I (Physics)
PART – A
1. A, B, D 2. B, C, D 3. A, C, D 4. A, B, D
5. A, B, D 6. B, C 7. A, B 8. B
9. C 10. D 11. C 12. A
13. C
PART – C
1. 2 2. 3 3. 8 4. 3
5. 5
Section – II (Chemistry)
PART - A
1. AD 2. ABD 3. BC 4. BCD
5. BCD 6. ABC 7. ACD 8. C
9. C 10. B 11. C 12. B
13. A
PART - C
1. 2 2. 2 3. 1 4. 6
5. 3
Section – III (Mathematics)
PART – A
1. B, C, D 2. A, B, C 3. A, B 4. A, B, D
5. A, D 6. A, B, C 7. A, B, C 8. D
9. C 10. A 11. A 12. B
13. C
PART – C
1. 1 2. 3 3. 5 4. 6
5. 0

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 19

HINTS & SOLUTIONS

Section – I (Physics)
PART – A
1. A, B, D
Sol. These is no change in flux through the loop y
OABO due to the movement of loop. So
A B
potential difference developed in curved L
wire and the straight wire OA is same.
For  = 0,  = 2B0 V0 L V = V0ˆi
 y 
L 2
B
For  = 2,  =  B0 1 + 2  V0 dy
0  L  0 L x
4
= B0 V0 L
3
2. B, C, D
Sol. When n1 = n2 = n
1 2
= ( n − 1)   …(i)
f R
When, n1 = n and n 2 = n + n
1 1 1
= ( n − 1)   + ( n + n − 1)   …(ii)
f + f R R
So from equation (i) and (ii)
1 1 1
− = − ( n )  
f f + f R
f 1
 = − ( n )  
R
2
f
f n n
So =− −
f 2 ( n − 1) 2n
3. A, C, D
Sol. When T1 is in contact with water
2T cos 1
then h = = 7.5cm  8cm .
rg
But in option (B) height is insufficient.
When T2 is in contact with water
2T cos 2
then h = = 3.75 cm  5cm
rg
Volume of water in the meniscus depends upon the angle of contact.
4. A, B, D

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 20

Option (B)

Option (A)
h > 2R
3R
8R 5
 h
5

Sol. r>R
Option (D)

37°
Q
h > 2R = ( 2 ) 2 (1 − cos 37 )
40

3R
r=
5
5. A, B, D
Sol.  M 0 L0 T 0  =  ML2 T −1 
   
  L2  =  T 

Energy =  MLT −2 L  = L−2

Force =  MLT −2  = L−3

Power =  MLT −2 LT −1  = L−4


linear momentum = MLT–1 = L–1
6. B, C
Sol. S1 closed for long time
5V
P
80 F

10 F 80 F

Q
 40 
V10F =   5 = 4V
 40 + 10 
VP − VQ = 4V
 t = 0 , key S is closed
5
i= = 25 mA
70 + 100 + 30

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 21

0.5 V

i1 i2
− + 30  i1 + i2
+ 0V 5V
4V −
− 30  0.5 V
+
70  10 V

– 70i1 + 30 i2 – 6 = 0

– 30i1 – 60 i2 + 6 = 0
 i2 = 0.11 A
7. A, B
RT0 P
Sol. Wcycle = P0 V0 =
2
(T0) (2T0)
Q1→ 2 nC p ( 2 − T1 )
T 5 5
= = − = 2P0
nCV ( T3 − T2 ) 1 2
Q 2 →3 3 3

Q1→ 2 nC p ( T2 − T1 )
= =2 4 3
Q 2 →3 nC V ( T4 − T3 ) P0
(T0/2) (T0)

T
V0 2V0
8. B

1 d(gr 2 )
Sol. = . . . (i)
4Gr 2 dr
mv2
Because = mg
r
1 mgr
so mv2 = K =
2 2
so from equation (i)
1 d  2k  K
=  r =
4Gr 2 dr  m  2Gmr 2
 K
so, =
m 2Gm2 r 2
9. C
4R 2 V
Sol. V0 =  = 0 0
4 0 R R
1 2 V0  0
so V at R/2 = v0 - R 2 = V0 (1 − 2)
40 R R
1 1 V0 0 4R 2
and V at centre = V0 - = V0 (1 - )
40 R R
10. D
dT
Sol. At equilibrium, C =P
dt
dT T0 − 34
= t
dt 4
4P 34
So heat capacity C = t
 T0

