A-19, MSDS

DEEPAK PHENOLICS LIMITED
12/B, GIDC DAHEJ, Tal: VAGRA, Dist: BHARUCH – 392130, GUJARAT.

MATERIAL SAFETY DATA SHEET
DPLD-001-QAQC-406-0002
SECTION – 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME : Hydrated Phenol
SYNONYMS : Monohydroxy benzene, Benzenol, Phenyl hydroxide, Phenic Acid,
Carbolic acid.
PROPER SHIPPING NAME : Phenol Hydrated
PRODUCT USE : It is used for manufacturing of Phenol-
Formaldehyde Resins & other industrial product manufacturing.
MANUFACTURER / SUPPLIER : Deepak Phenolics Limited
12/B/1, GIDC, Dahej, Tal: Vagra, Dist: Bharuch -392130, Gujarat.
www.godeepak.com
Emergency Coordination Centre contact details:
Deepak Phenolics Limited Security / Safety / CCR / 02641-280723 / 02641-280702 /
Logistic / Lab 02641-280814/02641-280708/02641-
280700
SECTION - 2 HAZARD IDENTIFICATION

GHS - Classification
Acute oral toxicity Category 3
Acute dermal toxicity Category 3
Acute inhalation toxicity Category 3
Germ cell mutagenicity Category 2
Specific target organ systemic toxicity (repeated Category 2
exposure)
Acute aquatic toxicity Category 2
Skin corrosion/irritation Category 1
Serious eye damage/eye irritation Category 1
GHS Label elements, including precautionary statements
Signal Word: DANGER

Hazard statements
H301 Toxic if swallowed
H311 Toxic in contact with skin
H331 Toxic if inhaled
H314 Causes severe skin burns and eye damage
H341 Suspected of causing genetic defects
H373 May cause damage to organs through prolonged or repeated exposure
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DPLD-001-QAQC-406-0002
H411 Toxic to aquatic life with long lasting effects
H318 Causes serious eye damage
Precautionary Statements
P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P260 – Do not breathe dust/fume/gas/mist/vapors/spray.
P264 – Wash hands thoroughly after handling
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/ protective clothing/ eye protection/ face protection.
P281 – Use personal protective equipment as required.
P284 – Wear respiratory protection.
P301 + P310+P330 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. Rinse
mouth.
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
P304 + P340+ P310 - IF INHALED: Remove person to fresh air and keep at rest in a position
comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338+ P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/
doctor.
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.
P210 - Keep away from heat/sparks/open flames/hot surfaces.
P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
P391– Collect pillage.
P501 – Dispose of contents/containers in accordance with local/regional/national/international
regulation.
SECTION – 3 COMPOSITION & INFORMATION ON INGREDIENTS
Ingredients / Hazardous CAS No. % By Weight

Phenol, solid, Molten / Yes 108-95-2 ≥ 90.0
Water 7732-18-5 ≤ 10.0
SECTION – 4 FIRST AID MEASURES
General Advice: Immediate medical attention is required.

Main Symptoms: Burn. Central nervous system depression. Liver and kidney injuries may occur.
Inhalation of vapors in high concentration may cause shortness of breath
After Inhalation: If inhaled, remove to fresh air. Loosen tight clothing such as a collar, tie, belt or
waistband. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. It may be
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DPLD-001-QAQC-406-0002
dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention
immediately.
Serious Inhalation: Evacuate the victim to a safe area as soon as possible. Loosen tight clothing
such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not
breathing, perform mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person
providing aid to give mouth-to- mouth resuscitation when the inhaled material is toxic, infectious
or corrosive. Seek immediate medical attention.
After skin contact: Call medical doctor or poison control center immediately. Remove all clothing.
Patient should be immediately placed in an emergency shower and skin should be flushed with
large amount of water for at least 20 minutes. If phenol has contaminated the face or head, victim
should wear goggles in the shower to prevent phenol from entering the eyes. After emergency
shower, swab affected area(s) of the patient with cotton soaked in polyethylene glycol 300 (PEG) or
PEG 400 for a minimum of 10 to 20 minutes. Do not rub. After treatment with PEG, patient should
be transported to an emergency medical facility for cardiac monitoring and further treatment.
Phenol may have an effect on many different organ systems, especially the heart and kidneys. Even
if exposure is small, patient should be admitted for at least 24 hours for observation. Dispose off
contaminated shoes and clothing in accordance with all local, regional, national and international
regulations.
After eye contact: Immediate medical attention is required. Check for and remove any contact
lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open.
Cold water may be used. Do not rub affected area. Get medical attention immediately.
After ingestion: Do NOT induce vomiting. Never give anything by mouth to an unconscious person.
Loosen tight clothing such as a collar, tie, belt or waistband. Ingest immediately about 350 ml (5
ml/kg body weight) of activated charcoal slurry. Get medical attention if symptoms appear. Note:
To prepare activated charcoal slurry, mix thoroughly 50 gm of activated charcoal in 400 ml (about 2
cups) water. Get medical attention immediately.
Advice to physician: Product is corrosive material. In case of inhalation prophylactic treatment to
prevent pulmonary edema is important. Phenol causes strong caustic burns of the skin and mucous
membranes due to its protein degenerating action. The skin initially discolors white, later red. After
initial pain, local anesthesia appears. Absorption poisoning by large amounts of phenol is possible
also through small affected skin regions and quickly leads to paralysis of the central nervous system
as well as strong depression of the body temperature. Possible perforation of stomach or esophagus
should be investigated. Do not give chemical antidotes. Marked decrease in blood pressure may
occur with moist rales, frothy sputum, and high pulse pressure. Systematic damage to kidneys, liver
and heart as well as neuropsychiatric disturbances are produced. Treat symptomatically.
SECTION – 5 FIRE FIGHTING MEASURES

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide. Avoid use of water jet for extinguishing.
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DPLD-001-QAQC-406-0002
Flash Point: 79 C (174 F) CC
Autoignition temperature : 715C (1319F)
Flammable limits in air % by volume:
Lel : 1.3, Uel : 8.6
Combustible. Contact with strong oxidizers may cause fire.
Firefighting procedures: Stay in danger area only with self-contained breathing apparatus. Prevent
skin contact by keeping a safe distance or by wearing suitable protective clothing. Suppress (knock
down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from
contaminating surface water or the ground water system.
SECTION – 6 ACCIDENTAL RELEASE MEASURES

Personnel protection procedure to be followed in case of leak or spill: Wear respiratory
protection. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.
Evacuate personnel to safe areas.
Procedure of personal precaution: Wear self-contained breathing air apparatus, rubber boots, and
heavy rubber gloves.
Methods for cleaning up: Cover drains. Collect, bind, and pump off spills. Observe possible material
restrictions. Take up carefully with liquid-absorbent material (e.g. Chemisorb®). Dispose of properly.
Clean up affected area.
SECTION – 7 HANDLING AND STORAGE
Handling: Keep locked up. Keep container dry. Keep away from heat. Keep away from sources of
ignition.
Empty containers pose a fire risk; evaporate the residue under a fume hood. Ground all equipment
containing material. Do not ingest. Do not breathe dust. Never add water to this product. In case of
insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice
immediately and show the container or the label. Avoid contact with skin and eyes.
Storage: Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Light
sensitive. Store under inert gas. Air sensitive.
Storage class (TRGS 510): Combustible solids, toxic.
Do not store together with food. Do not store together with: solvent, aluminum, aldehydes,
halogens, hydrogen peroxide, oxidizing agents, strong acids, strong bases, formaldehyde, nitrites,
nitrates, halogenated, peroxide compounds.
Storage temperature: 30˚C to 60˚C.
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DPLD-001-QAQC-406-0002
SECTION – 8 EXPOSURE CONTROL AND PERSONAL PROTECTION
HANDS EYES BODY RESPIRATORY
8.1 Control parameters:

EXPOSURE LIMITS: TWA: 5 (ppm) from ACGIH (TLV) [United States] SKIN TWA: 19 (mg/m3) from
ACGIH (TLV) [United States] SKIN TWA: 5 from NIOSH [United States] TWA: 19 (mg/m3) from
NIOSH [United States] TWA: 5 (ppm) from OSHA (PEL) [United States] TWA: 19 (mg/m3) from
OSHA (PEL) [United States] TWA: 5 (ppm) [Canada] TWA: 19 (mg/m3) [Canada]Consult local
authorities for acceptable exposure limits.
Immediately Dangerous to Life or Health Concentrations (IDLH) : 250 ppm
Engineering measures: Use process enclosures, local exhaust ventilation, or other engineering
controls to keep airborne levels below recommended exposure limits. If user operations generate
dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the
exposure limit.
Respiratory Protection: If the exposure limit is exceeded and engineering controls are not feasible,
wear a supplied air full-face piece respirator, airline hood, or full-face piece self-contained breathing
air apparatus.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible.
Maintain eye wash fountain and quick-drench facilities in work area.
Hand Protection: Protective gloves according to ASTM F739 permeation tests:
Glove material:
Neoprene – Best
Viton - Best
Polyvinyl Chloride (PVC) – Acceptable
Nitrile – Not recommended
Observe glove manufacturer’s instructions concerning penetrability and breakthrough time.
Body Protection: Complete suit protecting against chemicals, the type of protective equipment
must be selected according to the concentration and amount of the dangerous substance at the
specific workplace. Where splashing is possible, full chemically resistant protective clothing and
boots are required.
Recommended materials acceptable for use as protective clothing: Polyvinyl Chloride (PVC) ,
Neoprene
SECTION – 9 PHYSICAL AND CHEMICAL PROPERTIES
Physical state Liquid

Appearance Colorless
Odour Distinct, aromatic, somewhat sickening sweet
threshold: 0.022 – 22 mg/m3
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DPLD-001-QAQC-406-0002
Solubility in water at 20 ˚C: 84 g/L
at 25˚C: 87 g/L
at 68 ˚C: fully miscible
Molecular formula C6H5OH
Boiling Point °C 182°C (359.6°F)
Solidification Point °C 19-22°C
Relative Vapor Density (Air=1) 3.24
Flash point °C 79°C - closed cup
Auto ignition °C 715°C
Vapor pressure (mmHg) @ 20 °C 5 mbar
Molecular weight 94.11 g/mole
Explosive limits in air % by volume NA
pH 4-5 at 20°C 10 g/L
Viscosity , dynamic at 50˚C : 3437 mPaS
Density at 20˚C: 1.07 g/cm3
at 25˚C: 1.13 g/cm3
Pour point NA
Evaporation rate (water=1) NA
Water/Oil Dist. Co eff.: The product is more soluble in oil; log(oil/water) = 1.5
% volatile NA
NA: NOT AVAILABLE
SECTION – 10 CHEMICAL STABILITY AND REACTIVITY INFORMATION
10.1 Reactivity: See section 10.3.
10.2 Chemical stability: Stable under recommended storage and handling conditions.
10.3 Possibility of hazardous reactions: Air and light sensitive. Prone to redden on exposure to
light and air. Incompatible with aluminum chloride, peroxydisulfuirc acid, acetaldehyde, sodium
nitrite, boron tri fluoride diethyl ether + 1,3-butadiene, isocyanates, nitrides, mineral oxidizing
acids, calcium hypochlorite, halogens, formaldehyde, metals and alloys, lead, zinc, magnesium and
their alloys, plastics, rubber, coatings, sodium nitrate + tri fluoroacetic acid. Phenol + isocyanates
results in heat generation, and violent polymerization. Phenol + 1,3-butadiene and boron tri
fluoride diethyl ether complex results in intense exothermic reaction. Phenol +acetaldehyde results
in violent condensation.
10.4 Conditions to avoid: Heat, ignition sources (flames, sparks), light, incompatible materials.
10.5 Material to avoid: Incompatible materials: Strong oxidizing agents, Strong bases, Strong acids.
10.6 Hazardous decomposition products: Hazardous decomposition products formed under fire
conditions. - Carbon oxides other decomposition products - No data available.
Hazardous polymerization does not occur.
SECTION – 11 TOXICOLOGICAL INFORMATION
11.1 Rout of Entry: Absorbed through skin, dermal contact, Inhalation, Ingestion.
11.2 Acute oral toxicity: LD50 (rat): 317 mg/kg, LD50 (Mouse) : 270 mg/Kg
11.3 Acute dermal toxicity: LD50 (rat): 670 mg/kg, LD50 (Rabbit) : 630 mg/Kg
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DPLD-001-QAQC-406-0002
11.4 Acute inhalation toxicity: LC50 (rat) : 316 mg/M3
11.5 Germ cell mutagenicity: Mutagenic; positive in in-vivo and in-vitro assays.
11.6 Specific target organ systemic toxicity: Kidney: can cause kidney damage. Liver: can cause liver
Damage. Respiratory system: caused breathing difficulty in animals. Heart: can cause heart damage.
11.7 Acute aquatic toxicity: 0% of the mixture consists of ingredient(s) of unknown toxicity.
11.8 Chronic effect on human : Carcinogenic effects: A4 (Not classifiable for human or animal.) by
ACGIH, 3 (Not classifiable for human.) by IARC. Mutagenic effects: Mutagenic for mammalian
somatic cells. Mutagenic for bacteria and/or yeast. May cause damage to the following organs:
kidneys, liver, central nervous system (CNS). System, skin, central nervous system (CNS).
11.9 Skin corrosion/irritation: Contact with skin will result in severe irritation. Corrosive to skin -
may cause skin burns. Component/s of this material can be absorbed through the skin with
resultant toxic effects.
11.10 Serious eye damage/eye irritation: A severe eye irritant. Corrosive to eyes; contact can cause
corneal burns. Contamination of eyes can result in permanent injury.
11.11 Toxic to reproduction: Animal passes through the placental barrier. May cause adverse
reproductive effects and birth defects (teratogenic) Embryotoxic and/or foetotoxic in animal. May
affect genetic material (mutagenic).
SECTION – 12 ECOLOGICAL INFORMATION
12.1 Eco Toxicity data:
12.1.1 Toxicity to fish: LC50 - Leuciscus idus (Golden orfe) - 14.00 - 25.00 mg/l - 48 h(Phenol) LC50 -
Carassius auratus (goldfish) - 36.10 - 68.80 mg/l - 96 h(Phenol)
12.1.2 Toxicity to algae: Not available.
12.2 Persistence and degradability: Readily biodegradable.
12.3 Bio accumulative potential: Danio rerio (zebra fish) - 5 h - 2 mg/l(Phenol) Bio concentration
factor (BCF): 17.5 Remarks: Does not bio accumulate.
12.4 Mobility in soil: Mobility potential is high. Koc: 82.8 l/kg (measured log Pow value of
1.47). The soil sorption coefficient indicates a low sorption of phenol onto soil organic
matter.
12.5 Results of PBT assessment Persistence and Degradation: This substance/mixture contains no
components considered to be either persistent, bio accumulative and toxic (PBT), or very persistent
and very bio accumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects: Toxic to aquatic life with long lasting effects.
SECTION – 13 DISPOSAL CONSIDERATION

13.1 Local Legislation: Disposal should be in accordance with applicable regional, national, and local
laws and regulations. This product should not be dumped, spilled, rinsed or washed into sewers or
public waterways.
13.2 Recommended disposal methods for the substance / mixture: Offer surplus and non-
recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible
solvent and burn in a chem scrubber.
13.3 Recommended disposal methods for contaminated packaging: Dispose of as unused product.
13.4 Waste management measures that control exposure of humans and environment: Proceed in
accordance with valid health, air and water legislative regulations.
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DPLD-001-QAQC-406-0002
13.5 Waste regulation: Follow local regulation.
SECTION – 14 TRANSPORT INFORMATION
Phenol Hydrated
UN 2821
IMDG/IMO
Proper Shipping Name Phenol Hydrated
Hazard class 6.1
UN/ID No UN 2821
Packing group II
EmS No. F-A, S-A
Marine pollutant This product contains a chemical which is listed as a marine
pollutant according to IMDG/IMO.
ICAO/IATA
Hazard class 6.1
UN/ID No UN2821
Packing group II
DOT
Hazard class 6.1
UN/ID No UN2821
Packing group II
SECTION – 15 REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
National legislation: Storage class 6.1A
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical
Substances.
WHMIS (Canada): CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC).
CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive solid.
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 2
Reactivity: 0
Personal Protection: j
National Fire Protection Association (U.S.A.): Health: 4
Flammability: 2
Reactivity: 0
Specific hazard: Protective Equipment:
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DPLD-001-QAQC-406-0002
Gloves, lab coat, dust respirator, splash goggles. Be sure to use an approved/certified respirator or
equivalent.
SECTION – 16 OTHER INFORMATION
MSDS Revision Status:
Date of preparation Date of Revision Revised Sections Supersedes
01/01/2019 30/04/2021 2.0 Hazard Identification
Disclaimer:
Deepak Phenolics Ltd (DPL), believes that the information and recommendations contained herein
(including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR
ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY,
EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN.
The information provided herein relates only to the specific product designated and may not be
applicable where such product is used in combination with any other materials or in any process.
Company will not take any responsibility/guarantee/warranty, if this product is used in a manner
inconsistent with its labeling. Further, since the conditions and methods of use are beyond the
control of DPL, expressly disclaims any and all liability as to any results obtained or arising from any
use of the product or DPL on such information.
END OF MSDS
Page 9 of 9
KANORIA CHEMICALS & INDUSTRIES LIMITED
P.O. ANKLESHWAR – 393002, BHARUCH, (GUJ.)
FORMALDEHYDE SOLUTION
General Information:
CAS Number 50 - 00 - 0
EINECS Number 200 - 001 - 8
Chemical Name Formaldehyde
Chemical Classification Aldehyde
Formalin; formic aldehyde; formal; methyl aldehyde; methylene

glycol; methylene oxide; methanal; morbicid; oxamethane;
Synonyms
oxymethylene; paraform; polyoxymethylene glycol;
superlysoform.
Formula HCHO
Molecular weight 30.03
Shipping Name Formaldehyde solution
Codes / Label Flammable liquid, Class - 3.1
Hazardous Waste ID No. 5
Hazchem Code 2 SE / 2 T
UN Number 1198
Description Colourless liquid with characteristic pungent odour.
In the manufacture of phenolic resins:- amino (MF/UF/MUF)

resins, artificial silk and cellulose esters, dyes, organic chemicals,
glass mirrors, explosives; disinfectant for dwellings, ship, storage
houses, utensils, clothes etc., as a germicide & fungicide for
Product uses
plants & vegetables, improving fastness of dyes on fabrics,
tanning & preserving hides;, mordanting & water proofing
fabrics; preserving & coagulating rubber latex; in embalming
fluids.
1
KANORIA CHEMICALS & INDUSTRIES LIMITED
P.O. ANKLESHWAR – 393002, BHARUCH, (GUJ.)

