SAFETY DATA SHEET

DOW EUROPE GMBH

Product name: VORACOR™ CD 526 Isocyanate Issue Date: 05/30/2016

Print Date: 07/28/2016

DOW EUROPE GMBH encourages and expects you to read and understand the entire (M)SDS, as
there is important information throughout the document. We expect you to follow the precautions
identified in this document unless your use conditions would necessitate other appropriate methods or
actions.

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: VORACOR™ CD 526 Isocyanate

Recommended use of the chemical and restrictions on use

Identified uses: Component(s) for the manufacture of urethane polymers. For industrial use.

COMPANY IDENTIFICATION
DOW EUROPE GMBH
BACHTOBELSTRASSE 3
8810 HORGEN
SWITZERLAND

Customer Information Number: (31) 115 67 2626

SDSQuestion@dow.com

EMERGENCY TELEPHONE NUMBER

24-Hour Emergency Contact: 00 41 447 28 2820
Local Emergency Contact: 00 31 115 69 4982

2. HAZARDS IDENTIFICATION
Hazard classification
Limited evidence of a carcinogenic effect.
Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Harmful by inhalation.
Irritating to eyes, respiratory system and skin.
May cause sensitisation by inhalation and skin contact.

Other hazards
No data available

3. COMPOSITION/INFORMATION ON INGREDIENTS

This product is a substance.

CASRN / EC-No. /
Concentration Component Classification
Index-No.

® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 12

company of Dow
Product name: VORACOR™ CD 526 Isocyanate Issue Date: 05/30/2016

CASRN 100.0 % Diphenylmethane Diisocyanate, Xn - R20

9016-87-9 isomers and homologues Xi - R36/37/38
EC-No. Xn - R42/43
618-498-9 Xn - Carc.Cat.3 - R40
Index-No.
–
CASRN 40.0 - 50.0 % 4,4' -Methylenediphenyl Carc.Cat.3 - R40
101-68-8 diisocyanate Xn - R20 - R48/20
EC-No. Xi - R36/37/38
202-966-0 R42/43
Index-No.
615-005-00-9
The full text of each R phrase is listed in section 16.

Note
Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9.

4. FIRST AID MEASURES

Description of first aid measures
General advice: First Aid responders should pay attention to self-protection and use the
recommended protective clothing (chemical resistant gloves, splash protection). If potential for
exposure exists refer to Section 8 for specific personal protective equipment.

Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility.

Skin contact: Remove material from skin immediately by washing with soap and plenty of water.
Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists.
Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very
soon after exposure is important, and that a polyglycol-based skin cleanser or corn oil may be more
effective than soap and water. Discard items which cannot be decontaminated, including leather
articles such as shoes, belts and watchbands. Suitable emergency safety shower facility should be
available in work area.

Eye contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5
minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay,
preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately
available.

Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by
medical personnel.

Most important symptoms and effects, both acute and delayed: Aside from the information found
under Description of first aid measures (above) and Indication of immediate medical attention and
special treatment needed (below), any additional important symptoms and effects are described in
Section 11: Toxicology Information.

Indication of any immediate medical attention and special treatment needed

Notes to physician: Maintain adequate ventilation and oxygenation of the patient. May cause
respiratory sensitization or asthma-like symptoms. Bronchodilators, expectorants and antitussives

Page 2 of 12
Product name: VORACOR™ CD 526 Isocyanate Issue Date: 05/30/2016

may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids.
Respiratory symptoms, including pulmonary edema, may be delayed. Persons receiving significant
exposure should be observed 24-48 hours for signs of respiratory distress. If you are sensitized to
diisocyanates, consult your physician regarding working with other respiratory irritants or sensitizers.
Treatment of exposure should be directed at the control of symptoms and the clinical condition of the
patient. Excessive exposure may aggravate preexisting asthma and other respiratory disorders (e.g.
emphysema, bronchitis, reactive airways dysfunction syndrome).

