Safety data sheet

according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931 date of compilation: 2016-08-18

Version: 3.0 en Revision: 2022-04-11
Replaces version of: 2020-07-22
Version: (2)

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Identification of the substance Aniline ≥99 %, for synthesis
Article number 9931
Registration number (REACH) It is not required to list the identified uses be-
cause the substance is not subject to registration
according to REACH (< 1 t/a).
Index number in CLP Annex VI 612-008-00-7
EC number 200-539-3
CAS number 62-53-3
Alternative name(s) Aminobenzene
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Laboratory chemical
Laboratory and analytical use
Uses advised against: Do not use for products which come into contact
with foodstuffs. Do not use for private purposes
(household).
1.3 Details of the supplier of the safety data sheet
Carl Roth GmbH + Co KG
Schoemperlenstr. 3-5
D-76185 Karlsruhe
Germany

Telephone:+49 (0) 721 - 56 06 0

Telefax: +49 (0) 721 - 56 06 149
e-mail: sicherheit@carlroth.de
Website: www.carlroth.de
Competent person responsible for the safety data :Department Health, Safety and Environment
sheet:
e-mail (competent person): sicherheit@carlroth.de
1.4 Emergency telephone number
Name Street Postal Telephone Website
code/city

National Poisons Information Beaumont Road Dublin 9 01 809 2166 https://

Centre www.poisons.ie/
Beaumont Hospital

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 (CLP)
Section Hazard class Cat- Hazard class and Hazard
egory category statement

3.1O Acute toxicity (oral) 3 Acute Tox. 3 H301

3.1D Acute toxicity (dermal) 3 Acute Tox. 3 H311

3.1I Acute toxicity (inhal.) 3 Acute Tox. 3 H331

3.3 Serious eye damage/eye irritation 1 Eye Dam. 1 H318

3.4S Skin sensitisation 1 Skin Sens. 1 H317

3.5 Germ cell mutagenicity 2 Muta. 2 H341

3.6 Carcinogenicity 2 Carc. 2 H351

3.9 Specific target organ toxicity - repeated exposure 1 STOT RE 1 H372

4.1A Hazardous to the aquatic environment - acute hazard 1 Aquatic Acute 1 H400

4.1C Hazardous to the aquatic environment - chronic hazard 2 Aquatic Chronic 2 H411

For full text of abbreviations: see SECTION 16

The most important adverse physicochemical, human health and environmental effects
Delayed or immediate effects can be expected after short or long-term exposure. Spillage and fire wa-
ter can cause pollution of watercourses.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008 (CLP)

Signal word Danger

Pictograms

GHS05, GHS06,
GHS08, GHS09

Hazard statements
H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H341 Suspected of causing genetic defects
H351 Suspected of causing cancer
H372 Causes damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects

Precautionary statements
Precautionary statements - prevention
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

Precautionary statements - response
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 IF exposed or concerned: Get medical advice/attention

For professional users only

Labelling of packages where the contents do not exceed 125 ml

Signal word: Danger

Symbol(s)

H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled.

H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H341 Suspected of causing genetic defects.
H351 Suspected of causing cancer.
H372 Causes damage to organs through prolonged or repeated exposure.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.

2.3 Other hazards

This material is combustible, but will not ignite readily.
Results of PBT and vPvB assessment
According to the results of its assessment, this substance is not a PBT or a vPvB.

SECTION 3: Composition/information on ingredients

3.1 Substances
Name of substance Aniline
Molecular formula C₆H₇N
Molar mass 93,13 g/mol

CAS No 62-53-3
EC No 200-539-3
Index No 612-008-00-7

Substance, Specific Conc. Limits, M-factors, ATE

Specific Conc. Limits M-Factors ATE Exposure route

STOT RE 1; H372: C ≥ 1 % - 100 mg/kg oral

STOT RE 2; H373: 0,2 % ≤ C < 1 % 300 mg/kg dermal
3 mg/l/4h inhalation: vapour

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

SECTION 4: First aid measures

4.1 Description of first aid measures

General notes
Take off immediately all contaminated clothing. Self-protection of the first aider.
Following inhalation
Call a physician immediately. If breathing is irregular or stopped, administer artificial respiration.
Following skin contact
Rinse skin with water/shower. After contact with skin, wash immediately with plenty of water. In case
of skin reactions, consult a physician.
Following eye contact
In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes hold-
ing eyelids apart and consult an ophthalmologist.
Following ingestion
Rinse mouth immediately and drink plenty of water. In case of accident or unwellness, seek medical
advice immediately (show directions for use or safety data sheet if possible).
4.2 Most important symptoms and effects, both acute and delayed
Nausea, Vomiting, Allergic reactions, Irritant effects, Risk of serious damage to eyes, Risk of blind-
ness, Headache, Dyspnoea, Spasms, Cardiac arrhythmias, Blood pressure drop, Methaemoglobin-
aemia, Cyanosis (blue coloured blood)
4.3 Indication of any immediate medical attention and special treatment needed
Give sodium sulfate as laxative (1 tablespoon in 1 glass of water).

