Night Exam CH 3

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1) Which of the following is not affect by changing temperature?

a) equilibrium constant
b) equilibrium position
c) vapour pressure
d) saturated vapour pressure
2) Which of the following reactions is considered a complete reaction in an open vessel,
but if the vessel is closed and the same reaction is per considered a reversible reaction?
a) Ca(HCO3)2(aq)==CaCO3(s) + H2O(l) + CO2(g)
b) Na3PO4(aq) + 3AgNO3(aq) ==3NaNO3(aq) + Ag3PO4(s)
c) HNO3(aq) + KOH(aq) == KNO3(aq) + H2O(l)
d) 3Fe(s) + 8H2SO4(l) == FeSO4(aq) + Fe2(SO4)3(aq) + 4SO2(g) + 8H2O(l)
3) All of the following are revisable reaction occurs in closed container except ………..
a) N2(g) + 3H2(g) ⇌ 2NH3(g)
b) 2Cu(NO3)2(s) ⇌ 2CuO(s) + 4NO2(g) + O2(g)
c) HCOOH(aq) + CH3OH(aq) ⇌ H2O(l) + HCOOCH3(aq)
d) 2SO2(g) + O2(g) ⇌ 2SO3(g)
4) At equilibrium concentration of reactants and products should be .......... and rate of
forward and backward reaction are ..........
a) constant – constant
b) equal – equal
c) constant – equal
d) equal – constant
5) At equilibrium ……..
a) concentration of the reactants is constant and equal to the concentration of the products
b) rate of formation of product equal the rate of consuming of reactants
c) rate of formation of substance equal the rate of consuming of the same substance
d) rate of forward reaction = rate of backward reaction = zero
6) Which of the following is correct about reaction of barium chloride with potassium
phosphate?
a) the rate of the forward reaction at the start of reaction is very low
b) the rate of the backward reaction at the end of reaction is very low
c) the rate of the backward reaction at the start of reaction is very high
d) the rate of the forward reaction at the end of reaction is very high
7) In the following reaction: A(aq) + 2B(aq) ⇌ 3C(aq) + 2D(aq)
If you know that [B] decreased by 10-2 M/sec, which of the following is true for [A], [C]?
a) Decreases by rate 0.5 x10-2 M/sec, increases by rate of 0.5 x10-2 M/sec
b) Decreases by rate 0.5 x10-2 M/sec, increases by rate of 1.5 x10-2 M/sec
c) Decreases by rate 10-2 M/sec, increases by rate of 10-2 M/sec
d) Decreases by rate 10-2 M/sec, decreases by rate of 10-2 M/sec

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8) If the concentration of N2O4 change from 0.099 M to 0.079 M in 18 min, so the rate of
consumption of NO2 in the following reaction equal ............ M/min 2NO2 ⇌ N2O4
a) 2.22x10-3
b) 1.85x10-5
c) 3.7x10-5
d) 1.11x10-3
9) In a certain reaction: C12H22O11(s) → 11 H2O(v) +12C(s)
If the decomposition rate of C12H22O11 is 0.75 mol/min, then the mass of carbon
produced in 10 seconds equals ………………gram [C=12]
a) 1.5 g
b) 61.8 g
c) 15 g
d) 18 g
10) According to the following reaction: 2A(aq)+4B(aq) ⇌ 3C(aq) + D(aq)
If the concentration of the substance A changed from 0.1M until it became 0.02 M
during 20 second at 250C : the rate of consumption of substance B during the same time
at 350 is equal to ………….
a) 6x10-3 M/sec
b) 8x10-3 M/sec
c) 16×10-3 M/sec
d) 4x10-³ M/sec
11) Which of the following equations represents the opposite
figure?
a) X(g) → 2Y(g) + Z(g)
b) 2Y(g) + Z(g) → X(g)
c) 2Y(g) + Z(g) ⇌ X(g)
d) Y(g) + Z(g) → X(g)
12) Which of the following equations represents the opposite
figure?
a) A ⇌ 2B + C
b) 2A ⇌ 2B + C
c) 2A ⇌ B + 2C
d) A ⇌ B + 2C

