Confidential

DENKA “RESISFY”
New High Heat Resistant
Styrenic Polymer
Jul. 1. 2016 ver.3 1
Characteristics of RESISFY Confidential
High Heat Resistance
High Transparency
Excellent Thermal Stability Plates of PMMA/RESISYFY
Pellets of RESISFY
Low Specific Gravity
Low Moisture Absorption
High Hardness
Miscible with PMMA and the heat resistant improvement of
PMMA without decrease of transparency
Application for “Piano-Black” Resin 2
Properties of RESISFY Confidential
R-310
Properties Method Condition Unit R-100 R-200 PMMA PC
(KX435)
220℃,98N g/10min 10.2 7.1 4.0 2.9 2.4
MFR ISO 1133
230℃,37.3N g/10min 4.2 2.9 1.8 1.6 -
Tensile Strength ISO 527-1,-2 5mm/min MPa 55 56 50 72 81
at Break
Flexural Strength ISO 178 2mm/min MPa 94 125 80 122 99
Flexural Modulus ISO 178 2mm/min MPa 3,460 3,590 3,460 3,340 2,230
Charpy Impact Notched kJ/m2 2 2 2 2 82
ISO 179
Strength Unnotched kJ/m2 13 13 12 23 -
Vicat Softening ISO 306 50N ℃ 126 132 143 108 150
Temperature
HDT ℃ 102 107 116 83 126
ISO 75-1,-2 1.8MPa
Anneal (JIS K 6717) ℃ 122 136 135 102 -
Rockwell Hardness ISO 2039-2 23℃ M scale 95 101 101 105 79
Density ISO 1183 23℃ g/cm3 1.14 1.16 1.15 1.19 1.19
Pencil Hardness - 500g Load - H H F 3H 6B
※Values are typical and not guaranteed. 3
Optical Properties of RESISFY Confidential
R-310
Properties Method Condition Unit R-100 R-200 PMMA PC
(KX435)
Total Luminous
Transmittance
ISO 13468-1 2mmt % 91 91 91 93 91
Haze ISO 14782 2mmt % 0.2 0.2 0.2 0.2 0.2
Yellow Index - 2mmt - 1.0 1.1 1.4 0.5 1.3
Refractive Index ISO 489 D line - 1.56 1.55 1.57 1.49 1.58
Abbe Number - νD - 36 38 34 58 30
※Values are typical and not guaranteed.
Appearances of
Injection molded plates
R-100 R-200 R-310 PMMA PC
4
Light Transmittance of RESISFY Confidential
High Transmittance in LED Spectrum
（Condition） Sample Thickness：2mmt 5
Refractive Index of RESISFY Confidential
6
Thermal Stability of RESISFY Confidential
RESISFY is more stable than PMMA
（Conditions）
Equipment：TGA／DTA
Atmosphere：N2
Heating rate：5℃／min
7
Thermal Stability of RESISFY Confidential
Residence test of Injection molding is the same level with PMMA
（Conditions）
Molding Temperature：240℃ (PC 280℃)
Residence time：10 minutes
Sample Thickness：2mm
Color difference：The difference of Zero
time shot and an average of 5 shots
8
Water Absorption of RESISFY Confidential
RESISFY has lower water absorption than PMMA
（Conditions）
Temperature：23℃
Atmosphere：Under water
Sample：3-step Plates
120×40×3, 2, 1mmt
9
Light Stability of RESISFY Confidential
Improve the Light stability of RESISFY with Stabilizer (UVA,HALS)
Sunshine Carbon Arc Weather-Ometer Xenon Weather-Ometer
※Without Stabilizer
（Conditions of SWOM） （Conditions of Xenon Test）
BP Temp=63℃, Relative Humidity=50％, BP Temp=89±3℃
No water fog, 500hr Radiant Exposure=100MJ/m2
10
Heat Resistant Improvement of PMMA Confidential
RESISFY improves Heat Resistance of PMMA.
11
Transparency of PMMA/RESISFY Blends Confidential
Almost no change of Haze, More than 90% of Total Luminous Transmittance
12
Changes of Hardness by the blend to PMMA Confidential
The hardness of PMMA is kept to 50% of RESISFY
13
Improvement of Dimension Stability Confidential
Deformation by Water absorption is controlled by blending RESISFY
PMMA／R-100=100／0
PMMA／R-100=75／25
（Conditions）
PMMA／R-100=50／50 Sample Length：200mm
Test Atmosphere：60℃,90%RH
PMMA／R-100=25／75
PMMA／R-100=0／100
14
Application for Piano-Black Resin Confidential
Piano-Black Resin can be obtained by the following combination.
Compound of “R-200／PMMA／Impact Modifier／Colorant (Jet Black)”
This compound has Excellent colorability (Piano-Black), elegant appearance,
high gloss, high heat resistance and mar resistance.