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media

co-ordinate firefighting measures to the fire surroundings
water spray, alcohol resistant foam, dry extinguishing powder, BC-powder, carbon dioxide (CO₂)
Unsuitable extinguishing media
water jet
5.2 Special hazards arising from the substance or mixture
Combustible. Vapours are heavier than air, spread along floors and form explosive mixtures with air.
Hazardous combustion products
In case of fire may be liberated: Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO₂)

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

5.3 Advice for firefighters
In case of fire and/or explosion do not breathe fumes. Do not allow firefighting water to enter drains
or water courses. Fight fire with normal precautions from a reasonable distance. Wear self-contained
breathing apparatus. Wear full chemical protective clothing.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

Use personal protective equipment as required. Avoid contact with skin, eyes and clothes. Do not
breathe vapour/spray.
6.2 Environmental precautions
Keep away from drains, surface and ground water. Retain contaminated washing water and dispose
of it.
6.3 Methods and material for containment and cleaning up
Advice on how to contain a spill
Covering of drains.
Advice on how to clean up a spill
Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents).
Other information relating to spills and releases
Place in appropriate containers for disposal. Ventilate affected area.
6.4 Reference to other sections
Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incom-
patible materials: see section 10. Disposal considerations: see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Provision of sufficient ventilation. Use extractor hood (laboratory). Handle and open container with
care. Avoid exposure. Clear contaminated areas thoroughly.
Measures to prevent fire as well as aerosol and dust generation

Keep away from sources of ignition - No smoking.

Measures to protect the environment
Avoid release to the environment.
Advice on general occupational hygiene
When using do not eat or drink. Thorough skin-cleansing after handling the product.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed.
Incompatible substances or mixtures

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

Observe hints for combined storage.

Protect against external exposure, such as
direct light irradiation, UV-radiation/sunlight
Consideration of other advice:
Store locked up.
Ventilation requirements
Keep any substance that emits harmful vapours or gases in a place that allows these to be perman-
ently extracted.
Specific designs for storage rooms or vessels
Recommended storage temperature: 15 – 25 °C
7.3 Specific end use(s)
No information available.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
National limit values
Occupational exposure limit values (Workplace Exposure Limits)
Cou Name of agent CAS No Identi- TW TWA STE STEL Ceil Ceil- Nota- Source
ntr fier A [mg/ L [mg/ ing- ing-C tion
y [pp m³] [pp m³] C [mg/
m] m] [pp m³]
m]

EU aniline 62-53-3 IOELV 2 7,74 5 19,35 skin 2019/

1831/EU

IE aniline 62-53-3 OELV 2 7,74 5 19,35 H S.I. No.

619 of
2001

Notation
Ceiling-C Ceiling value is a limit value above which exposure should not occur
H Absorbed through the skin
skin A skin notation assigned to the occupational exposure limit value indicates the possibility of significant uptake
through the skin
STEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-
minute period (unless otherwise specified)
TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8
hours time-weighted average (unless otherwise specified)

Human health values

Relevant DNELs and other threshold levels

Endpoint Threshold Protection goal, Used in Exposure time

level route of exposure

DNEL 7,7 mg/m³ human, inhalatory worker (industry) chronic - systemic effects

DNEL 15,4 mg/m³ human, inhalatory worker (industry) acute - systemic effects

DNEL 2 mg/kg bw/day human, dermal worker (industry) chronic - systemic effects

DNEL 4 mg/kg bw/day human, dermal worker (industry) acute - systemic effects

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

Environmental values

Relevant PNECs and other threshold levels

End- Threshold Organism Environmental com- Exposure time

point level partment

PNEC 0,001 mg/l aquatic organisms freshwater short-term (single instance)

PNEC 0 mg/l aquatic organisms marine water short-term (single instance)

PNEC 2 mg/l aquatic organisms sewage treatment plant short-term (single instance)
(STP)

PNEC 0,153 mg/kg aquatic organisms freshwater sediment short-term (single instance)

PNEC 0,015 mg/kg aquatic organisms marine sediment short-term (single instance)

PNEC 0,033 mg/kg terrestrial organisms soil short-term (single instance)

8.2 Exposure controls

Individual protection measures (personal protective equipment)
Eye/face protection

Use safety goggle with side protection.