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13) Which of the following equations represents the opposite
figure?
a) CO(g) + 3H2(g) ⇌ CH4(g) + H2O(v)
b) 2NO2(g) ⇌ N2(g) + 2O2(g)
c) 2SO2(g) + O2(g) ⇌ 2SO3(g)
d) N2(g) + 3H2(g) ⇌ 2NH3(g)
14) In the following equilibrium reaction and through the
opposite graph, deduce the value of KC for the reaction at
equilibrium 2A ⇌ B
a) 2.22
b) 20
c) 3
d) 0.05
15) In the opposite figure:
a) Write the correct balanced chemical equation
……………………………………………………………………………
……………………………………………………………………………
……………………………………………………………………………
b) Calculate the Kc value
……………………………………………………………………………
……………………………………………………………………………
……………………………………………………………………………
16) In the opposite figure:
a) Write the correct balanced chemical equation
……………………………………………………………………………
……………………………………………………………………………
……………………………………………………………………………
b) Calculate the Kc value
……………………………………………………………………………
……………………………………………………………………………
……………………………………………………………………………
17) The following graph represents equilibrium
endothermic reaction at 250C system. so the value of
Kc at 350C = ...........
a) 6.66
b) 14.81
c) 0.9
d) 15.49

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18) The opposite curve shows change in the number of moles of gas
A when put in closed container its volume 2L to form gas B. so
the Kc value of the decomposition of 2 mole gas B equal ……….
a) 16
b) 1/64
c) 1/8
d) 4
19) In the following equilbrium: HF(aq) ⇌ H+(aq) + F-(aq) Kc = 32.
Which of the following graphs represents the inverse reaction?

20) If it is a value of Kc equals 0.001. for the following hypothetical reaction,


A2(g) + B2(g) ⇌ 2AB(g) ,The largest value of K will be for the reaction ..
a) 2A2(g) + 2B2(g) ⇌ 4AB(g)
b) 3A2(g) + 3B2(g) ⇌ 6AB(g)
c) AB(g) ⇌ ½ A2(g) + ½ B2(g)
d) ½ A2(g) + ½ B2(g) ⇌ AB(g)
21) For the following reaction: 2HBr(g) ⇌ H2(g) + Br(g) Kc= 1.26x10-12 at 500 K
2HBr(g) ⇌ H2(g) + Br(g) Kc= 8.99x10-12 at 298 K
so the formation of HBr is an exothermic reaction
a) True
b) False
22) By using the equilibrium constant for the following system:
Fe(s) + CO2(g) ⇌ FeO(s) + CO(g) Kc = 1.47
Fe(s) + H2O(g) ⇌ FeO(s) + H2(v)- Kc= 2.38
So the value of equilbrium constant for CO2(g) + H2(g) ⇌ CO(g) + H2O(g)
a) 0.617
b) 3.498
c) 0.285
d) 0.349
23) The total pressure of the following equilibrium equal 1.1 atm.
A(g) + 2B(g) ⇌ C(g) + 3D(g) , if the partial pressure of A , B and D are respectively are 0.2,
0.1 and 0.5 atm So the value of Kc equal ..........
a) 11.25
b) 18.75
c) 5
d) 3.75
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24) In the reversible reaction : 2HI(g) ⇌ H2(g) +I2(v)
The initial pressure of HI equals 0.2 atm, and at equilibrium equals 0.04 atm, so K p of
this reaction equals ……….
a) 4
b) 16
c) 20
d) 25
25) putting 1.25 mole of N2O4 in closed reaction vessel 10 liter, the concentration of N 2O4
at equilibrium 0.075M so Kc ......... N2O4(g) ⇌ 2NO2(g)
a) 0.13
b) 0.67
c) 0.033
d) 1.33
26) An equilibrium mixture, put in a 1500mL container, involving the chemical system
X2(g) + Y2(g)=2XY(g) , it is found to contain, [X2] = 0.1mol/L [Y2] = 0.1 mol/L, equilibrium
constant is 0.01 so the mass of XY in the container at equilibrium is.... (molar mass of XY =
40 g/mol)
a) 0.6 g
b) 0.4 g
c) 0.01g
d) 0.9 g
27) In the following reaction 2A(g) ⇌ B(g) + C(g) Kc=2x10-3
At a certain point he found that: [A] =[B]=[C]= 2×10-4 M. Which of the following is true at
that moment and at the same temperature?
a) The reaction at equilibrium and the forward direction is dominant
b) The reaction at equilibrium and the reverse direction is dominant
c) The reaction not at equilibrium and must be activated to backward direction to reach
equilibrium
d) The reaction not at equilibrium and must be activated to forward direction to reach
equilibrium
28) The opposite reaction occur in close vessel its volume 2L: 2H2S(g) ⇌ 2H2(g) + S2(s)
At equilibrium the number of moles of H2S H2 and S2 are respectively 1.2x10-3 ,
7.2x10-6 and 6x10-2. So the value of rate constant for forward reaction equal ………… if
the value of rate constant for backward reaction 3x10-4
a) 3.6 x10-6
b) 1.1x10-8
c) 1.1 x 10-6
d) 3.3 x 10-10