Development High Heat
Natural Color
Article ABS
Black Coloring
15
Properties of Piano-Black Resin Confidential
Properties Methods Conditions Units Natural Black
Sample-A Sample-B Sample-A Sample-B High heat ABS
MFR ISO 1133 220℃,98N g/10min 6.1 2.0 6.6 3.4 10
Tensile Strength ISO 527-1,-2 50mm/min MPa 63 65 64 66 48
at Yield
Flexural Strength ISO 178 2mm/min MPa 97 103 99 102 76
Flexural Modulus ISO 178 2mm/min MPa 2,820 2,850 2,830 2,850 2,450
Charpy Impact
ISO 179 Notched kJ/m2 5 6 5 6 21
Strength
VST ISO 306 50N ℃ 112 115 112 115 110
HDT ISO 75-1,-2 1.8MPa ℃ 88 90 87 91 90
Rockwell ISO 2039-2 23℃ M scale 87 89 87 89 -
Hardness
Density ISO 1183 23℃ g/cm3 1.15 1.15 1.15 1.15 1.07
Pencil Hardness - 500g Load - H H H H 2B
Total Luminous
ISO 13468-1 2mmt % 91 91 - - -
Transmittance
Haze ISO 14782 2mmt % 4 4 - - -
※Sample-A：R-200／PMMA(Good fluidity)／Impact modifier, Sample-B：R-200／PMMA(Heat Resistance)／ Impact modifier
16
Application to Glass Fiber Reinforced Compounds Confidential
Properties Methods Conditions Units R-100
No GF GF① 30% GF② 30%
MFR ISO 1133 220℃,98N g/10min 10.2 3.1 3.6
Tensile Strength
at Break
ISO 527-1,-2 5mm/min MPa 55 108 103
Flexural Strength ISO 178 2mm/min MPa 94 153 173
Flexural Modulus ISO 178 2mm/min MPa 3,460 10,280 10,310
Charpy Impact
Strength
ISO 179 Notched kJ/m2 2 7 9
Charpy Impact
Strength
ISO 179 Unnotched kJ/m2 13 14 21
Vicat Softening
Temperature
ISO 306 50N ℃ 126 131 131
HDT ISO 75-1,-2 1.8MPa ℃ 102 127 127
Density ISO 1183 23℃ g/cm3 1.14 1.36 1.36
※Diameter of Glass Fiber 13μm, melt blend by single screw extruder 17
Interfacial adhesion between fibers and matrices Confidential
R-100/GF① RESISFY is excellent in adhesion
with Glass fiber.
Adhesion is further improvable
by optimizing Glass fiber.
R-100/GF② AS/GF①（Reference）
18
Application Confidential
Mar resistance
‣ Heat Resistant Modifier of PMMA
RESISFY / PMMA
Dimension
‣ High Heat Piano Black Resin
PC stability
‣ Decorative film
Toughness
‣ Touch Panel Figure. Schematic of cover sheet for touch panel
‣ Polarizer Protective Film
‣ Optical Lenses Cover sheet（PMMA/PC）
‣ Automotive Meter Panel
Polarizer Protective Film
‣ Compatibilizer
Compensation Film
Figure. Application for display
19
 Confidential
Denka Company Limited
http://www.denka.co.jp
Head Office Nihonbashi Mitsui Tower, 1-1, Nihonbashi-Muromachi-2-chome,
Chuo-ku, Tokyo 103-8338, JAPAN
TEL: +81-3-5290-5055 FAX: +81-3-5290-5059
Denka Corporation 780 Third Avenue, 15th Floor New York, NY10017,U.S.A.
TEL : 1-212-688-8700, FAX : 1-212-688-8727
E-mail: info@denkany.com
DENKA Chemicals GmbH Wehrhahn-Center Cantadorstr.3 D-40211Düsseldorf, Germany
TEL： 49-211-130990, FAX： 49-211-329942
E-mail: info@denkagermany.de
Denka Singapore Pte.Ltd. (Sales & Marketing) 4 Shenton Way #29-02 SGX Centre 2, Singapore 068807
TEL： 65-6225-6120, FAX： 65-6224-3840
E-mail: denkasingapore@denka.com.sg
(Seraya Plant) 40 Seraya Avenue, Singapore 627873
TEL ： 65-6867-6089, FAX ： 65-6867-6090
Denka Chemicals Shanghai Co.,Ltd. Room 2702, New Hongqiao Center Bldg No:83 Loushanguan Rd, Chang Ning Area,
Shanghai China 200336
Chiba Plant 6 Minamikaigan, Goi, Ichihara-shi, Chiba-ken 290-8588, Japan
TEL : +81-436-26-3200, FAX : +81-436-26-3300
20