5. FIREFIGHTING MEASURES
Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon
dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose
synthetic foams (including AFFF) or protein foams may function, but will be less effective.

Unsuitable extinguishing media: Do not use direct water stream. May spread fire.

Special hazards arising from the substance or mixture

Hazardous combustion products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen cyanide.
Carbon monoxide. Carbon dioxide.

Unusual Fire and Explosion Hazards: Product reacts with water. Reaction may produce heat and/or
gases. This reaction may be violent. Container may rupture from gas generation in a fire situation.
Violent steam generation or eruption may occur upon application of direct water stream to hot liquids.
Dense smoke is produced when product burns.

Advice for firefighters

Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay
upwind. Keep out of low areas where gases (fumes) can accumulate. Water is not recommended, but
may be applied in large quantities as a fine spray when other extinguishing agents are not available.
Do not use direct water stream. May spread fire. Fight fire from protected location or safe distance.
Consider the use of unmanned hose holders or monitor nozzles. Immediately withdraw all personnel
from the area in case of rising sound from venting safety device or discoloration of the container.
Move container from fire area if this is possible without hazard. Use water spray to cool fire-exposed
containers and fire-affected zone until fire is out. Contain fire water run-off if possible. Fire water run-
off, if not contained, may cause environmental damage. Review the "Accidental Release Measures"
and the "Ecological Information" sections of this (M)SDS.

Special protective equipment for firefighters: Wear positive-pressure self-contained breathing

apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely,
change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is
not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight
fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer
to the relevant sections.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures: Isolate area. Keep
unnecessary and unprotected personnel from entering the area. Keep personnel out of low areas.

Page 3 of 12
Product name: VORACOR™ CD 526 Isocyanate Issue Date: 05/30/2016

Keep upwind of spill. Spilled material may cause a slipping hazard. Ventilate area of leak or spill. If
available, use foam to smother or suppress. Refer to section 7, Handling, for additional precautionary
measures. See Section 10 for more specific information. Use appropriate safety equipment. For
additional information, refer to Section 8, Exposure Controls and Personal Protection.

Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.

Methods and materials for containment and cleaning up: Contain spilled material if possible.
Absorb with materials such as: Dirt. Vermiculite. Sand. Clay. Do NOT use absorbent materials such
as: Cement powder (Note: may generate heat). Collect in suitable and properly labeled open
containers. Do not place in sealed containers. Suitable containers include: Metal drums. Plastic
drums. Polylined fiber pacs. Wash the spill site with large quantities of water. Attempt to neutralize
by adding suitable decontaminant solution: Formulation 1: sodium carbonate 5 - 10%; liquid detergent
0.2 - 2%; water to make up to 100%, OR Formulation 2: concentrated ammonia solution 3 - 8%; liquid
detergent 0.2 - 2%; water to make up to 100%. If ammonia is used, use good ventilation to prevent
vapor exposure. Contact your supplier for clean-up assistance. See Section 13, Disposal
Considerations, for additional information.

7. HANDLING AND STORAGE

Precautions for safe handling: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing.
Avoid prolonged or repeated contact with skin. Use with adequate ventilation. Wash thoroughly after
handling. Keep container closed. See Section 8, EXPOSURE CONTROLS AND PERSONAL
PROTECTION.

Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition
temperatures possibly resulting in spontaneous combustion.

Conditions for safe storage: Store in a dry place. Protect from atmospheric moisture. Do not store
product contaminated with water to prevent potential hazardous reaction. See Section 10 for more
specific information. Additional storage and handling information on this product may be obtained by
calling your sales or customer service contact.