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29) In the following equilibrium reaction: 2A(g) + B(g) ⇌ 2C(g) Kp=4 At 35 atm, if partial
pressure of B and C are 0.1 and 0.2 atom. So the partial pressure of A at 50 atm =..…..
a) 0.316
b) 0.24
c) 0.43
d) 4
30) Through the following balanced reaction: 2A(g) + B(g) ⇌ 2C(g Kc=8 If you know that [B],
[C] respectively at equilibrium is 0.1, 0.2, then if you know that more substance B was
added after reaching equilibrium, then it is expected That [A] equals .........
a) 8
b) 0.22
c) 0.16
d) 0.30
31) The following diagram show two experiment for the volume
of hydrogen evolved by reaction of Mg metal with excess of
hydrochloric acid. which of the following factors that causing
the diffrence between the two experiments?
a) change the surface area of the Mg
b) change the volume of reaction vessel
c) change amount of Mg
d) adding catalyst
32) Two experiments are performed to measure the rate of evolution of oxygen gas
resulting from the decomposition of hydrogen peroxide:
In experiment (1): 300 mL of 1 M hydrogen peroxide are used.
In experiment (2): 100 ml. of 2 M hydrogen peroxide are used.
Which of the following charts shows the rate of evolution of O2 in these experiments?
a) b) c) d)