(According to 91/155 EC)
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING:
Product details:
Product Identifier FORMALDEHYDE, 37% SOLUTION IN WATER
Synonyms Formalin
Relevant identified uses of the substance or mixture and

Industrial. For professional use only.
uses advised against
Details of the supplier of the safety sheet
Kanoria Chemicals & Industries Ltd. Kanoria Chemicals & Industries Ltd.
3407, GIDC, Industrial Estate, A304/305/306, Universal Business Park,

ANKLESHWAR, 393 002 (Gujarat), Chandivali Farm Road, Off.Saki Vihar Road,
India Tel:+91 2646 668801-04 Near Kamani Oil Mills, Saki Naka, Andheri(East),
Fax: +91 2646 251816 Mumbai 400 072 (Maharashtra) I n d i a.
Email: ank@kanoriachem.com Tel: +91 22 28470216, 28470217
www.kanoriachem.com Fax: +91 22 28470235
Email: kcil@bom3.vsnl.net.in
Further information obtainable from in case of Safety Department.

emergency +91 2646 668869.
2. HAZARD IDENTIFICATION:
2.1 Classification of the substance or mixture:
Classification according to Regulation (EC) No 1272/2008 [CLP/GHS]
Hazard Categories
Acute toxicity, Oral : Category 3 , H301

Acute toxicity, Inhalation : Category 3 , H331
Acute toxicity, Dermal : Category 3,H311
Health hazard
Skin sensitization : Category 1,H317
Germ cell mutagenicity : Category 2 , H341
Carcinogenicity: Category 1B, H350
2
2.2 Label elements:
Labelling according Regulation (EC) No 1272/2008 [CLP/GHS]
Pictogram
H301+H311+H331: Toxic if swallowed, in contact with skin or inhaled.

H314: Causes severe skin burns and eye damage.
H317: May causes an allergic skin reaction.
Hazard statement
H335: May causes respiratory irritation.
H341: Suspected of causing genetic defects.
H350: May cause cancer.
P201: Obtain special instruction before use.

P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310+P330: If swallowed, immediately call a doctor/physician.
Precautionary statement
P303+P361+P353: If on skin, Take of immediately all contaminated clothing. Rinse skin
with water/shower.
P403+P233: Store in a well ventilated place. Keep container tightly closed.
3. COMPOSITION/ INFORMATION ON INGREDIENTS:
Description CAS No. EINECS Number
Formaldehyde 50-00-0 200-001-8
Methanol 67-56-1 200-659-6
Water 7732-18-5
4. FIRST-AID MEASURES:
Inhalation Remove victim to fresh air, restore breathing, get medical attention.
Skin contact Remove contaminated clothing, flush with plenty of water atleast for 15 minutes.
Eye contact Immediately flush opened eye with plenty of running water for atleast 15 minutes.
Swallowing DO NOT induce vomiting. Seek urgent medical assistance.
5. FIRE-FIGHTING MEASURES:
Suitable extinguishing agents CO2, Dry chemical powder, water spray and alcohol foam.
6. ACCIDENTAL RELEASE MEASURES:
Person-related safety precautions Proper protective equipment and self contained breathing apparatus with full
face piece operated in positive pressure mode.
Measures for cleaning/collecting Shut off sources of ignition, Avoid flares smoking or flames in area. Stop
leakage if possible. Use water spray to reduce vapour. Take up with sand or
other non combustible absorbent and place into container for disposal
according to item 13.
3
7. HANDLING AND STORAGE:
Handling
Information for safe handling Avoid breathing vapours; avoid contact with eyes, skin and clothing.
Decontaminate soiled clothing thoroughly before use.
Information about fire and explosion Flammable liquid. Closed containers exposed to heat may explode.
protection
Storage
Requirements to be met by store Store in tightly closed containers in a dry, cool, well ventilated, flammable
rooms and receptacles liquid storage area.
8. EXPOSURE CONTROLS / PROTECTION:
50-00-0 Formaldehyde
OES Short term value *3 mg/m3

Long term value **1.5mg/m3
* total inhalable vapour, ** permissible exposure
Personal protective equipment Self contained breathing apparatus and full protective clothing.
Respiratory protection Self contained breathing apparatus.
Protection of hands Gloves of natural rubber.
Eye protection Safety glasses Wear face shield.
9. PHYSICAL AND CHEMICAL PROPERTIES:
General information:
Form Liquid
Colour Colourless
Odour Pungent odour
Change in condition
Melting point --
Boiling Point / Boiling range 96oC
Flash point: (CC) * 85oC
Flammable limits Upper 73.0%, Lower 7.0%
Auto ignition temperature 423oC
Specific gravity, at 25 oC 1.108
Vapour density (Air = 1) 1.0

o
Vapour Pressure (mm Hg) at 20 C 1.3
Solubility/Miscibility with water at 20 Complete

o
C
* Flash point varies with the concentration of Methanol.

4
10. STABILITY & REACTIVITY:
This product is stable, strong reducing agent, especially in alkaline solution. Keep away from strong bases and
acids, oxidizing agents, aniline, phenol, isocyanates, and anhydride. Combustible light and air sensitive,
polymerizes spontaneously.
Dangerous reactions With bases / acids and oxidizing agents.
Dangerous decomposition products CO, CO2 & vapours of formaldehyde
11. TOXICOLOGICAL INFORMATION:
Acute toxicity:
LD/LC50 values relevant for Oral/LD 50 : 100 mg/Kg (rat)

classification: SKN LD 50: 270 µl/kg (rabbit)
Primary irritant effect:
On the skin Irritating effect (severe)
On the eye Irritating effect (severe)
Sensitization Prolonged contact may cause skin sensitization.
12. ECOLOGICAL INFORMATION:
Environmental toxicity The product is expected to be slightly toxic to aquatic life. The LC 50/96 hrs values for
fish are between 10 and 100 mg/l.
Environmental fate When released into the soil, material is expected to reach into ground water. When
released into water, the material is expected to readily bio-degrade and is not expected
to bio-accumulate. When released into air, the material is expected to readily degrade
by photolysis, readily removed from atmosphere by dry and deposition. Half life of the
material is less than one day, when released into air.
13. DISPOSAL CONDITIONS:
Whatever cannot be recycled, should be absorbed in sand or other non-combustible absorbent, containerized
and transferred to appropriate and approved waste disposal facility. Dispose waste, containers and unused
contents in accordance with official regulations.
14. TRANSIT INFORMATION:
Shipping name Formaldehyde Solution
UN number 1198 Class: 3, 3.3, 8
ADG Classification, Sub risk Class3, 8
Packing Group III Label: Flammable liquid.
5
15. REGULATORY INFORMATION:
This product is extremely hazardous. It is listed as an "ACGIH" 'suspected' human carcinogen and a "NTP"
anticipated human carcinogen. It may cause (mutagenic) reproductive effects.
16. OTHER INFORMATION:
Kanoria Chemicals & Industries Limited provides the information contained herein in good faith, but makes no
representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person using this product. Individuals
receiving the information must exercise their independent judgment in determining its appropriateness for a
particular purpose. KANORIA CHEMICALS & INDUSTRIES LIMITED MAKES NO REPRESENTATIONS OR
WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF
MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, KANORIA CHEMICALS &
INDUSTRIES LIMITED WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE
UPON THIS INFORMATION.
Department issuing MSDS: Safety Department
Date of Issue: 01-07-2018 Date of Revision: 30-06-2021
This document is valid for 03 years from the date of issue, and is bound to be canceled, if not revised on or
before the date of revision.
6
MONOPOLY INNOVATIONS PRIVATE LIMITED
Email: info@monopolyin.com
Web: www.monopolyin.com
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1 Product identifiers

Product name : METHYL ESTER OF SOYABEAN OIL
CAS-No. : 67784-80-9
Other Names : Methyl Soyate
1.2 Relevant identified uses of the substance or mixture

Identified uses : Laboratory chemicals, Manufacture of substances, Industrial Uses
1.3 Details of the supplier of the safety data sheet

Company : Monopoly Innovations Private Limited
109 Sheikh Memon Street, 2/25 Shahiwala Building, Zaveri Bazar, Mumbai
400002, Maharashtra, INDIA.
2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
a) Eye irritation.
b) Respiratory system irritation.
c) Skin irritation.
2.2 Label elements

Pictogram :
Signal word : Warning

Hazard statements : a) Causes slightly eye irritation.
b) Causes slightly skin irritation.
Precautionary statement: a) Wear protective gloves/ protective clothing/ eye protection/ face shield
IF SWALLOWED : Immediately call a POISON CENTER or doctor/physician.
2.3 Other hazards - none

3. COMPOSITION/INFORMATION
3.1 Substances information

Component CAS No. Assay %
Methyl ester of soyabean oil 67784-80-9 Min 96.5
4. FIRST AID MEASURES
4.1 Description of first aid measures
Page 1
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
In case of skin contact

Wash off with soap and plenty of water.
In case of eye contact

Flush eyes with water as a precaution
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water.
5. FIRE-FIGHTING MEASURES
5.1 Extinguishing media

Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture

None Identified
5.3 Precautions for fire-fighters

Wear self contained breathing apparatus for fire fighting if necessary.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures

Avoid dust formation. Avoid breathing vapors, mist or gas.
6.2 Environmental precautions

Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up

Sweep up and shovel. Keep in suitable, closed containers for disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling

Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire
protection.
7.2 Conditions for safe storage, including any incompatibilities

Store in cool place . Keep container tightly closed in a dry and well-ventilated place
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters

Components with workplace control parameters
8.2 Exposure controls

Appropriate engineering controls
General industrial hygiene practice.
Personal protective equipment
a) Eye/face protection
Use equipment such as goggles and face mask for eye and face protection.
Page 2
b) Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
( without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
c) Body Protection
Choose body protection in relation to its type, to the concentration and amount of dangerous
substances , and to the specific work-place., The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
d) Respiratory protection
Respiratory protection is not required.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
a) Appearance Form : Liquid

Colour : pale yellow colour
b) Odour : No data available
c) pH : No data available
d) Melting/freezing point : > 200 0c
e) Boiling point : -5 to -10 0c
f) Flammability (solid, gas) : No data available
g) Water solubility : insoluble
h) Autoignition temperature : No data available
i) Explosive properties : No data available
j) Oxidizing properties : No data available
k) Specific Gravity : 0.90 max
l) Solubility in water : No data available
j) Molecular Weight : No data available
k) Flash point : 120 oC min Close cup method
10. STABILITY AND REACTIVITY
10.1 Stability: Stable
10.2 Hazardous Decomposition: combustion product CO2, CO and thick smoke.
10.3 Conditions to Avoid: Sensitive to air, and light
10.4 Materials to avoid: Strong oxidizing agents.
10.5 Incompatible materials: no data available.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects

Acute toxicity: no data available
Skin corrosion/irritation: May cause skin irritation.
Serious eye damage/eye irritation: May cause eye irritation.
Respiratory or skin sensitization: no data available
Germ cell mutagenicity: no data available
Carcinogenicity: Not classifiable as to its carcinogenicity to humans.
Reproductive toxicity: no data available
Page 3
Specific target organ toxicity - single exposure: no data available
Specific target organ toxicity - repeated exposure: no data available
Aspiration hazard: no data available
12. ECOLOGICAL INFORMATION

12.1 Toxicity: no data available
12.2 Persistence and degradability: no data available
12.3 Bioaccumulative potential: no data available
12.4 Mobility in soil : no data available
12.6 Other adverse effects: no data available
13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.
14. TRANSPORT INFORMATION

Not dangerous goods.
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
15.2 Chemical Safety Assessment: no data available
16. OTHER INFORMATION
For questions contact: Monopoly Innovations Private Limited

109 Sheikh Memon Street, 2/25 Shahiwala Building, Zaveri Bazar, Mumbai 400002, Maharashtra, INDIA.
The statements contained herein are offered for informational purposes only and are based upon technical data
that MIPL believes to be accurate. It is intended for use only by persons having the necessary technical
Skills and at their own discretion and risk. Since conditions and manner of use are outside our control, we make
NO WARRANTY, EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS OR OTHERWISE.
Page 4
MONOETHYLENE GLYCOL SAFETY DATA SHEET
1. Chemical Product and Company Identification
Product Name: MONOETHYLENE GLYCOL

Other name(s): Ethylene glycol; MEG; 1,2-Ethanediol; 1,2-Dihydroxyethane.
Recommended Use of the Chemical and Restrictions on Use
Coolant and antifreeze; heat transfer agent; brake fluids; solvent; humectant.
Supplier`s Name Revlogi Materials
No. 25, Jalan TPP 1/13, Taman Perindustrian Puchong,
Batu 12, Jalan Puchong
47100 Puchong, Selangor Darul Ehsan
Telephone No. 016-2013753
Fax 03-80687791
2. Hazards Identification
Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG
Code) for transport by Road and Rail; NON-DANGEROUS GOODS.
This material is hazardous according to Safe Work Australia; HAZARDOUS CHEMICAL.
Classification of the chemical:

Acute Oral Toxicity - Category 4
Specific target organ toxicity (repeated exposure) - Category 2
SIGNAL WORD: WARNING
Hazard Statement(s):
H302 Harmful if swallowed.
H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary Statement(s):
Prevention:
P260 Do not breathe mist, vapours, spray.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
Response:
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P330 Rinse mouth.
P314 Get medical advice/attention if you feel unwell
Storage:
No storage statements.
Disposal:
P501 Dispose of contents and container in accordance with local, regional, national, international
regulations.
Poisons Schedule (SUSMP): S6 Poison
Page 1 of 6
Batu 12, Jalan Puchong, 47100 Puchong, Selangor, Malaysia.
Tel: +6016-2013753 Fax: +603-80687791
3. Composition/Information on Ingredients
Components CAS Number Proportion Hazard Codes

Ethylene glycol 107-21-1 100% H302 H373
4. Description of First Aid Measures
For advice, contact a Poisons Information Centre (e.g. phone Australia 131 126; New Zealand 0800
764 766) or a doctor.
Inhalation: Remove victim from area of exposure - avoid becoming a casualty. Remove
contaminated clothing and loosen remaining clothing. Allow patient to assume most comfortable
position and keep warm. Keep at rest until fully recovered. If patient finds breathing difficult and
develops a bluish discolouration of the skin (which suggests a lack of oxygen in the blood - cyanosis),
ensure airways are clear of any obstruction and have a qualified person give oxygen through a face
mask. Apply artificial respiration if patient is not breathing. Seek immediate medical advice.
Skin Contact: If skin contact occurs, remove contaminated clothing and wash skin with running
water. If irritation occurs seek medical advice.
Eye Contact: If in eyes, wash out immediately with water. In all cases of eye contamination it is a
sensible precaution to seek medical advice.
Ingestion: Rinse mouth with water. If swallowed, give a glass of water to drink. If vomiting occurs give
further water. Seek immediate medical assistance.
Indication of immediate medical attention and special treatment needed: Treat symptomatically.
Following ingestion admission to hospital should be the first priority. Gastric lavage or emesis should
be performed as soon as possible to minimise absorption and is recommended within four hours of
ingestion. Gastric lavage or emesis should not be attempted unless medical expertise or adequate
facilities are available. Ethanol may be given intravenously as an antidote to prevent build-up of toxic
metabolites and increase excretion of unchanged ethylene glycol by the kidneys. Uraemia, pulmonary
oedema and metabolic acidosis can occur and dialysis, preferably haemodialysis, may be employed
to treat these complications and to remove ethylene glycol and its metabolites from the blood.
Ethylene glycol can cause central nervous system depression and metabolic acidosis. Consider
removal by gastric lavage. Blockade of the diacid/hydroxyacid metabolites may follow competitive
inhibition of alcohol dehydrogenase with ethanol or 4-methyl pyrazole. Consider maintenance of a
plasma ethanol level of 100 mg/dL to 150 mg/dL.
5. Fire Fighting Measures
Suitable Extinguishing Media:

Fine water spray, normal foam, dry agent (carbon dioxide, dry chemical powder).
Unsuitable Extinguishing Media:

Water jet.
Specific hazards arising from the chemical:

Combustible liquid.
Special protective equipment and precautions for fire-fighters:

On burning will emit toxic fumes, including those of oxides of carbon . Fire fighters to wear self-
contained breathing apparatus and suitable protective clothing if risk of exposure to vapour or
products of combustion. Heating can cause expansion or decomposition of the material, which can
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lead to the containers exploding. If safe to do so, remove containers from the path of fire. Keep
containers cool with water spray.
6. Accidental Release Measures
Emergency procedures/Environmental precautions:

Clear area of all unprotected personnel. Shut off all possible sources of ignition. If contamination of
sewers or waterways has occurred advise local emergency services.
Personal precautions/Protective equipment/Methods and materials for containment and

cleaning up:
Slippery when spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent skin
and eye contact and breathing in vapours. Work up wind or increase ventilation. Contain - prevent run
off into drains and waterways. Use absorbent (soil, sand or other inert material). Collect and seal in
properly labelled containers or drums for disposal. Wash area down with excess water.
7. Handling and Storage
Classified as a C1 (COMBUSTIBLE LIQUID) for the purpose of storage and handling, in accordance
with the requirements of AS 1940. Refer to State Regulations for storage and transport requirements.
This material is a Scheduled Poison S6 and must be stored, maintained and used in accordance with
the relevant regulations.
Precautions for safe handling:

