REVISION WORKSHEET (2024-2025)

Subject: Chemistry Grade: XII

Date of issue: 15.05.2024 Date of submission:25.05.2024

Name of the Student: ………………………… Division:

Choose the correct answer:

1.

2 In an electrochemical process, a salt bridge is used

(a) as a reducing agent.
(b) as an oxidizing agent.
(c) to complete the circuit so that current can flow.
(d) None of these
3 Resistance of a conductivity cell filled with 0.1 mol L−1 KCl solution is 100 Ω. If the
resistance of the same cell when filled with 0.02 M KCl solution is 520 Ω, calculate the
conductivity and molar conductivity of 0.02 M KCl solution. The conductivity
of 0.1 M KCl solution is 1.29 × 10−2 Scm−1.
4 Calculate ΔrG° for the given reaction: Mg (s) + Cu2+ (aq.) → Mg2+ (aq.) + Cu (s)
[Given : E°cell = +2·71 V, 1 F = 96500 Cmol−1]
5 Define the following terms:
(a)Molar conductivity (⋀m)
(b)Secondary batteries
6 From the given cells: Lead storage cell, Mercury cell, Fuel cell and Dry cell Answer the
following:
 (i) Which cell is used in hearing aids?
(ii) Which cell was used in Apollo Space Programme?
(iii) Which cell is used in automobiles and inverters?
(iv) Which cell does not have long life?
7 (a) Define fuel cell
(b) Write the name of the cell which is generally used in transistors. Write the reactions
taking place at the anode and the cathode of this cell.
8 Calculate the mass of Ag deposited at cathode when a current of 2 amperes was
passed through a solution of AgNO3 for 15 minutes.
(Given : Molar mass of Ag = 108 g mol−1, 1 F = 96500 C mol−1)
9 Calculate the degree of dissociation (α) of acetic acid if it's molar conductivity (Λm) is
39.05 S cm2 mol−1. Given, λ°(H+) = 349.8 S cm2 mol−1 and
λ°(CH3COO−) = 40.9 S cm2 mol−1
10 (a) Write the cell reaction and calculate the e.m.f of the following cell at 298 K:
Sn(s)| Sn2+(0.004 M)||H+(0.020 M)|H2(g)(1bar) Pt (s)
(Given : E0Sn2+/Sn= −0. 14 V)
(b)Give reasons:
(i) On the basis of E° values, O2 gas should be liberated at anode but it is Cl2 gas
which is liberated in the electrolysis of aqueous NaCl.
(ii) Conductivity of CH3COOH decreases on dilution.
11 Assertion (A): Conductivity of an electrolyte increases with decrease in concentration.
Reason (R) : Number of ions per unit volume decreases on dilution.
(a) Assertion is correct, reason is correct; reason is a correct explanation for assertion.
(b) Assertion is correct, reason is correct; reason is not a correct explanation for
assertion
(c) Assertion is correct, reason is incorrect
(d) Assertion is incorrect, reason is correct
Answer the following:
12
1)State the condition resulting in reverse osmosis?
2) A 0.1539 molal aqueous solution of cane sugar (mol. Mass = 342 g mol-1) has a
freezing point of 271 K while the freezing point of pure water is 273.15 K. What will
be the freezing point of a aqueous solution containing 5 g of glucose ( mol mass =
180 g mol-1) per 100 g of solution?
13 1)State Raoult’s law for solutions of volatile liquid components. Taking a suitable
example, explain positive deviation from Raoult’s law.
2)A solution containing 8g of a substance in 100g of diethyl ether boils at 36.86oc,
whereas pure ether boils at 35.60oc. Determine the molecular mass of the solute.( For
ether, Kb= 2.02 K kg /mol.
3) State the law co-relating the pressure of a gas and its solubility in a liquid. State an
application of this law.
4) Define the term ‘osmotic pressure’ . Describe how the molecular mass of a
substance can be determined on the basis of osmotic pressure measurement.
5) Calculate the temperature at which a solution containing 54 g glucose in 250 g