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33) From the opposite graph, if you know that hydrochloric
acid is added to equal masses of Zn in the two cases (X) and
(Y), which of the following is correct?
a) Equal moles of HCl are used
b) The curve (Y) expresses the usage of Zn pieces while the
curve (X) expresses the usage of Zn powder
c) the curve (X) expresses the reaction of 40 ml of HCl 0.1 M
while the curve (Y) expresses the reaction of 60 ml of HCI 0.01 M
d) The curve (X) expresses the reaction of 50 ml of HCl 0.1 M while the curve (Y) expresses
the reaction of 40ml of HCI 0.2M
34) In the chart, curve (X) represents the volume of H₂ gas
produced from the reaction of 2 g of zinc granules with
excess of an acid at 25°C. What is the change which leads to
the formation of curve (Y) on repeating the experiment?
a) Using 1 g of zinc powder (at 25°C)
b) Using 2 g of zinc powder (at 30°C).
c) Using 1 g of zinc granules (at 25°C)
d) Using 2 g of zinc granules (at 30°C).
35) Two cubes of calcium carbonate have the same volume, 25 ml. of 1 M hydrochloric acid
are added to one of them at 40°C. What is the effect of adding 60 mL of 0.5 M
hydrochloric acid to the second cube at 40°C in relation to the first reaction?
a) The rate of reaction decreases, and larger amounts of products are produced.
b) The rate of reaction increases, and lesser amounts of products are produced.
c) The rate of reaction increases, and larger amounts of products are produced.
d) The rate of reaction decreases, and lesser amounts of products are produced
36) When a catalyst is added to an equilibrium system, which of the following is true?
a) The amount of product increases and the equilibrium constant does not change
b) The quantity of product does not change and the equilibrium constant does not change
c) The quantity of product increases and the equilibrium constant increases
d) Transfer the quantity of product and the equilibrium constant decreases
37) Which of the following is incorrect on adding catalyst to a reaction?
a) decrease time needed for reaction
b) increase the amount of the product
c) for reversible reaction, reach equilibrium faster
d) decrease the activation energy of the reaction
38) Which of the following factors affect equilibrium position and has no effect on
equilibrium constant?
a) pressure
b) temperature
c) catalyst
d) all the previous
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39) In the equilibrium reaction: NH4Cl(s) ⇌ NH3(g)+HCl(g)
How does adding more NH4Cl affect each of the forward and the backward reactions?
a) Both the forward and the backward reaction rates increase.
b) Both the forward and the backward reaction rates do not change.
c) The forward reaction rate increases, while the backward reaction rate decreases.
d) The forward reaction rate decreases, while the backward reaction rate increases
40) All of the following are true about this reaction except....... S8(S) +8O2(g) → 8SO2(g)
a) Using larger pieces of sulfur increases the reaction time
b) Using a suitable catalyst increases the reaction time
c) Increasing the concentration of oxygen gas increases the speed of the reaction.
d) Using sulfur powder increases the speed of the reaction
41) Which of the following is the best condition to obtain highest amount of HCl from the
following reaction? 4HCl(g) + O2(g) ⇌ 2Cl2(g) + 2H2O(g) ∆H=113 kJ
a) increase temperature and increase the volume of container
b) increase temperature and decrease the volume of container
c) decrease temperature and increase the volume of container
d) decrease temperature and decrease the volume of container
42) In the following equilibrium X2 (g) + 3Y2(aq) ⇌ 2XY3 (g) , if increasing temperature
increases K2 by large value than K1 which of the following statements is correct?
a) cooling decreases [Y2]
b) cooling decreases [XY3]
c) heating increases [XY3]
d) adding catalyst increases Kc
43) In the following equilibrium system: 2NO2(g) ⇌ 2NO(g) + O2(g) ∆H=+114 KJ
Which of the following is correct about that equilbrium?
a) decrease the volume of container, the reddish brown colour decrease
b) decrease temperature, decreases the partial pressure of oxygen gas
c) increase temperature, the reddish brown colour increase
d) decrease pressure, the reddish brown colour increase
44) In the following equilibrium, which of the following is correct on decreasing total
pressure on the reaction? NO(g) + O2(g) ⇌ 2NO2 + energy
reaction shift Kc
a) left not change
b) right decrease
c) not change not change
d) right increase
45) In the following equilibrium system: H2(g) + N2(g) – heat ⇌ NH2-NH2(g)
which of the folloeing will increase the dissociation of hydrazine?
a) cooling
b) heating
c) increase total pressure
d) increase [H2]
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46) In the following equilibrium: ZnO(s) + CO(g) ⇌ CO2(g) + Zn(s) ∆H= -40KJ
All of the following will change the equilibrium position except ..........
a) increase temperature
b) adding CO
c) adding Zn
d) adding O2
47) The graph in front of you shows the effects of
temperature and pressure on the concentration of
reactants in one of the reversible reactions. In which of
the following reactions can this behavior be observed?
a) 2N2O5 ⇌ 4NO2 + O2 ΔH=110 KJ/mol
b) CO+H₂O ⇌ CO₂+H₂ +41 KJ/mole
c) 2SO2+O2 ⇌ 2SO3 +196 KJ/mole
d) N2 +2O2 ⇌ 2NO2 – 66.4 KJ/mole
48) The following table shows the change of the tempertaure
with Kp value of the following equilibrium, which of the
following is correct? N2(g) + O2(g) ⇌ 2NO(g)
a) decompodition of NO increases by heating Temperature 0C Kp
b) reaction shift backward by heating 25 4x10-33
c) Kp for decomposition of NO is smaller than Kp for 827 4x10-8
formation of NO 1227 1x10-5
d) The decomposition of NO is exothermic reaction
49) From the following two equilibrium reactions: H2(g) + CO2(g) ⇌ H2O(g) + CO(g)
Fe2O3(s) + 3CO(g) ⇌ 2Fe(s) + 3CO2(g) , Which of the following is correct on adding H2 gas?
a) Reaction shift forward and amount of iron increases
b) Reaction shift forward and amount of iron decreases
c) Reaction shift backward and amount of iron increases
d) Reaction shift backward and amount of iron decreases
50) In the following equilibrium 4NH3(g) + 3O2(g) ⇌ 2N2(g) + 6H2O(v)
Which of the following is correct on adding mixture of (O2(g) + 2N2(g))?
a) Reaction shift forward and [NH3] increases
b) Reaction shift backward and [O2] decreases
c) Reaction shift backward and [NH3] increases
d) Reaction shift forward and [N2] decreases
51) The following equilibrium takes place in a closed vessel, when transferred to a larger
vessel while raising the temperature, the ………….. A(g) + 2B(g) ⇌ 3C(g) – 100 Kj
a) Kp for the reaction increases and the C concentration decreases
b) Kp for the reaction decrentes and the C concentration increases
c) Kp for the reaction increases and the C concentration increases
d) Kp for the reaction decreases and the C concentration increases