Storage stability
Storage temperature: Storage Period:
15 - 25 °C 6 Month

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Exposure limits are listed below, if they exist.
Component Regulation Type of listing Value/Notation
Diphenylmethane KE OEL TWA SEN
Diisocyanate, isomers and
homologues
KE OEL STEL SEN
KE OEL TWA 0.02 mg/m3 , NCO
KE OEL STEL 0.07 mg/m3 , NCO
4,4' -Methylenediphenyl ACGIH TWA 0.005 ppm
diisocyanate

Page 4 of 12
Product name: VORACOR™ CD 526 Isocyanate Issue Date: 05/30/2016

Dow IHG TWA 0.005 ppm

Dow IHG STEL 0.02 ppm
KE OEL TWA 0.02 mg/m3
KE OEL STEL 0.07 mg/m3

Exposure controls
Engineering controls: Use only with adequate ventilation. Local exhaust ventilation may be
necessary for some operations. Provide general and/or local exhaust ventilation to control airborne
levels below the exposure guidelines. Exhaust systems should be designed to move the air away
from the source of vapor/aerosol generation and people working at this point. The odor and irritancy
of this material are inadequate to warn of excessive exposure.

Individual protection measures

Eye/face protection: Use chemical goggles. Chemical goggles should be consistent with EN
166 or equivalent.
Skin protection
Hand protection: Use chemical resistant gloves classified under Standard EN374:
Protective gloves against chemicals and micro-organisms. Examples of preferred
glove barrier materials include: Butyl rubber. Polyethylene. Chlorinated polyethylene.
Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials
include: Neoprene. Viton. Polyvinyl chloride ("PVC" or "vinyl"). Nitrile/butadiene
rubber ("nitrile" or "NBR"). When prolonged or frequently repeated contact may occur,
a glove with a protection class of 5 or higher (breakthrough time greater than 240
minutes according to EN 374) is recommended. When only brief contact is expected,
a glove with a protection class of 3 or higher (breakthrough time greater than 60
minutes according to EN 374) is recommended. Glove thickness alone is not a good
indicator of the level of protection a glove provides against a chemical substance as
this level of protection is also highly dependent on the specific composition of the
material that the glove is fabricated from. The thickness of the glove must, depending
on model and type of material, generally be more than 0.35 mm to offer sufficient
protection for prolonged and frequent contact with the substance. As an exception to
this general rule it is known that multilayer laminate gloves may offer prolonged
protection at thicknesses less than 0.35 mm. Other glove materials with a thickness of
less than 0.35 mm may offer sufficient protection when only brief contact is expected.
NOTICE: The selection of a specific glove for a particular application and duration of
use in a workplace should also take into account all relevant workplace factors such
as, but not limited to: Other chemicals which may be handled, physical requirements
(cut/puncture protection, dexterity, thermal protection), potential body reactions to
glove materials, as well as the instructions/specifications provided by the glove
supplier.
Other protection: Use protective clothing chemically resistant to this material.
Selection of specific items such as face shield, boots, apron, or full body suit will
depend on the task.
Respiratory protection: Atmospheric levels should be maintained below the exposure
guideline. When atmospheric levels may exceed the exposure guideline, use an approved air-
purifying respirator equipped with an organic vapor sorbent and a particle filter. For situations
where the atmospheric levels may exceed the level for which an air-purifying respirator is
effective, use a positive-pressure air-supplying respirator (air line or self-contained breathing
apparatus). For emergency response or for situations where the atmospheric level is
unknown, use an approved positive-pressure self-contained breathing apparatus or positive-
pressure air line with auxiliary self-contained air supply.
Use the following CE approved air-purifying respirator: Organic vapor cartridge with a
particulate pre-filter, type AP2.

