Liquid Molly Diesel Purge
Liquid Molly Diesel Purge
Liquid Molly Diesel Purge
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Page 2 of 15
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509
H304-May be fatal if swallowed and enters airways. H412-Harmful to aquatic life with long lasting effects.
P101-If medical advice is needed, have product container or label at hand. P102-Keep out of reach of children.
P301+P310-IF SWALLOWED: Immediately call a POISON CENTER / doctor. P331-Do NOT induce vomiting.
P405-Store locked up.
P501-Dispose of contents / container to an approved waste disposal facility.
3.1 Substance
n.a.
3.2 Mixture
Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics
Registration number (REACH) 01-2119457273-39-XXXX
Index ---
EINECS, ELINCS, NLP 918-481-9 (REACH-IT List-No.)
CAS ---
content % 80-<100
Classification according to Regulation (EC) 1272/2008 (CLP) Asp. Tox. 1, H304
2-Ethylhexylnitrate
Registration number (REACH) 01-2119539586-27-XXXX
Index ---
EINECS, ELINCS, NLP 248-363-6
CAS 27247-96-7
content % 5-15
Classification according to Regulation (EC) 1272/2008 (CLP) Acute Tox. 4, H302
Acute Tox. 4, H312
Acute Tox. 4, H332
Aquatic Chronic 2, H411
Impurities, test data and additional information may have been taken into account in classifying and labelling the product.
For the text of the H-phrases and classification codes (GHS/CLP), see Section 16.
The substances named in this section are given with their actual, appropriate classification!
For substances that are listed in appendix VI, table 3.1 of the regulation (EC) no. 1272/2008 (CLP regulation) this means that all notes that may
be given here for the named classification have been taken into account.
If, for example, the note P is applied for a hydrocarbon then this has already been taken into account for the classification named here.
Page 3 of 15
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509
Quote: "Note P - The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0,1 %
w/w benzene (EINECS No 200-753-7)."
Article 4 of the regulation (EC) no. 1272/2008 (CLP regulation) was also observed and taken into account for the classification named here.
In addition to information given in this section, relevant information can also be found in section 8 and 6.1.
7.1 Precautions for safe handling
7.1.1 General recommendations
Ensure good ventilation.
Keep away from sources of ignition - Do not smoke.
Eating, drinking, smoking, as well as food-storage, is prohibited in work-room.
Observe directions on label and instructions for use.
Use working methods according to operating instructions.
7.1.2 Notes on general hygiene measures at the workplace
General hygiene measures for the handling of chemicals are applicable.
Wash hands before breaks and at end of work.
Keep away from food, drink and animal feedingstuffs.
Remove contaminated clothing and protective equipment before entering areas in which food is consumed.
7.2 Conditions for safe storage, including any incompatibilities
Keep out of access to unauthorised individuals.
Store product closed and only in original packing.
Not to be stored in gangways or stair wells.
Solvent resistant floor
Do not store with oxidizing agents.
Store in a well ventilated place.
Protect from direct sunlight and warming.
Store cool.
7.3 Specific end use(s)
No information available at present.
Content %:80-
Chemical Name Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics
<100
WEL-TWA: 800 mg/m3 WEL-STEL: --- ---
Monitoring procedures: - Draeger - Hydrocarbons 2/a (81 03 581)
- Draeger - Hydrocarbons 0,1%/c (81 03 571)
- Compur - KITA-187 S (551 174)
BMGV: --- Other information: (OEL acc. to RCP-method,
paragraphs 84-87, EH40)
Chemical Name Hydrocarbons, C10, aromatics, >1% naphthalene Content %:0,1-<1
WEL-TWA: 500 mg/m3 (Aromatics) WEL-STEL: --- ---
Monitoring procedures: - Draeger - Hydrocarbons 2/a (81 03 581)
- Draeger - Hydrocarbons 0,1%/c (81 03 571)
- Compur - KITA-187 S (551 174)
BMGV: --- Other information: ---
2-Ethylhexylnitrate
Area of application Exposure route / Effect on health Descriptor Value Unit Note
Environmental
compartment
Environment - freshwater PNEC 0,8 µg/l
Environment - marine PNEC 0,08 µg/l
Environment - sediment PNEC 0,00074 mg/kg dw
Environment - soil PNEC 0,00019 mg/kg dw
1
Consumer Human - dermal Long term, systemic DNEL 0,52 mg/kg
effects bw/day
Consumer Human - inhalation Long term, systemic DNEL 0,087 mg/m3
effects
Consumer Human - oral Long term, systemic DNEL 0,025 mg/kg
effects bw/day
Consumer Human - dermal Long term, local effects DNEL 0,022 mg/cm2
Workers / employees Human - dermal Long term, systemic DNEL 1 mg/kg
effects bw/day
Workers / employees Human - inhalation Long term, systemic DNEL 0,35 mg/m3
effects
Workers / employees Human - dermal Long term, local effects DNEL 0,044 mg/cm2
WEL-TWA = Workplace Exposure Limit - Long-term exposure limit (8-hour TWA (= time weighted average) reference period) EH40. AGW =
"Arbeitsplatzgrenzwert" (workplace limit value, Germany).