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52) In the opposite curve for exothermic reaction:
a) Write the chemical equation?
..............................................................
……………………………………………
……………………………………………
…………………………………………….
b) Calculate Kc befor 2 min?
.......................................................................
.......................................................................
.......................................................................
........................................................................
c) What is the change occur at 2,
4 and 6 min and its effect on equlibrium position and equlibrium constant value?
At 2min……………………equlibrium …………… and Kc ………………………………………………..
At 4min…………………… equlibrium …………… and Kc ………………………………………………..
At 6min…………………… equlibrium …………… and Kc ……………………………………………….
53) If the activation energy of an exothermic reaction is decreased by 20 kJ by the effect of
a catalyst to become 150 kJ and the activation energy of the backward reaction without
using a catalyst is 220 kJ, so the value of ΔH equals ………..
a) 220
b) -220
c) 50
d) -50
54) In an endothermic reaction, the AH of the reaction was (150 KJ), and the energy of the
resulting substances was 80 KJ, when a catalyst was used the activation energy of the
forward reaction decreased by 30 KJ to become 220 KJ, so the activation energy of the
backward uncatalyzed reaction was …………….
a) 180
b) 100
c) 260
d) 270
55) If the activation energy of backward reaction 150 kJ, activation energy of forward
reaction 40 kJ and energy of reactant 200 kJ/mole. Which of the following is correct?
a) ∆H= 100 kJ
b) product energy= 90 kJ
c) the reaction endothermic
d) on adding catalyst energy of reactants and products decrease

