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    Atomic Structure-51-52

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    Atomic Structure-51-52

    Uploaded by

    amanb03xx
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    ATOMIC STRUCTURE-51-52

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    16 views2 pages

    Atomic Structure-51-52

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    SOLVED PROBLEMS (SUBJECTIVE)

    Ex 1. Find the wavelengths of the first line of He + ion spectral series whose interval with extreme lines is
    1 1
     4 –1
    1 2 = 2.7451 × 10 cm
    Sol. Extreme lines means first and last

    1 1 1 1  1 1 
     =RZ 2  2  2  – RZ 2  2  2 
    1 2 n
     1   n
     1 (n 1  1) 

    1 1 RZ 2
    or  =
    1 2 (n 1  1)2

    109677.76  2 2
    2.7451 × 10 4 =
    (n 1  1) 2
    (n 1 + 1) = 4
    n1 = 3
    Wavelength of first line,

    1 1 1 
    = 109677.76 × 2 2 ×  2  2 
      3 4 

     = 4689 × 10 –8 cm = 4689 Å

    Ex 2. Find the wavelength emitted during the transition of electron in between two levels of Li 2+ ion whose sum
    is 5 and difference is 3.
    Sol. Let the transition occurs between the level n 1 and n 2 and n 2 > n 1
    Given that n 1 + n 2 = 5
    n2 – n1 = 3
     n 1 = 1 and n 2 = 4

    1  1 1  15 
    Therefore, = Rh × Z2  2  2
     = 109678 × (3) 2  
      1   4   16 

      = 1.08 × 10 –6 cm
    Ex 3. The Lyman series of the hydrogen spectrum can be represented by the equation.
     1 1 
    v = 3.2881 × 10 15 s –1  2  
     1   n 2 
    (where n = 2, 3,.....)
    Calculate the maximum and minimum wavelength of lines in this series.
     1 1 
    1  3.2881  10 15 –1   2
    Sol.  = = m 2
     c 3  10 8  1  n 

    1
    Wavelength is maximum  min  when n is minimum so that
    n2
    is maximum

     
    1 3.2881  10 15  1  1 
     min  = 2 2
     max 3  10 8  1  2  
    3  10 8 4
      max = 
    3.2881  10 15 3

    = 1.2165 × 10 –7 m = 121.67 nm

    Wavelength is minimum  max  when n is 

    i.e. series converge

    1 3.2881  10 15
      max = 
     min 3  10 8
      min = 0.9124 × 10 –7 m 91.24 nm
    Ex 4. When certain metal was irradiated with light frequency 0.4 × 10 13 Hz the photo electrons emitted had
    twice the kinetic energy as did photo electrons emitted when the same metal was irradiated with light frequency
    1.0 × 10 13 Hz. Calculate threshold frequency ( 0 ) for the metal.
    Sol. hv = h 0 + KE
    KE 1 = h( 1 –  0 )
    KE 1
    KE 2 = h( 2 –  0 ) =
    2

    v 2  0 1 1.0  10 13   0 1
     v 1  0 = 2     0 = 1.6 × 10 13 Hz
    0.4  10 13   0 2

    Ex 5. Iodine molecule dissociates into atoms after absorbing light of 3000 Å. If one quantum of radiation is absorbed
    by each molecule, calculate the kinetic energy of iodine atoms. (Bond energy of I 2 = 240 kJ (mol).
    Sol. Energy given to iodine molecule
    hc 6.62  10 34  3  10 8
     = 6.62 × 10 –19 J
     3000  10 10
    Also energy used for breaking up
    240  10 3
    I 2 molecule =  3.984  10 19 J
    6.023  10 23
     Energy used in imparting kinetic to two atoms = (6.62 – 3.984) × 10 –19 J

     KE of iodine atom =
     6.62  3.984   10 19 =
    1.318 × 10 –19 J
    2
    Ex 6. Two hydrogen atoms collide head on and end up with zero kinetic energy. Each atom then emits a photon
    of wavelength 121.6 nm. Which transition leads to this wavelength ? How fast were the hydrogen atoms
    travelling before collision ?
    Sol. Wavelength is emitted in UV region and thus n 1 = 1

    1 1 1 
    For H atom =  RH 12  n 2 
      

    1 1 1 
     7
    9 =1.097 × 10  2
     2
    121.6  10 1 n 

     n = 2
    Also the energy released is due to collision and all the kinetic energy is released in form of photon.
    1 hc
     mv 2 
    2 

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