Avoid skin and eye contact and breathing in vapour. Keep out of reach of children.
Conditions for safe storage, including any incompatibilities:

Store in a cool, dry, well ventilated place and out of direct sunlight. Store away from foodstuffs. Store
away from incompatible materials described in Section 10. Keep containers closed when not in use -
check regularly for leaks.
8. Exposure Controls/Personal Protection
Ethylene glycol (vapour): 8hr TWA = 52 mg/m3 (20 ppm), 15 min STEL = 104 mg/m3 (40 ppm), Sk
Ethylene glycol (particulate): 8hr TWA = 10 mg/m3 , Sk
As published by Safe Work Australia Workplace Exposure Standards for Airborne Contaminants.
TWA - The time-weighted average airborne concentration of a particular substance when calculated
over an eight-hour working day, for a five-day working week.
STEL (Short Term Exposure Limit) - the airborne concentration of a particular substance calculated as
a time-weighted average over 15 minutes, which should not be exceeded at any time during a normal
eight hour work day. According to current knowledge this concentration should neither impair the
health of, nor cause undue discomfort to, nearly all workers.
`Sk' (skin) Notice - absorption through the skin may be a significant source of exposure. The exposure
standard is invalidated if such contact should occur.
These Workplace Exposure Standards are guides to be used in the control of occupational health
hazards. All atmospheric contamination should be kept to as low a level as is workable.
These workplace exposure standards should not be used as fine dividing lines between safe and
dangerous concentrations of chemicals. They are not a measure of relative toxicity.
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Appropriate engineering controls:
Ensure ventilation is adequate and that air concentrations of components are controlled below quoted
Workplace Exposure Standards. Vapour heavier than air - prevent concentration in hollows or sumps.
DO NOT enter confined spaces where vapour may have collected. Keep containers closed when not
in use.
If in the handling and application of this material, safe exposure levels could be exceeded, the use of
engineering controls such as local exhaust ventilation must be considered and the results
documented. If achieving safe exposure levels does not require engineering controls, then a detailed
and documented risk assessment using the relevant Personal Protective Equipment (PPE) (refer to
PPE section below) as a basis must be carried out to determine the minimum PPE requirements.
Individual protection measures, such as Personal Protective Equipment (PPE):

The selection of PPE is dependent on a detailed risk assessment. The risk assessment should
consider the work situation, the physical form of the chemical, the handling methods, and
environmental factors.
OVERALLS, SAFETY SHOES, SAFETY GLASSES, GLOVES, RESPIRATOR.
Wear overalls, safety glasses and impervious gloves. Use with adequate ventilation. If determined by
a risk assessment an inhalation risk exists, wear an organic vapour respirator meeting the
requirements of AS/NZS 1715 and AS/NZS 1716. Always wash hands before smoking, eating,
drinking or using the toilet. Wash contaminated clothing and other protective equipment before
storage or re-use.
9. Physical and Chemical Properties
Physical state: Slightly Viscous Liquid

Colour: Colourless
Odour: Odourless
Molecular Formula: CH2OHCH2OH
Solubility: Miscible in water.
Specific Gravity: 1.12 @20°C
Relative Vapour Density (air=1): 2.2
Vapour Pressure (20 °C): 0.01 kPa
Flash Point (°C): 110 (CC)
Flammability Limits (%): 3.2-12.8 (vapour in air)
Autoignition Temperature (°C): 412
Boiling Point/Range (°C): 197
pH: Not available
Viscosity: 21 cP @20°C
Partition Coefficient: log Pow = -1.36
Freezing Point/Range (°C): -13
10. Stability and Reactivity
Reactivity: Reacts with strong oxidising agents.

Chemical stability: Stable under normal conditions of use.
Possibility of hazardous reactions: None known.
Conditions to avoid: Excessive heat will lead to accelerated oxidative degradation.
Incompatible materials: Incompatible with strong oxidising agents.
Hazardous decomposition products: Oxides of carbon.
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11. Toxicological Information
No adverse health effects expected if the product is handled in accordance with this Safety Data
Sheet and the product label. Symptoms or effects that may arise if the product is mishandled and
overexposure occurs are:
Ingestion:
Initial symptoms following a large dose (>100ml) are those of alcohol intoxication progressing to
vomiting, headache, stupor, convulsions and unconsciousness. Respiratory system involvement may
occur 12 - 24 hours after ingestion. Symptoms may include hyperventilation and rapid shallow
breathing. Death may occur from respiratory failure or pulmonary oedema.
Eye contact:
May be an eye irritant.
Skin contact:
Contact with skin may result in irritation. Will have a degreasing action on the skin. Repeated or
prolonged skin contact may lead to irritant contact dermatitis. Can be absorbed through the skin.
Effects can include those described for 'INGESTION'.
Inhalation:
Breathing in vapour can result in headaches, dizziness, drowsiness, and possible nausea.
Acute toxicity:
Oral LD50 (rat): 4700 mg/kg
Skin corrosion/irritation: Mild irritant (rabbit).

Serious eye damage/irritation: Mild irritant (rabbit).
Chronic effects: Available evidence from animal studies indicate that repeated or prolonged
exposure to this material could result in effects on the central nervous system, liver and kidneys .
Estimated minimum lethal dose (human) following ingestion of ethylene glycol is thought to be
1.4ml/kg. High doses of ethylene glycol in rats and mice have resulted in reproductive and
developmental toxicity following exposure by the oral and inhalation (respirable aerosol) routes. These
particular data sets are not considered relevant to normal industrial use but do emphasise the need
for care in handling.
Data from animal and human studies to date do not provide evidence that exposure to ethylene glycol
has mutagenic or carcinogenic effects.
12. Ecological Information
Ecotoxicity Avoid contaminating waterways.

Persistence/degradability: Expected to be readily biodegradable.
Bioaccumulative potential: This product shows a low bioaccumulation potential.
96hr LC50 (fish): >10,000 mg/L (marine water); 8050 mg/L (fresh water).
13. Disposal Considerations
Disposal methods:
Refer to Waste Management Authority. Dispose of material through a licensed waste contractor.
Normally suitable for incineration by an approved agent.
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s
14. Transport Information
Road and Rail Transport

Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG
Code) for transport by Road and Rail; NON-DANGEROUS GOODS.
Marine Transport
Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods
Code (IMDG Code) for transport by sea; NON-DANGEROUS GOODS.
Air Transport
Not classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA)
Dangerous Goods Regulations for transport by air; NON-DANGEROUS GOODS.
15. Regulatory Information
Classification:
This material is hazardous according to Safe Work Australia; HAZARDOUS CHEMICAL.
Classification of the chemical:

Acute Oral Toxicity - Category 4
Specific target organ toxicity (repeated exposure) - Category 2
Hazard Statement(s):
H302 Harmful if swallowed.
H373 May cause damage to organs through prolonged or repeated exposure.
Poisons Schedule (SUSMP): S6 Poison
This material is listed on the Australian Inventory of Chemical Substances (AICS).
16. Other Information
Supplier Safety Data Sheet; 11/ 2010.

`Registry of Toxic Effects of Chemical Substances'. Ed. D. Sweet, US Dept. of Health & Human
Services: Cincinatti, 2014. Product Name: MONOETHYLENE GLYCOL Issued: 17/07/2014
This safety data sheet has been prepared by Ixom Operations Pty Ltd Toxicology & SDS Services.
Reason(s) for Issue:

Product Name change Substance No: 000030116701
This SDS summarises to our best knowledge at the date of issue, the chemical health and safety
hazards of the material and general guidance on how to safely handle the material in the workplace.
Revlogi Materials cannot anticipate or control the conditions under which the product may be used,
each user must, prior to usage, assess and control the risks arising from its use of the material.
If clarification or further information is needed, the user should contact their Ixom representative or
Ixom Operations Pty Ltd at the contact details on page 1.
Revlogi Materials responsibility for the material as sold is subject to the terms and conditions of sale,
a copy of which is available upon request.
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Ammonia, anhydrous
Safety Data Sheet P-4562
according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1981 Revision date: 03/23/2015 Supersedes: 01/06/2015
SECTION: 1. Product and company identification

1.1. Product identifier
Product form : Substance
Name : Ammonia, anhydrous
CAS No : 7664-41-7
Formula : NH3
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial use. Use as directed.
1.3. Details of the supplier of the safety data sheet
Praxair, Inc.
39 Old Ridgebury Road
Danbury, CT 06810-5113 - USA
T 1-800-772-9247 (1-800-PRAXAIR) - F 1-716-879-2146
www.praxair.com
1.4. Emergency telephone number
Emergency number : Onsite Emergency: 1-800-645-4633
CHEMTREC, 24hr/day 7days/week — Within USA: 1-800-424-9300, Outside USA: 001-703-

527-3887 (collect calls accepted, Contract 17729)
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification (GHS-US)
Liquefied gas H280
Acute Tox. 3 (Inhalation) H331
Skin Corr. 1B H314
2.2. Label elements

GHS-US labeling
Hazard pictograms (GHS-US) :
GHS04 GHS05 GHS06 GHS09

Signal word (GHS-US) : DANGER
Hazard statements (GHS-US) : H221 - FLAMMABLE GAS
H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H331 - TOXIC IF INHALED
H314 - CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H400 - VERY TOXIC TO AQUATIC LIFE
CGA-HG22 - CORROSIVE TO THE RESPIRATORY TRACT
Precautionary statements (GHS-US) : P202 - Do not handle until all safety precautions have been read and understood
P210 - Keep away from Heat, Open flames, Sparks, Hot surfaces. - No smoking
P260 - Do not breathe gas
P262 - Do not get in eyes, on skin, or on clothing.
P271+P403 - Use and store only outdoors or in a well-ventilated place.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, eye protection, face protection
P377 - Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 - Eliminate all ignition sources if safe to do so
P501 - Dispose of contents/container in accordance with container supplier/owner instructions
CGA-PG05 - Use a back flow preventive device in the piping.
EN (English US) SDS ID: P-4562 1/9
This document is only controlled while on the Praxair, Inc. website and a copy of this controlled version is available for download.
Praxair cannot assure the integrity or accuracy of any version of this document after it has been downloaded or removed from our website.
Ammonia, anhydrous
CGA-PG20+CGA-PG10 - Use only with equipment of compatible materials of construction and

rated for cylinder pressure.
CGA-PG12 - Do not open valve until connected to equipment prepared for use.
CGA-PG06 - Close valve after each use and when empty.
CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F).
2.3. Other hazards

Other hazards not contributing to the : Contact with liquid may cause cold burns/frostbite.
classification
2.4. Unknown acute toxicity (GHS US)
No data available
SECTION 3: Composition/information on ingredients

3.1. Substance
Name Product identifier %
Ammonia, anhydrous (CAS No) 7664-41-7 100
(Main constituent)
3.2. Mixture
Not applicable
SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures after inhalation : Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep
victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped.
First-aid measures after skin contact : In case of contact, immediately flush affected areas with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Call a physician. Wash clothing before reuse.
Discard contaminated shoes.
First-aid measures after eye contact : Immediately flush eyes thoroughly with water for at least 15 minutes. Hold the eyelids open and
away from the eyeballs to ensure that all surfaces are flushed thoroughly. Contact an
ophthalmologist immediately. Get immediate medical attention.
First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.
4.2. Most important symptoms and effects, both acute and delayed
No additional information available
4.3. Indication of any immediate medical attention and special treatment needed
Treat with corticosteroid spray as soon as possible after inhalation. Obtain medical assistance.
SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Carbon dioxide, Dry chemical, Water spray or fog.
5.2. Special hazards arising from the substance or mixture
Reactivity : No reactivity hazard other than the effects described in sub-sections below.
5.3. Advice for firefighters
Firefighting instructions : Take care not to extinguish flames. If flames are accidentally extinguished, explosive re-
ignition may occur. Allow fire to burn out.
Evacuate all personnel from the danger area. Use self-contained breathing apparatus (SCBA)
and protective clothing. Immediately cool containers with water from maximum distance. Stop
flow of gas if safe to do so, while continuing cooling water spray. Remove ignition sources if
safe to do so. Remove containers from area of fire if safe to do so. On-site fire brigades must
comply with OSHA 29 CFR 1910.156 and applicable standards under 29 CFR 1910 Subpart
L—Fire Protection.
Protection during firefighting : Compressed gas: asphyxiant. Suffocation hazard by lack of oxygen.
Special protective equipment for fire fighters : Wear gas tight chemically protective clothing in combination with self contained breathing
apparatus. Standard protective clothing and equipment (Self Contained Breathing Apparatus)
for fire fighters.
Ammonia, anhydrous
Other information : Heat of fire can build pressure in cylinder and cause it to rupture. No part of a cylinder should
be subjected to a temperature higher than 125ºF (52ºC). Cylinders are equipped with a
pressure-relief device. (Exceptions may exist where authorized by DOT, in this case where
cylinders contain less than 165 pounds of product.) If leaking or spilled product catches fire, do
not extinguish flames. Flammable and toxic vapors may spread from leak and could explode if
reignited. Vapors can be ignited by pilot lights, other flames, smoking, sparks, heaters,
electrical equipment, static discharge, or other ignition sources at locations distant from product
handling point. Explosive atmospheres may linger. Before entering area, especially confined
areas, check atmosphere with an appropriate device. Reverse flow into cylinder may cause
rupture. To protect persons from cylinder fragments and toxic fumes if a rupture occurs, totally
evacuate the area if the fire cannot be brought under immediate control.
SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : Evacuate personnel to a safe area. Appropriate self-contained breathing apparatus may be
required. Approach suspected leak area with caution. Remove all sources of ignition. if safe
to do so. Reverse flow into cylinder may cause rupture. Reduce gas with fog or fine water
spray. Stop flow of product if safe to do so. Ventilate area or move container to a well-
ventilated area. Flammable gas may spread from leak. Before entering the area, especially a
confined area, check the atmosphere with an appropriate device.
6.1.1. For non-emergency personnel

6.1.2. For emergency responders
6.2. Environmental precautions
Prevent waste from contaminating the surrounding environment. Prevent soil and water pollution.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Contact supplier for any special requirements.
6.3. Methods and material for containment and cleaning up
6.4. Reference to other sections
See also sections 8 and 13.
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Do not breathe gas/vapor. Avoid all contact with skin, eyes, or clothing. Emergency eye wash
fountains and safety showers should be available in the immediate vicinity of any potential
exposure.
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Use only non-sparking tools. Use only explosion-proof equipment.
Wear leather safety gloves and safety shoes when handling cylinders. Protect cylinders from
physical damage; do not drag, roll, slide or drop. While moving cylinder, always keep in place
removable valve cover. Never attempt to lift a cylinder by its cap; the cap is intended solely to
protect the valve. When moving cylinders, even for short distances, use a cart (trolley, hand
truck, etc.) designed to transport cylinders. Never insert an object (e.g., wrench, screwdriver,
pry bar) into cap openings; doing so may damage the valve and cause a leak. Use an
adjustable strap wrench to remove over-tight or rusted caps. Slowly open the valve. If the
valve is hard to open, discontinue use and contact your supplier. Close the container valve
after each use; keep closed even when empty. Never apply flame or localized heat directly to
any part of the container. High temperatures may damage the container and could cause the
pressure relief device to fail prematurely, venting the container contents. For other precautions
in using this product, see section 16.
Ammonia, anhydrous
7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Store in a cool, well-ventilated place. Store and use with adequate ventilation. Store only
where temperature will not exceed 125°F (52°C). Firmly secure containers upright to keep
them from falling or being knocked over. Install valve protection cap, if provided, firmly in place
by hand. Store full and empty containers separately. Use a first-in, first-out inventory system
to prevent storing full containers for long periods.
OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product
under pressure, use piping and equipment adequately designed to withstand the pressures to
be encountered. Never work on a pressurized system. Use a back flow preventive device in
the piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use
with adequate ventilation. If a leak occurs, close the container valve and blow down the system
in a safe and environmentally correct manner in compliance with all international,
federal/national, state/provincial, and local laws; then repair the leak. Never place a container
where it may become part of an electrical circuit.
7.3. Specific end use(s)
None.
SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Ammonia, anhydrous (7664-41-7)
ACGIH ACGIH TLV-TWA (ppm) 25 ppm
ACGIH ACGIH TLV-STEL (ppm) 35 ppm
USA OSHA OSHA PEL (TWA) (mg/m³) 35 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 50 ppm
8.2. Exposure controls

Appropriate engineering controls : Use a local exhaust system, if necessary, to prevent oxygen deficiency and to keep hazardous
fumes and gases below all applicable limits in the worker's breathing zone. MECHANICAL
ENGINEERING CONTROLS: Not recommended as a primary ventilation system to control
worker's exposure. USE ONLY IN A CLOSED SYSTEM. An explosion-proof, corrosion-
resistant, forced-draft fume hood is preferred.
Personal protective equipment : Wear metatarsal shoes and work gloves for cylinder handling, and protective clothing where
needed. Wear appropriate chemical gloves (e.g. neoprene, nitrile, etc.) during cylinder
changeout or wherever contact with product is possible. Select per OSHA 29 CFR 1910.132,
1910.136, and 1910.138.
Eye protection : Wear safety glasses when handling cylinders; vapor-proof goggles and a face shield during
cylinder changeout or whenever contact with product is possible. Select eye protection in
accordance with OSHA 29 CFR 1910.133.
Skin and body protection : Wear metatarsal shoes and work gloves for cylinder handling, and protective clothing where
needed. Wear appropriate chemical gloves (e.g. neoprene, nitrile, etc.) during cylinder
changeout or wherever contact with product is possible. Select per OSHA 29 CFR 1910.132,
1910.136, and 1910.138.
Respiratory protection : When workplace conditions warrant respirator use, follow a respiratory protection program that
meets OSHA 29 CFR 1910.134, ANSI Z88.2, or MSHA 30 CFR 72.710 (where applicable).
Use an air-supplied or air-purifying cartridge if the action level is exceeded. Ensure that the
respirator has the appropriate protection factor for the exposure level. If cartridge type
respirators are used, the cartridge must be appropriate for the chemical exposure (e.g., an
organic vapor cartridge). For emergencies or instances with unknown exposure levels, use a
self-contained breathing apparatus (SCBA).
Thermal hazard protection : Wear cold insulating gloves when transfilling or breaking transfer connections.
Environmental exposure controls : Refer to local regulations for restriction of emissions to the atmosphere. See section 13 for
specific methods for waste gas treatment.
Other information : Keep suitable chemically resistant protective clothing readily available for emergency use.
Wear leather safety gloves and safety shoes when handling cylinders.
Ammonia, anhydrous
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Gas
Appearance : Colorless gas. Liquid under pressure.
Molecular mass : 17 g/mol
Color : Colorless.
Odor : Ammoniacal.
Odor threshold : No data available
pH : Not applicable.
Relative evaporation rate (butyl acetate=1) : No data available
Relative evaporation rate (ether=1) : Not applicable.
Melting point : -77.7 °C
Freezing point : No data available
Boiling point : -33 °C
Flash point : No data available
Critical temperature : 132 °C
Auto-ignition temperature : 650 °C
Decomposition temperature : No data available
Flammability (solid, gas) : ≥ 16 vol % 25
Vapor pressure : 860 kPa
Critical pressure : 11350 kPa
Relative vapor density at 20 °C : No data available
Relative density : 0.7
Density : 0.682 g/cm³ (at -33 °C)
Relative gas density : 0.6
Solubility : Water: 517000 mg/l
Log Pow : Not applicable.
Log Kow : Not applicable.
Viscosity, kinematic : Not applicable.
Viscosity, dynamic : Not applicable.
Explosive properties : Not applicable.
Oxidizing properties : None.
Explosion limits : No data available
9.2. Other information
Gas group : Liquefied gas
Additional information : None.
SECTION 10: Stability and reactivity

10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions may occur on contact with certain chemicals. (Refer to the list of incompatible
materials section 10: "Stability-Reactivity").
10.4. Conditions to avoid
Avoid moisture in installation systems.
Ammonia, anhydrous
10.5. Incompatible materials

Gold, silver, mercury, Oxidizing agents, Halogens, Halogenated compounds, Acids, Copper, Zinc,
Copper/Zinc alloys (Brass), Chlorates.
10.6. Hazardous decomposition products
The normal products of combustion are nitrogen and water. Hydrogen may be formed at
temperatures above 1,544°F (840°C).
SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity : Inhalation: TOXIC IF INHALED.