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56) When a suitable catalyst to hydrogen peroxide, it decomposes as follows: All the
following describe the reaction rate, except 2H2O2(aq) ⇌ 2H2O(l) + O2(g)
a) the rate of decomposition of H2O2 equals the rate of formation of H2O
b) decreasing [H2O2] decreases the rate of formation of O2
c) decreasing the temperature increases the rate of formation of O2
d) increasing the amount of the catalyst decreases the rate of of O2
57) In the following equilibrium, which of the following is incorrect on decrease
temperature? 2H2O(l) + energy ⇌ H3O+(aq) + OH-(aq)
a) pH value increase
b) pOH value decrease
c) Kw decrease
d) water is neutral
58) According to the ionization equation of water 2H2O(l) ⇌ H3O+(aq) + OH-(aq), which of the
following is correct on adding drops of NaOH to water?
a) pH decrease and [H3O+] increase
b) pH decrease and [H3O+] decrease
c) pH increase and [H3O+] increase
d) pH increase and [H3O+] decrease
59) which of the following is true when more water is added to hydrochloric acid solution?
a) The number of produced ions increses and the pH value increases
b) The number of produced ions inceases and the pH value decreases
c) The number of ions remains constant and the pH value decreases
d) The number of ions remains constant and the pH value increases
60) When water is added to a solution of ammonium hydroxide,
a) The number of produced ions increases and the pH value increases
b) The degree of electrical conductivity decreases and the pH value decreases
c) [HO-] increases and the PH value decreases
d) The number of produced ions remains constant and the POH value decreases
61) 2M nitrous acid its ionization constant is 4.6x10-4 and 0.01 M hydrochloric acid. which
of the following is correct relation between them?
a) pH of nitrous acid is greater than pH of hydrochloric acid
b) the summation of pH of nitrous acid and pOH of hydrochloric acid equals 13
c) pOH of nitrous acid is greater than pH of hydrochloric acid
d) the summation of pOH of nitrous acid and pH of hydrochloric acid equals 14
62) Two equal volume and conc. solution of hydrochloric and sulphuric acid, so
a) they have equal pH values
b) pH of sulphuric acid is larger
c) pH of hydrochloric is larger
d) they have equal pOH values

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63) If you known that 0.25 L from benzoic acid solution contains 1.6555x1020 of benozate
ions. what is the pH of the solution?
a) 2.69
b) 3.69
c) 2.96
d) 3.93
64) Acetic acid solution its concentration is 0.03 M at 398°C and its ionization degree is
2.5x10-3, a quantity of water was added to it, so its concentration became 0.01 M
calculate its ionization degree after dilution.
a) 1.875x10-7
b) 7.5x10-3
c) 4.33x10-3
d) 8.3x10-6
65) Which of the following equal concentration solutions has the highest pH value?
a) HF (Ka= 6.8x10-4)
b) CH3COOH (Ka= 1.8x10-5)
c) HNO2 (Ka= 4.5x10-4)
d) HClO (Ka= 3x10-8)
66) Which of the following has highest pH value?HCN Ka= 5.8x10-10 &CH3COOH Ka= 1.8x10-5
a) 0.1 M HCN
b) 0.1 M CH3COOH
c) HCN has α= 0.001
d) CH3COOH has α= 0.1
67) Weak acid its concentration 0.5M and its ionization constant 1.8x10 -5 so its ionization
degree= .............. and hydronium ion concentration = ..............M respectively
a) 0.006 / 0.003 M
b) 0.06 / 0.03 M
c) 0.09 / 0.09 M
d) 0.1 / 0.002 M
68) If 0.196 gram of H2SO4 (molar mass =98g/mole) are placed in 2 liter of distilled water
at 250C, What will the pH of the solution be?
a) 3
b) 2.7
c) 2.3
d) 11
69) If the ionization constant for HCO2H equal Ka=1.8x10-4) so Kc for the following equation
equal .......... HCO2-(aq) + H3O+(aq) ⇌ HCO2H(aq) + H2O(l)
a) 5.56x103
b) 1.8x10-4
c) 9x10-5
d) 0.028

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70) A solution of formic acid contains 9.6 g of acid per liter and its dissociation percent is
3%, what is the value of its ionization constant ? [Molar mass=46]
a) 9,6×10-3
b) 1.8×10-4
c) 1.5x10-6
d) 4.8x10-5
71) If the dissociation percent of a weak acid is 4% and the pH value of its solution at 25°C
2.06, then the ionization constant of this acid is...
a) 5.3x10-4
b) 3.5x10-4
c) 3.5x10-5
d) 1.8x10-5
72) At 250, the concentration of a solution of hydrofluoric acid was 3.75x10 -5 M, and its
pOH value was 10.2: The value of Kc for the following reaction that occurs in this
solution is equal ………….. F -(aq) + H3O+ ⇌ HF(aq) + H2O(l)
a) 8.7x105
b) 6.7x10-4
c) 2.5x10-6
d) 1492.9
73) What is the unionized percentage of nitrous acid found in 1L of its 0.5 M solution, if its
ionization constant equals 7.1x0-4?
a) 1.88%
b) 3.77%
c) 96.2%
d) 98.1%
74) If you know that the ionization constant of hydrofluoric acid at a given temperature is
K= 6.6x10-4 and its concentration is 0.3 M in a solution of volume 130 ml, then
dissociated moles is ……………..
a) 1.83x10-4
b) 1.38x10-3
c) 1.83x10-3
d) 3.81x10-3
75) How many moles of ions are found in 200 ml. of 0.2 M solution of a monoprotic acid
its ionization constant equals 5.1 x 10-4?
a) 0.04x10-2
b) 0.08x10-2
c) 2x10-3
d) 4x10-3