water will freeze. (Kf for water is 1.86 K Kg mol-1)
14 1)Define: a) Mole fraction b) van’t Hoff factor
2)100mg of a protein is dissolved in enough water to make 10.0ml of a solution. If this
solution has an osmotic pressure of 13.3mm Hg at 25oc, what is the molar mass of the
protein?( R=0.0821 L atm K-1mol-1 and 760mm Hg= 1 atm.)
3) What is meant by :
a) Colligative properties b) Molality of a solution
4. What conc of nitrogen should be present in a glass of water at room temp?
Assume a temp of 250C , a total pressure of 1 atmosphere and mol fraction of nitrogen
in air of 0.78 ( KH for nitrogen = 8.42 × 10-7 M / mm Hg)
15 (i) On mixing liquid X and liquid Y , the volume of the resulting solution increases.
What type of deviation from Raoult’s law is shown by the resulting solution? What
change in temperature would you observe after mixing liquids X and Y ?
(ii) How can the direction of osmosis be reversed ? Write one use of reverse osmosis.
(iii) A solution is prepared by dissolving 5 g of non volatile solute in 95 g of water. It
has a vapour pressure of 23.375 mm Hg at 250C. Calculate the molar mass of the
solute. ( Vapour pressure of pure water at 250C is 23.75 mm Hg)
16 Give reasons for the following : (a) Aquatic species are more comfortable in cold water
than warm water. (b) At higher altitudes people suffer from anoxia resulting in inability
to think.
What type of azeotropic mixture will be formed by a solution of acetone and
chloroform? Justify on the basis of strength of intermolecular interactions that develop
in the solution.
 At 300 K, 30 g of glucose present in a litre of its solution has an osmotic pressure of
4·98 bar. If the osmotic pressure of a glucose solution is 1·52 bar at the same
temperature, what would be its concentration ?
17 When a steady current of 2A was passed through two electrolytic cells A and B
containing electrolytes ZnSO4 and CuSO4 connected in series, 2g of Cu were
deposited at the cathode of cell B.
(a)How long did the current flow?
(b) What mass of Zn was deposited at cathode of cell A? [Atomic mass: Cu = 63.5 g
mol–1, Zn = 65 g mol–1; 1F = 96500C mol–1]
18 (a) A steady current of 2 amperes was passed through two electrolytic cells X and Y
connected in series containing electrolytes FeSO4 and ZnSO4 until 2.8 g of Fe
deposited at the cathode of cell X. How long did the current flow? Calculate
the mass of Zn deposited at the cathode of cell Y. (Molar mass : Fe = 56 g mol–1 Zn =
65.3 g mol–1, 1F = 96500 C mol–1)
(b) In the plot of molar conductivity (∧m) vs square root of concentration (c1/2),
following curves are obtained for two electrolytes A and B:

Answer the following:

Predict the nature of electrolytes A and B.
What happens on extrapolation of ∧m to concentration approaching zero for
electrolytes A and B?
19 Read the passage given below and answer the questions that follow:
(i) Is silver plate the anode or cathode?
(ii)What will happen if the salt bridge
is removed?
(iii) When does electro-chemical cell
behaves like an electrolytic cel1?
 (iv)What will happen to the concentration of Zn2+ and Ag+ when Ecell = 0.
(v) Why does conductivity of a solution decreases with dilution?
(vi) The molar conductivity of a 1.5 M solution of an electrolyte is found to be 138.9 S
cm2 mol–1. Calculate the conductivity of this solution.
20 E°cell for the given redox reaction is 2.71 V.
Mg(s) + Cu2+ (0.01 M) → Mg2+(0.001 M) + Cu(s)
Calculate Ecell for the reaction. Write the direction of flow of current when an external
opposite potential applied is
(i) less than 2.71 V and
(ii) greater than 2.71 V

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