Page 5 of 12
Product name: VORACOR™ CD 526 Isocyanate Issue Date: 05/30/2016

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Physical state Liquid.
Color Brown
Odor Musty
Odor Threshold 0.4 ppm Based on Literature for MDI. Odor is inadequate
warning of excessive exposure.
pH Not applicable
Melting point/range No test data available
Freezing point No test data available
Boiling point (760 mmHg) Decomposes before boiling
Flash point closed cup >= 200 °C Estimated.
Evaporation Rate (Butyl Acetate No test data available
= 1)
Flammability (solid, gas) Not applicable to liquids
Lower explosion limit No test data available
Upper explosion limit No test data available
Vapor Pressure <= 0.00001 mmHg at 20 °C Literature
Relative Vapor Density (air = 1) 8.5 Literature
Relative Density (water = 1) 1.19 - 1.23 at 25 °C / 25 °C ASTM D891
Water solubility insoluble, reacts, evolution of CO2
Partition coefficient: n- No data available
octanol/water
Auto-ignition temperature No test data available
Decomposition temperature No data available
Kinematic Viscosity 100 - 250 mm2/s at 25 °C ASTM D 445
Explosive properties Not explosive
Oxidizing properties No
Molecular weight No test data available

NOTE: The physical data presented above are typical values and should not be construed as a
specification.

10. STABILITY AND REACTIVITY

Reactivity: Diisocyanates react with many materials and the rate of reaction increases with
temperature as well as increased contact; these reactions can become violent. Contact is increased
by stirring or if the other material mixes with the diisocyanate. Diisocyanates are not soluble in water
and sink to the bottom, but react slowly at the interface. The reaction forms carbon dioxide gas and a
layer of solid polyurea. Reaction with water will generate carbon dioxide and heat.

Chemical stability: Stable under recommended storage conditions. See Storage, Section 7.

Page 6 of 12
Product name: VORACOR™ CD 526 Isocyanate Issue Date: 05/30/2016

Possibility of hazardous reactions: Can occur. Exposure to elevated temperatures can cause
product to decompose and generate gas. This can cause pressure build-up and/or rupturing of closed
containers. Polymerization can be catalyzed by: Strong bases. Water.

Conditions to avoid: Exposure to elevated temperatures can cause product to decompose.

Generation of gas during decomposition can cause pressure in closed systems. Pressure build-up
can be rapid. Avoid moisture. Material reacts slowly with water, releasing carbon dioxide which can
cause pressure buildup and rupture of closed containers. Elevated temperatures accelerate this
reaction.

Incompatible materials: Avoid contact with: Acids. Alcohols. Amines. Water. Ammonia. Bases.
Metal compounds. Moist air. Strong oxidizers. Diisocyanates react with many materials and the rate
of reaction increases with temperature as well as increased contact; these reactions can become
violent. Contact is increased by stirring or if the other material mixes with the diisocyanate.
Diisocyanates are not soluble in water and sink to the bottom, but react slowly at the interface. The
reaction forms carbon dioxide gas and a layer of solid polyurea. Reaction with water will generate
carbon dioxide and heat. Avoid contact with metals such as: Aluminum. Zinc. Brass. Tin. Copper.
Galvanized metals. Avoid contact with absorbent materials such as: Moist organic absorbents. Avoid
unintended contact with polyols. The reaction of polyols and isocyanates generate heat.

Hazardous decomposition products: Decomposition products depend upon temperature, air supply
and the presence of other materials. Gases are released during decomposition.

11. TOXICOLOGICAL INFORMATION

Toxicological information appears in this section when such data is available.

Acute toxicity
Acute oral toxicity
Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal
handling operations are not likely to cause injury; however, swallowing larger amounts may
cause injury. Observations in animals include: Gastrointestinal irritation.

As product: Single dose oral LD50 has not been determined.

LD50, Rat, > 2,000 mg/kg Estimated.

Acute dermal toxicity

Prolonged skin contact is unlikely to result in absorption of harmful amounts.

As product: The dermal LD50 has not been determined.

LD50, Rabbit, > 2,000 mg/kg Estimated.

Acute inhalation toxicity

At room temperature, vapors are minimal due to low volatility. However, certain operations
may generate vapor or mist concentrations sufficient to cause respiratory irritation and other
adverse effects. Such operations include those in which the material is heated, sprayed or
otherwise mechanically dispersed such as drumming, venting or pumping. Excessive
exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. May
cause pulmonary edema (fluid in the lungs.) Effects may be delayed. Decreased lung
function has been associated with overexposure to isocyanates.
As product: The LC50 has not been determined.