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 22

T ( t ) − T0 1
From the given equation = t4
T0
(T ( t ) − T )
3
3

So t 4 =
0

3 T03

4 4 (
T ( t ) − T0 )
4P 3
So C =
 T0
11. C

Sol. So equivalent decay constant = 1 +  2 = 5  10−10 per 1 40


20 Ca
year
40
N − t N −N K
=e
19
and given that 0
eq
= 99
N0 N 2 40
Ar
So t = 9.2 10 year 9 18

12. A
Sol. In CM fram both the mass execute SHM with
k 2k
= = SHM
 m
Initially particles are at extreme
2k
Distance = L0 + ( L − L0 ) cos t
m
13. C
 F-(m+M)g sinθ 
Sol. a=  
 (m+M) 
So, f=ma cos
 F-(m+M)g sinθ 
a=   m cos 
 (m+M) 
PART – C
1. 2
Sol. TS sin 30 = TC sin 60 TS
TC
 T A Y 
C
= C C  S S  = 2.00 30
 S AC YC  TS S  60

100
2. 3
1
Sol. w AB =  ydx = −1
0
0.5
w BC =  2xdy = +1
1
0.5
w CD =  ydx = +0.25
1

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 23

0
w DE =  2xdy = +0.5
0.5

w EF = w FA = 0
Wnet = 0.75

3. 8
 330 + 10cos53  30 m/s
Sol. f1 = 120   S2
 330 − 30cos37  S1
800 m 37
 330 + 10 
f 2 = 120  
 330 
fb = f1 − f2 = 8.128Hz = 8.13 Hz 600 m

53

10 m/s
O
4. 3
Sol. 5 (s )(50) + 5L = C (30) …(i)
80 (s )( 20) = C (30) …(ii)
 from (i) and (ii)
L
= 270C
S
 270.00
5. 5
Sol. 1.5sin C = 1.44sin 90
24 = 1.44
sin C =
25  = 1.5
x 25
= = x x
sin C 4
total length for light to travel
25
=  9.6 = 10m
4

 time = = 5 10−8 s  50 10−9 s
c /1.5
t = 50.00
Section – II (Chemistry)
PART - A
1. AD
Sol.
OH OH OH

CHO
( i )O2
⎯⎯⎯⎯
( ii ) H3O+
→ ⎯⎯⎯⎯⎯→
CHCl3 / NaOH
+

P Q ( major )
CHO
O CH 2Ph
OH R ( min or )
CHO CHO
⎯⎯⎯⎯→NaOH
PhCH2 Br

S
Q is steam volatile not R.
FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480
FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 24

Q & R show positive test with 1% aqueous FeCl3 solution.


Q,R,S show positive 2,4-dinitrophenyl hydrazine.

2. ABD
Sol. 2-s-2p not operative means cases of O2 & F2 in NOT where 2s and 2p are considered at
sufficient distance a part.
Then energy order is:-
1s   *1s  2s  2* s  2 px  ( 2 py  2 pz )  (  *2 py   *2 pz )   *2 px
Configurations:-
1s  *1s 2s 2* s 2px 2py  *2py  *2px 2pz  *2pz
Be2 2 2 2 2
B2 2 2 2 2 2
C2 2 2 2 2 2 1 → Paramagnetic
N2 2 2 2 2 2 2

3. BC
Sol.
O O
O CH 2
Ph C CH 2 CH 2 C CH3 +OH − ⎯⎯

O
Ph
Carbanion
OH
O − H2O O
⎯⎯⎯
H2O
→ Ph ⎯⎯⎯ →Ph

Dehydration
4. BCD
Sol. Theoretical

5. BCD
Sol. Conceptual

6. ABC
Sol. The structures of these oxides are
N N O O O
N N

(a)
O
(b)
O O O
O
N N N N
O O O O O
(c ) (d )

