Grade 10 Chemical Bonding

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Chemical bonding

A chemical bond is an attraction between atoms.

Electrons are responsible for the reactivity of chemical substances (atoms, molecules, ions).
Specifically, the valence electrons in atoms are the ones that take part in chemical reactions.
Atoms of elements react with each other to achieve a full valence shell of eight electrons (2
electrons for hydrogen) like the Group VIII or Group 0 elements, which are already stable and
unreactive so they do not readily partake in chemical reactions.

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Atoms can form chemical bonds by losing, gaining or sharing electrons.

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Types of chemical bonding .

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There are THREE main types of chemical bonds.

Metallic bonding Ionic bonding


B. Covalent bonding

Atoms involved Within metals only Between a metal and a Between two or more
nonmetal nonmetals OR a
semimetal (metalloid)
by
Main group metals and a nonmetal
(Groups IA, IIA and IIIA)
AND Transition metals Group IVA, VA, VIA
(eg. iron, copper, zinc, and VIIA
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lead, etc)

Nonmetals (Main groups


VA, VIA and VIIA)
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Description Electrostatic attraction Transfer of valence Sharing of valence


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between sea of electrons from metals to electrons between


negatively charged nonmetals atoms
“mobile” or
“delocalized” electrons
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on the shells and


positively charged
protons in the nucleus
of atoms

Chemical Metallic crystals Ionic substances Covalent substances or


substances molecular substances

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Prepared by. B. A. Panton November (2023)

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formed

Smallest unit Atom Formula unit Molecule

Names and Platinum (Pt), gold Sodium chloride (Na+Cl-), Water (H2o), oxygen
chemical (Au), silver (Ag), magnesium oxide (O2), nitrogen (N2),
formulae of mercury (Hg), calcium (Mg2+O2-), aluminum carbon dioxide (CO2)
examples of (Ca), lithium (Li) bromide (Al3+Br3-) silicon dioxide (SiO2),
substances carbon (graphite and
containing diamond)

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bonding

Diagrammatic

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representation
(using an
example)

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B.
More on Covalent Bonding
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Classifications of covalent bonds

1. By types of atoms
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Type 1 Type 2
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Atoms involved Atoms of the SAME Atoms of DIFFERENT


element elements
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Examples There are 7 diatomic Water (H2o), carbon


atomics in the Periodic dioxide (CO2) silicon
Table of Elements. These dioxide (SiO2), glucose
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atoms become stabilized (C6H1206), methane (CH4),


only when they exist as Mothball (naphthalene,
pairs. C10H8), camphor ball
(C10H15O)
Names Mnemonic

Hydrogen Have

2
Nitrogen No

Fluorine Fear

Oxygen Of

Iodine Ice

Chlorine Cold

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Beer Bromine

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Substances formed Molecular element AND Molecular/Covalent
giant covalent (molecular compound

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substances)

2. By number of bonds
B.
by
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ep
Pr

NB’: Hydrogen has the lowest reactivity but the fastest reactivity. In other words,

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lowest reactivity corresponds to the number of bonds present, while highest
reactivity corresponds to the stability of the bond (s) present.

3. By the electronegativity of atoms

Electronegativity refers to the ability of an atom to attract bonded or shared electron


pairs. Some atoms attract electrons more readily than others, so most of the electron
clouds in bonded pairs are concentrated toward that atom/region of the molecule. This
creates polarity in individual molecules, whereby a slightly negative charge is induced in

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the atom that attracts the electrons more readily and a slightly positive charge in the atom
of a molecule that attracts the electrons less readily. The latter is referred to as the
electropositive atom/element. Comparatively, nonmetals are more electronegative than

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metals, or metals are more electropositive than nonmetals. The polarity in individual
molecules results in polarity in overall covalent substances. If two atoms that withdraw

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electrons equally, or almost equally, are bonded, then none will have more focus of the
electron cloud. In such a case, a nonpolar covalent bond results. Nonpolar covalent
bonds in individual molecules lead to the formation of nonpolar covalent substances.
B.
The polarity/nonpolarity of a covalent bond, and consequently of a covalent substance,
can be determined by calculations and reasoning. Each element is assigned an
electronegativity value, with fluorine at the top of group 7 being the most electronegative
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atom (its E.N. value is 4.0) and francium at the lowest end of group 1 being the most
electropositive atom (its E.N. value is 0.7). It follows, therefore, that fluorine is the most
reactive nonmetal(easiest to attract electrons)l and francium is the most reactive metal
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(easiest to give away electrons) of the Periodic Table.

The table below displays the assignment of the electronegativity values by the American
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chemist Linus Carl Pauling. The chart is referred to as the Pauling Scale of
Electronegativity or Pauling Electronegativity Scale.
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Electronegativity Type of bond Examples
(E.N.) difference

Less than 0.5 Nonpolar C-H


covalent C-C
X-X (X - halogen atom)
H-H
O=O

Between 0.5 and Polar H-X (X os a halogen

on
1.6 covalent atom)
H-O
N-H

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2.0 and more Ionic Y-Z (Y is any metal
and Z is any nonmetal
atom)

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Na-Cl, Mg-S

B.
by
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ep
Pr

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