SAFETY DATA SHEET

GENAPOL X 080 Page 1

Substance key: SXR004861 Revision Date: 10/04/2021

Version : 6 - 2 / USA Date of printing :07/01/2024

SECTION 1. IDENTIFICATION

Identification of the Clariant Produkte (Deutschland) GmbH

company: Frankfurt am Main, 65926
Telephone No.: +49 69 305 18000

Information of the substance/preparation:

Product Stewardship, +1-704-331-7710
e-mail: SDS.NORAM@clariant.com
Emergency tel. number: +1 800-424-9300 CHEMTREC

Trade name: GENAPOL X 080

Material number: 100288
Synonyms: Product Has No Synonyms

Primary product use: Auxiliary for formulating plant protection products

Primary product use: Surface active agents
Chemical family: A fatty alcohol polyglycol ether.

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Acute toxicity (Oral) : Category 4

Serious eye damage : Category 1

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : H302 Harmful if swallowed.

H318 Causes serious eye damage.

Precautionary statements :
Prevention:
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear eye protection/ face protection.
Response:
P301 + P312 + P330 IF SWALLOWED: Call a POISON
CENTER/ doctor if you feel unwell. Rinse mouth.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
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Substance key: SXR004861 Revision Date: 10/04/2021

Version : 6 - 2 / USA Date of printing :07/01/2024

water for several minutes. Remove contact lenses, if present

and easy to do. Continue rinsing. Immediately call a POISON
CENTER/ doctor.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Substance

Substance name : A fatty alcohol polyglycol ether.

CAS-No. : Not Assigned

Components
Chemical name CAS-No. Concentration (% w/w)
Alcohols, C11-14-iso-, C13-rich, 78330-21-9 >= 90 - <= 100
ethoxylated
Actual concentration is withheld as a trade secret

SECTION 4. FIRST AID MEASURES

General advice : Remove/ Take off immediately all contaminated clothing.

Show this safety data sheet to the doctor in attendance.

If inhaled : If irritation of nose or throat develops from exposure to fumes,

move away from source of exposure and into fresh air. If
irritation develops, get medical attention.

In case of skin contact : Wash thoroughly with soap and water for 15 minutes. If skin
irritation occurs, seek medical attention.

In case of eye contact : Do not wear contact lenses.

Rinse immediately with plenty of water, also under the eyelids.
Get medical attention immediately.

If swallowed : IF SWALLOWED: Immediately call a POISON CENTER/

doctor.

Most important symptoms : The possible symptoms known are those derived from the
and effects, both acute and labelling (see section 2).
delayed No additional symptoms are known.

Protection of first-aiders : First Aid responders should pay attention to self-protection

and use the recommended protective clothing
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Substance key: SXR004861 Revision Date: 10/04/2021

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Notes to physician : None known.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water spray jet

Alcohol-resistant foam
Carbon dioxide (CO2)
Dry powder

Unsuitable extinguishing : High volume water jet

media

Specific hazards during : In case of fire hazardous decomposition products may be

firefighting produced such as:
Carbon monoxide
Carbon dioxide (CO2)
Combustion gases of organic materials must in principle be
graded as inhalation poisons.

Emits toxic fumes under fire conditions. Product floats on

water creating a potential floating fire hazard..

Further information : Apply alcohol-type or all purpose-type foams by

manufacturers' recommended techniques for large fires. Use
carbon dioxide or dry chemical media for small fires. Do not
direct a solid stream of water or foam into hot burning pools;
this may cause frothing and increase fire intensity. Use self-
contained breathing apparatus and protective equipment.

Special protective equipment : Self-contained breathing apparatus

for firefighters

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Wear suitable protective clothing.

protective equipment and Wearing appropriate personal protective equipment, contain
emergency procedures spill, collect onto inert absorbent, and place in a suitable
container.

Environmental precautions : Do not empty into drains.

Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Can be landfilled or incinerated, when in compliance with local
regulations.

SECTION 7. HANDLING AND STORAGE

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Advice on protection against : Observe the general rules of industrial fire protection
fire and explosion

Advice on safe handling : Avoid contact with skin and eyes.

Further information on : Keep container closed.

storage conditions

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Contains no substances with occupational exposure limit values.
Engineering measures : Use adequate exhaust ventilation and/or dust collection to
keep dust levels below exposure limits.

Personal protective equipment

Respiratory protection : If airborne concentrations pose a health hazard, become
irritating or exceed recommended limits, use a NIOSH
approved respirator in accordance with OSHA respiratory
protection requirements under 29 CFR 1910.134

Hand protection
Remarks : Butyl Rubber, PVC Or Neoprene.