Hence, options (a), (b) and (c) have N-N bonds

7. ACD
Sol. (a) Undergoes an ester hydrolysis in hot aqueous alkali as
O
CH3 O
O
( )
⎯⎯⎯⎯→
NaOH aq
Hot
HO ONa
H3C
Soluble in aquoues NaOH
T

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 25

(b) LiAlH 4 reduces ester to alcohol as


CH3

T + LiAlH4 ⎯⎯
→HO OH
(Optically inactive )
“U” No chiral carbon optically inactive
(c) U on treatment with excess of acetic anhydride forms a diester as
OCOCH3
U + (CH3CO )2 O ⎯⎯

Excess OCOCH3
H3C
C10 H18O4 (W )

(d) U on treatment with CrO3 H + undergo oxidation to diacid which given effervescence
with NaHCO3
O

O ( )
⎯⎯⎯⎯→
NaOH aq
Hot

H3C
Soluble in aquoues NaOH
T

CH3

T + LiAlH 4 ⎯⎯
→ HO OH
(Optically inactive )

CH2

OH
U + CrO3 ⎯⎯⎯
H

+
⎯⎯⎯⎯
NaHCO3
→ CO2 
COOH
H3C
V
Single Correct
8. C
Sol.
O O
O
*
OH ⎯⎯⎯
→ Ph * ⎯⎯⎯→ Ph − COONa + CHI3
Heat I2
Ph C CH 3 NaOH
* E F G

9. C
Sol. Theoretical

10. B
Sol.
CH3NH2 + HCl ⎯⎯ →CH3NH3+Cl −
0.1 0.08 0
0.02 0 0.08
As it is a basic buffer, so
0.08
p (OH ) = pK b + log = − log5  10−4 + log4
0.02
= 3.30 + 0.602 = 3.902
pH = 14 − p (OH ) = 14 − 3.902 = 10.09

11. C
Sol. Here, Ni2+ has d8 configuration with CN- as strong ligand.

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 26

3d 4s 4p

dsp 2
in strong ligand field gives dsp2 hybridisaton.
d8 configuration
Hence square planar geometry.
→NiCl 4 
2−
Ni 2+ + 4Cl − ⎯⎯
3d 4s 4p

dsp 2
d configuration in weak ligand field gives sp3 hybridisaton.
8

Hence tetrahedral geometry.


2+
Ni 2+ with H 2O form Ni ( H 2O )6  complex and H 2O is a weak ligand.
3d

4s 4p 4d

sp 3 d 2
2+
Therefore, Ni ( H2O )6  has octahedral geometry.
12. B
Sol. Iodoform test the compound containing −COCH3 or
−CH (OH ) group will undergo iodoform test.
H ⎯⎯⎯⎯⎯ →
NaNH2 C
1 equivalent

OH
Br
+
⎯⎯⎯
H3O

NaNH2 (1eq ) mild

O OH

⎯⎯⎯⎯
H2 ,Pd / C
→ CrO3
OH O

Y
Me CH3
Thus, X and Y are functional isomers of each other and Y gives iodoform test due to the presence
of CH3CO group as Indicated.

13. A
Sol. The required reaction can be obtained in the following way
Cu + + e− ⎯⎯→Cu + G = −0.15F ( G = −nFE)
2+ − +
In + e ⎯⎯
→In G = +0.40F
+ 3+ −
In ⎯⎯
→In + 2e G = −0.84F
2+ 2+ 3+ +
On adding, Cu + In ⎯⎯ →In + Cu E = −0.59F
Now we know that −nFE = −0.59F
0.0591 0.0591
Ecell = Ecell
0
− log KC ; Ecell = 0, thenEcell
0
= log KC
n n
0.0591
0.59 = = 10; KC = 1010
0.0591

Integer Type :-
1. 2
FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480
FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 27

Sol.
+
C3 H8O ⎯⎯⎯⎯⎯
K2Cr2O7 / H
→C3 H6O ⎯⎯⎯⎯⎯
amm. AgNO3
→ Silver mirror
( A) (B )

H2NCONHNH2 .HCl
(C )
Reaction of (B) indicates that it is an aldehyde which should be C2H5CHO or CH3CH2CHO ,
Hence C should be CH3CH2CH = NNHCONH2
2. 2
Sol.

