Liquid Molly Diesel Purge

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Safety data sheet according to Regulation (EC) No 1907/2006, Annex II


Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509

Safety data sheet


according to Regulation (EC) No 1907/2006, Annex II
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Diesel Spuelung 500 mL


Art.: 2509
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture:
System cleaner for vehicle fuel units (diesel engines)
Uses advised against:
No information available at present.

1.3 Details of the supplier of the safety data sheet

LIQUI MOLY GmbH, Jerg-Wieland-Str. 4, 89081 Ulm-Lehr, Germany


Phone:(+49) 0731-1420-0, Fax:(+49) 0731-1420-88

Qualified person's e-mail address: info@chemical-check.de, k.schnurbusch@chemical-check.de Please DO NOT use for requesting Safety
Data Sheets.

1.4 Emergency telephone number


Emergency information services / official advisory body:
---
Telephone number of the company in case of emergencies:
+49 (0) 700 / 24 112 112 (LMR)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture


Classification according to Regulation (EC) 1272/2008 (CLP)
Hazard class Hazard category Hazard statement
Asp. Tox. 1 H304-May be fatal if swallowed and enters airways.
Aquatic Chronic 3 H412-Harmful to aquatic life with long lasting effects.

2.2 Label elements


Labeling according to Regulation (EC) 1272/2008 (CLP)

Danger
Page 2 of 15
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509

H304-May be fatal if swallowed and enters airways. H412-Harmful to aquatic life with long lasting effects.

P101-If medical advice is needed, have product container or label at hand. P102-Keep out of reach of children.
P301+P310-IF SWALLOWED: Immediately call a POISON CENTER / doctor. P331-Do NOT induce vomiting.
P405-Store locked up.
P501-Dispose of contents / container to an approved waste disposal facility.

EUH044-Risk of explosion if heated under confinement.


EUH066-Repeated exposure may cause skin dryness or cracking.

Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics

2.3 Other hazards


The mixture does not contain any vPvB substance (vPvB = very persistent, very bioaccumulative) or is not included under XIII of the regulation
(EC) 1907/2006 (< 0,1 %).
The mixture does not contain any PBT substance (PBT = persistent, bioaccumulative, toxic) or is not included under XIII of the regulation (EC)
1907/2006 (< 0,1 %).

SECTION 3: Composition/information on ingredients

3.1 Substance
n.a.
3.2 Mixture
Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics
Registration number (REACH) 01-2119457273-39-XXXX
Index ---
EINECS, ELINCS, NLP 918-481-9 (REACH-IT List-No.)
CAS ---
content % 80-<100
Classification according to Regulation (EC) 1272/2008 (CLP) Asp. Tox. 1, H304

2-Ethylhexylnitrate
Registration number (REACH) 01-2119539586-27-XXXX
Index ---
EINECS, ELINCS, NLP 248-363-6
CAS 27247-96-7
content % 5-15
Classification according to Regulation (EC) 1272/2008 (CLP) Acute Tox. 4, H302
Acute Tox. 4, H312
Acute Tox. 4, H332
Aquatic Chronic 2, H411

Hydrocarbons, C10, aromatics, >1% naphthalene


Registration number (REACH) 01-2119463588-24-XXXX
Index ---
EINECS, ELINCS, NLP 919-284-0 (REACH-IT List-No.)
CAS (64742-94-5)
content % 0,1-<1
Classification according to Regulation (EC) 1272/2008 (CLP) Carc. 2, H351
STOT SE 3, H336
Asp. Tox. 1, H304
Aquatic Chronic 2, H411

Impurities, test data and additional information may have been taken into account in classifying and labelling the product.
For the text of the H-phrases and classification codes (GHS/CLP), see Section 16.
The substances named in this section are given with their actual, appropriate classification!
For substances that are listed in appendix VI, table 3.1 of the regulation (EC) no. 1272/2008 (CLP regulation) this means that all notes that may
be given here for the named classification have been taken into account.
If, for example, the note P is applied for a hydrocarbon then this has already been taken into account for the classification named here.
Page 3 of 15
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509

Quote: "Note P - The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0,1 %
w/w benzene (EINECS No 200-753-7)."
Article 4 of the regulation (EC) no. 1272/2008 (CLP regulation) was also observed and taken into account for the classification named here.