Skin protection

• hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374.
Check leak-tightness/impermeability prior to use. For special purposes, it is recommended to check
the resistance to chemicals of the protective gloves mentioned above together with the supplier of
these gloves. The times are approximate values from measurements at 22 ° C and permanent con-
tact. Increased temperatures due to heated substances, body heat etc. and a reduction of the effect-
ive layer thickness by stretching can lead to a considerable reduction of the breakthrough time. If in
doubt, contact manufacturer. At an approx. 1.5 times larger / smaller layer thickness, the respective
breakthrough time is doubled / halved. The data apply only to the pure substance. When transferred
to substance mixtures, they may only be considered as a guide.
• type of material
Butyl caoutchouc (butyl rubber)
• material thickness
0,5 mm
• breakthrough times of the glove material
>480 minutes (permeation: level 6)
• other protection measures
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is
recommended.

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

Respiratory protection

Respiratory protection necessary at: Aerosol or mist formation. Type: A-P2 (combined filters against
particles and organic gases and vapours, colour code: Brown/White).
Environmental exposure controls
Keep away from drains, surface and ground water.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state liquid
Colour colourless - light brown
Odour disagreeable
Melting point/freezing point -6,2 °C (ECHA)
Boiling point or initial boiling point and boiling 184,4 °C at 1.013 hPa (ECHA)
range
Flammability this material is combustible, but will not ignite
readily
Lower and upper explosion limit 48 g/m³ (LEL) - 425 g/m³ (UEL) /
1,2 vol% (LEL) - 11 vol% (UEL)
Flash point 76 °C at 1.013 hPa (ECHA)
Auto-ignition temperature 630 °C at 1.013 hPa (ECHA)
Decomposition temperature not relevant
pH (value) 8,8 (in aqueous solution: 36 g/l, 20 °C)

Kinematic viscosity 4,265 mm²/s at 20 °C

Dynamic viscosity 4,35 mPa s at 20 °C

Solubility(ies)
Water solubility 35 g/l at 20 °C (ECHA)

Partition coefficient
Partition coefficient n-octanol/water (log value): 0,91 (pH value: 7,5, 25 °C) (ECHA)
Soil organic carbon/water (log KOC) 2,114 (ECHA)

Vapour pressure 0,4 hPa at 20 °C

Density and/or relative density

Density 1,02 g/cm³ at 20 °C

Relative vapour density 3,22 (air = 1)

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

Particle characteristics not relevant (liquid)

Other safety parameters

Oxidising properties none
9.2 Other information
Information with regard to physical hazard hazard classes acc. to GHS
classes: (physical hazards): not relevant
Other safety characteristics:
Temperature class (EU, acc. to ATEX) T1
Maximum permissible surface temperature on
the equipment: 450°C

SECTION 10: Stability and reactivity

10.1 Reactivity
This material is not reactive under normal ambient conditions.
If heated
Vapours may form explosive mixtures with air.
10.2 Chemical stability
The material is stable under normal ambient and anticipated storage and handling conditions of tem-
perature and pressure.
10.3 Possibility of hazardous reactions

Exothermic reaction with: Acids, Acetic anhydride,

Violent reaction with: Oxygen, Nitric acid, Perchlorates, Oxidisers, Nitrate,
=> Explosive properties
10.4 Conditions to avoid
UV-radiation/sunlight. Direct light irradiation. Keep away from heat.
10.5 Incompatible materials
There is no additional information.
10.6 Hazardous decomposition products
Hazardous combustion products: see section 5.

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Classification according to GHS (1272/2008/EC, CLP)
Acute toxicity
Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled.

Acute toxicity

Exposure route Endpoint Value Species Method Source

oral LD50 442 mg/kg rat ECHA

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

Skin corrosion/irritation
Shall not be classified as corrosive/irritant to skin.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitisation
May cause an allergic skin reaction.
Germ cell mutagenicity
Suspected of causing genetic defects.
Carcinogenicity
Suspected of causing cancer.
Reproductive toxicity
Shall not be classified as a reproductive toxicant.
Specific target organ toxicity - single exposure
Shall not be classified as a specific target organ toxicant (single exposure).
Specific target organ toxicity - repeated exposure
Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.