Ammonia, anhydrous ( \f )7664-41-7
LC50 inhalation rat (ppm) 7338 ppm/1h
ATE US (gases) 700.000 ppmV/4h
ATE US (vapors) 3.000 mg/l/4h
ATE US (dust, mist) 0.500 mg/l/4h
Skin corrosion/irritation : CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.

pH: Not applicable.
Serious eye damage/irritation : Not classified
pH: Not applicable.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated : Not classified
exposure)
Aspiration hazard : Not classified
SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : VERY TOXIC TO AQUATIC LIFE. No ecological damage caused by this product.
LC50 fish 1 0.44 mg/l (Exposure time: 96 h - Species: Cyprinus carpio)
EC50 Daphnia 1 25.4 mg/l (Exposure time: 48 h - Species: Daphnia magna)
LC50 fish 2 0.26 - 4.6 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus)
12.2. Persistence and degradability

Persistence and degradability The substance is biodegradable. Unlikely to persist.
12.3. Bioaccumulative potential

Log Pow Not applicable.
Log Kow Not applicable.
Bioaccumulative potential Not expected to bioaccumulate due to the low log Kow (log Kow < 4). Refer to section 9.
12.4. Mobility in soil

Mobility in soil No data available.
Ecology - soil Because of its high volatility, the product is unlikely to cause ground or water pollution.
Ammonia, anhydrous
12.5. Other adverse effects

Other adverse effects : May cause pH changes in aqueous ecological systems.
Effect on ozone layer : None.
Effect on the global warming : No known effects from this product.
SECTION 13: Disposal considerations

13.1. Waste treatment methods
Waste disposal recommendations : Do not attempt to dispose of residual or unused quantities. Return container to supplier.
SECTION 14: Transport information

In accordance with DOT
Transport document description : UN1005 Ammonia, anhydrous, 2.2
UN-No.(DOT) : UN1005
Proper Shipping Name (DOT) : Ammonia, anhydrous
Department of Transportation (DOT) Hazard : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115
Classes
Hazard labels (DOT) : 2.2 - Non-flammable gas
DOT Symbols : D - Proper shipping name for domestic use only, or to and from Canada
DOT Special Provisions (49 CFR 172.102) : 13 - The words Inhalation Hazard shall be entered on each shipping paper in association with
the shipping description, shall be marked on each non-bulk package in association with the
proper shipping name and identification number, and shall be marked on two opposing sides of
each bulk package. Size of marking on bulk package must conform to 172.302(b) of this
subchapter. The requirements of 172.203(m) and 172.505 of this subchapter do not apply.
T50 - When portable tank instruction T50 is referenced in Column (7) of the 172.101 Table, the
applicable liquefied compressed gases are authorized to be transported in portable tanks in
accordance with the requirements of 173.313 of this subchapter.
Marine pollutant : Yes
Additional information
Emergency Response Guide (ERG) Number : 125 (UN1005);154 (UN2672)
Other information : No supplementary information available.

Special transport precautions : Avoid transport on vehicles where the load space is not separated from the driver's
compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows
what to do in the event of an accident or an emergency. Before transporting product containers:
- Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure
cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided)
is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.
Transport by sea
UN-No. (IMDG) : 1005
Proper Shipping Name (IMDG) : AMMONIA, ANHYDROUS
Class (IMDG) : 2 - Gases
MFAG-No : 125
Ammonia, anhydrous
Air transport
UN-No.(IATA) : 1005
Proper Shipping Name (IATA) : Ammonia, anhydrous
Class (IATA) : 2
Civil Aeronautics Law : Gases under pressure/Gases toxic under pressure
SECTION 15: Regulatory information

15.1. US Federal regulations
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Listed on the United States SARA Section 302
Listed on United States SARA Section 313

SARA Section 302 Threshold Planning Quantity 500
(TPQ)
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Delayed (chronic) health hazard
Sudden release of pressure hazard
Fire hazard
SARA Section 313 - Emission Reporting 1.0 % (includes anhydrous Ammonia and aqueous Ammonia from water
dissociable Ammonium salts and other sources, 10% of total aqueous Ammonia is
reportable under this listing)
Chemical(s) subject to the reporting requirements of Section 313 or Title III of the
Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR
Part 372.
Ammonia, anhydrous CAS No 7664-41-7 100%
15.2. International regulations

CANADA

Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations

Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
15.2.2. National regulations

Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Japanese Poisonous and Deleterious Substances Control Law
Listed on the Canadian IDL (Ingredient Disclosure List)
15.3. US State regulations

Ammonia, anhydrous(7664-41-7)
U.S. - California - Proposition 65 - Carcinogens List No
U.S. - California - Proposition 65 - Developmental No
Toxicity
U.S. - California - Proposition 65 - Reproductive No
Toxicity - Female
Ammonia, anhydrous
Ammonia, anhydrous(7664-41-7)
U.S. - California - Proposition 65 - Reproductive No
Toxicity - Male
State or local regulations U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
California Proposition 65 - This product contains, or may contain, trace quantities of a substance(s) known to the state of
California to cause cancer and/or reproductive toxicity
SECTION 16: Other information

Revision date : 3/23/2015 12:00:00 AM
Other information : When you mix two or more chemicals, you can create additional, unexpected hazards. Obtain
and evaluate the safety information for each component before you produce the mixture.
Consult an industrial hygienist or other trained person when you evaluate the end product.
Before using any plastics, confirm their compatibility with this product.
Praxair asks users of this product to study this SDS and become aware of the product hazards
and safety information. To promote safe use of this product, a user should (1) notify
employees, agents, and contractors of the information in this SDS and of any other known
product hazards and safety information, (2) furnish this information to each purchaser of the
product, and (3) ask each purchaser to notify its employees and customers of the product
hazards and safety information.
The opinions expressed herein are those of qualified experts within Praxair, Inc. We believe
that the information contained herein is current as of the date of this Safety Data Sheet. Since
the use of this information and the conditions of use are not within the control of Praxair, Inc., it
is the user's obligation to determine the conditions of safe use of the product.
Praxair SDSs are furnished on sale or delivery by Praxair or the independent distributors and
suppliers who package and sell our products. To obtain current SDSs for these products,
contact your Praxair sales representative, local distributor, or supplier, or download from
www.praxair.com. If you have questions regarding Praxair SDSs, would like the document
number and date of the latest SDS, or would like the names of the Praxair suppliers in your
area, phone or write the Praxair Call Center (Phone: 1-800-PRAXAIR/1-800-772-9247;
Address: Praxair Call Center, Praxair, Inc., P.O. Box 44, Tonawanda, NY 14151-0044).
PRAXAIR and the Flowing Airstream design are trademarks or registered trademarks of Praxair
Technology, Inc. in the United States and/or other countries.
NFPA health hazard : 3 - Short exposure could cause serious temporary or

residual injury even though prompt medical attention was
given.
NFPA fire hazard : 1 - Must be preheated before ignition can occur.
NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,
and are not reactive with water.
HMIS III Rating

Health : 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is
given
Flammability : 1 Slight Hazard
Physical : 2 Moderate Hazard
SDS US (GHS HazCom 2012) - Praxair
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product.
SAFETY DATA SHEET
SABIC® Methanol
Section 1. Identification
SABIC® Methanol : GHS product identifier
methanol : Chemical name
Methyl alcohol; Wood spirit; Wood naphtha; Wood alcohol; Pyroligneous spirit; : Other means of
Columbian spirits; Carbinol; Methanol (I); Methyl alcohol (I) identification
Liquid. : Product type
Annex II : MARPOL category
Intermediate. Solvent. Fuel additive. : Use of the substance/
mixture
Saudi Basic Industries Corporation (SABIC) : Supplier's details
P.O. Box 5101
Riyadh, 11422
Kingdom of Saudi Arabia
Asia Pacific: 001-760-476-3960 (0-24h) : Emergency telephone

Middle East: 001-760-476-3959 (0h - 24h) number (with hours of
Australia: +61 1 800 686 (0-24h) operation)
New Zealand: +64 0800 451719 (0-24h)
SABIC Access Code: 333619
Section 2. Hazards identification

FLAMMABLE LIQUIDS - Category 2 : Classification of the
ACUTE TOXICITY (oral) - Category 3 substance or mixture
ACUTE TOXICITY (dermal) - Category 3
ACUTE TOXICITY (inhalation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (central nervous
system (CNS), optic nerve) - Category 1
GHS label elements

: Hazard pictograms
Danger : Signal word

Highly flammable liquid and vapor. : Hazard statements
Toxic if swallowed, in contact with skin or if inhaled.
Causes damage to organs. (central nervous system (CNS), optic nerve)
Precautionary statements
Wear protective gloves: > 8 hours (breakthrough time): butyl rubber. Wear : Prevention
protective clothing. Wear eye or face protection: Recommended: full-face mask.
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking. Use only outdoors or in a well-ventilated area. Do not breathe vapor.
Do not eat, drink or smoke when using this product. Wash hands thoroughly after
handling.
IF exposed or concerned: Call a POISON CENTER or physician. IF INHALED: : Response
Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER or physician. IF SWALLOWED: Immediately call a POISON CENTER or
physician. Rinse mouth. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. IF ON SKIN: Take off immediately
all contaminated clothing and wash it before reuse. Wash with plenty of soap and
water. Call a POISON CENTER or physician if you feel unwell.
Store locked up. : Storage
Dispose of contents and container in accordance with all local, regional, national : Disposal
and international regulations.
10/4/2018 : Date of issue/Date of revision 10 : Version

Page: 2/11 SABIC® Methanol
Section 2. Hazards identification
Prolonged or repeated contact may dry skin and cause irritation. : Other hazards which do not
result in classification
Section 3. Composition/information on ingredients

Substance : Substance/mixture
methanol : Chemical name
Methyl alcohol; Wood spirit; Wood naphtha; Wood alcohol; Pyroligneous spirit; : Other means of
Columbian spirits; Carbinol; Methanol (I); Methyl alcohol (I) identification
CAS number/other identifiers

67-56-1 : CAS number
200-659-6 : EC number
CAS number % Ingredient name
67-56-1 ≥99.85 methanol
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures

Description of necessary first aid measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower : Eye contact
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention. If necessary, call a poison center or physician.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. : Inhalation
If it is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. If not breathing, if breathing is irregular
or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel. It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. Get medical attention. If necessary, call a poison center or physician.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.
Wash skin thoroughly with soap and water or use recognized skin cleanser. : Skin contact
Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves. Continue to rinse for at least 10
minutes. Get medical attention. If necessary, call a poison center or physician.
Wash clothing before reuse. Clean shoes thoroughly before reuse.
Get medical attention immediately. Call a poison center or physician. Wash out : Ingestion
mouth with water. Remove dentures if any. Remove victim to fresh air and keep at
rest in a position comfortable for breathing. If material has been swallowed and the
exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to
an unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a
collar, tie, belt or waistband.
Most important symptoms/effects, acute and delayed

Potential acute health effects
No known significant effects or critical hazards. : Eye contact
Toxic if inhaled. : Inhalation

Section 4. First aid measures

Toxic in contact with skin. Defatting to the skin. May cause skin dryness and : Skin contact
irritation.
Toxic if swallowed. : Ingestion
Over-exposure signs/symptoms
No specific data. : Eye contact
nausea or vomiting : Inhalation
central nervous system depression
Permanent vision changes, loss of vision or total blindness.
Severe over-exposure can result in death.
Adverse symptoms may include the following: : Skin contact
irritation
dryness
cracking
nausea or vomiting : Ingestion
Indication of immediate medical attention and special treatment needed, if necessary

Treat symptomatically. Contact poison treatment specialist immediately if large : Notes to physician
quantities have been ingested or inhaled. Symptoms may occur after a latency
period has elapsed.
Antidote exists. Medical staff should contact Poisons Information Center. : Specific treatments
No action shall be taken involving any personal risk or without suitable training. If it : Protection of first-aiders
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11)
Section 5. Fire-fighting measures

Extinguishing media
Use dry chemical, CO₂, alcohol-resistant foam or water spray (fog). : Suitable extinguishing
media
Do not use water jet. : Unsuitable extinguishing
media
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion : Specific hazards arising
hazard. In a fire or if heated, a pressure increase will occur and the container may from the chemical
burst, with the risk of a subsequent explosion.
Decomposition products may include the following materials: : Hazardous thermal
carbon dioxide decomposition products
carbon monoxide
Promptly isolate the scene by removing all persons from the vicinity of the incident if : Special protective actions
there is a fire. No action shall be taken involving any personal risk or without for fire-fighters
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Fire-fighters should wear appropriate protective equipment and self-contained : Special protective
breathing apparatus (SCBA) with a full face-piece operated in positive pressure equipment for fire-fighters
mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
No action shall be taken involving any personal risk or without suitable training. : For non-emergency
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from personnel
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate.
Put on appropriate personal protective equipment.
If specialized clothing is required to deal with the spillage, take note of any : For emergency responders
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".
Avoid dispersal of spilled material and runoff and contact with soil, waterways, : Environmental precautions
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and : Small spill
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and : Large spill
explosion-proof equipment. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilled product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.
Section 7. Handling and storage

Eating, drinking and smoking should be prohibited in areas where this material is : Precautions for safe
handled, stored and processed. Workers should wash hands and face before handling
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved : Conditions for safe storage,
area. Store in original container protected from direct sunlight in a dry, cool and well- including any
ventilated area, away from incompatible materials (see section 10) and food and incompatibilities
drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing
materials. Keep container tightly closed and sealed until ready for use. Containers
that have been opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabeled containers. Use appropriate containment to
avoid environmental contamination. See Section 10 for incompatible materials
before handling or use.
Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits

Section 8. Exposure controls/personal protection

Exposure limits Product/ingredient name
ACGIH TLV (United States, 3/2017). methanol
Absorbed through skin. Notes:
Substances for which there is a
Biological Exposure Index or Indices
STEL: 328 mg/m³ 15 minutes.
STEL: 250 ppm 15 minutes.
TWA: 262 mg/m³ 8 hours.
TWA: 200 ppm 8 hours.
If this product contains ingredients with exposure limits, personal, workplace : Recommended monitoring
atmosphere or biological monitoring may be required to determine the effectiveness procedures
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring
standards. Reference to national guidance documents for methods for the
determination of hazardous substances will also be required.
Use only with adequate ventilation. Use process enclosures, local exhaust : Appropriate engineering
ventilation or other engineering controls to keep worker exposure to airborne controls
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapor or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
Emissions from ventilation or work process equipment should be checked to ensure : Environmental exposure
they comply with the requirements of environmental protection legislation. In some controls
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures

Wash hands, forearms and face thoroughly after handling chemical products, before : Hygiene measures
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Safety eyewear complying with an approved standard should be used when a risk : Eye/face protection
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: safety glasses with
side-shields. Recommended: full-face mask
Chemical-resistant, impervious gloves complying with an approved standard should : Hand protection
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated. > 8 hours (breakthrough time): butyl rubber
Personal protective equipment for the body should be selected based on the task : Body protection
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
Appropriate footwear and any additional skin protection measures should be : Other skin protection
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Based on the hazard and potential for exposure, select a respirator that meets the : Respiratory protection
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use. Recommended: self-contained breathing apparatus (SCBA)