SECTION 4: First aid measures

4.1 Description of first aid measures


First-aiders should ensure they are protected!
Never pour anything into the mouth of an unconscious person!
Inhalation
Remove person from danger area.
Supply person with fresh air and consult doctor according to symptoms.
If the person is unconscious, place in a stable side position and consult a doctor.
Skin contact
Remove polluted, soaked clothing immediately, wash thoroughly with plenty of water and soap, in case of irritation of the skin (flare), consult a
doctor.
Eye contact
Remove contact lenses.
Wash thoroughly for several minutes using copious water. Seek medical help if necessary.
Ingestion
Rinse the mouth thoroughly with water.
Do not induce vomiting - give copious water to drink. Consult doctor immediately.
Danger of aspiration.
In case of vomiting, keep head low so that the stomach content does not reach the lungs.
4.2 Most important symptoms and effects, both acute and delayed
Irritation of the eyes
Product removes fat.
Dermatitis (skin inflammation)
Ingestion:
Oedema of the lungs
Lung damage
Chemical pneumonitis (condition similar to pneumonia)
In certain cases, the symptoms of poisoning may only appear after an extended period / after several hours.
4.3 Indication of any immediate medical attention and special treatment needed
Gastric lavage (stomach washing) only under endotracheal intubation.
Subsequent observation for pneumonia and pulmonary oedema.

SECTION 5: Firefighting measures

5.1 Extinguishing media


Suitable extinguishing media
CO2
Extinction powder
Foam
Unsuitable extinguishing media
High volume water jet
5.2 Special hazards arising from the substance or mixture
In case of fire the following can develop:
Oxides of carbon
Oxides of nitrogen
Hydrocarbons
Toxic pyrolysis products.
Danger of explosion.
Explosive vapour/air or gas/air mixtures.
Dangerous vapours heavier than air.
5.3 Advice for firefighters
In case of fire and/or explosion do not breathe fumes.
Protective respirator with independent air supply.
Page 4 of 15
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509

According to size of fire


Full protection, if necessary.
Cool container at risk with water.
Dispose of contaminated extinction water according to official regulations.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


Remove possible causes of ignition - do not smoke.
Ensure sufficient supply of air.
Avoid inhalation, and contact with eyes or skin.
If applicable, caution - risk of slipping.
6.2 Environmental precautions
If leakage occurs, dam up.
Resolve leaks if this possible without risk.
Prevent from entering drainage system.
Prevent surface and ground-water infiltration, as well as ground penetration.
If accidental entry into drainage system occurs, inform responsible authorities.
6.3 Methods and material for containment and cleaning up
Soak up with absorbent material (e.g. universal binding agent, sand, diatomaceous earth) and dispose of according to Section 13.
6.4 Reference to other sections
For personal protective equipment see Section 8 and for disposal instructions see Section 13.

SECTION 7: Handling and storage

In addition to information given in this section, relevant information can also be found in section 8 and 6.1.
7.1 Precautions for safe handling
7.1.1 General recommendations
Ensure good ventilation.
Keep away from sources of ignition - Do not smoke.
Eating, drinking, smoking, as well as food-storage, is prohibited in work-room.
Observe directions on label and instructions for use.
Use working methods according to operating instructions.
7.1.2 Notes on general hygiene measures at the workplace
General hygiene measures for the handling of chemicals are applicable.
Wash hands before breaks and at end of work.
Keep away from food, drink and animal feedingstuffs.
Remove contaminated clothing and protective equipment before entering areas in which food is consumed.
7.2 Conditions for safe storage, including any incompatibilities
Keep out of access to unauthorised individuals.
Store product closed and only in original packing.
Not to be stored in gangways or stair wells.
Solvent resistant floor
Do not store with oxidizing agents.
Store in a well ventilated place.
Protect from direct sunlight and warming.
Store cool.
7.3 Specific end use(s)
No information available at present.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters


Workplace exposure limit (WEL) of the total hydrocarbon solvent content of the mixture (RCP method according to EH40):
800 mg/m3
Page 5 of 15
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509