Symptoms related to the physical, chemical and toxicological characteristics

• If swallowed
vomiting, nausea
• If in eyes
Causes serious eye damage, risk of blindness
• If inhaled
cough, Dyspnoea
• If on skin
May produce an allergic reaction, pruritis, localised redness
• Other information
Other adverse effects: Headache, Spasms, Cardiac arrhythmias, Blood pressure drop, Methaemoglo-
binaemia, Cyanosis (blue coloured blood)
11.2 Endocrine disrupting properties
Not listed.
11.3 Information on other hazards
There is no additional information.

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

SECTION 12: Ecological information

12.1 Toxicity
Very toxic to aquatic life with long lasting effects.
.

Aquatic toxicity (acute)

Endpoint Value Species Source Exposure

time

LC50 10,6 mg/l fish ECHA 96 h

EC50 0,16 mg/l aquatic invertebrates ECHA 48 h

ErC50 175 mg/l algae ECHA 72 h

Aquatic toxicity (chronic)

Endpoint Value Species Source Exposure

time

EC50 0,044 mg/l aquatic invertebrates ECHA 21 d

Biodegradation
The substance is readily biodegradable.
12.2 Process of degradability
Theoretical Oxygen Demand with nitrification: 3,006 mg/mg
Theoretical Oxygen Demand: 2,405 mg/mg
Theoretical Carbon Dioxide: 2,835 mg/mg

Process of degradability

Process Degradation rate Time

oxygen depletion 70 % 15 d

DOC removal 100 % 5d

12.3 Bioaccumulative potential

Does not significantly accumulate in organisms.

n-octanol/water (log KOW) 0,91 (pH value: 7,5, 25 °C) (ECHA)

BCF 2,6 (ECHA)

12.4 Mobility in soil

Henry's law constant 0,205 Pa m³/mol at 25 °C (ECHA)

The Organic Carbon normalised adsorption 2,114 (ECHA)

coefficient

12.5 Results of PBT and vPvB assessment

Data are not available.
12.6 Endocrine disrupting properties

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

Not listed.
12.7 Other adverse effects
Data are not available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

This material and its container must be disposed of as hazardous waste. Dispose of contents/contain-
er in accordance with local/regional/national/international regulations.
Sewage disposal-relevant information
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data
sheets.
Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used.
13.2 Relevant provisions relating to waste
The allocation of waste identity numbers/waste descriptions must be carried out according to the
EEC, specific to the industry and process. Waste catalogue ordinance (Germany).
13.3 Remarks
Waste shall be separated into the categories that can be handled separately by the local or national
waste management facilities. Please consider the relevant national or regional provisions.

SECTION 14: Transport information

14.1 UN number or ID number
ADRRID UN 1547
IMDG-Code UN 1547
ICAO-TI UN 1547
14.2 UN proper shipping name
ADRRID ANILINE
IMDG-Code ANILINE
ICAO-TI Aniline
14.3 Transport hazard class(es)
ADRRID 6.1
IMDG-Code 6.1
ICAO-TI 6.1
14.4 Packing group
ADRRID II
IMDG-Code II
ICAO-TI II

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

14.5 Environmental hazards hazardous to the aquatic environment
14.6 Special precautions for user
Provisions for dangerous goods (ADR) should be complied within the premises.
14.7 Maritime transport in bulk according to IMO instruments
The cargo is not intended to be carried in bulk.

14.8 Information for each of the UN Model Regulations

Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN) - Additional
information
Proper shipping name ANILINE
Particulars in the transport document UN1547, ANILINE, 6.1, II, (D/E), environmentally
hazardous
Classification code T1
Danger label(s) 6.1, "Fish and tree"

Environmental hazards yes (hazardous to the aquatic environment)

Special provisions (SP) 279, 802(ADN)
Excepted quantities (EQ) E4
Limited quantities (LQ) 100 ml
Transport category (TC) 2
Tunnel restriction code (TRC) D/E
Hazard identification No 60
Regulations concerning the International Carriage of Dangerous Goods by Rail (RID)Additional
information
Classification code 6.1
Danger label(s) 6.1
Fish and tree