Element %Relative no. of atoms Simplest ratio


C 42.86 42.86 3.57
= 3.57 =3
12 1.19
H 2.40 2.40 2.40
= 2.40 =2
1 1.19
N 16.67 16.67 1.19
= 1.19 =1
14 1.19
O 38.07 38.07 2.38
= 2.38 =2
16 1.19
Emprical formula of the minor product is C3 H2NO2
Molar empirical formula mass of the minor product = 84 g mol −2
Let M be the molar mass of the minor product.
For 5.5 g of the minor product dissolved in 45 g benzene.
5.5g / M
The molality ‘m’ of the solution
0.045kg
Tb = K b m  1.84K
Or M = 168 g mol −1
168g mol −1
No. of unit of empirical formula in molecular formula = =2
84 g mol −1
3. 1
Sol. N2 = 0.001 at ,;T = 300 K ;V = 2.46 cm 3
PV 0.001 2.46  10−3
Number of N2 molecules =  N0 =  6.023  1023 = 6.016  1016
RT 0.082  300
Now, total number of surface sites= Density Total surface are =6.02310141000=6.0231017
10
Site occupied by N2 molecules =  6.023  1017 = 6.023  1016
100
6.023  1016
Number of sites occupied by each N2 molecule = =1
6.016  1616
4. 6
55.2
Sol. Mass of Fe2O3 in the simple =  1 = 0.552g
100
55.2
Number of moles of Fe2O3 = = 3.454  10−3
159.8
Number of moles of Fe3 + ions = 2  3.454  10−3 = 6.9  10−3 mol = 6.90 mmol
Since there is only 1 electron is exchanged in the conversion of Fe3 + to Fe2+ , the molecular
mass is the same as equivalent mass.
Amount of Fe2+ ion in 100 ml. of sol.=6.90 meq.
Volume of oxidant used for 100 ml of Fe2+ sol. = 17  4 = 68ml .
Amount of oxidant used = 68  0.0167mmol = 1.1356mmol

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 28

Let the number of electrons taken by oxidant =n


No. of meq. Of oxidant used =1.1356n
Thus 1.1356n=6.90
6.90
n= =6
1.1356
5. 3
Sol.
Br PPh3 Br CO

Rh Rh

H2O CO H2O PPh3

Br PPh3

Rh

OC H2O

Section – III (Mathematics)


PART – A
1. B, C, D
Sol. Clearly we have  +  = 1 &  = – 1
1 5
,  =
2
As bn = an–1 + an+1
 n −1 − n −1  n +1 − n +1
= +
 −  −
n −1 (1 + 2 ) − n −1 (1 + 2 )
=
 −
n −1 (  + 2) − n −1 ( + 2)
=
 −
 5 + 5  n −1  5 − 5 
 n −1   −  
=  2   2 
 −
5 ( n + n )
= = n + n : As  − = 5
 −
 
a  n − n
(D)  nn = 
n =1 (  −  )10
n
n =1 10

 
10 − 10
 
1− 1−
= 10 10
( − )
 (10 −) − (10 −  ) 10
= =
(10 −  ) (10 −)(  − ) 89
 
 
bn  n + n
(A)  n =  = 10 + 10
n =1 10 n =1 10
n  
1− 1−
10 10

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 29

 (10 −  ) +  (10 −  )
=
(10 −  ) (10 −  )
10 (  +  ) − 2 12
= =
100 − (  +  )10 +  89
n n
r − r
(C) a1 + a2 + a3 + ... + an = ar = 
r =1 r =1  − 