Eye protection : Chemical splash goggles with face shield.

Skin and body protection : Protective clothing to minimize skin contact should be worn.
Chemically resistant safety shoes. Wash contaminated
clothing with soap and water and dry before reuse. Safety
showers and eyewash stations should be provided in all
areas where this material is handled.

Protective measures : Avoid contact with skin and eyes.

Hygiene measures : Wash hands before breaks and at the end of workday.
Use protective skin cream before handling the product.
Take off immediately all contaminated clothing and wash it
before reuse.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Liquid

Colour : colourless to slightly yellow

Odour : characteristic
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Odour Threshold : not determined

pH : 6 - 8 (68 °F / 20 °C)
Concentration: 50 g/l
Method: DIN 53996
Ethanol/Water 1:1

pour point : approx. 52 °F / 11 °C

Method: ISO 3016

Boiling point : not determined

Flash point : approx. 374 °F / 190 °C

Method: DIN/ISO 2592 (open cup)

Evaporation rate : not determined

Flammability (solid, gas) : Not applicable

Self-ignition : no data available

Upper explosion limit / upper : Not applicable

flammability limit

Lower explosion limit / Lower : Not applicable

flammability limit

Vapour pressure : < 0.001 kPa (68 °F / 20 °C)

Method: Calculated by Syracuse.

Relative vapour density : no data available

Density : 0.98 g/cm3 (122 °F / 50 °C)

Method: DIN 51757

Solubility(ies)
Water solubility : soluble (68 °F / 20 °C)

Partition coefficient: n- : Not applicable

octanol/water

Auto-ignition temperature : Not applicable

Decomposition temperature : > 572 °F / > 300 °C

Method: DSC
No decomposition if used as directed.

Viscosity
Viscosity, dynamic : 100 mPa.s (68 °F / 20 °C)
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Substance key: SXR004861 Revision Date: 10/04/2021

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Method: DIN 53015

Viscosity, kinematic : no data available

Metal corrosion rate : Not applicable

Particle size : Not applicable

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : Stable

Possibility of hazardous : No dangerous reaction known under conditions of normal use.

reactions Stable

Conditions to avoid : Strong acids and oxidizing agents

Incompatible materials : not known

Hazardous decomposition : When handled and stored appropriately, no dangerous

products decomposition products are known

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Eye contact
Skin contact
Ingestion
Inhalation
Acute toxicity
Product:
Acute oral toxicity : LD50 (Rat): 500 - 2,000 mg/kg

Acute inhalation toxicity : Remarks: no data available

Acute dermal toxicity : LD50 (Rat, female): > 2,000 mg/kg

Method: OECD Test Guideline 402

Components:
Alcohols, C11-14-iso-, C13-rich, ethoxylated:
Acute oral toxicity : Assessment: The component/mixture is moderately toxic after
single ingestion.

Skin corrosion/irritation
Product:
Species: Rabbit
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Result: No skin irritation

Serious eye damage/eye irritation

Product:
Species: rabbit eye
Result: Risk of serious damage to eyes.

Components:
Alcohols, C11-14-iso-, C13-rich, ethoxylated:
Result: Risk of serious damage to eyes.

Respiratory or skin sensitisation

Product:
Remarks: no data available

Germ cell mutagenicity

Product:
Germ cell mutagenicity - : No information available.
Assessment

Carcinogenicity
Product:
Carcinogenicity - : No information available.
Assessment

IARC No component of this product present at levels greater than or

equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

OSHA No component of this product present at levels greater than or

equal to 0.1% is on OSHA’s list of regulated carcinogens.

NTP No component of this product present at levels greater than or

equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Reproductive toxicity
Product:
Reproductive toxicity - : No information available.
Assessment No information available.

STOT - single exposure

Product:
Remarks: no data available
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STOT - repeated exposure

Product:
Remarks: no data available

Repeated dose toxicity

Product:
Remarks: no data available

Aspiration toxicity
Product:
no data available

Experience with human exposure

Product:
General Information : The possible symptoms known are those derived from the
labelling (see section 2).

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Product:
Toxicity to fish : LC50 (Danio rerio (zebra fish)): > 1 - 10 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 7.07 mg/l
aquatic invertebrates Exposure time: 48 h
Method: OECD Test Guideline 202
GLP: yes

Toxicity to algae/aquatic : EC50 (Desmodesmus subspicatus (green algae)): >= 10 mg/l

plants Exposure time: 72 h
Method: OECD Test Guideline 201
GLP: yes

Toxicity to microorganisms : EC50 (Pseudomonas putida): > 1,000 mg/l

Exposure time: 17 h
Method: DIN 38412 T.8

Components:
Alcohols, C11-14-iso-, C13-rich, ethoxylated:
Ecotoxicology Assessment
Acute aquatic toxicity : Toxic to aquatic life.
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Chronic aquatic toxicity : Harmful to aquatic life with long lasting effects.