Environmental hazards Yes

Hazardous to water
Special provisions (SP) 279, 802(ADN)
Excepted quantities (EQ) E4
Limited quantities (LQ) 100 ml
Transport category (TC) 2
Hazard identification No 60

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

International Maritime Dangerous Goods Code (IMDG) - Additional information
Proper shipping name ANILINE
Particulars in the shipper's declaration UN1547, ANILINE, 6.1, II, MARINE POLLUTANT
Marine pollutant yes (P) (hazardous to the aquatic environment)
Danger label(s) 6.1, "Fish and tree"

Special provisions (SP) 279

Excepted quantities (EQ) E4
Limited quantities (LQ) 100 mL
EmS F-A, S-A
Stowage category A
International Civil Aviation Organization (ICAO-IATA/DGR) - Additional information
Proper shipping name Aniline
Particulars in the shipper's declaration UN1547, Aniline, 6.1, II
Environmental hazards yes (hazardous to the aquatic environment)
Danger label(s) 6.1

Special provisions (SP) A113

Excepted quantities (EQ) E4
Limited quantities (LQ) 1L

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Relevant provisions of the European Union (EU)
Restrictions according to REACH, Annex XVII

Dangerous substances with restrictions (REACH, Annex XVII)

Name of substance Name acc. to inventory CAS No Restriction No

Aniline this product meets the criteria for R3 3

classification in accordance with Reg-
ulation No 1272/2008/EC

Aniline substances in tattoo inks and perman- R75 75

ent make-up

Legend
R3 1. Shall not be used in:
- ornamental articles intended to produce light or colour effects by means of different phases, for example in orna-
mental lamps and ashtrays,
- tricks and jokes,
- games for one or more participants, or any article intended to be used as such, even with ornamental aspects,
2. Articles not complying with paragraph 1 shall not be placed on the market.
3. Shall not be placed on the market if they contain a colouring agent, unless required for fiscal reasons, or perfume,
or both, if they:

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

Legend
— can be used as fuel in decorative oil lamps for supply to the general public, and
— present an aspiration hazard and are labelled with H304.
4. Decorative oil lamps for supply to the general public shall not be placed on the market unless they conform to the
European Standard on Decorative oil lamps (EN 14059) adopted by the European Committee for Standardisation
(CEN).
5. Without prejudice to the implementation of other Union provisions relating to the classification, labelling and pack-
aging of substances and mixtures, suppliers shall ensure, before the placing on the market, that the following require-
ments are met:
(a) lamp oils, labelled with H304, intended for supply to the general public are visibly, legibly and indelibly marked as
follows: “Keep lamps filled with this liquid out of the reach of children”; and, by 1 December 2010, “Just a sip of lamp oil
– or even sucking the wick of lamps – may lead to life-threatening lung damage”;
(b) grill lighter fluids, labelled with H304, intended for supply to the general public are legibly and indelibly marked by
1 December 2010 as follows: ‘Just a sip of grill lighter fluid may lead to life threatening lung damage’;
(c) lamps oils and grill lighters, labelled with H304, intended for supply to the general public are packaged in black
opaque containers not exceeding 1 litre by 1 December 2010.’;

