MediPal IPA Alcohol - EU - 2023 03 23

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According to Regulation (EC) No 1907/2006

Medipal Alcohol Disinfectant Wipes


SAFETY DATA SHEET

Version number: 1
Issued: 2023-03-23

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
Trade name
W500110MPCE, W505110MPCE, W508110MPCE,W600110CE,
W600110ECE,W600110CEMOH,W600110MPCEA, W605110EMPCE, W605110MPCE
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
Cleaning and disinfecting wipes for hard surfaces. Restricted to professional users.

1.3. Details of the supplier of the safety data sheet


Supplier
Pal Hygiene Products Limited

Street address
Unit 5B & Unit 5H, Fingal Bay Business Park
Balbriggan
K32 NY57 Co. Dublin
Ireland

Telephone
+44 (0) 1455 555 700

Email
info@palinternational.com

1.4. Emergency telephone number


112

Available outside office hours


Yes

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture


Classification according to Regulation (EC) No 1272/2008
Classification
Flammable liquids, hazard category 2
Eye irritation, hazard category 2
Specific Target Organ Toxicity — Single exposure, hazard category 3 - narcosis

Hazard statements
H225, H319, H336

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According to Regulation (EC) No 1907/2006
SAFETY DATA SHEET

M2029
Version number: 1
Issued: 2023-03-23

2.2. Label elements


Labelling according to Regulation (EC) No 1272/2008
Hazard pictograms

Signal word
Danger

Hazard statements
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.

Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 Keep container tightly closed.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P403 + P235 Store in a well-ventilated place. Keep cool.
P261 Avoid breathing vapours.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.

More information
EUH066 Repeated exposure may cause skin dryness or cracking.

Contains: Propan-2-ol

2.3. Other hazards


This product does not contain any PBT or vPvB substances. Endocrine disrupting properties: no

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Chemical name CAS No. Concentration Classification H-phrase Note


EC No. M factor acute
REACH No. M factor chronic
Index No.
Propan-2-ol 67-63-0 70% Flam. Liq. 2, Eye H225, H319, -
200-661-7 Irrit. 2, STOT SE H336
01-2119457558- 3 -
25-xxxx -
603-117-00-0

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According to Regulation (EC) No 1907/2006
SAFETY DATA SHEET

M2029
Version number: 1
Issued: 2023-03-23

Substance additional information


For the complete text of H- / EUH-statements mentioned in this section, see section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures


Inhalation
If inhaled, remove to fresh air. If symptoms persist, call a physician. If unconscious place in
recovery position and seek medical advice.

Skin contact
Wash off immediately with plenty of water.

Eye contact
Rinse cautiously with water for several minutes. Hold eyelids apart. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Ingestion
Rinse mouth with water. Get medical attention if symptoms occur.

4.2. Most important symptoms and effects, both acute and delayed
Inhalation
In high concentrations, vapours and spray mists are narcotic and may cause headache, fatigue,
dizziness and nausea.

Skin contact
Prolonged skin contact may cause redness, irritation and dry skin.

Eye contact
Irritating and may cause redness and pain.

Ingestion
Nausea, vomiting.

4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.

Unsuitable extinguishing media


Do not use water jet as an extinguisher, as this will spread the fire.

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According to Regulation (EC) No 1907/2006
SAFETY DATA SHEET

M2029
Version number: 1
Issued: 2023-03-23

5.2. Special hazards arising from the substance or mixture


Solvent vapours are heavier than air and may spread along floors. Solvent vapours may form
explosive mixtures with air. Flash back possible over considerable distance. Highly flammable
liquid and vapour.

Hazardous combustion products:


carbon monoxide
carbon dioxide (CO2)
sulphur oxides
oxides of phosphorus

5.3. Advice for firefighters


Special protective equipment for fire-fighters
Use protective equipment appropriate for surrounding materials.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Use personal protective equipment as required. Keep away from sources of ignition - No smoking.
Ensure adequate ventilation. Avoid breathing vapours.

