NEET(Pre-Medical) 2024 | 05th May, 2024| Question Paper | Code: T4

PART-B: Chemistry
SECTION-A
51. Match List I with List II.
List I List II
(Process) (Conditions)
A. Isothermal process I. No heat exchange
B. Isochoric process II. Carried out at constant temperature
C. Isobaric process III. Carried out at constant volume
D. Adiabatic process IV. Carried out at constant pressure
Choose the correct answer from the options given below:
(1) A-I, B-II, C-III, D-IV (2) A-II, B-III, C-IV, D-I
(3) A-IV, B-III, C-II, D-I (4) A-IV, B-II, C-III, D-I
Ans. (2)
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52. Match List I with List II.

List I (Complex) List II (Type of isomerism)
A. Co (NH3 ) (NO2 )  Cl 2 I. Solvate isomerism
 5 
B. Co (NH3 ) ( SO4 )  Br II. Linkage isomerism
 5 
C. Co (NH3 )  Cr(CN)6  III. Ionization isomerism
 6

D. Co (H2O)  Cl 3 IV. Coordination isomerism

 6

Choose the correct answer from the options given below:

(1) A-I, B-IV, C-III, D-II (2) A-II, B-IV, C-III, D-I
(3) A-II, B-III, C-IV, D-I (4) A-I, B-III, C-IV, D-II
Ans. (3)
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53. The most stable carbocation among the following is:

CH3

⊕ ⊕
(1) CH2 (2)

CH3 CH3
⊕
CH CH
(3) H3C CH CH3 (4) CH3 CH2
⊕ CH3
Ans. (2)
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54. On heating, some solid substances change from solid to vapour state without passing through
liquid" state. "The technique used for the purification of such solid substances based on the
above principle is known as
(1) Distillation (2) Chromatography (3) Crystallization (4) Sublimation
Ans. (4)
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NEET(Pre-Medical) 2024 | 05th May, 2024| Question Paper | Code: T4
55. Match List I with List II.
List I (Reaction) List II (Reagents/Condition)
O
A. 2 O Cl/Anhyd.AlCl3
I.

B. II. CrO3

OH O
C. III. KMnO4/KOH, ∆

CH2CH3 COOK
D. IV. (i) O3 (ii) Zn-H2O

Choose the correct answer from the options given below:

(1) A-IV, B-I, C-II, D-III (2) A-I, B-IV, C-II, D-III
(3) A-IV, B-I, C-III, D-II (4) A-III, B-I, C-II, D-IV
Ans. (1)
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56. Intramolecular hydrogen bonding is present in

NO2
(1) (2) HF

OH
NO2 NO2
(3) (4)
OH HO
Ans. (3)
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57. The highest number of helium atoms is in

(1) 4 g of helium (2) 2.271098 L of helium at STP
(3) 4 mol of helium (4) 4 u of helium
Ans. (3)
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58. For the reaction 2A  B + C, KC = 4 × 10–3. At a given time, the composition of reaction mixture is:
[A] = [B] = [C] = 2 × 10–3 M
Then, which of the following is correct?
(1) Reaction has a tendency to go in backward direction.
(2) Reaction has gone to completion in forward direction.
(3) Reaction is at equilibrium.
(4) Reaction has a tendency to go in forward direction.
Ans. (1)
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NEET(Pre-Medical) 2024 | 05th May, 2024| Question Paper | Code: T4
59. The Eo value for the Mn3+/Mn2+ couple is more positive than that of Cr3+/Cr2+ or Fe3+/Fe2+ due to
change of :
(1) d4 to d5 configuration (2) d3 to d5 configuration
(3) d5 to d4 configuration (4) d5 to d2 configuration
Ans. (1)
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60. Fehling's solution 'A' is

(1) Alkaline solution of sodium potassium tartrate (Rochelle's salt)
(2) Aqueous sodium citrate
(3) Aqueous copper sulphate
(4) Alkaline copper sulphate
Ans. (3)
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61. Match List I with List II

List-I List-II
Compound Shape/geometry
A NH3 I Trigonal pyramidal
B BrF5 II Square planar
C XeF4 III Octahedral
D SF6 IV Square pyramidal

Choose the correct answer form the options given below

(1) A-III, B-IV, C-I, D-II
(2) A-II, B-III, C-IV, D-I
(3) A-I, B-IV, C-II, D-III
(4) A-II, B-IV, C-III, D-I
Ans. (3)
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62. Given below are tow statements:

3+ 3–
Statement I : Both Co(NH3 )6  and CoF6  complexes are octahedral but differ in their
magnetic behavior.
3+ 3–
Statement II : Co(NH3 )6  is diamagnetic whereas CoF6  is paramagnetic