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

Legend
R75 1. Shall not be placed on the market in mixtures for use for tattooing purposes, and mixtures containing any such sub-
stances shall not be used for tattooing purposes, after 4 January 2022 if the substance or substances in question is or
are present in the following circumstances:
(a) in the case of a substance classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 as carcinogen category
1A, 1B or 2, or germ cell mutagen category 1A, 1B or 2, the substance is present in the mixture in a concentration
equal to or greater than 0,00005 % by weight;
(b) in the case of a substance classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 as reproductive toxicant
category 1A, 1B or 2, the substance is present in the mixture in a concentration equal to or greater than 0,001 % by
weight;
(c) in the case of a substance classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 as skin sensitiser cat-
egory 1, 1A or 1B, the substance is present in the mixture in a concentration equal to or greater than 0,001 % by
weight;
(d) in the case of a substance classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 as skin corrosive cat-
egory 1, 1A, 1B or 1C or skin irritant category 2, or as serious eye damage category 1 or eye irritant category 2, the
substance is present in the mixture in a concentration equal to or greater than:
(i) 0,1 % by weight, if the substance is used solely as a pH regulator;
(ii) 0,01 % by weight, in all other cases;
(e) in the case of a substance listed in Annex II to Regulation (EC) No 1223/2009 (*1), the substance is present in the
mixture in a concentration equal to or greater than 0,00005 % by weight;
(f) in the case of a substance for which a condition of one or more of the following kinds is specified in column g
(Product type, Body parts) of the table in Annex IV to Regulation (EC) No 1223/2009, the substance is present in the
mixture in a concentration equal to or greater than 0,00005 % by weight:
(i) “Rinse-off products”;
(ii) “Not to be used in products applied on mucous membranes”;
(iii) “Not to be used in eye products”;
(g) in the case of a substance for which a condition is specified in column h (Maximum concentration in ready for use
preparation) or column i (Other) of the table in Annex IV to Regulation (EC) No 1223/2009, the substance is present in
the mixture in a concentration, or in some other way, that does not accord with the condition specified in that column;
(h) in the case of a substance listed in Appendix 13 to this Annex, the substance is present in the mixture in a concen-
tration equal to or greater than the concentration limit specified for that substance in that Appendix.
2. For the purposes of this entry use of a mixture “for tattooing purposes” means injection or introduction of the mix-
ture into a person’s skin, mucous membrane or eyeball, by any process or procedure (including procedures com-
monly referred to as permanent make-up, cosmetic tattooing, micro-blading and micro-pigmentation), with the aim of
making a mark or design on his or her body.
3. If a substance not listed in Appendix 13 falls within more than one of points (a) to (g) of paragraph 1, the strictest
concentration limit laid down in the points in question shall apply to that substance. If a substance listed in Appendix
13 also falls within one or more of points (a) to (g) of paragraph 1, the concentration limit laid down in point (h) of
paragraph 1 shall apply to that substance.
4. By way of derogation, paragraph 1 shall not apply to the following substances until 4 January 2023:
(a) Pigment Blue 15:3 (CI 74160, EC No 205-685-1, CAS No 147-14-8);
(b) Pigment Green 7 (CI 74260, EC No 215-524-7, CAS No 1328-53-6).
5. If Part 3 of Annex VI to Regulation (EC) No 1272/2008 is amended after 4 January 2021 to classify or re-classify a sub-
stance such that the substance then becomes caught by point (a), (b), (c) or (d) of paragraph 1 of this entry, or such
that it then falls within a different one of those points from the one within which it fell previously, and the date of ap-
plication of that new or revised classification is after the date referred to in paragraph 1 or, as the case may be, para-
graph 4 of this entry, that amendment shall, for the purposes of applying this entry to that substance, be treated as
taking effect on the date of application of that new or revised classification.
6. If Annex II or Annex IV to Regulation (EC) No 1223/2009 is amended after 4 January 2021 to list or change the listing
of a substance such that the substance then becomes caught by point (e), (f) or (g) of paragraph 1 of this entry, or
such that it then falls within a different one of those points from the one within which it fell previously, and the
amendment takes effect after the date referred to in paragraph 1 or, as the case may be, paragraph 4 of this entry,
that amendment shall, for the purposes of applying this entry to that substance, be treated as taking effect from the
date falling 18 months after entry into force of the act by which that amendment was made.
7. Suppliers placing a mixture on the market for use for tattooing purposes shall ensure that, after 4 January 2022, the
mixture is marked with the following information:
(a) the statement “Mixture for use in tattoos or permanent make-up”;
(b) a reference number to uniquely identify the batch;
(c) the list of ingredients in accordance with the nomenclature established in the glossary of common ingredient
names pursuant to Article 33 of Regulation (EC) No 1223/2009, or in the absence of a common ingredient name, the
IUPAC name. In the absence of a common ingredient name or IUPAC name, the CAS and EC number. Ingredients shall
be listed in descending order by weight or volume of the ingredients at the time of formulation. “Ingredient” means
any substance added during the process of formulation and present in the mixture for use for tattooing purposes. Im-
purities shall not be regarded as ingredients. If the name of a substance, used as ingredient within the meaning of
this entry, is already required to be stated on the label in accordance with Regulation (EC) No 1272/2008, that ingredi-
ent does not need to be marked in accordance with this Regulation;
(d) the additional statement “pH regulator” for substances falling under point (d)(i) of paragraph 1;
(e) the statement "Contains nickel. Can cause allergic reactions." if the mixture contains nickel below the concentra-
tion limit specified in Appendix 13;
(f) the statement "Contains chromium (VI). Can cause allergic reactions." if the mixture contains chromium (VI) below
the concentration limit specified in Appendix 13;
(g) safety instructions for use insofar as they are not already required to be stated on the label by Regulation (EC) No
1272/2008.
The information shall be clearly visible, easily legible and marked in a way that is indelible.
The information shall be written in the official language(s) of the Member State(s) where the mixture is placed on the
market, unless the Member State(s) concerned provide(s) otherwise.
Where necessary because of the size of the package, the information listed in the first subparagraph, except for point
(a), shall be included instead in the instructions for use.
Before using a mixture for tattooing purposes, the person using the mixture shall provide the person undergoing the
procedure with the information marked on the package or included in the instructions for use pursuant to this para-
graph.
8. Mixtures that do not contain the statement “Mixture for use in tattoos or permanent make-up” shall not be used for
tattooing purposes.