6.2. Environmental precautions


Do not discharge into drains, water courses or onto the ground.

6.3. Methods and material for containment and cleaning up


Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth,
diatomaceous earth, vermiculite) and place in container for disposal according to local / national
regulations (see section 13). Stop leak if safe to do so.

6.4. Reference to other sections


For personal protection, see section 8. For waste disposal, see section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling


Preventive handling precautions
Keep container tightly closed. Ensure adequate ventilation. Handle in accordance with good
industrial hygiene and safety practice. Keep away from sources of ignition - No smoking.

General hygiene
Wash hands before breaks and at the end of workday.

7.2. Conditions for safe storage, including any incompatibilities


Store in tightly closed original container in a dry, cool and well-ventilated place. Do not store
together with oxidizing and self-igniting products. Keep away from heat, hot surfaces, sparks, open
flames and other ignition sources. No smoking. Storage temperature -10 - 40 °C.

7.3. Specific end use(s)


The identified uses for this product are detailed in Section 1.2.

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According to Regulation (EC) No 1907/2006
SAFETY DATA SHEET

M2029
Version number: 1
Issued: 2023-03-23

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

DNEL/DMEL
Product/Substance name Type Exposure Value Population Effects
(CAS No./EC No.)
Propan-2-ol DNEL Chronic (long term) 888 mg/kg bw/day Workers Systemic
(67-63-0/200-661-7) Dermal
Propan-2-ol DNEL Chronic (long term) 500 mg/m³ Workers Systemic
(67-63-0/200-661-7) Inhalation
Propan-2-ol DNEL Chronic (long term) 319 mg/kg bw/day Consumers Systemic
(67-63-0/200-661-7) Dermal
Propan-2-ol DNEL Chronic (long term) 89 mg/m³ Consumers Systemic
(67-63-0/200-661-7) Inhalation
Propan-2-ol DNEL Chronic (long term) 26 mg/kg bw/day Consumers Systemic
(67-63-0/200-661-7) Oral

PNEC/PEC
Product/Substance name Type Environmental compartment Value
(CAS No./EC No.)
Propan-2-ol PNEC Freshwater 140.9 mg/l
(67-63-0/200-661-7)
Propan-2-ol PNEC Marine water 140.9 mg/l
(67-63-0/200-661-7)
Propan-2-ol PNEC Intermittent releases 140.9 mg/l
(67-63-0/200-661-7)
Propan-2-ol PNEC Sewage Treatment Plant 2251 mg/l
(67-63-0/200-661-7)
Propan-2-ol PNEC Soil 28 mg/kg
(67-63-0/200-661-7)
Propan-2-ol PNEC Oral (Secondary Poisoning) 160 mg/kg
(67-63-0/200-661-7) food
Propan-2-ol PNEC Sediment 552 mg/kg
(67-63-0/200-661-7) dwt

8.2. Exposure controls


Appropriate engineering controls
Provide good ventilation.

Eye / face protection


No special protective equipment required.

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According to Regulation (EC) No 1907/2006
SAFETY DATA SHEET

M2029
Version number: 1
Issued: 2023-03-23

Hand protection
Gloves are recommended for prolonged use. Wear protective gloves made of the following
material: Nitrile.

Other skin protection


No special protective equipment required.

Respiratory protection
No special protective equipment required.

Thermal hazards
No special protective equipment required.

Environmental exposure controls


Do not flush into surface water or sanitary sewer system.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties


Physical state
Liquid-impregnated wipe

Colour
White (clear liquid)

Odour
Alcohol

Melting point / freezing point


-20 °C

Boiling point or initial boiling point and boiling range


79.5 °C

Flammability
Flammable

Lower and upper explosion limit


No data available

Flash point
20 °C
Method
Abel closed cup

Auto-ignition temperature
No data available

Decomposition temperature
No data available

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According to Regulation (EC) No 1907/2006
SAFETY DATA SHEET

M2029
Version number: 1
Issued: 2023-03-23

pH
6.5 - 7.5

Kinematic viscosity
No data available

Solubility
Soluble in water.