Section 9. Physical and chemical properties

Appearance
Liquid. : Physical state
Colorless. : Color
Pungent. [Slight] : Odor
Not available. : Odor threshold
Not available. : pH
-97.5°C (-143.5°F) : Melting point/freezing point
64.5°C (148.1°F) : Boiling point
Closed cup: 9.7°C (49.5°F) : Flash point
Open cup: 15.85°C (60.5°F)
Not applicable. : Burning time
Not applicable. : Burning rate
2.1 (butyl acetate = 1) : Evaporation rate
Not available. : Flammability (solid, gas)
Lower: 6% : Lower and upper explosive
Upper: 36.5% (flammable) limits
16.9 kPa [at Temperature (°C): 25°C] : Vapor pressure
1 [Air = 1] : Vapor density
≤0.7928 : Relative density
Not available. : Solubility
Not available.
Not available. : Partition coefficient: n-
octanol/water
455°C (851°F) : Auto-ignition temperature
Not available. : Decomposition temperature
Not available. : SADT
Dynamic (room temperature): 0.54 to 0.59 mPa·s (0.54 to 0.59 cP) : Viscosity
Section 10. Stability and reactivity

No specific test data related to reactivity available for this product or its ingredients. : Reactivity
The product is stable. : Chemical stability
Under normal conditions of storage and use, hazardous reactions will not occur. : Possibility of hazardous
reactions
Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, : Conditions to avoid
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Reactive or incompatible with the following materials: : Incompatible materials

oxidizing materials
Under normal conditions of storage and use, hazardous decomposition products : Hazardous decomposition
should not be produced. products

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Exposure Dose Species Result Product/ingredient name
4 hours 128200 mg/m³ Rat LC50 Inhalation Vapor methanol
- 17100 mg/kg Rabbit LD50 Dermal
- 1187 to 2769 Rat LD50 Oral
mg/kg
- 300 to 1000 mg/ Human LDLo Oral
kg
Special remarks on other toxic effects on humans; acidosis : Conclusion/Summary
Irritation/Corrosion
Conclusion/Summary
Prolonged or repeated contact with skin or mucous membrane may result in : Skin
irritation symptoms, such as redness, blistering, dermatitis etc.
Slightly irritating to the eyes. : Eyes
Sensitization
Not available.
Conclusion/Summary
Non-sensitizer to skin. : Skin
Non-sensitizer to lungs. : Respiratory
Mutagenicity
No known significant effects or critical hazards. : Conclusion/Summary
Carcinogenicity
Based on available data, the classification criteria are not met. : Conclusion/Summary
Reproductive toxicity
Exposure Dose Species Development Fertility Maternal Product/ingredient name
toxin toxicity
- Inhalation: Rat - Male, Female Positive - Negative methanol
1330 mg/
m³ NOEC
- Inhalation: Mouse - Male, Positive - Negative
1330 mg/ Female
m³ NOEC
Developmental Toxicity: Mice, Rats. Not suspected for humans. : Conclusion/Summary
Teratogenicity
Exposure Dose Species Result Product/ingredient name
- 1330 mg/m³ Rat - Male, Positive - Inhalation methanol
NOEC Female
- 1330 mg/m³ Mouse - Male, Positive - Inhalation
NOEC Female
Developmental Toxicity: Mice, Rats. Not suspected for humans. : Conclusion/Summary
Specific target organ toxicity (single exposure)
Target organs Route of Category Name
exposure
central nervous All Category 1 methanol
system (CNS) and
optic nerve
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.

Routes of entry anticipated: Oral, Dermal, Inhalation. : Information on the likely

routes of exposure
Potential acute health effects
No known significant effects or critical hazards. : Eye contact
Toxic if inhaled. : Inhalation
Toxic in contact with skin. Defatting to the skin. May cause skin dryness and : Skin contact
irritation.
Toxic if swallowed. : Ingestion
Symptoms related to the physical, chemical and toxicological characteristics

No specific data. : Eye contact
nausea or vomiting : Inhalation
Adverse symptoms may include the following: : Skin contact
irritation
dryness
cracking
nausea or vomiting : Ingestion
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Not available. : Potential immediate
effects
Not available. : Potential delayed effects
Long term exposure
Not available. : Potential immediate
effects
Not available. : Potential delayed effects
Potential chronic health effects
Not available.
Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/ : General
or dermatitis.
No known significant effects or critical hazards. : Carcinogenicity
No known significant effects or critical hazards. : Mutagenicity
No known significant effects or critical hazards. : Teratogenicity
No known significant effects or critical hazards. : Developmental effects
No known significant effects or critical hazards. : Fertility effects
Numerical measures of toxicity

Acute toxicity estimates
ATE value Route
100 mg/kg Oral
300 mg/kg Dermal
3 mg/l Inhalation (vapors)

Section 12. Ecological information

Toxicity
Exposure Species Result Product/ingredient name
15 hours Micro-organism EC50 20000 mg/l Fresh water methanol
48 hours Daphnia Acute EC50 >10000 mg/l Fresh water
3 minutes Micro-organism - Tubiflex Acute EC50 71700 mg/l
tubiflex
48 hours Crustaceans - Crangon crangon Acute LC50 2500 mg/l Marine water
- Adult
48 hours Daphnia - Daphnia magna - Acute LC50 3289 to 4395 mg/l Fresh
Neonate water
96 hours Fish - Lepomis macrochirus Acute LC50 15400 mg/l Fresh water
96 hours Fish - Danio rerio - Egg Acute LC50 290 mg/l Fresh water
96 hours Algae - Selenastrum Chronic EC50 22000 mg/l Fresh water
capricornutum
200 hours Fish - Oryzias latipes - Juvenile Chronic NOEC 7900 mg/l Fresh water
(Fledgling, Hatchling, Weanling)
Persistence and degradability

Inoculum Dose Result Test Product/ingredient name
Fresh water - 83 to 91 % - 3 days 311 Anaerobic methanol
sediment Biodegradation
of Organic
Compounds in
Digested Sludge
- Method by
Measurement of
Gas Production
Soil - 53.4 % - 5 days Aerobic
Soil - 53.4 % - 5 days Anaerobic
Biodegradability Photolysis Aquatic half-life Product/ingredient name

Inherent 50%; 17 day(s) - methanol
Bioaccumulative potential
Potential BCF LogPow Product/ingredient name
low <10 - methanol
Mobility in soil
0.13 to 1 : Soil/water partition
coefficient (KOC)
No known significant effects or critical hazards. : Other adverse effects
Section 13. Disposal considerations

The generation of waste should be avoided or minimized wherever possible. : Disposal methods
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible. This material and
Section 13. Disposal considerations

its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Vapor from product residues
may create a highly flammable or explosive atmosphere inside the container. Do
not cut, weld or grind used containers unless they have been cleaned thoroughly
internally. Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers.
Section 14. Transport information

IATA IMDG UN
UN1230 UN1230 UN1230 UN number
Methanol METHANOL METHANOL UN proper

shipping name
3 (6.1) 3 (6.1) 3 (6.1) Transport hazard
class(es)
II II II Packing group
No. No. No. Environmental
hazards
Quantity limitation Emergency schedules F-E, Special provisions 279 Additional

Passenger and Cargo Aircraft: S-D information
1 L. Packaging instructions: Special provisions 279
352. Cargo Aircraft Only: 60 Remarks This product is
L. Packaging instructions: 364. being carried under the scope
Limited Quantities - of Annex II (MARPOL)
Passenger Aircraft: 1 L.
Packaging instructions: Y341.
Special provisions A113
Transport in bulk according

to Annex II of MARPOL and
the IBC Code
Methyl alcohol : Proper shipping name
3 : Ship type
Y : Pollution category
Section 15. Regulatory information

No known specific national and/or regional regulations applicable to this product : Safety, health and
(including its ingredients). environmental regulations
specific for the product
Chemical Weapons : Not listed

Convention List Schedule I
Chemicals
Convention List Schedule II
Chemicals
Convention List Schedule III
Chemicals

Section 15. Regulatory information

: National Fire Protection
Association (U.S.A.)
3 Flammability
Health 1 0 Instability/Reactivity
Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be
interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Section 16. Other information

History
10/4/2018 : Date of printing
10/4/2018 : Date of issue/Date of
revision
9/19/2018 : Date of previous issue
10 : Version
ADN = European Provisions concerning the International Carriage of Dangerous : Key to abbreviations
Goods by Inland Waterway
ADR = The European Agreement concerning the International Carriage of
Dangerous Goods by Road
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
RID = The Regulations concerning the International Carriage of Dangerous Goods
by Rail
UN = United Nations
Chemical Safety Report : References
Indicates information that has changed from previously issued version.
Notice to reader
The information contained in the Safety Data Sheet is at the date of its issuance to the best of our knowledge
correct according to the data available to us. The information is meant as a guideline for safe use, handling,
disposal, storage and transport of products and does not imply any warranty (not implied nor explicitly) or
specification. The Supplier shall to the extent permitted by law not be liable for any error or incorrectness in
the information contained in this Safety Data Sheet. The information relates exclusively to the specified
products, which may not be suitable for combination with other materials or use in processes other than
those specifically described here.

Material Safety Data Sheet
Product Name: Caustic Soda

Revision date: R1- 01/01/2018
Section1: Manufacturer and Substance Identification:
CHEMFAB ALKALIS LIMITED

Gnanananda place
Kalapet
Puducherry- 605014
India.
Product Identifier: CAUSTIC SODA LIQUID (31.5% and 48%)
Caustic soda Solution

Sodium hydroxide solution
Caustic Soda lye
CAS #: 1310-73-2 Formula: NaOH

UN #: 1824 Molecular mass: 40.0 g/mol
SECTION 1. Product company identification

Emergency Contact number: 0413- 2655111-113
Email: chemfabalkalis@drraoholings.com
Website: www.chemfabalkalis.com
AMAI CERN NO (Emergency Contact Number): 1800-11-1735
SECTION 2: Composition/Information on ingredients
Component Percent [%] CAS Number
Water 69 - 52 % 7732-18-5
Sodium Hydroxide 31- 48 % 1310-73-2
SECTION 3: Hazard identification
MAJOR HEALTH HAZARDS: CORROSIVE. CAUSES SERIOUS EYE DAMAGE. CAUSES SEVERE SKIN BURNS
CAUSES DAMAGE TO THE RESPIRATORY SYSTEM AND GASTROINTESTINAL SYSTEM. EFFECTS OF CONTACT OR
INHALATION MAY BE DELAYED.
PHYSICAL HAZARDS: MAY BE CORROSIVE TO METALS. Mixing with water, acid or incompatible materials
may cause splattering and release of heat. Do not store in aluminum container or use aluminum fittings or
transfer lines, as flammable hydrogen gas may be generated.
1

SECTION 4: First Aid Measures
INHALATION: If inhalation of mists, vapors, or spray occurs and adverse effects result, remove to
uncontaminated area. Evaluate ABC's (is Airway constricted, is Breathing occurring, and is blood
Circulating) and treat symptomatically. GET MEDICAL ATTENTION IMMEDIATELY. There is no specific
antidote, treat symptomatically.
SKIN CONTACT: Immediately flush contaminated areas with water. Remove contaminated clothing,
jewelry, and shoes immediately. Wash contaminated areas with large amount of water. GET MEDICAL
ATTENTION IMMEDIATELY. Thoroughly clean and dry contaminated clothing before reuse. Discard
contaminated leather goods.
EYE CONTACT: Immediately flush contaminated eyes with a directed stream of water for as long as
possible. Remove contact lenses, if present and easy to do. Continue rinsing. GET MEDICAL ATTENTION
IMMEDIATELY. Washing eyes within several seconds is essential to achieve maximum effectiveness.
INGESTION: If swallowed, do not induce vomiting. For definite or probable ingestion, do not administer
oral fluids. If vomiting occurs spontaneously, keep airway clear. Monitor airway. Volume resuscitation (IV
fluids) and circulatory support (CPR) may be required. Never give anything by mouth to an unconscious
or convulsive person. GET MEDICAL ATTENTION IMMEDIATELY.
SECTION 5: Fire Fighting Measures
Fire Hazard: Non-combustible, substance itself does not burn but may decompose upon heating to
produce corrosive and/or toxic fumes. May react with chemically reactive metals such as aluminum, zinc,
magnesium, copper, etc. to release hydrogen gas which can form explosive mixtures in air.
Extinguishing Media: Use extinguishing agents appropriate for surrounding fire.
Fire Fighting: Move container from fire area if it can be done without risk. Cool containers with water.
Do not apply water directly on this product. Heat is generated when mixed with water.
Component Immediately Dangerous to Life/ Health (IDLH)
Sodium Hydroxide 10 mg/m3 IDLH

1310-73-2
Hazardous Combustion Sodium hydroxide fumes can be generated by thermal decomposition at elevated
Products: temperatures
Sensitivity to Mechanical Not sensitive.

Impact:
Sensitivity to Static Discharge: Not sensitive.
Lower Flammability Level (air): Not flammable
2

Upper Flammability Level (air): Not flammable
Flash point: Not flammable
Auto-ignition Temperature: Not applicable
GHS: PHYSICAL HAZARDS:

- Corrosive to Metals
SECTION 6: Accidental Release Measures
Personal Precautions:
Do not get in eyes, on skin or on clothing. Avoid breathing mist, vapour, or spray. Do not ingest.
Wear appropriate personal protective equipment recommended in Section 8 of the MSDS.
Methods and Materials for Containment and Cleaning Up:

In case of spill or leak, stop the leak as soon as possible, collect spilled materials with dikes, sandbags,
etc. Shovel dry material into suitable container. Liquid material may be removed with a vacuum truck.
Remaining material may be diluted with water and neutralized with dilute acid. Flush spill area with
water, if appropriate.
SECTION 7: Handling and Storage
Precautions for Safe Handling:

Avoid breathing vapor or mist. Do not get in eyes, on skin, or on clothing. Wash thoroughly after
handling. Do not ingest. Do not eat, drink or smoke in areas where this material is used. Wear
personal protective equipment as described in Exposure Controls/Personal Protection.
Safe Storage Conditions:

Store and handle in accordance with all current regulations and standards. Keep container tightly closed
and properly labeled. Do not store in aluminum container or fittings or transfer lines, as flammable
hydrogen gas may be generated.
SECTION 8: Exposure Controls/Personal Protection:
Regulatory Exposure Limit(s): Listed below for the product components that have regulatory
occupational exposure limits (OEL's).
Component OSHA Final PEL

TWA
Sodium Hydroxide 2 mg/m3
1310-73-2
.
PERSONAL PROTECTIVE EQUIPMENT:
Eye Protection: Wear chemical safety goggles with a face-shield to protect against eye and skin
contact when appropriate. Provide an emergency eye wash fountain and quick drench shower in the
immediate work area.
3

Skin and Body Protection: Wear protective clothing to minimize skin contact. Wear chemical
resistant clothing and rubber boots when potential for contact with the material exists. Always place
pants legs over boots. Contaminated clothing should be removed, then discarded or laundered.
Discard contaminated leather goods.
Hand Protection: Wear appropriate chemical resistant gloves. Consult a glove supplier for
assistance in selecting an appropriate chemical resistant glove.
Protective Material Types: Natural rubber, Neoprene, Nitrile, Polyvinyl chloride (PVC),
Respiratory Protection: A NIOSH approved respirator with N95 (dust, fume, mist) cartridges may be
permissible under certain circumstances where airborne concentrations are expected to exceed
exposure limits, or when symptoms have been observed that are indicative of overexposure. If eye
irritation occurs, a full face style mask should be used.
Immediately Dangerous to Life/ Health

Component (IDLH)
Sodium Hydroxide 10 mg/m3 IDLH
1310-73-2
HYGIENE MEASURES: Handle in accordance with good industrial hygiene and safety practices.
Wash hands and affected skin immediately after handling, before breaks, and at the end of the
workday.
SECTION 9: Physical and Chemical Properties.
Physical state : Liquid

Appearance : Clear to opaque
Color : Colorless to slightly colored
Odor : Odorless
Molecular Weight : 40.01
Molecular Formula : NaOH
Vapor Pressure : 13 - 135 mmHg @ 60 °C
Relative Density/Specific Gravity : 1.35–1.56@ 25°C
Water Solubility : 100%
pH : 14.0 (theoretical value of 7.5% solution)
Flash point : Not flammable
Flammability (solid, gas) : Not flammable
Lower Flammability Level (air) : Not flammable
Upper Flammability Level (air) : Not flammable
Auto-ignition Temperature : Not applicable
SECTION 10: Stability and Reactivity.
Reactivity: Soluble in water and reacts with metals, and may form hydrogen gas.
Chemical Stability: Stable at normal temperatures and pressures.
4

SECTION 11: Toxicological Information.
TOXICITY DATA:
Component LD50 Oral: LD50 Dermal: LC50 Inhalation:

Sodium Hydroxide ----- 1350 mg/kg -----
1310-73-2
SECTION 12: Ecological Information.
ECOTOXICITY DATA:
Aquatic Toxicity:
This material has exhibited moderate toxicity to aquatic organisms.
SECTION 13: Disposal Consideration.
Waste from material:

Reuse or reprocess, if possible. May be subject to disposal regulations. Dispose in accordance with all
applicable regulations.
Container Management:
Dispose of container in accordance with applicable local, regional, national, and/or international
regulations. Container reinstate must be disposed of in compliance with applicable regulations.
SECTION 15: Transport Information:
GHS Classification
Signal: Danger
Harmful if swallowed
Causes severe skin burns and eye damage
May cause respiratory irritation
SECTION 15: Regulatory Information:
Occupational exposure limits

TLV: 2mg/m³ (ceiling value)
5

SECTION 16: Other Information:
The Information provided in this MSDS is given in good faith and is correct to the best of our knowledge
and information at the date of Publication. It is designed only a guidance of safe handling, transportation,
use and disposal. No Warranty is expressed or implied.
Contact: Section 1
Disclaimer:
This document is only controlled while on the Chemfab Alkalis Limited. Website and a copy of this
controlled version is available for download. Chemfab Alkalis Ltd cannot assure the integrity or accuracy
of any version of this document after it has been downloaded or removed from our website.
Revision History:
Revision Effective date Changed Date
6
Ganga Rasayanie (P) Ltd. GaroSOL-160
MSDS# 2
Material Safety Data Sheet Effective Date 25/02/2005
Page No.1
SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME : GaroSOL 160