Persistence and degradability

Product:
Biodegradability : Biodegradation: approx. 70 %
Method: OECD Test Guideline 302B

Inoculum: activated sludge, non-adapted

Concentration: 25 mg/l
Result: Biodegradable
Biodegradation: 60 %
Exposure time: 28 d
Method: OECD Test Guideline 301F
GLP: yes

Chemical Oxygen Demand : 1,980 mg/g

(COD) Method: DIN 38409-H-41

Dissolved organic carbon : 600 mg/g

(DOC)

Bioaccumulative potential
Product:
Bioaccumulation : Remarks: no data available

Mobility in soil
Product:
Distribution among : Remarks: no data available
environmental compartments

Other adverse effects

Product:
Additional ecological : no data available
information

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
RCRA - Resource : This product, if discarded as sold, is not a Federal RCRA
Conservation and Recovery hazardous waste.
Authorization Act
Waste Code : NONE

Waste from residues : Must be incinerated in a suitable incineration plant holding a

permit delivered by the competent authorities.
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Contaminated packaging : Regulations concerning reuse or disposal of used packaging

materials must be observed.

SECTION 14. TRANSPORT INFORMATION

DOT not restricted

IATA not restricted
IMDG not restricted

SECTION 15. REGULATORY INFORMATION

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 302 Extremely Hazardous Substances Threshold Planning Quantity
This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards : Serious eye damage or eye irritation
Acute toxicity (any route of exposure)

SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

Clean Air Act

This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 112 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111
SOCMI Intermediate or Final VOC's (40 CFR 60.489).
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act,
Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section
307
This product does not contain any priority pollutants related to the U.S. Clean Water Act
The components of this product are reported in the following inventories:
TSCA : On TSCA Inventory, All components are compliant with the
TSCA Inventory Notification (Active) rule.
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SECTION 16. OTHER INFORMATION

Further information

NFPA 704:

Flammability

1
Health Instability
3 0

Special hazard

Full text of other abbreviations

AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response,
Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN -
Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL -
Domestic Substances List (Canada); ECx - Concentration associated with x% response; EHS -
Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS -
Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx -
Concentration associated with x% growth rate response; ERG - Emergency Response Guide;
GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous
Materials Identification System; IARC - International Agency for Research on Cancer; IATA -
International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test
population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise
Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals;
OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical
Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS
- Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure
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Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation
(EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-
Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization
Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand
Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United
Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative

Observe national and local legal requirements

This product may contain trace amounts of Ethylene Oxide (75-21-8) which may accumulate in
the headspace of shipping and storage containers and in enclosed areas where the product is
handled or used and as such may be regulated by OSHA's Ethylene Oxide standard (29 CFR
1910.1047). Ethylene Oxide is listed as a human carcinogen by OSHA; and a potential human
carcinogen by NTP and IARC. At excess levels, Ethylene Oxide may present reproductive,
mutagenic, genotoxic, neurologic, and sensitization hazards in humans. Users should monitor
personnel to determine levels of exposure and take appropriate action to protect employees and
to comply with the OSHA standard. OSHA Ethylene Oxide exposure limit: OSHA Action level: 0.5
ppm for 8-hr twa. OSHA Permissible Exposure limit: 1 ppm for 8-hr twa. OSHA Excursion limit: 5
ppm for 15 minutes. ACGIH Threshold Limit value for Ethylene Oxide: 1 ppm for 8-hr twa.

Revision Date : 10/04/2021

This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information’s accuracy, adequacy, sufficiency or freedom from defect and
assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application. NO
EXPRESS OR IMPLIED WARRANTY IS MADE OF THE MERCHANTABILITY, SUITABILITY,
FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE OF ANY PRODUCT OR
SERVICE. Nothing included in this information waives any of Clariant’s General Terms and
Conditions of Sale, which control unless it agrees otherwise in writing. Any existing
intellectual/industrial property rights must be observed. Due to possible changes in our products
and applicable national and international regulations and laws, the status of our products could
change. Material Safety Data Sheets providing safety precautions, that should be observed when
handling or storing Clariant products, are available upon request and are provided in compliance
with applicable law. You should obtain and review the applicable Material Safety Data Sheet
information before handling any of these products. For additional information, please contact
Clariant.

US / EN