Content %:80-
Chemical Name Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics
<100
WEL-TWA: 800 mg/m3 WEL-STEL: --- ---
Monitoring procedures: - Draeger - Hydrocarbons 2/a (81 03 581)
- Draeger - Hydrocarbons 0,1%/c (81 03 571)
- Compur - KITA-187 S (551 174)
BMGV: --- Other information: (OEL acc. to RCP-method,
paragraphs 84-87, EH40)
Chemical Name Hydrocarbons, C10, aromatics, >1% naphthalene Content %:0,1-<1
WEL-TWA: 500 mg/m3 (Aromatics) WEL-STEL: --- ---
Monitoring procedures: - Draeger - Hydrocarbons 2/a (81 03 581)
- Draeger - Hydrocarbons 0,1%/c (81 03 571)
- Compur - KITA-187 S (551 174)
BMGV: --- Other information: ---

2-Ethylhexylnitrate
Area of application Exposure route / Effect on health Descriptor Value Unit Note
Environmental
compartment
Environment - freshwater PNEC 0,8 µg/l
Environment - marine PNEC 0,08 µg/l
Environment - sediment PNEC 0,00074 mg/kg dw
Environment - soil PNEC 0,00019 mg/kg dw
1
Consumer Human - dermal Long term, systemic DNEL 0,52 mg/kg
effects bw/day
Consumer Human - inhalation Long term, systemic DNEL 0,087 mg/m3
effects
Consumer Human - oral Long term, systemic DNEL 0,025 mg/kg
effects bw/day
Consumer Human - dermal Long term, local effects DNEL 0,022 mg/cm2
Workers / employees Human - dermal Long term, systemic DNEL 1 mg/kg
effects bw/day
Workers / employees Human - inhalation Long term, systemic DNEL 0,35 mg/m3
effects
Workers / employees Human - dermal Long term, local effects DNEL 0,044 mg/cm2

Hydrocarbons, C10, aromatics, >1% naphthalene


Area of application Exposure route / Effect on health Descriptor Value Unit Note
Environmental
compartment
Consumer Human - dermal Long term, systemic DNEL 7,5 mg/kg
effects bw/day
Consumer Human - inhalation Long term, systemic DNEL 32 mg/m3
effects
Consumer Human - oral Long term, systemic DNEL 7,5 mg/kg
effects bw/day
Workers / employees Human - dermal Long term, systemic DNEL 12,5 mg/kg
effects bw/day
Workers / employees Human - inhalation Long term, systemic DNEL 151 mg/m3
effects

WEL-TWA = Workplace Exposure Limit - Long-term exposure limit (8-hour TWA (= time weighted average) reference period) EH40. AGW =
"Arbeitsplatzgrenzwert" (workplace limit value, Germany).
(8) = Inhalable fraction (2017/164/EU, 2017/2398/EU). (9) = Respirable fraction (2017/164/EU, 2017/2398/EU). | WEL-STEL = Workplace
Exposure Limit - Short-term exposure limit (15-minute reference period).
(8) = Inhalable fraction (2017/164/EU, 2017/2398/EU). (9) = Respirable fraction (2017/164/EU, 2017/2398/EU). (10) = Short-term exposure limit
value in relation to a reference period of 1 minute (2017/164/EU). | BMGV = Biological monitoring guidance value EH40. BGW = "Biologischer
Grenzwert" (biological limit value, Germany) | Other information: Sen = Capable of causing occupational asthma. Sk = Can be absorbed through
skin. Carc = Capable of causing cancer and/or heritable genetic damage.
Page 6 of 15
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509

** = The exposure limit for this substance is repealed through the TRGS 900 (Germany) of January 2006 with the goal of revision.

8.2 Exposure controls


8.2.1 Appropriate engineering controls
Ensure good ventilation. This can be achieved by local suction or general air extraction.
If this is insufficient to maintain the concentration under the WEL or AGW values, suitable breathing protection should be worn.
Applies only if maximum permissible exposure values are listed here.
Suitable assessment methods for reviewing the effectiveness of protection measures adopted include metrological and non-metrological
investigative techniques.
These are specified by e.g. BS EN 14042.
BS EN 14042 "Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and
biological agents".

8.2.2 Individual protection measures, such as personal protective equipment


General hygiene measures for the handling of chemicals are applicable.
Wash hands before breaks and at end of work.
Keep away from food, drink and animal feedingstuffs.
Remove contaminated clothing and protective equipment before entering areas in which food is consumed.