 (1 −  n )  (1 −  ) n

1−  1− 
=
 −
(  −  ) (1 − n ) −  (1 −  ) (1 − n )
=
(  −  ) (1 −  ) (1 −  )
(  − ) − n (1 +  ) + n (1 +  )
=
− (  − )
(  −  ) −  n + 2 + n + 2
= ; As 1 + x = x2
− (  − )
 n + 2 − n + 2
= −1 + = −1 + a n + 2
 −
2. A, B, C
Sol. By sine rule P
sin P 1 3
=  sinP =  P = 60º or 120º
P 2R 2
sin  1 1
=  sin  =   = 30º , 150º
2 2R 2 S 1
so only possible combination, P = 120º & Q = 30º  R = 30º O
(C) Length of RS  (PR)2 + (QR)2 = 2 (RS2 + PS2)  RS =
7
E
2 Q 3 R
3
(A) One PQR = ½ PQ . PR sin 120º =  PE = ½ Circum radius = 1
4
 OE = 1/3 PE = 1/6
3
2
 2
(B) r = = = 4 =
3
=
3
(2 − 3)
s p+q+r 3 + 2 2(2 + 3) 2

(D) are of OSE = ½ SE . OE sin SEO


1 1 1 3
  sin 60º = unit2
2 2 6 48
3. A, B
Sol. Equation tangent
dy (x1, y1)
y − y1 = 1 ( x − x1 ) yP
dx1
 dy  P
yp  0, y1 − x1 1 
 dx1 
2
 dy 
Pyp = x12 +  − x1 1  = 1
 dx1 

dy 1− x2 1− x2
 =  dy =   dx , 1 – x2 t2, – x dx = t dt
dx x x
FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480
FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 30

−t 2
dy =   dt
1− t2
 1 
y =    1dt +  dt 
 1 − t 2

 1 1+ t 
y = t − n  +c
 2 1− t 
 1 1 + 1 − x  
y =   1− x2 − +c
 2 1 − 1 − x 2 

y is passing through (1, 0) so c = 0
 1  1 + 1 − x 2  
y =   1− x2 − n  
  2 
 2  1 − 1 − x 
  1+ 1− x2  
y =   1 − x 2 − n   
  x 
As curve y = y(x) lies in the first quadrant so option A and B will only satisfy.

so AB are correct.
4. A, B, D
Sol. M adj M = |M| I  a = 2, b = 1
0 1 2
 M = 1 2 3   |M| = – 2
 3 1 1 
M M 2M
(A) (adj M)–1 + (adj M–1) = (|M| M–1)–1 + |M–1| M = + = =–M
M M M
  1     −1 1 −1 1   1 
 
(B) M    =  2     = −  8 −6 2   2  =  −1
    1
2
    3     −5 3 −1  3   1 
 = 1,  = – 1,  = 1   –  +  = 3
(C) |adj M2| = |M2|2 = |M|4 = 16
(D) a = 2, b = 1, a + b = 3
5. A, D
Sol. Area of Rn = 2a cos  2b sin
=2ab sin 2
which will be maximum when  = 45º
 Rn |max = 2ab
a b
E1 3 2
3 2
E2
2 2
3 2
E3
( 2) ( 2)
2 2

3 2
En
( 2) ( 2)
n −1 n −1

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 31

(A) Area of R1 + Area of R2 ... Area of Rn


< Area of R1 + Area of R2 ....  (a cos, b sin)

 6 6 
< 2  6 + + + .... 
 2 4 
 1 
 12 1 + + .... 
 2 
1
< 12  < 24
1
1−
2
(B) b2 = a2(1 – e2)
for equation
2 2
 2   3 
 8 

=
 8 

(1 − e92 )
 ( 2)   ( 2) 
4 5
e92 = 1 − =
9 9
5
e9 =
3
Distance between centre and focus = ae
3 5 5
=  =
( 2 ) 3 16
8

(C) e18 = e19


2
 2 
2 
2  ( 2 )8
(D) Latus rectum (length) =
2b
=   =1
a 3 6
( 2)
8

6. A, B, C
Sol. Range will contain set
 x 5 + 5x 4 + 10x 3 + 10x 2 + 3x + 1 x0 → ( −, 1)

 3 
x2 − x +1 0  x 1 →  4 , 1


f(x) =  2 3 8 1 
 x − 4x 2 + 7x − 1 x  3 →  3 , 1
 3 3  
 10 1 
 ( x − 2) n ( x − 2) − x + x3 →  , 
 3  3 
5 ( x 4 + 4x 3 + 6x 2 + 4x + 1) − 2 x0

