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    L29B Chy 222 - 22 04 2024

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    L29B Chy 222 - 22 04 2024

    Uploaded by

    tedanag282
    8 views8 pages

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    L29B-CHY-222_22-04-2024

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    8 views8 pages

    L29B Chy 222 - 22 04 2024

    Uploaded by

    tedanag282

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    © All Rights Reserved
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    Chemistry of Iminium Ion

    Dr. Ajoy Kapat


    22-04-2024
    Synthesis of Imine from Carbonyl Compounds
    Alternative Way to Synthesize Amines

    O NHR

    R2 X R2 H
    H
    X = H, Cl, CN

    Synthesis of amines other than reductive amination:

    O ??
    NH2

    O O
    ?? ??
    R2 R2
    R1 Cl R1 N R1 N
    H H

    ??
    N NH2
    R1
    R1
    Alternative Way to Synthesize Amines

    O NHR

    R2 X R2 H
    H
    X = H, Cl, CN

    Synthesis of amines other than reductive amination:

    O NH3,
    NH2

    70 ºC
    H2, Ni
    90 atm

    NH3,

    H 70 ºC
    H2, Ni NH2
    N 90 atm
    H

    hydrogenation
    Alternative Way to Synthesize Amines

    O NHR

    R2 X R2 H
    H
    X = H, Cl, CN

    Synthesis of amines other than reductive amination:

    O O
    ?? ??
    R2 R2
    R1 Cl R1 N R1 N
    H H

    R2NH2 (2 equiv.)

    H3Al
    O
    O LiAlH4
    LiAlH4 R2
    R2 R1 N
    R2 R1 N
    R1 N H
    H
    H
    Alternative Way to Synthesize Amines

    O NHR

    R2 X R2 H
    H
    X = H, Cl, CN

    Synthesis of amines other than reductive amination:

    O ??
    NH2

    O O
    ?? ??
    R2 R2
    R1 Cl R1 N R1 N
    H H

    LiAlH4
    N NH2
    R1
    R1

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