Eye/face protection:
Tight fitting protective goggles with side protection (EN 166).

Skin protection - Hand protection:


Solvent resistant protective gloves (EN 374).
If applicable
Protective nitrile gloves (EN 374).
Minimum layer thickness in mm:
0,4
Permeation time (penetration time) in minutes:
> 480
Protective gloves made of polyvinyl alcohol (EN 374)
Protective Viton® / fluoroelastomer gloves (EN 374)
Protective hand cream recommended.
The breakthrough times determined in accordance with EN 16523-1 were not obtained under practical conditions.
The recommended maximum wearing time is 50% of breakthrough time.

Skin protection - Other:


Protective working garments (e.g. safety shoes EN ISO 20345, long-sleeved protective working garments).

Respiratory protection:
If OES or MEL is exceeded.
Gas mask filter A (EN 14387), code colour brown
At high concentrations:
Respiratory protection appliance (insulation device) (e.g. EN 137 or EN 138)
Observe wearing time limitations for respiratory protection equipment.

Thermal hazards:
Not applicable

Additional information on hand protection - No tests have been performed.


In the case of mixtures, the selection has been made according to the knowledge available and the information about the contents.
Selection of materials derived from glove manufacturer's indications.
Final selection of glove material must be made taking the breakthrough times, permeation rates and degradation into account.
Selection of a suitable glove depends not only on the material but also on other quality characteristics and varies from manufacturer to
manufacturer.
In the case of mixtures, the resistance of glove materials cannot be predicted and must therefore be tested before use.
The exact breakthrough time of the glove material can be requested from the protective glove manufacturer and must be observed.

8.2.3 Environmental exposure controls


No information available at present.

SECTION 9: Physical and chemical properties


Page 7 of 15

Safety data sheet according to Regulation (EC) No 1907/2006, Annex II


Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509

9.1 Information on basic physical and chemical properties


Physical state: Liquid
Colour: Light brown, Clear
Odour: Characteristic
Odour threshold: Not determined
pH-value: n.a.
Melting point/freezing point: Not determined
Initial boiling point and boiling range: 180 °C
Flash point: 63 °C
Evaporation rate: Not determined
Flammability (solid, gas): Not determined
Lower explosive limit: 0,7 Vol-% (Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics,
<2% aromatics)
Upper explosive limit: 6 Vol-% (Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics,
<2% aromatics)
Vapour pressure: Not determined
Vapour density (air = 1): Vapours heavier than air.
Density: 0,816 g/ml (15°C)
Bulk density: Not determined
Solubility(ies): Not determined
Water solubility: Insoluble
Partition coefficient (n-octanol/water): Not determined
Auto-ignition temperature: Not determined
Decomposition temperature: Not determined
Viscosity: <7 mm2/s (40°C)
Explosive properties: Not determined
Oxidising properties: No
9.2 Other information
Miscibility: Not determined
Fat solubility / solvent: Not determined
Conductivity: Not determined
Surface tension: Not determined
Solvents content: Not determined

SECTION 10: Stability and reactivity

10.1 Reactivity
The product has not been tested.
10.2 Chemical stability
Stable with proper storage and handling.
10.3 Possibility of hazardous reactions
Risk of explosion if heated under confinement.
10.4 Conditions to avoid
Heating, open flame, ignition sources
Pressure increase will result in danger of bursting.
10.5 Incompatible materials
Avoid contact with strong oxidizing agents.
10.6 Hazardous decomposition products
No decomposition when used as directed.

SECTION 11: Toxicological information

11.1 Information on toxicological effects


Possibly more information on health effects, see Section 2.1 (classification).
Diesel Spuelung 500 mL
Art.: 2509
Page 8 of 15
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509

Toxicity / effect Endpoint Value Unit Organism Test method Notes


Acute toxicity, by oral route: ATE >2000 mg/kg calculated value
Acute toxicity, by dermal route: ATE >2000 mg/kg calculated value
Acute toxicity, by inhalation: ATE >20 mg/l/4h calculated value,
Vapours
Skin corrosion/irritation: n.d.a.
Serious eye damage/irritation: n.d.a.
Respiratory or skin n.d.a.
sensitisation:
Germ cell mutagenicity: n.d.a.
Carcinogenicity: n.d.a.
Reproductive toxicity: n.d.a.
Specific target organ toxicity - n.d.a.
single exposure (STOT-SE):
Specific target organ toxicity - n.d.a.
repeated exposure (STOT-RE):
Aspiration hazard: n.d.a.
Symptoms: n.d.a.

Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics


Toxicity / effect Endpoint Value Unit Organism Test method Notes
Acute toxicity, by oral route: LD50 >5000 mg/kg Rat OECD 401 (Acute Oral Analogous
Toxicity) conclusion
Acute toxicity, by dermal route: LD50 >5000 mg/kg Rabbit OECD 402 (Acute Analogous
Dermal Toxicity) conclusion
Acute toxicity, by inhalation: LC50 >4951 mg/m3/4h Rat OECD 403 (Acute Analogous
Inhalation Toxicity) conclusion,
Vapours
Skin corrosion/irritation: OECD 404 (Acute Not irritant,
Dermal Analogous
Irritation/Corrosion) conclusion
Serious eye damage/irritation: OECD 405 (Acute Eye Not irritant,
Irritation/Corrosion) Analogous
conclusion
Respiratory or skin OECD 406 (Skin Not sensitizising,
sensitisation: Sensitisation) Analogous
conclusion
Germ cell mutagenicity: OECD 473 (In Vitro Negative,
Mammalian Analogous
Chromosome conclusion
Aberration Test)
Germ cell mutagenicity: OECD 474 (Mammalian Negative,
Erythrocyte Analogous
Micronucleus Test) conclusion
Germ cell mutagenicity: Salmonella OECD 471 (Bacterial Negative
typhimurium Reverse Mutation Test)
Carcinogenicity: OECD 453 (Combined Negative,
Chronic Analogous
Toxicity/Carcinogenicity conclusion
Studies)
Reproductive toxicity: OECD 414 (Prenatal Negative,
Developmental Toxicity Analogous
Study) conclusion
Specific target organ toxicity - OECD 408 (Repeated Negative,
repeated exposure (STOT-RE): Dose 90-Day Oral Analogous
Toxicity Study in conclusion
Rodents)
Aspiration hazard: Yes
Symptoms: unconsciousness
, headaches,
dizziness
Page 9 of 15
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509

Other information: Repeated


exposure may
cause skin
dryness or
cracking.

2-Ethylhexylnitrate
Toxicity / effect Endpoint Value Unit Organism Test method Notes
Acute toxicity, by dermal route: Experiences on
persons.,
Harmful
Acute toxicity, by inhalation: Experiences on
persons.,
Harmful
Acute toxicity, by inhalation: LCLo >4,6 mg/l/1h Rat Mist
Skin corrosion/irritation: Rabbit OECD 404 (Acute Not irritant,
Dermal Repeated
Irritation/Corrosion) exposure may
cause skin
dryness or
cracking.
Serious eye damage/irritation: Rabbit OECD 405 (Acute Eye Mild irritant
Irritation/Corrosion)
Respiratory or skin Guinea pig OECD 406 (Skin No (skin contact)
sensitisation: Sensitisation)
Germ cell mutagenicity: Salmonella OECD 476 (In Vitro Negative
typhimurium Mammalian Cell Gene
Mutation Test)
Reproductive toxicity: NOAEL 100 mg/kg OECD 421 Negative
bw/d (Reproduction/Developm
ental Toxicity Screening
Test)
Symptoms: drying of the
skin., may cause
headaches and
vertigo., nausea,
drop in blood
pressure,
diarrhoea,
unconsciousness

Hydrocarbons, C10, aromatics, >1% naphthalene


Toxicity / effect Endpoint Value Unit Organism Test method Notes
Acute toxicity, by oral route: LD50 >5000 mg/kg Rat OECD 401 (Acute Oral
Toxicity)
Acute toxicity, by dermal route: LD50 >2000 mg/kg Rabbit OECD 402 (Acute
Dermal Toxicity)
Acute toxicity, by inhalation: LC50 >4688 mg/m3 Rat OECD 403 (Acute
Inhalation Toxicity)
Skin corrosion/irritation: OECD 404 (Acute Not irritant
Dermal
Irritation/Corrosion)
Serious eye damage/irritation: OECD 405 (Acute Eye Mild irritant
Irritation/Corrosion)
Respiratory or skin OECD 406 (Skin Not sensitizising,
sensitisation: Sensitisation) Analogous
conclusion
Germ cell mutagenicity: OECD 479 (Genetic Negative
Toxicology - In Vitro
Sister Chromatid
Exchange assay in
Mammalian Cells)
Page 10 of 15
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509