 2x − 1 0  x 1
f(x) = 
 2x − 8x + 7
2
1 x  3
 (
n x−2 ) x3

(A) f  (1)  f  (1+ ) & f  (1)  f (1− ) so f  ( x ) has local max. at x = 1
(B) L.H.D. = 2 are R.H.D. = – 2, f is not differentiable at x = 1
(C) f is containing (–, ), so f is onto
(D) f(x) = 5 (x + 1)4 – 2 is changing sign in (–, 0), so if is not increasing
7. A, B, C

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 32

Equation of L1 r = ˆi +  ( −ˆi + 2jˆ + 2kˆ )


(1 – , 2, 2)
Sol. A

Equation of L2 r =  ( 2iˆ − ˆj + 2kˆ )


L1

L1 & L2 are skew lines


The direction ratios of line AB which is perpendicular to L 1 and L2
will be
ˆi ˆj kˆ
L2
−1 2 2 = 6iˆ + 6ˆj − 3kˆ B
(2, –, 2)
2 −1 2
Hence direction ratios of AB will be (2, 2, –1)
direction ratios of AB proportional to (2, 2, –1)
1 –  – 2 = 2 k ... (i)
2 +  = 2k ... (ii)
2 – 2 = – k ... (iii)
solving (i) (ii) & (iii)
we get  = 1/9
 = 2/9
8 2 2 4 2 4
A  , ,  , B , − , 
9 9 9 9 9 9
Equation of line L3 (A, B) passing through A
8 2 2 
=  ˆi + ˆj + kˆ  + t ( 2iˆ + 2jˆ − kˆ ) , t  R
9 9 9 
option (A) correct
Equation of line L3 passing through B
4 2 4 
=  ˆi − ˆj + kˆ  + t ( 2iˆ + 2jˆ − kˆ )
9 9 9 
Option (C) is correct, option (B) also satisfy
8. D
Sol. Given a + b = –20, ab = –2020, c + d = 20, cd = 2020-09-28
a2c – ac2 + a2d – ad2 + b2c – b2c – bc2 + b2d – bd2
= (a2 + b2)(c + d) – (a + b)(c2 + d2)
= ((a + b)2 – 2ab)(c + d) – (a + b)((c + d)2 – 2cd)
= (400 – 2  2020)(20) – (–20)(400 – 2  2020)
= 20  800 = 16000
9. C
Sol. f(x) is odd, continuous function
 x ( x − sin x ) , x  0
f ( x) = 
− x ( x − sin x ) , x  0
for x  0, f(x) = 2x – sin x – x cos x = x(1 – cos x) + (x – sin x)  0
for x < 0, f(x) = –2x + sin x + x cos x = x(cos x – 1) – (x – sin x) > 0 as x < 0
 So f(x) strictly increases in (–, )  f(x) is one-one
x →  f(x) → 
x → – f(x) → –. So f(x) is onto
10. A
 0 , x 1 ( e−1 = 3 )
Sol. f ( x ) =  x −1
e − e
1− x
, x 1 ( , g (  ) )
1 ( x −1 1−x ) y = g(x)
g( x ) = e +e
2
f(x) = g(x)
ex −1 − e1− x = ( ex −1 + e1−x )
1
x=1 x=
2
e x −1 = 3e1− x
e x −1 = 3
FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480
FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 33

e−1 = 3 . Let x =  be P.O.I


1 
1 ( x −1 1 
Required area =  e + e1− x ) dx +  ( ex −1 + e1− x ) − ( ex −1 − e1− x )  dx

2 2 
0 1

1 1
1 3
= ex −1 − e1− x 0
+ − ex −1 − e1− x
2 2 2 1

=  e − e ) − ( e − e ) − e + 3e1− − ( e0 + 3e0 )
1 ( 0 0 −1 1 1 −1
2 2
1 1 1 3 
= e −  −  3 + − 4
2 e 2 3 
1 1
= − ( 3 − 2) + e − 
2 e
1 1
= (2 − 3 ) + e − 
2 e
11. A
Sol. Given a, b,   R+
2 y2
As P lies on ellipse + =1
a2 b2
P(, 2)

b2 −
So equation of tangent at P to ellipse ss, m = 
a2 2
(Slope of tangent for parabola at P) (Slope of tangent at P for ellipse) = –1
b2
 − 2 = −1 , b2 = 2a2
2a
1 1
e = 1− =
2 2
12. B
2 1
Sol. For C1 P ( h ) = , for C2 P ( h ) = , given roots of the equation x2 – x +  = 0 equal real roots
3 3
 2 = 4