Partition coefficient n-octanol/water


log Kow = 0.05

Vapour pressure
48 hPa

Density and/or relative density


0.795 - 0.885 g/cm³

Relative vapour density


No data available

Particle characteristics
Not applicable

9.2. Other information


Viscosity, dynamic = 2.41 mPas

SECTION 10: Stability and reactivity

10.1. Reactivity
There are no known reactivity hazards associated with this product.

10.2. Chemical stability


Stable under normal temperature conditions and recommended use.

10.3. Possibility of hazardous reactions


None under normal conditions.

10.4. Conditions to avoid


Avoid heat, flames and other sources of ignition.

10.5. Incompatible materials


Incompatible with strong acids and oxidizing agents.

10.6. Hazardous decomposition products


None at ambient temperatures.

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According to Regulation (EC) No 1907/2006
SAFETY DATA SHEET

M2029
Version number: 1
Issued: 2023-03-23

SECTION 11: Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008


Acute toxicity
Based on available data, the classification criteria are not met.

Product / Dose Value / Dose Exposure Duration of Test animals Method / Remarks
Substance descriptor route exposure Guideline
name
CAS / EC no.
Propan-2-ol LD50 5840 mg/kg Oral - Rat OECD Test -
67-63-0 / 200- Guideline 401
661-7
Propan-2-ol LC50 > 25 mg/l Inhalation 6 hours Rat OECD Test Vapour
67-63-0 / 200- Guideline 403
661-7
Propan-2-ol LD50 13 900 mg/kg Dermal - Rabbit OECD Test -
67-63-0 / 200- Guideline 402
661-7

Skin corrosion/irritation
Based on available data, the classification criteria are not met.

Serious eye damage/irritation


Causes serious eye irritation.

Respiratory or skin sensitisation


Based on available data, the classification criteria are not met.

Germ cell mutagenicity


Based on available data, the classification criteria are not met.

Carcinogenicity
Based on available data, the classification criteria are not met.

Reproductive toxicity
Based on available data, the classification criteria are not met.

STOT-single exposure
May cause drowsiness or dizziness.

STOT-repeated exposure
Based on available data, the classification criteria are not met.

Aspiration hazard
Based on available data, the classification criteria are not met.

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According to Regulation (EC) No 1907/2006
SAFETY DATA SHEET

M2029
Version number: 1
Issued: 2023-03-23

Symptoms related to the physical, chemical and toxicological characteristics


Repeated exposure may cause skin dryness or cracking. Vapours may be irritating to eyes, nose,
throat, and lungs. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and
vomiting. Central nervous system depression including narcotic effects such as drowsiness,
narcosis, reduced alertness, loss of reflexes, lack of coordination and vertigo. Unconsciousness,
possibly death.

11.2. Information on other hazards


Endocrine disrupting properties
Not applicable.

Other information
No other information noted.

SECTION 12: Ecological information

12.1. Toxicity
Acute toxicity
Not classified.

Toxicity
Not classified.

Acute fish toxicity

Product / Measurement type Value / Result Duration of Species Method / Guideline


Substance name exposure
CAS / EC no.
Propan-2-ol LC50 9640 mg/l 96 hours Pimephales OECD Test
67-63-0 / 200-661-7 promelas Guideline 203

Acute algae toxicity

Product / Substance Measurement type Value / Result Duration of exposure Species


name
CAS / EC no.
Propan-2-ol EC50 > 100 mg/l 72 hours Scenedesmus
67-63-0 / 200-661-7 subspicatus

Micro-/macro organism toxicity

Product / Substance Measurement type Value / Result Species Remark


name
CAS / EC no.
Propan-2-ol EC50 > 100 mg/l Bacteria No harming action

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According to Regulation (EC) No 1907/2006
SAFETY DATA SHEET

M2029
Version number: 1
Issued: 2023-03-23

Product / Substance Measurement type Value / Result Species Remark


name
CAS / EC no.
67-63-0 / 200-661-7

Chronical toxicity

Product / Substance Measurement type Value / Result Duration of exposure Species


name
CAS / EC no.
Propan-2-ol LOEC 1000 mg/kg 8 days Algae
67-63-0 / 200-661-7

12.2. Persistence and degradability


Propan-2-ol:
53 % (aerobic; domestic sewage; related to O2 consumption; exposure time 5 days)
The substance is readily biodegradable.