Germ cell mutagenicity: OECD 471 (Bacterial Negative,


Reverse Mutation Test) Analogous
conclusion
Reproductive toxicity: OECD 414 (Prenatal Negative,
Developmental Toxicity Analogous
Study) conclusion
Reproductive toxicity: OECD 416 (Two- Negative,
generation Analogous
Reproduction Toxicity conclusion
Study)
Reproductive toxicity Rat OECD 415 (One- Negative,
(Developmental toxicity): Generation Analogous
Reproduction Toxicity conclusion
Study)
Reproductive toxicity (Effects Rat OECD 415 (One- Negative,
on fertility): Generation Analogous
Reproduction Toxicity conclusion
Study)
Specific target organ toxicity - Vapours may
single exposure (STOT-SE): cause
drowsiness and
dizziness.
Specific target organ toxicity - OECD 408 (Repeated Negative,
repeated exposure (STOT-RE): Dose 90-Day Oral Analogous
Toxicity Study in conclusion
Rodents)
Specific target organ toxicity - OECD 413 (Subchronic Negative,
repeated exposure (STOT-RE): Inhalation Toxicity - 90- Analogous
Day Study) conclusion
Specific target organ toxicity - OECD 452 (Chronic Negative,
repeated exposure (STOT-RE): Toxicity Studies) Analogous
conclusion
Aspiration hazard: Yes
Symptoms: drowsiness,
headaches,
drowsiness,
dizziness

SECTION 12: Ecological information

Possibly more information on environmental effects, see Section 2.1 (classification).


Diesel Spuelung 500 mL
Art.: 2509
Toxicity / effect Endpoint Time Value Unit Organism Test method Notes
12.1. Toxicity to fish: n.d.a.
12.1. Toxicity to daphnia: n.d.a.
12.1. Toxicity to algae: n.d.a.
12.2. Persistence and Isolate as much
degradability: as possible with
an oil separator.
12.3. Bioaccumulative n.d.a.
potential:
12.4. Mobility in soil: n.d.a.
12.5. Results of PBT n.d.a.
and vPvB assessment
12.6. Other adverse n.d.a.
effects:
Other information: According to the
recipe, contains
no AOX.

Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics


Page 11 of 15
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509

Toxicity / effect Endpoint Time Value Unit Organism Test method Notes
12.5. Results of PBT No PBT
and vPvB assessment substance, No
vPvB substance
Water solubility: Product floats on
the water
surface.
12.1. Toxicity to fish: LL50 96h >1000 mg/l Oncorhynchus OECD 203 (Fish,
mykiss Acute Toxicity
Test)
12.1. Toxicity to fish: NOELR 28d 0,101 mg/l Oncorhynchus
mykiss
12.1. Toxicity to daphnia: EL50 48h >1000 mg/l Daphnia magna OECD 202
(Daphnia sp.
Acute
Immobilisation
Test)
12.1. Toxicity to daphnia: NOELR 21d 0,176 mg/l Daphnia magna
12.2. Persistence and 28d 80 % activated sludge OECD 301 F Readily
degradability: (Ready biodegradable
Biodegradability -
Manometric
Respirometry Test)
12.1. Toxicity to algae: EL50 72h >1000 mg/l Pseudokirchneriell OECD 201 (Alga,
a subcapitata Growth Inhibition
Test)
Other organisms: EL50 48h >1000 mg/l Tetrahymen
pyriformis