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76) Determine the pH of the solution that result from the addition of 20 ml of 0.01 M
Ca(OH)2 to 30 ml of 0.01M HCl
a) 10
b) 10.53
c) 8.35
d) 11.3
77) On mixing 150 ml of hydrochloric acid 0.2 M with 250ml sulphuric acid 0.3 M the
hydrogen ion concentration in the resulting solution equal = .....
a) 0.105
b) 0.450
c) 0.625
d) 0.180
78) On dilution of 1 ml of 0.1 M weak base to 100 ml at constant temperature if K b=1x10-5
so pH of the solution = ..........
a) 4
b) 11
c) 8
d) 10
79) What volume of water must be added to 200ml of 0.04 M calcium hydroxide Ca(OH)2
in order its pH value become 11.5?
a) 500 ml
b) 4.86 L
c) 2 L
d) 5.84 L
80) Arrange the following solution ascending according to pOH:
solution A has [H+]=10-2 M , solution B has [OH-]=10-8 M
solution C has [H+]=10-12 M , solution D has [OH-]=10-7 M
a) A < D < B < C
b) C < D < B < A
c) A < B < D < C
d) C < B < D < A
81) Which of the following salts has pOH lower than 7?
a) potassium sulphate
b) ammonium acetate
c) iron III nitrate
d) sodium acetate
82) Which of the following solutions has the lowest pH value?
a) NaCl
b) Na2CO3
c) NH4Cl
d) NaOH
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83) Which of the following solution has the lowest [H+]?
a) K2SO4
b) Al(NO3)3
c) NH4Cl
d) FeBr3
84) The 0.2M ammonium sulphate solution contains ............
a) [NH4+] = 0.2 M
b) [NH4+] = 0.4 M
c) [SO4-2] = 0.2 M
d) [SO4-2] = 0.4 M
85) Which of the following solutions First turns litmus violet and the second turn phenol
phthalein red?
a) FeCl3 and Na2CO3
b) NH4Cl and FeCl3
c) CH3COONH4 and Na2CO3
d) NaCl and FeCl2
86) When a solution of ammonium chloride is added to a solution of Sodium chloride:
a) The pH value increases
b) The pOH value increases
c) The pH value is not affected
d) The pH value becomes equals zero
87) When a solution of sodium chloride is added to a solution of hydrochloric acid
a) The pH value increases
b) The pOH value increases
c) The pH value is not affected
d) The pH value becomes equals zero
88) When 5 g of solid sodium chloride salt is added to a HCl solution
a) The pH value increases
b) The pOH value increases
c) The pH value is not affected
d) The pH value becomes equals zero
89) When a solution of sodium nitrate is added to a solution of sodium hydroxide
a) The pH value increases
b) The pOH value increases
c) The pH value is not affected
d) The pH value becomes equals zero
90) All of the following, when added to product of hydrolysis of ammonium sulphate salt,
leads to decrease the concentration of the ammonium sulphate salt except:
a) BaCl2
b) CaCl2
c) Na2SO4
d) Pb(NO3)2