In the light of the above statements, Choose the correct answer form the options given below
(1) Statement I is true but Statement II is false.
(2) Statement I is false but Statement II is true
(3) Both Statement I and Statement II are true
(4) Both Statement I and Statement II are false
Ans. (3)
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NEET(Pre-Medical) 2024 | 05th May, 2024| Question Paper | Code: T4
63. Among group 16 elements, which one does NOT show –2 oxidation state
(1) Te (2) Po (3) O (4) Se
Ans. (2)
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64. Which plot of ln k vs is consistent with Arrhenius equation?
T
ln k→

ln k→

ln k→

ln k→
(1) (2) (3) (4)
1 1 1 1
→ → → →
T T T T

Ans. (2)
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65. Arrange the following elements in increasing order of electronegativity:

N, O, F, C, Si
Choose the correct answer form the options given below
(1) O < F < N < C < Si (2) F < O < N < C < Si
(3) Si < C < N < O < F (4) Si < C < O < N < F
Ans. (3)
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66. Given below are two statements:

Statement I : The boiling point of three isomeric pentanes follows the order
n-pentane > isopentane > neopentane
Statement II : When branching increases, the molecule attains a shape of sphere. This results in
smaller surface area for contact, due to which the intermolecular forces between the spherical
molecules are weak thereby lowering the boiling point.
In the light of the above statements, Choose the most appropriate answer form the options given
below
(1) Statement I is correct but Statement II is incorrect
(2) Statement I is incorrect but Statement II is correct
(3) Both Statement I and Statement II are correct
(4) Both Statement I and Statement II are incorrect
Ans. (3)
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67. Which reaction is NOT a redox reaction?

(1) H2 + Cl 2 → 2HCl (2) BaCl 2 + Na2SO4 → BaSO4 + 2NaCl
(3) Zn + CuSO4 → ZnSO4 + Cu (4) 2KClO3 + I2 → 2KIO3 + Cl 2
Ans. (2)
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NEET(Pre-Medical) 2024 | 05th May, 2024| Question Paper | Code: T4
68. Arrange the following elements in increasing order of first ionization enthalpy:
Li, Be, B, C, N
Choose the correct answer from the options given below:
(1) Li < Be < C < B < N (2) Li < Be < N < B < C
(3) Li < Be < B < C < N (4) Li < B < Be < C < N
Ans. (4)
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69. Which one of the following alcohols reacts instantaneously with Lucas reagent?
CH3
(1) CH3–CH–CH2OH (2) CH3–C–OH (3) CH3-CH2-CH2-CH2OH (4) CH3–CH2–CH–OH
CH3 CH3 CH3
Ans. (2)
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70. Match List I with List II.

List I List II
(Molecule) (Number and types of bond/s
between two Corbon atoms)
A. ethane I one σ-bond and two π-bonds
B. ethene II two π-bonds
C. carbon III one σ-bond
molecule, C2
D. ethyne IV one σ-bond and one π-bond
Choose the correct answer from the options given below:
(1) A-III, B-IV, C-II, D-I (2) A-III, B-IV, C-I, D-II
(3) A-I, B-IV, C-II, D-III (4) A-IV, B-III, C-II, D-I
Ans. (1)
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71. Given below are two statements:

Statement I: The boiling point of hydrides of Group 16 elements follow the order
H2O > H2Te > H2Se > H2S.
Statement II: On the basis of molecular mass, H2O is expected to have lower boiling point than
the other members of the group but due to the presence of extensive H-bonding in H2O, it has
higher boiling point.
In the light of the above statements, choose the correct answer from the options given below:
(1) Statement I is true, but Statement II is false.
(2) Statement I is false, but Statement II is true.
(3) Both Statement I and Statement II are true.
(4) Both Statement I and Statement II are false.
Ans. (3)
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72. Given below are two statements:

Statement I: Aniline does not undergo Friedel-Crafts alkylation reaction.
Statement II: Aniline cannot be prepared through Gabriel synthesis.
In the light of the above statements, choose the correct answer from the options given below:
(1) Statement I is correct, but Statement II is false.
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NEET(Pre-Medical) 2024 | 05th May, 2024| Question Paper | Code: T4
(2) Statement I is incorrect, but Statement II is true.
(3) Both Statement I and Statement II are true.
(4) Both Statement I and Statement II are false.
Ans. (3)
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73. Match List I with List II.

List I List II
(Conversion) (Number of Faraday required)
A. 1mol of H2O to O2 I. 3F
B. 1mol of MnO 4
–
to Mn 2+
II. 2F
C. 1.5mol of Ca from molten CaCl2 III. 1F
D. 1mol of FeO to Fe2O3 IV. 5F
Choose the correct answer from the options given below:
(1) A-II, B-III, C-I, D-IV (2) A-III, B-IV, C-II, D-I
(3) A-II, B-IV, C-I, D-III (4) A-III, B-IV, C-I, D-II
Ans. (3)
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74. In which of the following equilibria, KP and KC are NOT equal?