Page 7 of 12
Product name: VORACOR™ CD 526 Isocyanate Issue Date: 05/30/2016

Skin corrosion/irritation
Prolonged contact may cause skin irritation with local redness.
May stain skin.

Serious eye damage/eye irritation

May cause moderate eye irritation.
May cause slight temporary corneal injury.

Sensitization
A component in this mixture has been shown to be a skin sensitizer.
Animal studies have shown that skin contact with isocyanates may play a role in respiratory
sensitization.

A component in this mixture may cause an allergic respiratory response.

MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in
individuals already sensitized.
Asthma-like symptoms may include coughing, difficult breathing and a feeling of tightness in the chest.
Occasionally, breathing difficulties may be life threatening.

Specific Target Organ Systemic Toxicity (Single Exposure)

Contains component(s) which are classified as specific target organ toxicant, single exposure,
category 3.

Specific Target Organ Systemic Toxicity (Repeated Exposure)

Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after
repeated excessive exposures to MDI/polymeric MDI aerosols.

Carcinogenicity
Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of
MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory
irritation and lung injury. Current exposure guidelines are expected to protect against these effects
reported for MDI.

Teratogenicity
In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only
at high doses which were toxic to the mother.

Reproductive toxicity
No specific, relevant data available for assessment.

Mutagenicity
Genetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in vitro studies; other
in vitro studies were negative. Animal mutagenicity studies were predominantly negative.

Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.

COMPONENTS INFLUENCING TOXICOLOGY:

Diphenylmethane Diisocyanate, isomers and homologues

Acute inhalation toxicity
LC50, Rat, 4 Hour, dust/mist, 0.49 mg/l

Page 8 of 12
Product name: VORACOR™ CD 526 Isocyanate Issue Date: 05/30/2016

For similar material(s): 4,4'-Methylenediphenyl diisocyanate (CAS 101-68-8). LC50, Rat, 1

Hour, Aerosol, 2.24 mg/l

For similar material(s): 2,4'-Diphenylmethane diisocyanate (CAS 5873-54-1). LC50, Rat, 4

Hour, Aerosol, 0.387 mg/l

4,4' -Methylenediphenyl diisocyanate

Acute inhalation toxicity
LC50, Rat, 1 Hour, dust/mist, 2.24 mg/l

12. ECOLOGICAL INFORMATION

Ecotoxicological information appears in this section when such data is available.

Toxicity
Acute toxicity to fish
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species.
Material is not classified as dangerous to aquatic organisms (LC50/EC50/IC50/LL50/EL50
greater than 100 mg/L in most sensitive species).

Based on information for a similar material:

LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 203 or
Equivalent

Acute toxicity to aquatic invertebrates

Based on information for a similar material:
EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline
202 or Equivalent

Acute toxicity to algae/aquatic plants

Based on information for a similar material:
NOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition,
1,640 mg/l, OECD Test Guideline 201 or Equivalent

Toxicity to bacteria
Based on information for a similar material:
EC50, activated sludge, static test, 3 Hour, Respiration rates., > 100 mg/l

Toxicity to soil-dwelling organisms

EC50, Eisenia fetida (earthworms), Based on information for a similar material:, 14 d, > 1,000
mg/kg

Toxicity to terrestrial plants

EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/l

EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l

Persistence and degradability

Biodegradability: In the aquatic and terrestrial environment, material reacts with water
forming predominantly insoluble polyureas which appear to be stable. In the atmospheric

Page 9 of 12
Product name: VORACOR™ CD 526 Isocyanate Issue Date: 05/30/2016

environment, material is expected to have a short tropospheric half-life, based on calculations

and by analogy with related diisocyanates.
10-day Window: Not applicable
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 302C or Equivalent

Bioaccumulative potential
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d

Mobility in soil
In the aquatic and terrestrial environment, movement is expected to be limited by its reaction
with water forming predominantly insoluble polyureas.