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

Legend
9. This entry does not apply to substances that are gases at temperature of 20 °C and pressure of 101,3 kPa, or gener-
ate a vapour pressure of more than 300 kPa at temperature of 50 °C, with the exception of formaldehyde (CAS No 50-
00-0, EC No 200-001-8).
10. This entry does not apply to the placing on the market of a mixture for use for tattooing purposes, or to the use of
a mixture for tattooing purposes, when placed on the market exclusively as a medical device or an accessory to a
medical device, within the meaning of Regulation (EU) 2017/745, or when used exclusively as a medical device or an
accessory to a medical device, within the same meaning. Where the placing on the market or use may not be exclus-
ively as a medical device or an accessory to a medical device, the requirements of Regulation (EU) 2017/745 and of this
Regulation shall apply cumulatively.

List of substances subject to authorisation (REACH, Annex XIV)/SVHC - candidate list

Not listed.
Seveso Directive

2012/18/EU (Seveso III)

No Dangerous substance/hazard categories Qualifying quantity (tonnes) for the ap- Notes
plication of lower and upper-tier re-
quirements

H2 acute toxic (cat. 2 + cat. 3, inhal.) 50 200 41)

Notation
41) - Category 2, all exposure routes
- category 3, inhalation exposure route

Deco-Paint Directive

VOC content 100 %

1.020 g/l

Industrial Emissions Directive (IED)

VOC content 100 %

VOC content 1.020 g/l

Directive on the restriction of the use of certain hazardous substances in electrical and
electronic equipment (RoHS)
not listed
Regulation concerning the establishment of a European Pollutant Release and Transfer
Register (PRTR)
not listed
Water Framework Directive (WFD)

List of pollutants (WFD)

Name of substance Name acc. to inventory CAS No Listed in Remarks

Aniline Substances and preparations, or a)

the breakdown products of such,
which have been proved to pos-
sess carcinogenic or mutagenic
properties or properties which
may affect steroidogenic, thyroid,
reproduction or other endocrine-
related functions in or via the
aquatic environment

Legend
A) Indicative list of the main pollutants

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

Regulation on the marketing and use of explosives precursors
not listed
Regulation on drug precursors
not listed
Regulation on substances that deplete the ozone layer (ODS)
not listed
Regulation concerning the export and import of hazardous chemicals (PIC)
not listed
Regulation on persistent organic pollutants (POP)
not listed

Other information
Directive 94/33/EC on the protection of young people at work. Observe employment restrictions un-
der the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
National inventories
Country Inventory Status

AU AICS substance is listed

CA DSL substance is listed

CN IECSC substance is listed

EU ECSI substance is listed

EU REACH Reg. substance is listed

JP CSCL-ENCS substance is listed

KR KECI substance is listed

MX INSQ substance is listed

NZ NZIoC substance is listed

PH PICCS substance is listed

TR CICR substance is listed

TW TCSI substance is listed

US TSCA substance is listed

Legend
AICS Australian Inventory of Chemical Substances
CICR Chemical Inventory and Control Regulation
CSCL-ENCS List of Existing and New Chemical Substances (CSCL-ENCS)
DSL Domestic Substances List (DSL)
ECSI EC Substance Inventory (EINECS, ELINCS, NLP)
IECSC Inventory of Existing Chemical Substances Produced or Imported in China
INSQ National Inventory of Chemical Substances
KECI Korea Existing Chemicals Inventory
NZIoC New Zealand Inventory of Chemicals
PICCS Philippine Inventory of Chemicals and Chemical Substances (PICCS)
REACH Reg. REACH registered substances
TCSI Taiwan Chemical Substance Inventory
TSCA Toxic Substance Control Act

15.2 Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this substance.