12.3. Bioaccumulative potential


Propan-2-ol:
log Kow = 0.05
Not bioaccumulable.

12.4. Mobility in soil


Mobility
Propan-2-ol:
Koc ≈ 1.1

12.5. Results of PBT and vPvB assessment


This product does not contain any PBT or vPvB substances.

12.6. Endocrine disrupting properties


Not applicable.

12.7. Other adverse effects


Other adverse effects
No information available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods


Disposal considerations
Do not flush into surface water or sanitary sewer system. Dispose of as hazardous waste in
compliance with local and national regulations. Dispose of wastes in an approved waste disposal
facility.

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According to Regulation (EC) No 1907/2006
SAFETY DATA SHEET

M2029
Version number: 1
Issued: 2023-03-23

Packaging
Empty contaminated packagings thoroughly. They can be recycled after thorough and proper
cleaning. If recycling is not practicable, dispose of in compliance with local regulations.

Other
Waste codes should be assigned by the user based on the application for which the product was
used.

SECTION 14: Transport information

14.1. UN number
3175

14.2. UN proper shipping name


ADR / RID / ADN proper shipping name
SOLIDS or mixtures of solids (such as preparations and wastes) CONTAINING FLAMMABLE
LIQUID, N.O.S. having a flash-point up to 60 °C (Propan-2-ol)

IMDG proper shipping name


SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. (Propan-2-ol)

14.3. Transport hazard class(es)


Label
ADR/RID/ADN

4.1

ADR / RID Class


4.1

ADR / RID Classification code


F1

ADR / RID hazard identification number


40

IMDG Class
4.1

ADN Class
4. 1

ADN Class Code


F1

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According to Regulation (EC) No 1907/2006
SAFETY DATA SHEET

M2029
Version number: 1
Issued: 2023-03-23

14.4. Packing group


II

14.5. Environmental hazards


No

IMDG Marine Pollutant


No

14.6. Special precautions for user


Tunnel restriction code E
Transport category 2

IMDG EmS: F-A, S-I

14.7. Maritime transport in bulk according to IMO instruments


Not applicable.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the
Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).
Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification,
labelling and packaging of substances and mixtures (CLP).
Directive 2008/98/EC of the European Parliament and of the Council on waste.
Directive 2012/18/EU of the European Parliament and of the Council on the control of major-
accident hazards involving dangerous substances (SEVESO III).

National regulations
No data available
15.2. Chemical safety assessment
No chemical safety assessment has been carried out.

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According to Regulation (EC) No 1907/2006
SAFETY DATA SHEET

M2029
Version number: 1
Issued: 2023-03-23

SECTION 16: Other information

Abbreviations
LC50: Deadly concentration for 50 % of a test population (Lethal Concentration).
LD50: Lethal dose for 50 % of a test population (Lethal Dose).
EC50: The concentration of a substance that affects 50 % of a population over a given period of
time (Effective Concentration).
LOEC: The lowest concentration at which effects are observed (Lowest Observed Effect
Concentration).
NOEC: The concentration at which no effects are observed (No Observed Effect Concentration).
Kow: Partition coefficient octanol/water.Koc: Partitioning coefficient organic carbon/water.
PBT: Persistent, Bioaccumulative, Toxic.
vPvB: very Persistent, very Bioaccumulative.
DNEL: Derived No Effect Level.
PNEC: Predicted No Effect Concentration.

Phrase meaning
Flam. Liq. 2 - Flammable liquids, hazard category 2
Eye Irrit. 2 - Eye irritation, hazard category 2
STOT SE 3 - Specific Target Organ Toxicity — Single exposure, hazard category 3
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.

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