(1) CO(g ) + H2O(g )  CO2( g ) + H2( g ) (2) 2BrCl (g )  Br2( g ) + Cl 2( g )

(3) PCl 5( g )  PCl 3( g ) + Cl 2( g ) (4) H2( g ) + I2( g )  2HI(g )

Ans. (3)
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75. The Henry's law constant (KH) values of three gases (A, B, C) in water are 145, 2×10–5 and 35 kbar,
respectively. The solubility of these gases in water follow the order:
(1) A > C > B (2) A > B > C (3) B > A > C (4) B > C > A
Ans. (4)
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76. Identify the correct reagents that would bring about the following transformation.


(1) (i) BH3 (ii) H2O2 / OH (iii) alk. KMnO4 (iv) H3O⊕

(2) (i) H2O / H+ (ii) PCC

(3) (i) H2O / H+ (ii) CrO3


(4) (i) BH3 (ii) H2O2 / OH (iii) PCC
Ans. (4)
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NEET(Pre-Medical) 2024 | 05th May, 2024| Question Paper | Code: T4
77. The compound that will undergo SN1 reaction with the fastest rate is:
CH3
Br
Br
(1) (2) (3) Br (4) Br

Ans. (2)
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78. The energy of an electron in the ground state (n = 1) for He+ ion is −x J , then that for an electron
in n = 2 state for Be3+ ion in J is :
4 x
(1) −4x (2) − x (3) −x (4) −
9 9
Ans. (3)
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79. A compound with a molecular formula of C6 H14 has two tertiary carbons. Its IUPAC name is:
(1) 2,3-dimethylbutane (2) 2,2-dimethylbutane
(3) n-hexane (4) 2-methylpentane
Ans. (1)
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80. The reagents with which glucose does not react to give the corresponding tests/products are
A. Tollen's reagent
B. Schiff's reagent
C. HCN
D. NH2OH
E. NaHSO3
Choose the correct options from the given below:
(1) B and E (2) E and D (3) B and C (4) A and D
Ans. (1)
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81. 'Spin only' magnetic moment same for which of the following ions?
A. Ti3+ B. Cr2+
C. Mn2+ D. Fe2+
E. Sc3+
Choose the most appropriate answer from the options given below:
(1) B and C only (2) A and D only (3) B and D only (4) A and E only
Ans. (3)
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NEET(Pre-Medical) 2024 | 05th May, 2024| Question Paper | Code: T4
82. Match List I with List II

List-I List-II
Quantum Information provided
Number
A ml I Shape of orbital
B ms II Size of orbital
C L III Orientation of orbital
D n IV Orientation of spin of electron

Choose the correct answer from the options given below:

(1) A-III, B-IV, C-II, D-I
(2) A-II, B-I, C-IV, D-III
(3) A-I, B-III, C-II, D-IV
(4) A-III, B-IV, C-I, D-II
Ans. (4)
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83. 1 gram of sodium hydroxide was treated with 25 mL of 0.75 M HCl solution, the mass of sodium
hydroxide left unreacted is equal to
(1) Zero mg (2) 200 mg (3) 750 mg (4) 250 mg
Ans. (4)
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84. In which of the following processes entropy increases?

A. A liquid evaporates to vapour.
B. Temperature of a crystalline solid lowered form 130 K to 0 K.
C. 2 NaHCO3(s) → Na2CO3(s) + CO2(g) + H2O(g)
D. Cl2(g) → 2Cl(g)
Choose the correct answer from the options given below:
(1) A, C and D (2) C and D (3) A and C (4) A, B and D
Ans. (1)
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85. Activation energy of any chemical reactions can be calculated if one knows the value of
(1) Orientation of reactant molecules during collision.
(2) Rate constant at two different temperatures.
(3) Rate constant at standard temperatures.
(4) Probability of collision.
Ans. (2)
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NEET(Pre-Medical) 2024 | 05th May, 2024| Question Paper | Code: T4
86. Major products A and B formed in the following reaction sequence, are
OH
H3 C
PBr3 A alc.KOH B
(major) ∆ (major)
OH OH OH O
H3 C Br H3 C H3 C Br H3 C
(1) A = ;B= (2) A = ;B=

Br Br
H3 C H3 C H3 C H3 C
(3) A = ;B= (4) A = ;B=

Ans. (3)
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87. The work done during reversible isothermal expansion of one mole of hydrogen gas at 25°C from
pressure of 20 atmosphere to 10 atmosphere is:
(Given R = 2.0 cal K −1 mol −1 )
(1) 413.14 calories (2) 100 calories (3) 0 calorie (4) -413.14 calories
Ans. (4)
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88. Consider the following reaction in a sealed vessel at equilibrium with concentrations of
N2 =
3.0 × 10−3 M,O2 =
4.2 × 10−3 M and