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

SECTION 16: Other information

Indication of changes (revised safety data sheet)
Alignment to regulation: Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Restructuring: section 9, section 14

Section Former entry (text/value) Actual entry (text/value) Safety-
relev-
ant

2.1 Classification according to Regulation (EC) No yes

1272/2008 (CLP):
change in the listing (table)

2.1 The most important adverse physicochemical, yes

human health and environmental effects:
Delayed or immediate effects can be expected
after short or long-term exposure. Spillage and
fire water can cause pollution of watercourses.

2.3 Other hazards: Other hazards: yes

There is no additional information. This material is combustible, but will not ignite
readily.

2.3 Results of PBT and vPvB assessment: yes

According to the results of its assessment, this
substance is not a PBT or a vPvB.

Abbreviations and acronyms

Abbr. Descriptions of used abbreviations

2019/1831/EU Commission Directive establishing a fifth list of indicative occupational exposure limit values pursuant to
Council Directive 98/24/EC and amending Commission Directive 2000/39/EC

ADN Accord européen relatif au transport international des marchandises dangereuses par voies de naviga-
tion intérieures (European Agreement concerning the International Carriage of Dangerous Goods by In-
land Waterways)

ADR Accord relatif au transport international des marchandises dangereuses par route (Agreement concern-
ing the International Carriage of Dangerous Goods by Road)

ATE Acute Toxicity Estimate

BCF Bioconcentration factor

CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)

Ceiling-C Ceiling value

CLP Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

DGR Dangerous Goods Regulations (see IATA/DGR)

DNEL Derived No-Effect Level

EC50 Effective Concentration 50 %. The EC50 corresponds to the concentration of a tested substance causing
50 % changes in response (e.g. on growth) during a specified time interval

EC No The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an identi-
fier of substances commercially available within the EU (European Union)

EINECS European Inventory of Existing Commercial Chemical Substances

ELINCS European List of Notified Chemical Substances

EmS Emergency Schedule

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

Abbr. Descriptions of used abbreviations

ErC50 ≡ EC50: in this method, that concentration of test substance which results in a 50 % reduction in either
growth (EbC50) or growth rate (ErC50) relative to the control

GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Na-
tions

IATA International Air Transport Association

IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)

ICAO International Civil Aviation Organization

ICAO-TI Technical instructions for the safe transport of dangerous goods by air

IMDG International Maritime Dangerous Goods Code

IMDG-Code International Maritime Dangerous Goods Code

index No The Index number is the identification code given to the substance in Part 3 of Annex VI to Regulation
(EC) No 1272/2008

IOELV Indicative occupational exposure limit value

LC50 Lethal Concentration 50%: the LC50 corresponds to the concentration of a tested substance causing 50 %
lethality during a specified time interval

LD50 Lethal Dose 50 %: the LD50 corresponds to the dose of a tested substance causing 50 % lethality during a
specified time interval

LEL Lower explosion limit (LEL)

NLP No-Longer Polymer

PBT Persistent, Bioaccumulative and Toxic

PNEC Predicted No-Effect Concentration

ppm Parts per million

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals

RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regula-
tions concerning the International carriage of Dangerous goods by Rail)

S.I. No. 619 of Safety, Health and Welfare at Work (Chemical Agents) Regulations 2001
2001

STEL Short-term exposure limit

SVHC Substance of Very High Concern

TWA Time-weighted average

UEL Upper explosion limit (UEL)

VOC Volatile Organic Compounds

vPvB Very Persistent and very Bioaccumulative

Key literature references and sources for data

Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures.
Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU.
Agreement concerning the International Carriage of Dangerous Goods by Road (ADR). Regulations
concerning the International Carriage of Dangerous Goods by Rail (RID). International Maritime Dan-
gerous Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA).

Ireland (en) Page 20 / 21

Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aniline ≥99 %, for synthesis

article number: 9931

List of relevant phrases (code and full text as stated in section 2 and 3)
Code Text

H301 Toxic if swallowed.

H311 Toxic in contact with skin.

H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.

H331 Toxic if inhaled.

H341 Suspected of causing genetic defects.

H351 Suspected of causing cancer.

H372 Causes damage to organs through prolonged or repeated exposure.

H400 Very toxic to aquatic life.

H411 Toxic to aquatic life with long lasting effects.

Disclaimer
This information is based upon the present state of our knowledge. This SDS has been compiled and
is solely intended for this product.

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