 = 2 and  = 1 ==0
2 2 2
2 1 2  1  2 16 4 20
So required probability =    2C1   +     = + =
3 3 3 3 3 81 81 81
13. C

Sol. 0  y  2 sin 2x, 0  x 
2
(, 2 sin 2) (, 2 sin 2)

(, 0) (, 0)

for rectangle 2 sin 2 = 2 sin 2   +  =
2
FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480
FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 34

  
Perimeter = 2( – ) + 4 sin 2 = 2   −  −    + 4sin2
 2 
= 4 –  + 4 sin 2
dp 1 
= 4 + 8cos 2 = 0 , cos2 = − ,  =
d 2 3
d2p
= −16sin2  0 so P is max
d2
   2 
So, area of rectangle = ( – )2 sin 2 =  −   2sin  
3 6  3 
 3 
= 2 =
6 2 2 3
PART – C
1. 1
/ 2
3 cos  d
I= (
cos  + sin  )
5
0
/ 2
3 sin 
= ( d
cos  + sin  )
5
0
/ 2 / 2
d 3d
 2I = 3  = 
( cos  + sin  ) cos  (1 + tan  )
4 4
2
0 0
/ 2
3 sec 2  d
 I= (
tan  )
4
2 0 1+

1
Let 1 + tan  = t  sec2  d = dt
2 tan 
 
3 2 ( t − 1) 3 2 2
2 1 t 4
I= dt = +
2 −2t 2 3t 3 1

3 2 2 1
=  −  = = 0.5
2 2 3 2
2. 3
c  (a + b)
Sol. =3 2
a+b
 a  a + b  b + (  +  ) a  b
 =3 2
3 2
 6 + 6 + (  +  ) 3 = 18
 +=2
( c − ( a  b ) )  c = 2 a 2 + 2 b 2 + 2 a  b − ( a  b )  c
= 62 + 62 + 6 (as c is linearly dependent on a & b )
= 6 (  +  ) −   , max  = 1
2

 min. ( c − ( a  b ) )  c = 18
3. 5

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com


NJEETS JEEA - 3 –CPT1-(FT-3)-PCM-IITJEE/24 35

Sol. Maximum number of hats of same colour are 2 and A

minimum colour required are 3. So, the selection of hats


will have to be of the type AABBC E B
3C ways to select hat having single colour. Then distribute
1
that single hat in 5C1 ways. 2C1 ways to distribute hat to
adjacent person, after that alternate coloured hat will be
given so 3  5  2 = 30
D C

4. 6
n n
k  n Ck k 2
k =0 k =0
Sol. n n
=0
 n
Ck k  n
Ck 3 k

k =0 k =0

n ( n + 1)
n ( n + 1) 2n − 2
 2 =0
n 2n −1 4n
1
2n − 2
 n ( n + 1) 2 n −1 2 =0
n +1
n 2
1
1
 n ( n + 1) 22n −3 2 =0
n 8
 n = 0, –1, 4  n = 4
4 4 4
C 1 1 ( 5 ) 31
 k +k1 =  5 5
Ck +1 =
5
2 −1 =
5
= 6.2
k =0 k =0
5. 0
 1 10  7  k   7  ( k + 1)   
Sol. sec −1   sec  +  sec  +  
 4 k =0  12 2 
  12 2 
 1 10  7 k   7 k  
= sec−1  −  sec  +  cosec  +  
 4 k =0  12 2   12 2  
 
 1 10 1 
= sec −1  −  
 2 k =0  7  
sin    ( −1)
k
 
  6  
 
 1 1 
= sec −1  −  = sec −1 (1) = 0
 2  7  
 sin   
  6 

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7825895321/9650037480


FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448

www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com

You might also like