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    Alkyl & Aryl Halides - DPP 11

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    Alkyl & Aryl Halides - DPP 11

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    mo-hit
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    Original Title

    Alkyl & Aryl Halides _ DPP 11

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    18 views5 pages

    Alkyl & Aryl Halides - DPP 11

    Uploaded by

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    © All Rights Reserved
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    1

    LAKSHAY (JEE)
    Alkyl and Aryl halides DPP-11

    RMgBr
    1. Product; The product
    S
    O O
    (A) HSO2 – CH2 – CH2 – CH2 – CH2 – R (B) H – SO2(CH2)3 – R

    (C) (D) H – SO2(CH)3 – R


    MgBr
    SO2

    2.
    (i) THF
    + MgBrCH2CH2CH2CH2MgBr (ii) H3O+
    O O
    product; Product of the reaction is:
    O
    ||
    (A) HO – (CH2)3 – C – CH2 – CH2 – CH3 (B)

    HO (CH2)3—OH

    (C) (D)
    HO CH – CH2 – CH3
    |
    OH HO CH2 – CH2 – CH3

    3. Which of the following compound is not a suitable solvent for Grignard reaction?
    O

    O
    (A) (B) (1, 4-dioxane)

    O
    (THF)

    (C) CH3 – O – CH2 – CH2 – O – CH3 (D)


    2

    MeO OMe
    n-Bu2CuLi
    4. Product of the reaction will be:
    (n-Bu=n-butyl group)

    Br
    MeO OMe MeO OMe
    (A) (B)

    n-Bu n-Bu
    OMe Bu OH OH
    (C) (D)

    Br Br

    5. In the given reaction:

    CH3MgBr
    Product
    H/H2O
    O
    Find the product of reaction.

    (A) OH (B)

    OH

    (C) OH (D)

    r1
    6. (i) + PhMgBr
    O
    PhCH2CH2OH
    r2
    (ii) + PhMgBr
    O
    PhCH2CH2CH2 OH
    (A) r2 > r1 (B) r1 > r2
    (C) r1 = r2 (D) r1 = 2r2

    7. Reaction – 1:
    SH O SH OH
    || | CH3
    HO C-Cl C
    1. xCH3MgBr CH3
    2. H3O CH3
    OH C
    C-Cl
    || | CH3
    O OH
    3

    Reaction – 2:
    O OH
    || ||
    C–O–Et CH3–C– CH3

    1. yCH3MgBr
    2. H3O

    CH2–Cl
    CH2Cl
    What is the ratio of (x/y) in above problem?
    (A) 1.5 (B) 2
    (C) 2.5 (D) 3
    8. What product would you expect to obtain from Grignard reaction when an excess of phenylmagnesium
    bromide reacts with dimethyl carbonate CH3OCOOCH3?
    OH
    | OH
    (A) CH3 — C — Ph (B) |
    | CH3 — CH — Ph
    Ph
    OH
    | O
    (C) Ph — C — Ph (D) ||
    | CH3 — C — Ph
    Ph

    9. In which of the following reactions product formed is same?


    O

    MeMgX
    (i) P

    MgX
    (ii) P

    MgBr P
    (iii) +

    (A) (i) and (ii) (B) (ii) and (iii)


    (C) (i) and (iii) (D) (i), (ii) and (iii)

    10. Which of the following reaction sequences would be the best for synthesis of 2-pentanone?
    OH
    (A) ||
    H3O
    CH 3 — CH 2 — CH 2 — C — H ⎯⎯⎯⎯ CH3 MgI
    Et 2 O
    → ⎯⎯⎯ →
    4

    CH 2 — CH 2
    (B) | |
    H 3 O
    CH3 — CH — O ⎯⎯⎯⎯
    CH3 MgI
    Et 2 O
    → ⎯⎯⎯ →

    (C) CH3 — CH2 — CH2 — C  H 2 ⎯⎯⎯
    CH3 MgI
    Et 2 O
    ⎯
    → ⎯⎯⎯
    H3 O
    →
    OH
    ||
    (D) H3 O
    CH3 — CH 2 — C — H ⎯⎯⎯⎯
    CH3 MgI
    Et 2 O
    → ⎯⎯⎯ →
    (propanal)
    5

    Answer Key
    1. (C)
    2. (B)
    3. (D)
    4. (A)
    5. (C)
    6. (B)
    7. (B)
    8. (C)
    9. (D)
    10. (C)

    *Note* - If you have any query/issue


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