CHEMICAL NAME : Aromatic Hydrocarbons
CHEMICAL FAMILY : Petroleum Hydrocarbons
PETROLEUM RULES CLASS : Class C
PRODUCT DESCRIPTION : Water White Liquid
______________________________________________________________________________
CONTACT ADDRESS:
Ganga Rasayanie (P) Ltd.
50B Harish Mukherjee Road, Kolkata, INDIA 700025
Tel Numbers: (9AM to 5PM M-F)
Head Office: 91 33 24552080 / 5814
Works : 91 2646 253064
______________________________________________________________________________
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Concentration

Aromatic Hydrocarbons 64742-94-5 100% by Weight
______________________________________________________________________________
SECTION 3 HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS

EYE CONTACT: Slightly irritating but does not injure eye tissue.
SKIN CONTACT: Frequent or prolonged contact may irritate and cause dermatitis. Low order of toxicity. Skin contact may aggravate an
existing dermatitis condition.
INHALATION: High vapor/aerosol concentrations (attainable at elevated temperatures well above ambient) are irritating to the eyes and the
respiratory tract, and may cause headaches, dizziness, anesthesia, drowsiness, unconsciousness, and other central nervous system effects,
including death.
INGESTION: Small amounts of this product aspirated into the respiratory system during ingestion or vomiting may cause mild to severe
pulmonary injury, possibly progressing to death. Minimal toxicity.
______________________________________________________________________________
SECTION 4 FIRST AID MEASURES
EYE CONTACT: Flush eyes with large amounts of water until irritation subside. If irritation persists, get medical attention.
SKIN CONTACT: Flush with large amounts of water; use soap if available. Remove grossly contaminated clothing, including shoes, and
launder before reuse.
INHALATION: Using proper respiratory protection, immediately remove the affected victim from exposure. Administer artificial respiration if
breathing is stopped. Keep at rest. Call for prompt medical attention.
INGESTION: If swallowed, DO NOT induce vomiting. Keep at rest. Get prompt medical attention.
SIGN & SYMPTOMS: Respiratory irritation signs and symptoms may include a temporary burning sensation of the nose and throat,
coughing, and/or difficulty breathing. Breathing of high vapour concentrations may cause central nervous system (CNS) depression resulting
in dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness and death.
Skin irritation signs and symptoms may include a burning sensation, redness, swelling, and/or blisters. Eye irritation signs and symptoms may
include a burning sensation, redness, swelling, and/or blurred vision. If material enters lungs, signs and symptoms may include coughing,
choking, wheezing, difficulty in breathing, chest congestion, shortness of breath, and/or fever.
______________________________________________________________________________
SECTION 5 FIRE-FIGHTING MEASURES
FLASH POINT : >68 °C

FLAMMABLE LIMITS : LEL: .8 UEL: 5.9
AUTOIGNITION TEMPERATURE : 480-500 °C
GENERAL HAZARD
Low Hazard, liquid can burn upon heating to temperatures at or above the flashpoint. "Empty" containers retain product residue (liquid and/or
vapor) and can be dangerous. DO NOT pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks,
MSDS# 2
Page No.2
static electricity, or other sources of ignition; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
Empty drums should be completely drained, properly bunged and stored, or properly disposed off.
FIRE FIGHTING Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Do not
discharge extinguishing waters into the aquatic environment. Avoid spraying water directly into storage containers due to danger of boil over.
PROTECTIVE CLOTHINGS FOR FIRE FIGHTING: Wear full protective clothing and self-contained breathing apparatus.
______________________________________________________________________________
SECTION 6 ACCIDENTAL RELEASE MEASURES
Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without hazard. For small spills transfer, by
mechanical means to a labeled, sealed container for product recovery or safe disposal. For large spills transfer to storage tanks by safe means
for recovery. Do not flush residue with water. Allow residue to evaporate or clean with appropriate absorbent and dispose safely. Remove
contaminated soil and dispose safely. If in public area, keep public away and advise authorities. Shut off leaks if possible without personal
risks. Prevent liquid from entering sewers, watercourses, or low areas. Contain spilled liquid with sand or earth. Consult an expert on disposal
of recovered material and ensure conformity to local disposal regulations. For Water Spill, eliminate sources of ignition. Warn occupants and
shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Consult an expert on disposal of
recovered material and ensure conformity to local disposal regulations.
______________________________________________________________________________
SECTION 7 STORAGE AND HANDLING
GENERAL PRECAUTIONS: Avoid breathing of or contact with material. Only use in well ventilated areas. Wash thoroughly after handling.
For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet.
STORAGE AND HANDLING: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from
incompatible materials. Do NOT handle or store near an open flame, heat or other sources of ignition. Protect material from direct sunlight.
Material will accumulate static charges, which may cause an electrical spark (ignition source). Use proper bonding and/or grounding
procedures. Do NOT pressurize, cut, heat, or weld containers. Empty product containers may contain product residue. Do NOT reuse empty
containers without commercial cleaning or reconditioning.
______________________________________________________________________________
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
EXPOSURE CONTROLS The use of local exhaust ventilation is recommended to control process emissions near the source. Laboratory
samples should be handled in a lab hood. Provide mechanical ventilation of confined spaces. See respiratory protection recommendations.
PERSONAL PROTECTION For open systems where contact is likely, wear safety glasses with side shields, long sleeves, and chemical
resistant gloves. Where contact may occur, wear safety glasses with side shields. Where concentrations in air may exceed the limits given in
this Section and engineering, work practice or other means of exposure reduction are not adequate, NIOSH approved respirators may be
necessary to prevent overexposure by inhalation.
______________________________________________________________________________
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE : Water White Liquid

ODOUR : Aromatic
SPECIFIC GRAVITY at 30 °C : 0.890 – 0.892
VAPOR PRESSURE, mmHg at 20 °C : <1.0
SOLUBILITY IN WATER : Insoluble
FREEZING/MELTING POINT IN °C : > -10 °C
EVAPORATION RATE, n-Bu Acetate=1 : <.1
BOILING POINT IN °C : 185-250 °C
AUTO INGINATION TEMPERATURE : 480 - 500 °C
FLASH POINT IN °C : >68 °C
MOLECULAR WEIGHT : 140
______________________________________________________________________________
SECTION 10 STABILITY AND REACTIVITY
STABILITY : Stable under normal condition of use

CONDITIONS TO AVOID INSTABILITY : Not Applicable
HAZARDOUS POLYMERIZATION : Will not occur
CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION : Not Applicable
MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY : Nitric acid, sulfuric acid, strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS : None
MSDS# 2
Page No.3
______________________________________________________________________________
SECTION 11 TOXICOLOGICAL INFORMATION
Please refer to Section 3 for available information on potential health effects.

______________________________________________________________________________
SECTION 12 ECOLOGICAL INFORMATION
Not available.
______________________________________________________________________________
SECTION 13 DISPOSAL CONSIDERATIONS
Follow Local & State Regulatory Measures. Please refer to Sections 5, 6.

______________________________________________________________________________
SECTION 14 TRANSPORT INFORMATION
This product is not DOT regulated. This product is exempted from Hazardous Labeling requirement as per IATA and not classified as
dangerous. This is not classified as dangerous as per IMDG regulations.
______________________________________________________________________________
SECTION 15 REGULATORY INFORMATION
TSCA: This product is listed on the TSCA Inventory as a UVCB (Unknown, Variable Composition or Biological) Chemical at CAS Registry
Number 64742-94-5, Clean Water Act/Oil Pollution Act: This product is classified as an oil under Section 311 of the Clean Water Act (40 CFR
110) and the Oil Pollution Act of 1990.
CERCLA: This product, as sold, is derived from a fraction of crude oil and is excluded from the spill reporting requirements by CERCLA
Section 101(14)(F).
SARA Hazardous Categories (311/312): Under the provisions of Title III, Sections 311/312 of the Superfund Amendments and
Reauthorization Act, this product is classified under Delayed Health Hazard.
______________________________________________________________________________
SECTION 16 OTHER INFORMATION
NOTES & DISCLAIMER:

The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the
purpose of health, safety and environmental requirements only. No warranty or guarantee is expressed or implied regarding the accuracy of
these data or the results to be obtained from the use of the product
MSDS VER : 2.5
EFFECTIVE FROM : 25.02.2005
PREPARED BY : HEALTH & SAFETY DEPT, GRPL.
MSDS DISTRIBUTION : TO ALL HANDLEING THE PRODUCT.
He a lt h 3
0 0
Fire
3 1
Re a c t iv it y 1
P e rs o n a l
P ro t e c t io n

Hydrochloric acid MSDS
Section 1: Chemical Product and Company Identification
Product Name: Hydrochloric acid Contact Information:

Catalog Codes: SLH1462, SLH3154 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: Mixture. Houston, Texas 77396
RTECS: MW4025000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Hydrochloric acid
Order Online: ScienceLab.com
CI#: Not applicable.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Hydrochloric Acid; Muriatic Acid 1-800-424-9300
Chemical Name: Not applicable. International CHEMTREC, call: 1-703-527-3887
Chemical Formula: Not applicable. For non-emergency assistance, call: 1-281-441-4400
Section 2: Composition and Information on Ingredients

Composition:
Name CAS # % by Weight

Hydrogen chloride 7647-01-0 20-38
Water 7732-18-5 62-80
Toxicological Data on Ingredients: Hydrogen chloride: GAS (LC50): Acute: 4701 ppm 0.5 hours [Rat].
Section 3: Hazards Identification
Potential Acute Health Effects:

Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion, . Slightly
hazardous in case of inhalation (lung sensitizer). Non-corrosive for lungs. Liquid or spray mist may produce tissue damage
particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the
spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath.
Severe over-exposure can result in death. Inflammation of the eye is characterized by redness, watering, and itching. Skin
inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Potential Chronic Health Effects:
Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for
human.) by IARC [Hydrochloric acid]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys, liver, mucous membranes, upper
respiratory tract, skin, eyes, Circulatory System, teeth. Repeated or prolonged exposure to the substance can produce target
p. 1
organs damage. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation.
Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial
infection. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one
or many human organs.
Section 4: First Aid Measures
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek immediate medical attention.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
Serious Ingestion: Not available.
Section 5: Fire and Explosion Data
Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: of metals
Explosion Hazards in Presence of Various Substances: Non-explosive in presence of open flames and sparks, of shocks.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards:
Non combustible. Calcium carbide reacts with hydrogen chloride gas with incandescence. Uranium phosphide reacts with
hydrochloric acid to release spontaneously flammable phosphine. Rubidium acetylene carbides burns with slightly warm
hydrochloric acid. Lithium silicide in contact with hydrogen chloride becomes incandescent. When dilute hydrochloric acid is
used, gas spontaneously flammable in air is evolved. Magnesium boride treated with concentrated hydrochloric acid produces
spontaneously flammble gas. Cesium acetylene carbide burns hydrogen chloride gas. Cesium carbide ignites in contact with
hydrochloric acid unless acid is dilute. Reacts with most metals to produce flammable Hydrodgen gas.
Special Remarks on Explosion Hazards:
p. 2
Hydrogen chloride in contact with the following can cause an explosion, ignition on contact, or other violent/vigorous reaction:
Acetic anhydride AgClO + CCl4 Alcohols + hydrogen cyanide, Aluminum Aluminum-titanium alloys (with HCl vapor), 2-Amino
ethanol, Ammonium hydroxide, Calcium carbide Ca3P2 Chlorine + dinitroanilines (evolves gas), Chlorosulfonic acid Cesium
carbide Cesium acetylene carbide, 1,1-Difluoroethylene Ethylene diamine Ethylene imine, Fluorine, HClO4 Hexalithium
disilicide H2SO4 Metal acetylides or carbides, Magnesium boride, Mercuric sulfate, Oleum, Potassium permanganate,
beta-Propiolactone Propylene oxide Rubidium carbide, Rubidium, acetylene carbide Sodium (with aqueous HCl), Sodium
hydroxide Sodium tetraselenium, Sulfonic acid, Tetraselenium tetranitride, U3P4 , Vinyl acetate. Silver perchlorate with carbon
tetrachloride in the presence of hydrochloric acid produces trichloromethyl perchlorate which detonates at 40 deg. C.
Section 6: Accidental Release Measures
Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If
necessary: Neutralize the residue with a dilute solution of sodium carbonate.
Large Spill:
Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material.
Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water spray
to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.
Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a concentration
level above TLV. Check TLV on the MSDS and with local authorities.
Section 7: Handling and Storage
Precautions:
Keep locked up.. Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product.
In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show
the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, organic
materials, metals, alkalis, moisture. May corrode metallic surfaces. Store in a metallic or coated fiberboard drum using a strong
polyethylene inner package.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.
Section 8: Exposure Controls/Personal Protection
Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:
Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
CEIL: 5 (ppm) from OSHA (PEL) [United States] CEIL: 7 (mg/m3) from OSHA (PEL) [United States] CEIL: 5 from NIOSH
CEIL: 7 (mg/m3) from NIOSH TWA: 1 STEL: 5 (ppm) [United Kingdom (UK)] TWA: 2 STEL: 8 (mg/m3) [United Kingdom
(UK)]Consult local authorities for acceptable exposure limits.
Section 9: Physical and Chemical Properties
Physical state and appearance: Liquid.
p. 3
Odor: Pungent. Irritating (Strong.)
Taste: Not available.
Molecular Weight: Not applicable.
Color: Colorless to light yellow.
pH (1% soln/water): Acidic.
Boiling Point:
108.58 C @ 760 mm Hg (for 20.22% HCl in water) 83 C @ 760 mm Hg (for 31% HCl in water) 50.5 C (for 37% HCl in water)
Melting Point:
-62.25°C (-80°F) (20.69% HCl in water) -46.2 C (31.24% HCl in water) -25.4 C (39.17% HCl in water)
Critical Temperature: Not available.
Specific Gravity:
1.1- 1.19 (Water = 1) 1.10 (20%and 22% HCl solutions) 1.12 (24% HCl solution) 1.15 (29.57% HCl solution) 1.16 (32% HCl
solution) 1.19 (37% and 38%HCl solutions)
Vapor Pressure: 16 kPa (@ 20°C) average
Vapor Density: 1.267 (Air = 1)
Volatility: Not available.
Odor Threshold: 0.25 to 10 ppm
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, diethyl ether.
Solubility: Soluble in cold water, hot water, diethyl ether.
Section 10: Stability and Reactivity Data
Stability: The product is stable.

Instability Temperature: Not available.
Conditions of Instability: Incompatible materials, water
Incompatibility with various substances:
Highly reactive with metals. Reactive with oxidizing agents, organic materials, alkalis, water.
Corrosivity:
Extremely corrosive in presence of aluminum, of copper, of stainless steel(304), of stainless steel(316). Non-corrosive in
presence of glass.
Special Remarks on Reactivity:
Reacts with water especially when water is added to the product. Absorption of gaseous hydrogen chloride on mercuric
sulfate becomes violent @ 125 deg. C. Sodium reacts very violently with gaseous hydrogen chloride. Calcium phosphide
and hydrochloric acid undergo very energetic reaction. It reacts with oxidizers releasing chlorine gas. Incompatible with,
alkali metals, carbides, borides, metal oxides, vinyl acetate, acetylides, sulphides, phosphides, cyanides, carbonates. Reacts
with most metals to produce flammable Hydrogen gas. Reacts violently (moderate reaction with heat of evolution) with
water especially when water is added to the product. Isolate hydrogen chloride from heat, direct sunlight, alkalies (reacts
vigorously), organic materials, and oxidizers (especially nitric acid and chlorates), amines, metals, copper and alloys (e.g.
brass), hydroxides, zinc (galvanized materials), lithium silicide (incandescence), sulfuric acid(increase in temperature and
pressure) Hydrogen chloride gas is emitted when this product is in contact with sulfuric acid. Adsorption of Hydrochloric Acid
onto silicon dioxide results in exothmeric reaction. Hydrogen chloride causes aldehydes and epoxides to violently polymerize.
Hydrogen chloride or Hydrochloric Acid in contact with the folloiwng can cause explosion or ignition on contact or
Special Remarks on Corrosivity:
p. 4
Highly corrosive. Incompatible with copper and copper alloys. It attacks nearly all metals (mercury, gold, platinium, tantalum,
silver, and certain alloys are exceptions). It is one of the most corrosive of the nonoxidizing acids in contact with copper alloys.
No corrosivity data on zinc, steel. Severe Corrosive effect on brass and bronze
Polymerization: Will not occur.
Section 11: Toxicological Information
Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation.
Toxicity to Animals:
Acute oral toxicity (LD50): 900 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 1108 ppm, 1 hours [Mouse]. Acute toxicity of
the vapor (LC50): 3124 ppm, 1 hours [Rat].
Chronic Effects on Humans:
CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Hydrochloric acid]. May cause damage to the
following organs: kidneys, liver, mucous membranes, upper respiratory tract, skin, eyes, Circulatory System, teeth.
Other Toxic Effects on Humans:
Very hazardous in case of skin contact (corrosive, irritant, permeator), of ingestion, . Hazardous in case of eye contact
(corrosive), of inhalation (lung corrosive).
Special Remarks on Toxicity to Animals:
Lowest Published Lethal Doses (LDL/LCL) LDL [Man] -Route: Oral; 2857 ug/kg LCL [Human] - Route: Inhalation; Dose: 1300
ppm/30M LCL [Rabbit] - Route: Inhalation; Dose: 4413 ppm/30M
Special Remarks on Chronic Effects on Humans:
May cause adverse reproductive effects (fetoxicity). May affect genetic material.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Corrosive. Causes severe skin irritation and burns. Eyes: Corrosive. Causes severe
eye irritation/conjuntivitis, burns, corneal necrosis. Inhalation: May be fatal if inhaled. Material is extremely destructive to
tissue of the mucous membranes and upper respiratory tract. Inhalation of hydrochloric acid fumes produces nose, throat,
and larryngeal burning, and irritation, pain and inflammation, coughing, sneezing, choking sensation, hoarseness, laryngeal
spasms, upper respiratory tract edema, chest pains, as well has headache, and palpitations. Inhalation of high concentrations
can result in corrosive burns, necrosis of bronchial epithelium, constriction of the larynx and bronchi, nasospetal perforation,
glottal closure, occur, particularly if exposure is prolonged. May affect the liver. Ingestion: May be fatal if swallowed. Causes
irritation and burning, ulceration, or perforation of the gastrointestinal tract and resultant peritonitis, gastric hemorrhage and
infection. Can also cause nausea, vomitting (with "coffee ground" emesis), diarrhea, thirst, difficulty swallowing, salivation,
chills, fever, uneasiness, shock, strictures and stenosis (esophogeal, gastric, pyloric). May affect behavior (excitement), the
cardiovascular system (weak rapid pulse, tachycardia), respiration (shallow respiration), and urinary system (kidneys- renal
failure, nephritis). Acute exposure via inhalation or ingestion can also cause erosion of tooth enamel. Chronic Potential Health
Effects: dyspnea, bronchitis. Chemical pneumonitis and pulmonary edema can also
Section 12: Ecological Information
Ecotoxicity: Not available.

BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal:
p. 5
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
DOT Classification: Class 8: Corrosive material

Identification: : Hydrochloric acid, solution UNNA: 1789 PG: II
Special Provisions for Transport: Not available.
Section 15: Other Regulatory Information
Federal and State Regulations:

Connecticut hazardous material survey.: Hydrochloric acid Illinois toxic substances disclosure to employee act: Hydrochloric
acid Illinois chemical safety act: Hydrochloric acid New York release reporting list: Hydrochloric acid Rhode Island RTK
hazardous substances: Hydrochloric acid Pennsylvania RTK: Hydrochloric acid Minnesota: Hydrochloric acid Massachusetts
RTK: Hydrochloric acid Massachusetts spill list: Hydrochloric acid New Jersey: Hydrochloric acid New Jersey spill list:
Hydrochloric acid Louisiana RTK reporting list: Hydrochloric acid Louisiana spill reporting: Hydrochloric acid California
Director's List of Hazardous Substances: Hydrochloric acid TSCA 8(b) inventory: Hydrochloric acid TSCA 4(a) proposed test
rules: Hydrochloric acid SARA 302/304/311/312 extremely hazardous substances: Hydrochloric acid SARA 313 toxic chemical
notification and release reporting: Hydrochloric acid CERCLA: Hazardous substances.: Hydrochloric acid: 5000 lbs. (2268 kg)
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada):
CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive liquid.
DSCL (EEC):
R34- Causes burns. R37- Irritating to respiratory system. S26- In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible).
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 1
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 0
Reactivity: 1
Specific hazard:
Protective Equipment:
Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Face shield.
Section 16: Other Information
p. 6
References:
-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -SAX, N.I.
Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library of
Chemical Safety Data, Edition II. -Guide de la loi et du règlement sur le transport des marchandises dangeureuses au canada.
Centre de conformité internatinal Ltée. 1986.
Other Special Considerations: Not available.
Created: 10/09/2005 05:45 PM
Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 7
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Sulfuric acid MSDS
Section 1: Chemical Product and Company Identification
Product Name: Sulfuric acid Contact Information:

Catalog Codes: SLS2539, SLS1741, SLS3166, SLS2371, Sciencelab.com, Inc.
SLS3793 14025 Smith Rd.
Houston, Texas 77396
CAS#: 7664-93-9
US Sales: 1-800-901-7247
RTECS: WS5600000 International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Sulfuric acid Order Online: ScienceLab.com
CI#: Not applicable. CHEMTREC (24HR Emergency Telephone), call:

1-800-424-9300
Synonym: Oil of Vitriol; Sulfuric Acid
International CHEMTREC, call: 1-703-527-3887
Chemical Name: Hydrogen sulfate
For non-emergency assistance, call: 1-281-441-4400
Chemical Formula: H2-SO4
Section 2: Composition and Information on Ingredients

Composition:
Name CAS # % by Weight

Sulfuric acid 7664-93-9 95 - 98
Toxicological Data on Ingredients: Sulfuric acid: ORAL (LD50): Acute: 2140 mg/kg [Rat.]. VAPOR (LC50): Acute: 510 mg/m
2 hours [Rat]. 320 mg/m 2 hours [Mouse].
Section 3: Hazards Identification
Potential Acute Health Effects:

Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion,
of inhalation. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and
respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory
tract, characterized by coughing, choking, or shortness of breath. Severe over-exposure can result in death. Inflammation of
the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening,
or, occasionally, blistering.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC, + (Proven.) by OSHA. Classified A2 (Suspected for
human.) by ACGIH. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL
TOXICITY: Not available. The substance may be toxic to kidneys, lungs, heart, cardiovascular system, upper respiratory tract,
eyes, teeth. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged
p. 1
contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray
mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated exposure to a highly
toxic material may produce general deterioration of health by an accumulation in one or many human organs.
Section 4: First Aid Measures
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek immediate medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.
Section 5: Fire and Explosion Data
Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion:
Products of combustion are not available since material is non-flammable. However, products of decompostion include fumes
of oxides of sulfur. Will react with water or steam to produce toxic and corrosive fumes. Reacts with carbonates to generate
carbon dioxide gas. Reacts with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively.
Fire Hazards in Presence of Various Substances: Combustible materials
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available. Slightly explosive in presence of oxidizing materials.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards:
Metal acetylides (Monocesium and Monorubidium), and carbides ignite with concentrated sulfuric acid. White Phosphorous +
boiling Sulfuric acid or its vapor ignites on contact. May ignite other combustible materials. May cause fire when sulfuric acid
is mixed with Cyclopentadiene, cyclopentanone oxime, nitroaryl amines, hexalithium disilicide, phorphorous (III) oxide, and
oxidizing agents such as chlorates, halogens, permanganates.
p. 2
Special Remarks on Explosion Hazards:
Mixturesofsulfuricacidandanyofthefollowingcanexplode:p-nitrotoluene,pentasi
l v e r trihydroxydiaminophosphate, perchlorates, alcohols with strong hydrogen peroxide, ammonium tetraperoxychromate,
mercuric nitrite, potassium chlorate, potassium permanganate with potassium chloride, carbides, nitro compounds, nitrates,
carbides, phosphorous, iodides, picratres, fulminats, dienes, alcohols (when heated) Nitramide decomposes explosively
on contact with concentrated sulfuric acid. 1,3,5-Trinitrosohexahydro-1,3,5-triazine + sulfuric acid causes explosive
decompositon.
Section 6: Accidental Release Measures
Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If
necessary: Neutralize the residue with a dilute solution of sodium carbonate.
Large Spill:
Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material.
Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water spray
to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.
Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a concentration
level above TLV. Check TLV on the MSDS and with local authorities.
Section 7: Handling and Storage
Precautions:
Keep locked up.. Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product.
In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show
the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, reducing
agents, combustible materials, organic materials, metals, acids, alkalis, moisture. May corrode metallic surfaces. Store in a
metallic or coated fiberboard drum using a strong polyethylene inner package.
Storage:
Hygroscopic. Reacts. violently with water. Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not
store above 23°C (73.4°F).
Section 8: Exposure Controls/Personal Protection
Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
TWA: 1 STEL: 3 (mg/m3) [Australia] Inhalation TWA: 1 (mg/m3) from OSHA (PEL) [United States] Inhalation TWA: 1 STEL: 3
(mg/m3) from ACGIH (TLV) [United States] [1999] Inhalation TWA: 1 (mg/m3) from NIOSH [United States] Inhalation TWA: 1
(mg/m3) [United Kingdom (UK)]Consult local authorities for acceptable exposure limits.
Section 9: Physical and Chemical Properties
p. 3
Physical state and appearance: Liquid. (Thick oily liquid.)
Odor: Odorless, but has a choking odor when hot.
Taste: Marked acid taste. (Strong.)
Molecular Weight: 98.08 g/mole
Color: Colorless.
pH (1% soln/water): Acidic.
Boiling Point:
270°C (518°F) - 340 deg. C Decomposes at 340 deg. C
Melting Point: -35°C (-31°F) to 10.36 deg. C (93% to 100% purity)
Critical Temperature: Not available.
Specific Gravity: 1.84 (Water = 1)
Vapor Pressure: Not available.
Vapor Density: 3.4 (Air = 1)
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility:
Easily soluble in cold water. Sulfuric is soluble in water with liberation of much heat. Soluble in ethyl alcohol.
Section 10: Stability and Reactivity Data
Stability: The product is stable.

Instability Temperature: Not available.
Conditions of Instability:
Conditions to Avoid: Incompatible materials, excess heat, combustible material materials, organic materials, exposure to moist
air or water, oxidizers, amines, bases. Always add the acid to water, never the reverse.
Incompatibility with various substances:
Reactive with oxidizing agents, reducing agents, combustible materials, organic materials, metals, acids, alkalis, moisture.
Corrosivity:
Extremely corrosive in presence of aluminum, of copper, of stainless steel(316). Highly corrosive in presence of stainless
steel(304). Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Hygroscopic. Strong oxidizer. Reacts violently with water and alcohol especially when water is added to the product.
Incompatible (can react explosively or dangerously) with the following: ACETIC ACID, ACRYLIC ACID, AMMONIUM
HYDROXIDE, CRESOL, CUMENE, DICHLOROETHYL ETHER, ETHYLENE CYANOHYDRIN, ETHYLENEIMINE, NITRIC
ACID, 2-NITROPROPANE, PROPYLENE OXIDE, SULFOLANE, VINYLIDENE CHLORIDE, DIETHYLENE GLYCOL
MONOMETHYL ETHER, ETHYL ACETATE, ETHYLENE CYANOHYDRIN, ETHYLENE GLYCOL MONOETHYL ETHER
ACETATE, GLYOXAL, METHYL ETHYL KETONE, dehydrating agents, organic materials, moisture (water), Acetic anhydride,
Acetone, cyanohydrin, Acetone+nitric acid, Acetone + potassium dichromate, Acetonitrile, Acrolein, Acrylonitrile, Acrylonitrile
+water, Alcohols + hydrogen peroxide, ally compounds such as Allyl alcohol, and Allyl Chloride, 2-Aminoethanol, Ammonium
hydroxide, Ammonium triperchromate, Aniline, Bromate + metals, Bromine pentafluoride, n-Butyraldehyde, Carbides, Cesium
acetylene carbide, Chlorates, Cyclopentanone oxime, chlorinates, Chlorates + metals, Chlorine trifluoride, Chlorosulfonic
acid, 2-cyano-4-nitrobenzenediazonium hydrogen sulfate, Cuprous nitride, p-chloronitrobenzene, 1,5-Dinitronaphthlene +
p. 4
sulfur, Diisobutylene, p-dimethylaminobenzaldehyde, 1,3-Diazidobenzene, Dimethylbenzylcarbinol + hydrogen peroxide,
Epichlorohydrin, Ethyl alcohol + hydrogen peroxide, Ethylene diamine, Ethylene glycol and other glycols, , Ethylenimine,
Fulminates, hydrogen peroxide, Hydrochloric acid, Hydrofluoric acid, Iodine heptafluoride, Indane + nitric acid, Iron, Isoprene,
Lithium silicide, Mercuric nitride, Mesityl oxide, Mercury nitride, Metals (powdered), Nitromethane, Nitric acid + glycerides,
p-Nitrotoluene, Pentasilver trihydroxydiaminophosphate, Perchlorates, Perchloric acid, Permanganates + benzene, 1-
Phenyl-2-methylpropyl alcohol + hydrogen peroxide, Phosphorus, Phosphorus isocyanate, Picrates, Potassium tert-butoxide,
Potassium chlorate, Potassium Permanganate and other permanganates, halogens, amines, Potassium Permanganate +
Potassium chloride, Potassium Permanganate + water, Propiolactone (beta)-, Pyridine, Rubidium aceteylene carbide, Silver
permanganate, Sodium, Sodium carbonate, sodium hydroxide, Steel, styrene monomer, toluene + nitric acid, Vinyl acetate,
Thalium (I) azidodithiocarbonate, Zinc chlorate, Zinc Iodide, azides, carbonates, cyanides, sulfides, sulfites, alkali hydrides,
carboxylic acid anhydrides, nitriles, olefinic organics, aqueous acids, cyclopentadiene, cyano-alcohols, metal acetylides,
Hydrogen gas is generated by the action of the acid on most metals (i.e. lead, copper, tin, zinc, aluminum, etc.). Concentrated
sulfuric acid oxidizes, dehydrates, or sulfonates most organic compounds.
Special Remarks on Corrosivity:
Non-corrosive to lead and mild steel, but dillute acid attacks most metals. Attacks many metals releasing hydrogen. Minor
corrosive effect on bronze. No corrosion data on brass or zinc.
Polymerization: Will not occur.
Section 11: Toxicological Information
Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity to Animals:
WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral
toxicity (LD50): 2140 mg/kg [Rat.]. Acute toxicity of the vapor (LC50): 320 mg/m3 2 hours [Mouse].
Chronic Effects on Humans:
CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC, + (Proven.) by OSHA. Classified A2 (Suspected
for human.) by ACGIH. May cause damage to the following organs: kidneys, lungs, heart, cardiovascular system, upper
respiratory tract, eyes, teeth.
Other Toxic Effects on Humans:
Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact (corrosive, irritant,
permeator), of eye contact (corrosive), of ingestion, .
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans:
Mutagenicity: Cytogenetic Analysis: Hamster, ovary = 4mmol/L Reproductive effects: May cause adverse reproductive effects
based on animal data. Developmental abnormalities (musculoskeletal) in rabbits at a dose of 20 mg/m3 for 7 hrs.(RTECS)
Teratogenecity: neither embryotoxic, fetoxic, nor teratogenetic in mice or rabbits at inhaled doses producing some maternal
toxicity
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Causes severe skin irritation and burns. Continued contact can cause tissue necrosis.
Eye: Causes severe eye irritation and burns. May cause irreversible eye injury. Ingestion: Harmful if swallowed. May cause
permanent damage to the digestive tract. Causes gastrointestial tract burns. May cause perforation of the stomach, GI
bleeding, edema of the glottis, necrosis and scarring, and sudden circulatory collapse(similar to acute inhalation). It may
also cause systemic toxicity with acidosis. Inhalation: May cause severe irritation of the respiratory tract and mucous
membranes with sore throat, coughing, shortness of breath, and delayed lung edema. Causes chemical burns to the repiratory
tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis,
and pulmonary edema. Cause corrosive action on mucous membranes. May affect cardiovascular system (hypotension,
depressed cardiac output, bradycardia). Circulatory collapse with clammy skin, weak and rapid pulse, shallow respiration, and
scanty urine may follow. Circulatory shock is often the immediate cause of death. May also affect teeth(changes in teeth and
supporting structures - erosion, discoloration). Chronic Potential Health Effects: Inhalation: Prolonged or repeated inhalation
may affect behavior (muscle contraction or spasticity), urinary system (kidney damage), and cardiovascular system, heart
(ischemic heart leisons), and respiratory system/lungs(pulmonary edema, lung damage), teeth (dental discoloration, erosion).
Skin: Prolonged or repeated skin contact may cause dermatitis, an allergic skin reaction.
p. 5
Section 12: Ecological Information
Ecotoxicity: Ecotoxicity in water (LC50): 49 mg/l 48 hours [bluegill/sunfish].

BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal:
Sulfuric acid may be placed in sealed container or absorbed in vermiculite, dry sand, earth, or a similar material. It may also
be diluted and neutralized. Be sure to consult with local or regional authorities (waste regulators) prior to any disposal. Waste
must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
DOT Classification: Class 8: Corrosive material

Identification: : Sulfuric acid UNNA: 1830 PG: II
Special Provisions for Transport: Not available.
Section 15: Other Regulatory Information
Federal and State Regulations:

Illinois toxic substances disclosure to employee act: Sulfuric acid New York release reporting list: Sulfuric acid Rhode
Island RTK hazardous substances: Sulfuric acid Pennsylvania RTK: Sulfuric acid Minnesota: Sulfuric acid Massachusetts
RTK: Sulfuric acid New Jersey: Sulfuric acid California Director's List of Hazardous Substances (8 CCR 339): Sulfuric acid
Tennessee RTK: Sulfuric acid TSCA 8(b) inventory: Sulfuric acid SARA 302/304/311/312 extremely hazardous substances:
Sulfuric acid SARA 313 toxic chemical notification and release reporting: Sulfuric acid CERCLA: Hazardous substances.:
Sulfuric acid: 1000 lbs. (453.6 kg)
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada):
CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS E: Corrosive liquid.
DSCL (EEC):
R35- Causes severe burns. S2- Keep out of the reach of children. S26- In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice. S30- Never add water to this product. S45- In case of accident or if you feel unwell,
seek medical advice immediately (show the label where possible).
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 2
p. 6
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 0
Reactivity: 2
Specific hazard:
Protective Equipment:
Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Face shield.
Section 16: Other Information
References:
-Material safety data sheet emitted by: la Commission de la Santé et de la Sécurité du Travail du Québec. -The Sigma-Aldrich
Library of Chemical Safety Data, Edition II. -Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van
Nostrand Reinold, 1987.
Other Special Considerations: Not available.
Created: 10/09/2005 11:58 PM
Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 7
(According to 91/155 EC)
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING:
Product details:
Trade name HEXAMINE; METHAMINE
Manufacturer / Supplier HEXAMETHYLENETETRAMINE, C6H12N4
Kanoria Chemicals & Industries Ltd. Kanoria Chemicals & Industries Ltd.
Plot No-32, Jawaharlal Nehru Pharma City, A-304/305/306, Universal Business Park,
Parawada, Visakhapatnam - 531019, Chandivali Farm Road, Off Saki Vihar Road,
(Andhra Pradesh) India Near Kamani Oil Mills, Saki Naka, Andheri (East),
Tel:+91 8924 236056 Mumbai 400 072 (Maharashtra), India.
Email: sales@kanoriachem.com Tel: +91 22 28470216, 28470217
Web: http://www.kanoriachem.com Fax: +91 22 28470235
Email: kcil@bom3.vsnl.net.in
Further information obtainable from Information in Safety Department
case of emergency Tel: +91 8924 236088
2. COMPOSITION/ INFORMATION ON INGREDIENTS:

Hexamine 100-97-0 202-905-8
3. HAZARD IDENTIFICATION:
Hazard description Harmful if swallowed or inhaled. Causes irritation to skin,
eyes, respiratory and gastronomical tracts.
Chronic Exposure No data available.
Carcinogen city (NTP/IARC/OSHA) No.
4. FIRST-AID MEASURES:
After inhalation Remove to fresh air, restore breathing. Get medical
attention.
After skin contact Flush skin with water. Decontaminate clothing before
reuse. Get medical attention if irritation persists.
After eye contact Flush opened eye for several minutes under running water.
After swallowing Rinse out mouth, give plenty of water in case conscious
and induce vomiting. Call physician immediately in case of
an unconscious victim.
5. FIRE-FIGHTING MEASURES:
Suitable extinguishing agents CO2, dry chemical powder for small fire. Water spray, foam
for large fire.
6. ACCIDENTAL RELEASE MEASURES:

Person-related safety precautions Use recommended respiratory protective device. Eliminate
ignition sources.
Measures for cleaning/collecting Sweep up and containerize for reclamation or disposal.
Dispose contaminated material as waste according to item
13.
7. HANDLING AND STORAGE:

Handling
Information for safe handling Avoid breathing dust, avoid contact with eyes, skin and
clothing. Decontaminate soiled clothing before reuse.
Information about fire and explosion protection Concentrated dust may form a cloud that could produce an
explosive hazard. This product is combustible and can be
readily ignited when a flame is applied.
Storage
Requirements to be met by store rooms and Store in a cool, dry, ventilated area. Keep away from
receptacles flame, acids and strong oxidizing agents. Avoid generation
of excessive dust.
8. EXPOSURE CONTROLS / PROTECTION:

100-97-0 Hexamine
OES Short term value *15 mg/m3

Long term value **--
* total inhalable dust
Personal protective equipment
General protective and hygienic measures The usual precautionary measures for handling chemicals
are to be followed.
Respiratory protection Suitable respiratory protective devise recommended.
Protection of hands Protective gloves of neoprene rubber.
Eye Protection Safety glasses with side shields.
9. PHYSICAL AND CHEMICAL PROPERTIES:

General information:
Form Crystalline powder
Colour White
Odour Odourless
Change in condition
Melting point / Melting Range 280oC
Boiling Point / Boiling range --
Flash point: (CC) 2500C
Density AT 20oC 1267 KG/m3
Bulk density at 20oC 600 - 700 kg/m3
Solubility in water at 20oC Complete
10. STABILITY & REACTIVITY:
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Keep

away from sources of ignition, oxidizers, acetic acid, acetic anhydride, ammonium nitrate, nitric acid.
Dangerous reactions Acidified solution on heating releases Formaldehyde.
Dangerous decomposition products Formaldehyde, Oxides of Nitrogen.
11. TOXICOLOGICAL INFORMATION:

Acute toxicity:
LD /LC50 values relevant for classification: Oral/LD 50 : Not established.

IVN LD 50 : 9200 mg/kg (Rat)
On the skin Mild irritant
On the eyes Mild irritant
Sensitization Mild
12. ECOLOGICAL INFORMATION:

Environmental toxicity Data not available
Environmental fate Data not available
13. DISPOSAL CONDITIONS:

Whatever cannot be recycled, should be transferred to appropriate and approved waste disposal facility. Dispose
waste, containers and unused contents in accordance with official regulations.
14. TRANSIT INFORMATION:

Shipping name HEXAMINE
UN number 1328; Class: 4.1
Packing Group III; DOT Label: Flammable solid.

This product is hazardous under the criteria of the OSHA Hazard Communication Standard 29CFR 1910.1200. This
product is on the EPA Toxic Substance Control Act (TSCA) inventory list.
To the best of our knowledge, this product contains on levels of listed substances, which may cause cancer, birth
defects or other reproductive effects.
16. OTHER INFORMATION:

Kanoria Chemicals & Industries Limited provides the information contained herein in good faith, but makes no
representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person using this product. Individuals
receiving the information must exercise their independent judgment in determining its appropriateness for a
particular purpose. KANORIA CHEMICALS & INDUSTRIES LIMITED MAKES NO REPRESENTATIONS OR
WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF
MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, KANORIA CHEMICALS &
INDUSTRIES LIMITED WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON
THIS INFORMATION.
Department issuing MSDS: Safety Department
Date of Issue: 27-06-2018 Date of Revision: 26-06-2021
This document is valid for 03 years from the date of issue, and is bound to be canceled, if not revised on or
before the date of revision.
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Type : PHENOL FORMALDEHYDE LIQUID RESIN
Trade name : MSDS applicable to all KCI manufactured phenol-formaldehyde liquid
Novolak materials
Manufacturer : Kanoria Chemicals & Industries Ltd.

Plot No-32,Jawaharlal Nehru Pharma City, Parawada,
Visakhapatnam - 531019 (Andhra Pradesh), India
Tel:+91 8924 236056
Email: sales@kanoriachem.com
Web: http://www.kanoriachem.com
Emergency Telephone: +91 8924 236088
2. COMPOSITION/ INFORMATION ON INGREDIENTS

Phenol formaldehyde resin NA NA

Phenol 108-95-2 203-632-7
Solvent Proprietary information
3. HAZARD IDENTIFICATION
GHS Label :
Exclamation mark Health hazard

Inhalation : Exposure to airborne concentrations or fumes from heated product
may cause irritation to nose, throat and lungs. Reduces Lungs
function on chronic exposure. Some symptoms like nausea,
vomiting and respiratory tract irritation. Coughing, dizziness,
unconsciousness may also be observed.
Ingestion : Extremely Harmful and can damage to organs
Skin : Causes skin irritation and dermatitis on prolonged contact with the
material
Eyes : This product may cause eye irritation when exposed. Symptoms
include redness and a burning sensation.
Chronic Exposure : Identified as a carcinogen by National toxicology program (NTP),

International Agency for Research on Carcinogens (IARC),
Occupational Safety and Health Administration (OSHA)
organizations.
4. FIRST-AID MEASURES
Inhalation : Remove to fresh air. Get medical attention in case of any breathing
difficulty.
Ingestion : Induce vomiting of conscious patient by giving plenty of water to drink.
In case of an unconscious victim, DONOT GIVE ANYTHING BY MOUTH and
consult physician immediately.
Skin : Remove the contaminated clothing and shoes and immediately flush skin
with plenty of water for at least 15 minutes. Get medical attention if
irritation persists.
Eyes : Immediately flush eyes with plenty of running water for at least 15
minutes, lifting upper and lower eyelids occasionally. Get medical
attention if irritation persists.
Flammability : Flammable liquid
Suitable Extinguishing : Use water, Dry chemical powder, foam, water fog or
media carbon dioxide directly on the burning material to
avoid spreading by wearing firefighting equipment.
Protective equipment for : Wear self contained breathing apparatus for
Firefighters firefighting if necessary

The following Steps to be taken in case material is spilled or released.
1. Ventilate and evacuate the premises

2. Shut off all possible ignition sources
3. Wear appropriate protective equipment as suggested in the section 8.
4. In case of spills, clean in a manner that does not disperse dust into air. Use non-
sparking tools and equipment for cleaning.
5. Use sand, saw dust to absorb and collecting the spilled material
6. Collect the spilled material into a suitable closed disposal container.
7. Use Waste Disposal Methods in accordance with Federal, State and Local laws rules
and regulations.
Handling procedures:
1. Avoid direct eye and skin contact and also avoid prolonged breathing vapors of the
material.
2. Handle the product with adequate ventilation.
3. Keep the product away from heat, sparks and open flame.
4. Wash hands after handling and before eating. Launder the work clothes frequently
and decontaminate the clothing thoroughly before re use.
Storage requirements:
1. Keep the material in tightly closed container in a cool and well-ventilated place.
Protect the container from physical damage and avoid storing in direct sun-light.
2. Do not store this material in un labeled containers
3. Store this material away from the oxidizing agents.
4. Keep this material away from food, drink and animal feed.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION:

Ventilation system:
Local exhaust is recommended to keep employee exposures as low as possible and

keep the workroom concentration below current applicable OSHA safety and health
requirements.
Respiratory Protection:
1. Appropriate Respirators/canister Masks with N95 filters type or with better filers may
be suitable under mild conditions, where mist is apparent and engineering controls
are feasible.
2. For Emergencies/ instances where exposure levels are not known, use full-face
protection with air supplied respirator.
Skin Protection:
Wear protective nitrile rubber/ butyl rubber/neoprene/chemical resistant gloves and

wear clean body-covering clothing.
Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities
in work area for emergencies.
Appearance : Yellowish to Reddish brown liquid
Odour : Odorless/ Slightly phenolic

Boiling Point / Boiling range : >180°C
Flash point: (Closed Cup) : >100oC

Viscosity at 25°C : >8000 cps
Flammable limits : Not applicable
Auto ignition temperature : >400°C
Specific gravity at 20°C (g/cc) : <2.0
Vapor density (Air = 1) : Not available
Vapor Pressure (mm Hg) at 25oC : Not available
Solubility/Miscibility with water at 20oC : Limited solubility in water
10. STABILITY & REACTIVITY

This product is stable under normal and anticipated storage and handling conditions.
However this material can undergo hazardous polymerization.
Dangerous reactions can occur when exposed to Strong oxidizing materials, acids.
Dangerous decomposition products CO, CO2, vapors of formaldehyde, oxides of nitrogen

Acute toxicity: Not established
LD/LC50 values relevant for classification: Oral/LD 50 : 2,900 mg/Kg (rat)

SKIN LD 50: 20,800 µl/kg (rabbit)
Primary effects:
On the skin Irritating effect (slight)

Prolonged contact leads to absorbing through skin.
Effects can include those described in ‘Ingestion’
On Ingestion Damage the internal organs. Symptoms such as
vomiting, headache, stupor, convulsions and
unconsciousness also may be observed.
Inhalation Breathing in vapour can result in headaches, dizziness,

drowsiness, and possible nausea.
Chronic effects Prolonged exposure to this material may effects on the
central nervous system, liver and kidneys
Environmental toxicity Avoid contaminating waterways.
Environmental fate The theoretical oxygen demand (ThOD) is 1.068. The 5-

day biochemical oxygen demand (BOD) was 60% using
sewage seed. The 5-day BOD was 47-99% using
activated sludge and 0% using pure bacteria culture.
This material is not known to bioconcentrate or
bioaccumulate.
13. DISPOSAL INFORMATION

It can be recycled, reclaim or recover when practical. Dispose in an approved landfill if
allowed locally. Comply with federal, state, and local regulations. Dispose of in a permitted
waste management facility if landfill is not practical.

Shipping name Not regulated
UN number Not applicable
Packing Group Not applicable

This product is irritating material. Hazard Categories under Criteria of SARA Title III Rules
(40 CFR Part 370), Immediate (Acute) Health, Delayed (Chronic) Health & Reactive. The
components of this product are all on the TSCA inventory list.

Kanoria Chemicals & Industries Limited provides the information contained herein in good
faith, but makes no representation as to its comprehensiveness or accuracy. This document
is intended only as a guide to the appropriate precautionary handling of the material by a
properly trained person using this product. Individuals receiving the information must
exercise their independent judgment in determining its appropriateness for a particular
purpose. KANORIA CHEMICALS & INDUSTRIES LIMITED MAKES NO REPRESENTATIONS OR
WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY
WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH
RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE
INFORMATION REFERS. ACCORDINGLY, KANORIA CHEMICALS & INDUSTRIES LIMITED
WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON
THIS INFORMATION.
Date of Issue : 1st September 2020

MSDS valid till : 31st August 2022

Product Type : PHENOL FORMALDEHYDE RESIN
Trade name : MSDS applicable to all KCI manufactured phenol-formaldehyde

novolak powder resins with hexamine.

Tel:+91 8924 236056

Phenol formaldehyde Novolak resin NA NA

(major quantity)
Phenol 108-95-2 203-632-7

(Present in <5wt % quantity)

(trace amounts, <0.01wt%)
Hexamine 100-97-0 202-905-8

(minor quantity)
GHS Label :

Ingestion : Harmful and can cause central nervous depression

material

organizations.
difficulty.
Ingestion : Induce vomiting of conscious patient by giving plenty of water to drink.
In case of an unconscious victim, DONOT GIVE ANYTHING BY MOUTH and
consult physician immediately.
Flammability : Non-Flammable, but fire may possible at elevated
temperatures or by contact with ignition source.

4. Airborne dust can be minimized by moistening with water.
and regulations.
material.
Ventilation system:

requirements.
are feasible.
Skin Protection:

Eye Protection:
Appearance : White to cream colored powder
Odour : Odorless/ Slightly phenolic
Melting point : 80-100°C

Boiling Point / Boiling range : No information found
Flash point: (Closed Cup) : >93oC
Flammable limits : Not applicable
Auto ignition temperature : Not applicable
Density (g/cc) : 0.3-0.6

o
Solubility/Miscibility with water at 20 C : Not soluble/miscible


Acute toxicity: Not established
LD/LC50 values relevant for classification: Oral/LD 50 : 2,900 mg/Kg (rat)

SKN LD 50: 20,800 µl/kg (rabbit)
On the skin Irritating effect (slight)

Environmental toxicity No known significant effects or critical hazards.

bioaccumulate.



THIS INFORMATION.


Product Type : PHENOL FORMALDEHYDE LIQUID RESOLE RESIN
Trade name : MSDS applicable to all grades of KCI manufactured phenol
formaldehyde liquid resole resins.

Tel:+91 8924 236056

Phenol formaldehyde resin NA NA
(major quantity)
Phenol 108-95-2 203-632-7

(minor quantity)

(minor quantity)
GHS Label :

Ingestion : Extremely Harmful and can cause central nervous depression

material

organizations.
difficulty.
Ingestion : If swallowed accidentally, give large quantities of water and dilute the
effects on the stomach. Do not induce vomiting and seek medical advice
Flammability : Non-Flammable, but fire may possible if water is
evaporated from the resin (normally at elevated
temperatures or by contact with ignition source).

4. Use saw dust/sand to abosob and collecting the spilled material if required.
and regulations.
material.

Ventilation system:

requirements.
are feasible.
Skin Protection:

Eye Protection:
Appearance : Reddish brown liquid

Odour : Phenolic odour
Boiling point : ≥ 100°C
Flash point: (Closed Cup) : >93oC closed cup
Flammable limits : Flammable if all water evaporates
Auto ignition temperature : Not available
Specific gravity (g/cc) : <2.0
pH : >6
Solubility/Miscibility with water at 20oC : Limited solubility

Acute toxicity: : Not established
LD/LC50 values relevant for classification: : Oral/LD 50 : 2000 mg/Kg (rat)

SKIN LD 50: 20,800 µl/kg (rabbit)
Primary irritant effect
On the skin : Irritating effect (slight)
On the eye : Irritating effect (severe)
Sensitization : Prolonged contact may cause skin sensitization.

Environmental toxicity No known significant effects or critical hazards.

bioaccumulation.




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DEEPAK PHENOLICS LIMITED

12/B, GIDC DAHEJ, Tal: VAGRA, Dist: BHARUCH – 392130, GUJARAT.

SECTION – 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

SECTION - 2 HAZARD IDENTIFICATION

Signal Word: DANGER

SECTION – 3 COMPOSITION & INFORMATION ON INGREDIENTS

Ingredients / Hazardous CAS No. % By Weight

SECTION – 4 FIRST AID MEASURES

General Advice: Immediate medical attention is required.

SECTION – 5 FIRE FIGHTING MEASURES

SECTION – 6 ACCIDENTAL RELEASE MEASURES

8.1 Control parameters:

SECTION – 9 PHYSICAL AND CHEMICAL PROPERTIES

Physical state Liquid

SECTION – 13 DISPOSAL CONSIDERATION

SECTION – 14 TRANSPORT INFORMATION

SECTION – 15 REGULATORY INFORMATION

EINECS Number 200 - 001 - 8

Chemical Name Formaldehyde

Chemical Classification Aldehyde

Formalin; formic aldehyde; formal; methyl aldehyde; methylene

Molecular weight 30.03

Shipping Name Formaldehyde solution

Codes / Label Flammable liquid, Class - 3.1

Hazardous Waste ID No. 5

Description Colourless liquid with characteristic pungent odour.

In the manufacture of phenolic resins:- amino (MF/UF/MUF)

P.O. ANKLESHWAR – 393002, BHARUCH, (GUJ.)

MATERIAL SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING:

Product Identifier FORMALDEHYDE, 37% SOLUTION IN WATER

Relevant identified uses of the substance or mixture and

Details of the supplier of the safety sheet

3407, GIDC, Industrial Estate, A304/305/306, Universal Business Park,

Further information obtainable from in case of Safety Department.

2.1 Classification of the substance or mixture:

Classification according to Regulation (EC) No 1272/2008 [CLP/GHS]

Acute toxicity, Oral : Category 3 , H301

Labelling according Regulation (EC) No 1272/2008 [CLP/GHS]

H301+H311+H331: Toxic if swallowed, in contact with skin or inhaled.

P201: Obtain special instruction before use.

3. COMPOSITION/ INFORMATION ON INGREDIENTS:

Description CAS No. EINECS Number

Formaldehyde 50-00-0 200-001-8

Methanol 67-56-1 200-659-6

Swallowing DO NOT induce vomiting. Seek urgent medical assistance.

6. ACCIDENTAL RELEASE MEASURES:

8. EXPOSURE CONTROLS / PROTECTION:

OES Short term value *3 mg/m3

* total inhalable vapour, ** permissible exposure

Respiratory protection Self contained breathing apparatus.

Protection of hands Gloves of natural rubber.

Eye protection Safety glasses Wear face shield.

9. PHYSICAL AND CHEMICAL PROPERTIES:

Odour Pungent odour

Boiling Point / Boiling range 96oC

Flash point: (CC) * 85oC

Flammable limits Upper 73.0%, Lower 7.0%

Auto ignition temperature 423oC

Specific gravity, at 25 oC 1.108