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91) Which of the following titration represents by
the opposite curve?
a) ammonium hydroxide solution with hydochloric
acid
b) Hydrochloric acid solution with sodium hydoxide
c) sulphuric acid solution with ammonium
hydroxide
d) barium hyroxide solution with hydroflouric acid
92) When …………………… titrate with ………….. the pH
of the resulting solution is more than 7
a) Weak acid – weak base
b) Weak acid – strong base
c) strong acid – weak base
d) strong acid – strong base
93) 100 ml saturated solution of Ag2Cr2O7 contain 0.16 gram of silver chromate at 250C
so the solubility product of that salt = ................. [Ag=108, Cr=52, O=16]
a) 2.9x10-2
b) 0.026x10-5
c) 1.026x10-7
d) 2.026x10-7
94) Weak basic solution B(OH) has [H+] = 10-8 so its solubility product =
a) 10-6
b) 10-12
c) 10-16
d) 10-8
95) If the solubility degree of copper II bromide equal 2x10-4 , the solubility product Ksp
of CuBr2 = ...........................
a) 4x10-4
b) 4x10-8
c) 3.2x10-11
d) 1.6x10-7
96) if the concentration of calcium ion in the saturated solution of calcium hydroxide
equal 0.011M and its solubility product 5.5x10-6 so the pH of the solution =
a) 11.35
b) 10.33
c) 12.1
d) 12.34
97) If the solubility product of BaSO4 = 1.6x10-10 , so the solution which obtain by mixing
10 ml of 0.1M solution contain sulphate ions with 10 ml of 0.01M solution contain
barium ion will ..............
a) not form precipitate
b) form precipitate
c) be saturated solution
d) not predictable
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98) If the Ksp of ACl2, compound is 1.7 x 10-5 then 8g of this salt is put in a liter of water,
So The insoluble mass of the salt in its saturated solution is:[Cl=35.5, A = 207]
a) 4.5g
b) 3.5g
c) 0.0162 g
d) 0.162 g
99) When 20 g of AgCl was dissolved in 2 L of water, then filtered and dried, it was found
that the mass of undissolved AgCl=18.565 g. The Ksp value of silver chloride salt is
equal to...........[Ag=108,Cl=35.5]
a) 5x10-3
b) 1x10-5
c) 2.5x10-5
d) 0.01
100) The solublity degree of barium oxalate (COO)2Ba in water is 4.8x10-4M. the Ksp of it
equal ...........
a) 3.9x10-6
b) 2.4x10-4
c) 2.3x10-7
d) 2.2x10-2
101) In the saturated solution of the two salts MgCO3 and Ag2CO3, [Mg2+] is 3.2x10-5M so if
Ksp of MgCO3 salt is 1.6x10-6. and that of Ag2CO3 is 8x10-12. Whar is [Ag+] in this
solution?
a) 1.26x10-4
b) 1.26x10-5
c) 1.76x10-4
d) 1.26x10-3
102) If the solubility degree of M(OH)2. is 4.095x0-6 g per 100 g of water, then the Ksp of
this salt is equal to........................... and the concentration of the hydroxyl ion is equal
to.................... I[M=65, O = 16, H=1]
a) 2.74 x10-16 - twice the solubility degree of the salt
b) 2.83 x10-19 -the solubility degree of the salt
c) 2.74 x 10-16 - the solubility degree of the salt
d) 2.83 x10-19 - twice the solubility degree of the salt
103) What is the value of solubility product for chromium III hydroxide Cr(OH) 3 solution
its pOH = 6.
a) 2.7 × 10-23
b) 2.7 × 10-31
c) 3.33x10-25
d) 3.33 × 10-33

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104) if the solubility degree of Mg(OH)2 in water is 1.2x10-4 so the Ksp= .......... and pH of the
solution = ..................
a) 1.7x10-7 and 10
b) 5.8x10-14 and 2.84
c) 6.9x10-12 and 10.4
d) 1.7x10-12 and 3.6
105) When a solution of lead nitrate is added to a saturated solution silver sulphid at
constant temperature,
a) The concentration of sulphide ions increases and the Ksp value increases
b) The concentration of silver ions decreases and the Ksp value increases
c) The concentration of sulphide ions decreases and the Ksp value remains constant
d) The concentration of silver ions increases and the Ksp value increases

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