2-Ethylhexylnitrate
Toxicity / effect Endpoint Time Value Unit Organism Test method Notes
12.1. Toxicity to fish: LC50 96h 1,88 mg/l Brachydanio rerio
12.1. Toxicity to fish: LC50 96h 2 mg/l Brachydanio rerio OECD 203 (Fish,
Acute Toxicity
Test)
12.1. Toxicity to daphnia: EC50 48h >12,6 mg/l Daphnia magna
12.1. Toxicity to daphnia: EC50 48h >12,6 mg/l Daphnia magna OECD 202
(Daphnia sp.
Acute
Immobilisation
Test)
12.2. Persistence and 28d 0 % OECD 310 Not readily
degradability: (Ready biodegradable
Biodegradability -
CO2 in sealed
vessels
(Headspace Test))
12.3. Bioaccumulative BCF 1332
potential:
12.3. Bioaccumulative Log Pow 3,74- A notable
potential: 5,24 biological
accumulation
potential has to
be expected
(LogPow > 3).
12.5. Results of PBT No PBT
and vPvB assessment substance, No
vPvB substance
Page 12 of 15
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509

12.4. Mobility in soil: Log Koc 3,75 OECD 121


(Estimation of the
Adsorption
Coefficient (Koc)
on Soil and on
Sewage Sludge
using HPLC)
Other information: AOX 0 % No
Water solubility: Slight

Hydrocarbons, C10, aromatics, >1% naphthalene


Toxicity / effect Endpoint Time Value Unit Organism Test method Notes
12.1. Toxicity to fish: LL50 96h 2-5 mg/l Oncorhynchus
mykiss
12.1. Toxicity to daphnia: EL50 48h 3-10 mg/l Daphnia magna
12.1. Toxicity to algae: EL50 72h 11 mg/l Pseudokirchneriell
a subcapitata
12.1. Toxicity to algae: NOELR 72h 2,5 mg/l Pseudokirchneriell
a subcapitata
12.2. Persistence and 28d 57,95 % Readily
degradability: biodegradable
12.3. Bioaccumulative Log Pow 2,8-6,5 High
potential:
12.5. Results of PBT No PBT
and vPvB assessment substance, No
vPvB substance

SECTION 13: Disposal considerations

13.1 Waste treatment methods


For the substance / mixture / residual amounts
EC disposal code no.:
The waste codes are recommendations based on the scheduled use of this product.
Owing to the user's specific conditions for use and disposal, other waste codes may be
allocated under certain circumstances. (2014/955/EU)
07 07 04 other organic solvents, washing liquids and mother liquors
14 06 03 other solvents and solvent mixtures
Recommendation:
Sewage disposal shall be discouraged.
Pay attention to local and national official regulations.
Implement substance recycling.
E.g. suitable incineration plant.
For contaminated packing material
Pay attention to local and national official regulations.
Empty container completely.
Uncontaminated packaging can be recycled.
Dispose of packaging that cannot be cleaned in the same manner as the substance.

SECTION 14: Transport information

General statements
14.1. UN number: n.a.
Transport by road/by rail (ADR/RID)
14.2. UN proper shipping name:
14.3. Transport hazard class(es): n.a.
14.4. Packing group: n.a.
Classification code: n.a.
LQ: n.a.
14.5. Environmental hazards: Not applicable
Page 13 of 15
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509

Tunnel restriction code:


Transport by sea (IMDG-code)
14.2. UN proper shipping name:
14.3. Transport hazard class(es): n.a.
14.4. Packing group: n.a.
Marine Pollutant: n.a
14.5. Environmental hazards: Not applicable
Transport by air (IATA)
14.2. UN proper shipping name:
14.3. Transport hazard class(es): n.a.
14.4. Packing group: n.a.
14.5. Environmental hazards: Not applicable
14.6. Special precautions for user
Unless specified otherwise, general measures for safe transport must be followed.
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Non-dangerous material according to Transport Regulations.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Observe restrictions:
Comply with trade association/occupational health regulations.

Directive 2010/75/EU (VOC): ~ 97,7 %


Directive 2010/75/EU (VOC): 797,2 g/l

15.2 Chemical safety assessment


A chemical safety assessment is not provided for mixtures.

SECTION 16: Other information

Revised sections: 2
These details refer to the product as it is delivered.
Employee instruction/training in handling hazardous materials is required.

Classification and processes used to derive the classification of the mixture in accordance with
the ordinance (EG) 1272/2008 (CLP):

Classification in accordance with regulation Evaluation method used


(EC) No. 1272/2008 (CLP)
Asp. Tox. 1, H304 Classification according to calculation procedure.
Aquatic Chronic 3, H412 Classification according to calculation procedure.