(8) = Inhalable fraction (2017/164/EU, 2017/2398/EU). (9) = Respirable fraction (2017/164/EU, 2017/2398/EU). | WEL-STEL = Workplace
Exposure Limit - Short-term exposure limit (15-minute reference period).
(8) = Inhalable fraction (2017/164/EU, 2017/2398/EU). (9) = Respirable fraction (2017/164/EU, 2017/2398/EU). (10) = Short-term exposure limit
value in relation to a reference period of 1 minute (2017/164/EU). | BMGV = Biological monitoring guidance value EH40. BGW = "Biologischer
Grenzwert" (biological limit value, Germany) | Other information: Sen = Capable of causing occupational asthma. Sk = Can be absorbed through
skin. Carc = Capable of causing cancer and/or heritable genetic damage.
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Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509
** = The exposure limit for this substance is repealed through the TRGS 900 (Germany) of January 2006 with the goal of revision.
Eye/face protection:
Tight fitting protective goggles with side protection (EN 166).
Respiratory protection:
If OES or MEL is exceeded.
Gas mask filter A (EN 14387), code colour brown
At high concentrations:
Respiratory protection appliance (insulation device) (e.g. EN 137 or EN 138)
Observe wearing time limitations for respiratory protection equipment.
Thermal hazards:
Not applicable
10.1 Reactivity
The product has not been tested.
10.2 Chemical stability
Stable with proper storage and handling.
10.3 Possibility of hazardous reactions
Risk of explosion if heated under confinement.
10.4 Conditions to avoid
Heating, open flame, ignition sources
Pressure increase will result in danger of bursting.
10.5 Incompatible materials
Avoid contact with strong oxidizing agents.
10.6 Hazardous decomposition products
No decomposition when used as directed.
2-Ethylhexylnitrate
Toxicity / effect Endpoint Value Unit Organism Test method Notes
Acute toxicity, by dermal route: Experiences on
persons.,
Harmful
Acute toxicity, by inhalation: Experiences on
persons.,
Harmful
Acute toxicity, by inhalation: LCLo >4,6 mg/l/1h Rat Mist
Skin corrosion/irritation: Rabbit OECD 404 (Acute Not irritant,
Dermal Repeated
Irritation/Corrosion) exposure may
cause skin
dryness or
cracking.
Serious eye damage/irritation: Rabbit OECD 405 (Acute Eye Mild irritant
Irritation/Corrosion)
Respiratory or skin Guinea pig OECD 406 (Skin No (skin contact)
sensitisation: Sensitisation)
Germ cell mutagenicity: Salmonella OECD 476 (In Vitro Negative
typhimurium Mammalian Cell Gene
Mutation Test)
Reproductive toxicity: NOAEL 100 mg/kg OECD 421 Negative
bw/d (Reproduction/Developm
ental Toxicity Screening
Test)
Symptoms: drying of the
skin., may cause
headaches and
vertigo., nausea,
drop in blood
pressure,
diarrhoea,
unconsciousness
Toxicity / effect Endpoint Time Value Unit Organism Test method Notes
12.5. Results of PBT No PBT
and vPvB assessment substance, No
vPvB substance
Water solubility: Product floats on
the water
surface.