Results of PBT and vPvB assessment

This substance is not considered to be persistent, bioaccumulating and toxic (PBT).

Other adverse effects

This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

13. DISPOSAL CONSIDERATIONS

Disposal methods: This product, when being disposed of in its unused and uncontaminated state
should be treated as a hazardous waste according to EC Directive 2008/98/EC. Any disposal
practices must be in compliance with all national and provincial laws and any municipal or local by-
laws governing hazardous waste. For used, contaminated and residual materials additional
evaluations may be required. Do not dump into any sewers, on the ground, or into any body of water.
Incineration under approved, controlled conditions using incinerators suitable or designed for the
disposal of hazardous chemical wastes, is the preferred method for disposal. Small quantities of
waste may be pretreated for example with polyol, to neutralise prior to disposal. Empty drums should
be decontaminated (see Section 6) and either punctured and scrapped or given to an approved drum
reconditioner.

14. TRANSPORT INFORMATION

Classification for ROAD and Rail transport:

Not regulated for transport

Classification for SEA transport (IMO-IMDG):

Not regulated for transport
Transport in bulk Consult IMO regulations before transporting ocean bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code

Classification for AIR transport (IATA/ICAO):

Not regulated for transport

Page 10 of 12
Product name: VORACOR™ CD 526 Isocyanate Issue Date: 05/30/2016

This information is not intended to convey all specific regulatory or operational

requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.

15. REGULATORY INFORMATION

Label

Classification and labeling have been performed according to regulations.

Hazard symbol and Indication of danger

Xn Harmful
Chemical name: Diphenylmethane Diisocyanate, isomers and homologues

R-phrase(s)
R40 Limited evidence of a carcinogenic effect.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through
inhalation.
R20 Harmful by inhalation.
R36/37/38 Irritating to eyes, respiratory system and skin.
R42/43 May cause sensitisation by inhalation and skin contact.

S-phrase(s)
S2 Keep out of the reach of children.
S46 If swallowed, seek medical advice immediately and show this container or label.
S36/37 Wear suitable protective clothing and gloves.
S23 Do not breathe gas/fumes/vapour/spray.

Contains isocyanates. See information supplied by the manufacturer.

Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control
of major-accident hazards involving dangerous substances.
Listed in Regulation: Not applicable

Page 11 of 12
Product name: VORACOR™ CD 526 Isocyanate Issue Date: 05/30/2016

16. OTHER INFORMATION

Full text of the R-phrases given in Section 3

R20 Harmful by inhalation.
R36/37/38 Irritating to eyes, respiratory system and skin.
R40 Limited evidence of a carcinogenic effect.
R42/43 May cause sensitisation by inhalation and skin contact.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through
inhalation.

Revision
Identification Number: 101196219 / A305 / Issue Date: 05/30/2016 / Version: 5.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.

Legend
ACGIH USA. ACGIH Threshold Limit Values (TLV)
Dow IHG Dow Industrial Hygiene Guideline
KE OEL Kenya. Occupational Exposure Limits
SEN Sensitizer
STEL Short term exposure limit
TWA Time weighted average

Information Source and References

This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.

DOW EUROPE GMBH urges each customer or recipient of this (M)SDS to study it carefully and
consult appropriate expertise, as necessary or appropriate, to become aware of and understand the
data contained in this (M)SDS and any hazards associated with the product. The information herein is
provided in good faith and believed to be accurate as of the effective date shown above. However, no
warranty, express or implied, is given. Regulatory requirements are subject to change and may differ
between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with
all federal, state, provincial or local laws. The information presented here pertains only to the product
as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is
the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to
the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and
cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have
obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current,
please contact us for the most current version.

Page 12 of 12