The following phrases represent the posted Hazard Class and Risk Category Code (GHS/CLP) of the product and the constituents (specified in
Section 2 and 3).
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H332 Harmful if inhaled.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H411 Toxic to aquatic life with long lasting effects.

Asp. Tox. — Aspiration hazard


Aquatic Chronic — Hazardous to the aquatic environment - chronic
Acute Tox. — Acute toxicity - oral
Acute Tox. — Acute toxicity - dermal
Page 14 of 15
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509

Acute Tox. — Acute toxicity - inhalation


Carc. — Carcinogenicity
STOT SE — Specific target organ toxicity - single exposure - narcotic effects

Any abbreviations and acronyms used in this document:

acc., acc. to according, according to


ADR Accord européen relatif au transport international des marchandises Dangereuses par Route (= European Agreement concerning the
International Carriage of Dangerous Goods by Road)
AOX Adsorbable organic halogen compounds
approx. approximately
Art., Art. no. Article number
ASTM ASTM International (American Society for Testing and Materials)
BAM Bundesanstalt für Materialforschung und -prüfung (Federal Institute for Materials Research and Testing, Germany)
BAuA Bundesanstalt für Arbeitsschutz und Arbeitsmedizin (= Federal Institute for Occupational Health and Safety, Germany)
BSEF The International Bromine Council
bw body weight
CAS Chemical Abstracts Service
CLP Classification, Labelling and Packaging (REGULATION (EC) No 1272/2008 on classification, labelling and packaging of substances
and mixtures)
CMR carcinogenic, mutagenic, reproductive toxic
DMEL Derived Minimum Effect Level
DNEL Derived No Effect Level
dw dry weight
e.g. for example (abbreviation of Latin 'exempli gratia'), for instance
EC European Community
ECHA European Chemicals Agency
EEC European Economic Community
EINECS European Inventory of Existing Commercial Chemical Substances
ELINCS European List of Notified Chemical Substances
EN European Norms
EPA United States Environmental Protection Agency (United States of America)
etc. et cetera
EU European Union
EVAL Ethylene-vinyl alcohol copolymer
Fax. Fax number
gen. general
GHS Globally Harmonized System of Classification and Labelling of Chemicals
GWP Global warming potential
IARC International Agency for Research on Cancer
IATA International Air Transport Association
IBC (Code) International Bulk Chemical (Code)
IMDG-code International Maritime Code for Dangerous Goods
incl. including, inclusive
IUCLID International Uniform Chemical Information Database
LQ Limited Quantities
MARPOL International Convention for the Prevention of Marine Pollution from Ships
n.a. not applicable
n.av. not available
n.c. not checked
n.d.a. no data available
OECD Organisation for Economic Co-operation and Development
org. organic
PBT persistent, bioaccumulative and toxic
PE Polyethylene
PNEC Predicted No Effect Concentration
ppm parts per million
PVC Polyvinylchloride
REACHRegistration, Evaluation, Authorisation and Restriction of Chemicals (REGULATION (EC) No 1907/2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals)
REACH-IT List-No. 9xx-xxx-x No. is automatically assigned, e.g. to pre-registrations without a CAS No. or other numerical identifier. List
Numbers do not have any legal significance, rather they are purely technical identifiers for processing a submission via REACH-IT.
Page 15 of 15
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509

RID Règlement concernant le transport International ferroviaire de marchandises Dangereuses (= Regulation concerning the International
Carriage of Dangerous Goods by Rail)
SVHC Substances of Very High Concern
Tel. Telephone
UN RTDG United Nations Recommendations on the Transport of Dangerous Goods
VOC Volatile organic compounds
vPvB very persistent and very bioaccumulative
wwt wet weight

The statements made here should describe the product with regard to the necessary safety precautions - they are
not meant to guarantee definite characteristics - but they are based on our present up-to-date knowledge.
No responsibility.
These statements were made by:
Chemical Check GmbH, Chemical Check Platz 1-7, D-32839 Steinheim, Tel.: +49 5233 94 17 0, Fax:
+49 5233 94 17 90
© by Chemical Check GmbH Gefahrstoffberatung. The copying or changing of this document
is forbidden except with consent of the Chemical Check GmbH Gefahrstoffberatung.

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