12.1. Toxicity to fish: LL50 96h >1000 mg/l Oncorhynchus OECD 203 (Fish,
mykiss Acute Toxicity
Test)
12.1. Toxicity to fish: NOELR 28d 0,101 mg/l Oncorhynchus
mykiss
12.1. Toxicity to daphnia: EL50 48h >1000 mg/l Daphnia magna OECD 202
(Daphnia sp.
Acute
Immobilisation
Test)
12.1. Toxicity to daphnia: NOELR 21d 0,176 mg/l Daphnia magna
12.2. Persistence and 28d 80 % activated sludge OECD 301 F Readily
degradability: (Ready biodegradable
Biodegradability -
Manometric
Respirometry Test)
12.1. Toxicity to algae: EL50 72h >1000 mg/l Pseudokirchneriell OECD 201 (Alga,
a subcapitata Growth Inhibition
Test)
Other organisms: EL50 48h >1000 mg/l Tetrahymen
pyriformis
2-Ethylhexylnitrate
Toxicity / effect Endpoint Time Value Unit Organism Test method Notes
12.1. Toxicity to fish: LC50 96h 1,88 mg/l Brachydanio rerio
12.1. Toxicity to fish: LC50 96h 2 mg/l Brachydanio rerio OECD 203 (Fish,
Acute Toxicity
Test)
12.1. Toxicity to daphnia: EC50 48h >12,6 mg/l Daphnia magna
12.1. Toxicity to daphnia: EC50 48h >12,6 mg/l Daphnia magna OECD 202
(Daphnia sp.
Acute
Immobilisation
Test)
12.2. Persistence and 28d 0 % OECD 310 Not readily
degradability: (Ready biodegradable
Biodegradability -
CO2 in sealed
vessels
(Headspace Test))
12.3. Bioaccumulative BCF 1332
potential:
12.3. Bioaccumulative Log Pow 3,74- A notable
potential: 5,24 biological
accumulation
potential has to
be expected
(LogPow > 3).
12.5. Results of PBT No PBT
and vPvB assessment substance, No
vPvB substance
Page 12 of 15
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509
General statements
14.1. UN number: n.a.
Transport by road/by rail (ADR/RID)
14.2. UN proper shipping name:
14.3. Transport hazard class(es): n.a.
14.4. Packing group: n.a.
Classification code: n.a.
LQ: n.a.
14.5. Environmental hazards: Not applicable
Page 13 of 15
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 18.07.2019 / 0028
Replacing version dated / version: 09.07.2018 / 0027
Valid from: 18.07.2019
PDF print date: 19.07.2019
Diesel Spuelung 500 mL
Art.: 2509
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Observe restrictions:
Comply with trade association/occupational health regulations.
Revised sections: 2
These details refer to the product as it is delivered.
Employee instruction/training in handling hazardous materials is required.
Classification and processes used to derive the classification of the mixture in accordance with
the ordinance (EG) 1272/2008 (CLP):
The following phrases represent the posted Hazard Class and Risk Category Code (GHS/CLP) of the product and the constituents (specified in
Section 2 and 3).
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H332 Harmful if inhaled.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H411 Toxic to aquatic life with long lasting effects.
RID Règlement concernant le transport International ferroviaire de marchandises Dangereuses (= Regulation concerning the International
Carriage of Dangerous Goods by Rail)
SVHC Substances of Very High Concern
Tel. Telephone
UN RTDG United Nations Recommendations on the Transport of Dangerous Goods
VOC Volatile organic compounds
vPvB very persistent and very bioaccumulative
wwt wet weight
The statements made here should describe the product with regard to the necessary safety precautions - they are
not meant to guarantee definite characteristics - but they are based on our present up-to-date knowledge.
No responsibility.
These statements were made by:
Chemical Check GmbH, Chemical Check Platz 1-7, D-32839 Steinheim, Tel.: +49 5233 94 17 0, Fax:
+49 5233 94 17 90
© by Chemical Check GmbH Gefahrstoffberatung. The copying or changing of this document
is forbidden except with consent of the Chemical Check GmbH Gefahrstoffberatung.