NO
= 2.8 × 10−3 M
2NO(g )  N2( g ) + O2( g )

If 0.1 molL−1 of NO(g) is taken in a closed vessel, what will be degree of dissociation (α) of NO(g) at
equilibrium?
(1) 0.8889 (2) 0.717 (3) 0.00889 (4) 0.0889
Ans. (2)
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89. For the given reaction:

KmnO4/H+
C=CH ‘P’
H (major
product)

‘P’ is:
OH OH O O
(1) CH CH (2) C—C

(3) CHO (4) COOH

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NEET(Pre-Medical) 2024 | 05th May, 2024| Question Paper | Code: T4
Ans. (4)
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90. The pair of lanthanoid ions which are diamagnetic is

(1) Gd3+ and Eu3+ (2) Pm3+ and Sm3+
(3) Ce4 + and Yb2+ (4) Ce3+ and Eu2+
Ans. (3)
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91. Identify the major product C formed in the following reaction sequence:
NaCN OH − NaOH
CH3 − CH2 − CH2 − I  → A 
Partial hydrolysis
→ B 
Br → C
2 (major)

(1) butanamide (2) α-bromobutanoic acid

(3) propylamine (4) butylamine
Ans. (3)
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92. The products A and B obtained in the following reactions, respectively, are
3ROH + PCl 3 → 3RCl + A
ROH + PCl 5 → RCl + HCl + B
(1) H3PO4 and POCl 3 (2) H3PO3 and POCl 3
(3) POCl 3 and H3PO3 (4) POCl 3 and H3PO4
Ans. (2)
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93. Given below are certain cations. Using inorganic qualitative analysis, arrange them in increasing
group number from 0 to VI.
A. Al 3+ B. Cu2+
C. Ba2+ D. Co2+
E. Mg 2+
Choose the correct answer from the options given below:
(1) E, C, D, B, A (2) E, A, B, C, D (3) B, A, D, C, E (4) B, C, A, D, E
Ans. (3)
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94. A compound X contains 32 % of A, 20% of B2 and remaining percentage of C. Then, the empirical
formula of X is:
(Given atomic masses of A = 64; B = 40; C = 32
(1) AB2C2 (2) ABC4 (3) A2BC2 (4) ABC3
Ans. (4)
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NEET(Pre-Medical) 2024 | 05th May, 2024| Question Paper | Code: T4
95. The rate of a reaction quadruples where temperature changes from 27°C to 57°C calculate the
energy of activation.
Given R = 8. 314 J K–1 mol–1, log 4 = 0.6021
(1) 3.80 kJ/mol (2) 3804 kJ/mol (3) 38.04 kJ/mol (4) 380.4 kJ/mol
Ans. (3)
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96. The plot of osmotic pressure (π) vs concentration (mol L–1) for a solution gives a straight line with
slope 25.73 L bar mol–1. The temperature at which the osmotic pressure measurement is done is
(Use R = 0.083 L bar mol–1 K–1)
(1) 25.73°C (2) 12.05°C (3) 37°C (4) 310°C
Ans. (3)
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97. During the preparation of Mohr's salt solution (Ferrous ammonium sulphate), which of the
following acid is added to prevent hydrolysis of Fe2+ ion
(1) Dilute nitric acid (2) Dilute sulphuric acid
(3) dilute hydrochloric acid (4) Concentrated sulphuric acid
Ans. (3)
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98. Mass in grams of copper deposited by passing 9.6487 A current through a voltmeter containing
copper sulphate solution for 100 seconds is:
(Given : Molar mass of Cu : 63 g mol–1, 1F = 96487 C)
(1) 31.5 g (2) 0.0315 g (3) 3.15 g (4) 0.315 g
Ans. (4)
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99. Identify the correct answer.

(1) Dipole moment of NF3 is greater than that of NH3.
(2) Three canonical forms can be drawn for CO2–
3
ion.
(3) Three resonance structures can be drawn for ozone
(4) BF3 has non-zero dipole moment.
Ans. (2)
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3+ +
100. Statement I : Co(NH3 )6  is a homoleptic complex whereas Co(NH3 )4 Cl 2  is a heteroleptic

complex.
3+ +
Statement II : Complex Co(NH3 )6  has only one kind of ligands but Co(NH3 )4 Cl 2  has more
than one kind of ligands.
In the light of the above statements, Choose the correct answer form the options given below
(1) Statement I is true but Statement II is false.

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NEET(Pre-Medical) 2024 | 05th May, 2024| Question Paper | Code: T4
(2) Statement I is false but Statement II is true
(3) Both Statement I and Statement II are true
(4) Both Statement I and Statement II are false
Ans. (3)
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